US3357047A - Nozzle for spinning fibers and method of making such nozzles - Google Patents

Nozzle for spinning fibers and method of making such nozzles Download PDF

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Publication number
US3357047A
US3357047A US481371A US48137165A US3357047A US 3357047 A US3357047 A US 3357047A US 481371 A US481371 A US 481371A US 48137165 A US48137165 A US 48137165A US 3357047 A US3357047 A US 3357047A
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Prior art keywords
nozzle
spinning
nozzles
bottom portion
plastic
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US481371A
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Keil Alfred
Bitterfeld Kreis
Mally Heinz
Gruhl Hans
Wolfl Adolf
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SACHSISCHES KUNSTSEIDENWERK SI
VEB SACHSISCHES KUNSTSEIDENWERK SIEGFRIED RADEL
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SACHSISCHES KUNSTSEIDENWERK SI
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Priority to NL99254D priority Critical patent/NL99254C/xx
Application filed by SACHSISCHES KUNSTSEIDENWERK SI filed Critical SACHSISCHES KUNSTSEIDENWERK SI
Priority to US481371A priority patent/US3357047A/en
Priority to US671172A priority patent/US3491181A/en
Application granted granted Critical
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C11/00—Tyre tread bands; Tread patterns; Anti-skid inserts
    • B60C11/14—Anti-skid inserts, e.g. vulcanised into the tread band
    • B60C11/18—Anti-skid inserts, e.g. vulcanised into the tread band of strip form, e.g. metallic combs, rubber strips of different wear resistance
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D4/00—Spinnerette packs; Cleaning thereof
    • D01D4/02—Spinnerettes
    • D01D4/022—Processes or materials for the preparation of spinnerettes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S425/00—Plastic article or earthenware shaping or treating: apparatus
    • Y10S425/055—Polytetrafluoroethylene, i.e. PTFE

Definitions

  • FIG. 2d
  • the present invention relates to a nozzle for spinning synthetic fibers and to a method for manufacturing such a nozzle.
  • the nozzle according to the invention is particularly suited for spinning fibers of regenerated cellulose.
  • spinning nozzles consisting of non-metallic materials, such as polyamide, polyvinyl chloride, porcelain, glass, and the like. These nozzles,
  • these spinning nozzles especially those made from the non-metallic materials mentioned above, are damaged and decompose during the necessary cleaning process with Warm chlorosulfuric acid.
  • the channels of the nozzle aperture of the plastic nozzles are especially unsatisfactory as far as their mechanical resistance is concerned.
  • the channels are heavily damaged within a short period of time so that the nozzles have to be removed.
  • the known nozzles have shortcomings in other respects, too. For example, the manufacture of porcelain and glass nozzles is very costly. For the above mentioned reasons, many attempts have been made to eliminate the difficulties caused by plastic, porcelain and other non-metallic nozzles.
  • One attempt consisted in providing a combined nozzle in which the body that had previously been made of a noble metal, Was made from one of theabove mentioned non-metallic materials, and the nozzle bottom carrying the nozzle aperture channels (spinning apertures) was made of a noble metal alloy of a known composition e.g. of gold/platinum, platinum/rhodium, or the like.
  • the nozzle bottom after completion of the nozzle body, is pressed into and/or glued into a ring groove applied to the nozzle body.
  • the nozzles made is this manner were not satisfactory in the spinning of synthetic fibers due to the lack of a firm connection between the nozzle bottom and the nozzle body.
  • the object of this invention to provide a spinning nozzle in which the nozzle body comprises a plastic material or a plastic containing an additive, and a nozzle bottom comprising a noble metal which is resistant to chemical and mechanical influences present during the spinning process of synthetic fibers, particularly those from regenerated cellulose.
  • the nozzle according to the invention consists of a composite body and bottom portion, the body being made of an especially suited plastic material and the apertured bottom portion being made of a noble metal or noble It is yet another object of the invention to provide a metal alloy, said portions being firmly connected to one another in a manner which permits them to be subjected to any pressure obtaining during the spinning process and to the cleaning of the nozzle, without damaging the connection between the component nozzle parts.
  • polychloro-fluoro-ethylene derivatives are especially suitable as plastic material in the manufacture of the spinning nozzles of this invention. These compounds may be represented by the formula wherein X is partly substituted by fluorine and partly by chlorine. Polyethylene, on the other hand, does not meet with the chemical requirements. The most suitable material for this die extrusion method is polymonochlorotrifluoroethylene.
  • a firm connection between the nozzle body consisting of polychloro-fiuoroethylene derivatives, and the nozzle bottom consisting of a noble metal is obtained by mounting the nozzle bottom into the body during the manufacture of the body.
  • thechannels in the perforations are bored into the nozzle bottom prior to inserting itinto the nozzle body.
  • the channels are filled with a temperature-resistant mass which is chemically removed after the manufacture of the nozzle has been completed.
  • the temperature-resistant mass is enamel, which can be removed by means of an acid or an alkaline solution.
  • the required positioning or seating of the nozzle bottom into the nozzle body may be achieved in various ways.
  • the nozzle bottom may, for instance, ha e a flat surface for contact with the body portion; or the bottom portion of the nozzle may be of a shape with the rim pulled up, bent at right angles or flanged.
  • the edge of the bottom is preferably provided with holes of various shapes to improve the positioning or fseating.
  • FIG. la shows a complete nozzle with a nozzle body of cylindrical shape anda nozzle bottom inserted therein;
  • FIG. lb shows another nozzle body of conical shape Without the nozzle bottom attached.
  • FIGS. 2a to d show cross-sectional views of various examples of nozzle bottoms
  • FIG. 3 is a top view of a nozzle bottom with four oles.
  • FIGS. 1a and 1b illustrate two diiferent shapes of the body portion of the nozzle according to the invention.
  • FIG. 1a shows a cylindrical body 10 with a straight wall portion 12 to be connected with a bottom, and a flange 14 for connection with the spinning device (not shown).
  • the bottom portion is shown at 16; it has a flat perforated plate 18 which serves as nozzle proper for the extrusion of the spinning solution, and a bent-back portion 20 with crimped edge for engagement with the end of wall 12 of the nozzle body.
  • FIG. 1b illustrates a different shape of a nozzle body 22, which is conical.
  • one end of the nozzle wall 24 is flanged, the other is flat for receiving a flat bottom, as shown, for. instance in FIG. 20.
  • FIGS. 2a to 2d show different shapes of nozzle bottoms.
  • FIG. 2a illustrates, as mentioned above, a flat, plateshaped bottom 24, with a plurality of perforations 2.6a.
  • FIG. 2b is a cup-shaped nozzle bottom 28 with perforations 26b.
  • FIG. 20 is a bottom in the shape of a flanged cup '30, likewise having perforations 26c and
  • FIG. 2d illustrates a bottom portion 32 similar to the one shown in FIG. 1a in assembled position; the bottom portion has perforations 26d.
  • FIG. *3 is a top view of the bottom portion which is designated by 34, having a rim '36 which is provided with holes 38. During the process of manufacturing the nozzle, these holes are filled with plastic which serves for the connection of the body and the bottom portion in the finished nozzle, as later described. While the holes shown in FIG. 3 are circular, it should be understood that they could have any desired shape, e.g. square, triangular or oval.
  • the nozzle body is given an appropriate shape in a thermo-plastic process under high pressure, with a nozzle bottom being positioned in a suitable manner in the body, or attached thereto, respectively.
  • a nozzle bottom being positioned in a suitable manner in the body, or attached thereto, respectively.
  • flowing of the plastic material' will not occur at temperatures slightly below the melting point despite high pressure. It is important to provide the nozzle bottom with the no'zzle apertures 26a to d and to polish the bottom prior to its insertion into or attachment tothe nozzle body.
  • the mass with which the channels of the nozzle perforations 26a-26d are filled during the polishing process is applied to the nozzle bottom at a high temperature, which would damage the plastic material of the *nozzle body.
  • the filling substance is removed chemically fr'o'rnthe nozzle apertures by acid or caustic alkalion'ly after'the completion of the nozzle so that the channels cannot be clogged with melted plastic materialduring the injection or pressing in of the nozzle bottom into the nozzle body.
  • the rigid connection of the nozzle body and the nozzle bottom is improved by the arrangement of holes 38 at the rim of the nozzle bottom whichmay have various shapes as mentioned.
  • the plastic material flows into these :holes during the Tthermo-p'la'stlc process and thus provides a firmconnectionbetween-nozzle body andnozzle bottom.
  • the nozzle body consisting of polychloro-fluoro-ethylene, particu larly polymonochloro trifluoro ethylene, has considerable advantages over that consisting of polyamides, polyvinyl chloride, and the like, which have been used up to now and especially with respect to the chemical requirements during the spinning process.
  • the plastic mentioned is resistant to spinning bath temperatures up to 70 C., sulphuric acid, carbon sulphide and warm chloro-sulphuric acid. It has not been possible to detach or loosen the nozzle bottom inserted into the nozzle body according to this invention at pressures far exceeding 11 atmospheres so that the advantage of the nozzle made according to the present invention is obvious in view of its resistance to chemical attack and the high durability.
  • plastic may be used very successfully, which contains additives of materials conventional in this art. Such materials are for instance, metallic oxides.
  • a composite nozzle for spinning synthetic fibers comprising a bottom portion made of a metallic material selected from the group consisting of noble metals and noble metal alloys, and a body portion consisting of a polymer material having the general formula poly-mon'ochloro trifuoro-ethylene and is several times the size of the bottom 'portion.

Description

Dec. 12, 1967 ET AL NOZZLE FOR SPINNING FIBERS AND METHOD OF MAKING SUCH NOZZLES Filed Aug. '20, 1965 FIG. 1b
FIG. 10
FIG. 2b
FIG. 20
FIG. 2d;
INVENTORS ALFRED KEIL 'HEINZ MALLY ADOLF wbLFL HANS GRUHL' ATTORNEYS United States Patent 3,357,047 NOZZLE FOR SPINNING FIBERS AND METHOD OF MAKING SUCH NOZZLES Alfred Keil, Wolfen, Kreis Bitterfeld, Heinz Mally, Dresden, and Hans Gruhl and Adolf Wolf], Pirna,-Germany, assignors to Veb Sachsisches Kunstseidenwerk Siegfried Radel, Pirna, Germany Filed Aug. 20, 1965, Ser. No. 481,371 2 Claims. (Cl. 188) The present invention relates to a nozzle for spinning synthetic fibers and to a method for manufacturing such a nozzle. The nozzle according to the invention is particularly suited for spinning fibers of regenerated cellulose.
Spinning nozzles previously made solely from noble metals, preferably gold and platinum, have proved suitable for the spinning of fibers from regenerated cellulose, and they are practically the only ones used for that purpose.
It was also known to. use spinning nozzles consisting of non-metallic materials, such as polyamide, polyvinyl chloride, porcelain, glass, and the like. These nozzles,
however, have many shortcomings regarding the chemical and mechanical resistance. For example, these spinning nozzles especially those made from the non-metallic materials mentioned above, are damaged and decompose during the necessary cleaning process with Warm chlorosulfuric acid. The channels of the nozzle aperture of the plastic nozzles are especially unsatisfactory as far as their mechanical resistance is concerned. The channels are heavily damaged within a short period of time so that the nozzles have to be removed. The known nozzles have shortcomings in other respects, too. For example, the manufacture of porcelain and glass nozzles is very costly. For the above mentioned reasons, many attempts have been made to eliminate the difficulties caused by plastic, porcelain and other non-metallic nozzles. One attempt consisted in providing a combined nozzle in which the body that had previously been made of a noble metal, Was made from one of theabove mentioned non-metallic materials, and the nozzle bottom carrying the nozzle aperture channels (spinning apertures) was made of a noble metal alloy of a known composition e.g. of gold/platinum, platinum/rhodium, or the like. The nozzle bottom, after completion of the nozzle body, is pressed into and/or glued into a ring groove applied to the nozzle body. However, the nozzles made is this manner were not satisfactory in the spinning of synthetic fibers due to the lack of a firm connection between the nozzle bottom and the nozzle body.
It is the object of this invention to provide an improved spinning nozzle for synthetic fiber spinning, said nozzle having higher chemical and mechanical stability.
It is also the object of this invention to provide a spinning nozzle in which the nozzle body comprises a plastic material or a plastic containing an additive, and a nozzle bottom comprising a noble metal which is resistant to chemical and mechanical influences present during the spinning process of synthetic fibers, particularly those from regenerated cellulose.
method for establishing a firm connection between the body and the bottom portion of the nozzle according to the invention.
Other objects and advantages of the invention will become apparent from the following detailed description taken in connection with the accompanying drawing.
The nozzle according to the invention consists of a composite body and bottom portion, the body being made of an especially suited plastic material and the apertured bottom portion being made of a noble metal or noble It is yet another object of the invention to provide a metal alloy, said portions being firmly connected to one another in a manner which permits them to be subjected to any pressure obtaining during the spinning process and to the cleaning of the nozzle, without damaging the connection between the component nozzle parts.
Tests with a number of thermoplastic materials have shown that polychloro-fluoro-ethylene derivatives, are especially suitable as plastic material in the manufacture of the spinning nozzles of this invention. These compounds may be represented by the formula wherein X is partly substituted by fluorine and partly by chlorine. Polyethylene, on the other hand, does not meet with the chemical requirements. The most suitable material for this die extrusion method is polymonochlorotrifluoroethylene.
A firm connection between the nozzle body consisting of polychloro-fiuoroethylene derivatives, and the nozzle bottom consisting of a noble metal is obtained by mounting the nozzle bottom into the body during the manufacture of the body.
In a special embodiment of the invention thechannels in the perforations are bored into the nozzle bottom prior to inserting itinto the nozzle body. The channels are filled with a temperature-resistant mass which is chemically removed after the manufacture of the nozzle has been completed. The temperature-resistant mass is enamel, which can be removed by means of an acid or an alkaline solution.
The required positioning or seating of the nozzle bottom into the nozzle body may be achieved in various ways. The nozzle bottom may, for instance, ha e a flat surface for contact with the body portion; or the bottom portion of the nozzle may be of a shape with the rim pulled up, bent at right angles or flanged. The edge of the bottom is preferably provided with holes of various shapes to improve the positioning or fseating.
The invention will now be more fully described with reference to the accompanying drawings in which; FIG. la shows a complete nozzle with a nozzle body of cylindrical shape anda nozzle bottom inserted therein;
FIG. lb shows another nozzle body of conical shape Without the nozzle bottom attached.
FIGS. 2a to d show cross-sectional views of various examples of nozzle bottoms, and h FIG. 3 is a top view of a nozzle bottom with four oles.
Referring nowto FIGS. 1a and 1b, these illustrate two diiferent shapes of the body portion of the nozzle according to the invention. FIG. 1a shows a cylindrical body 10 with a straight wall portion 12 to be connected with a bottom, and a flange 14 for connection with the spinning device (not shown). The bottom portion is shown at 16; it has a flat perforated plate 18 which serves as nozzle proper for the extrusion of the spinning solution, and a bent-back portion 20 with crimped edge for engagement with the end of wall 12 of the nozzle body.
FIG. 1b illustrates a different shape of a nozzle body 22, which is conical. In this embodiment, too, one end of the nozzle wall 24 is flanged, the other is flat for receiving a flat bottom, as shown, for. instance in FIG. 20.
FIGS. 2a to 2d show different shapes of nozzle bottoms. FIG. 2a illustrates, as mentioned above, a flat, plateshaped bottom 24, with a plurality of perforations 2.6a. FIG. 2b is a cup-shaped nozzle bottom 28 with perforations 26b. FIG. 20 is a bottom in the shape of a flanged cup '30, likewise having perforations 26c and FIG. 2d illustrates a bottom portion 32 similar to the one shown in FIG. 1a in assembled position; the bottom portion has perforations 26d.
FIG. *3 is a top view of the bottom portion which is designated by 34, having a rim '36 which is provided with holes 38. During the process of manufacturing the nozzle, these holes are filled with plastic which serves for the connection of the body and the bottom portion in the finished nozzle, as later described. While the holes shown in FIG. 3 are circular, it should be understood that they could have any desired shape, e.g. square, triangular or oval.
In the following, the method for manufacturing this nozzle will now be described in further detail.
The nozzle body is given an appropriate shape in a thermo-plastic process under high pressure, with a nozzle bottom being positioned in a suitable manner in the body, or attached thereto, respectively. For a successful molding operation it is advisable not to raise the temperature too far beyond the melting point of the plastic material, as decomposition may occur later as a result of the excessive heating, thus unfavorably influencing the durability of'the :nozzle body. On the other hand, flowing of the plastic material'will not occur at temperatures slightly below the melting point despite high pressure. It is important to provide the nozzle bottom with the no'zzle apertures 26a to d and to polish the bottom prior to its insertion into or attachment tothe nozzle body. The mass with which the channels of the nozzle perforations 26a-26d are filled during the polishing process is applied to the nozzle bottom at a high temperature, which would damage the plastic material of the *nozzle body. The filling substance is removed chemically fr'o'rnthe nozzle apertures by acid or caustic alkalion'ly after'the completion of the nozzle so that the channels cannot be clogged with melted plastic materialduring the injection or pressing in of the nozzle bottom into the nozzle body.
'The rigid connection of the nozzle body and the nozzle bottom is improved by the arrangement of holes 38 at the rim of the nozzle bottom whichmay have various shapes as mentioned. The plastic material flows into these :holes during the Tthermo-p'la'stlc process and thus provides a firmconnectionbetween-nozzle body andnozzle bottom.
As has been found in large scale tests the nozzle body consisting of polychloro-fluoro-ethylene, particu larly polymonochloro trifluoro ethylene, has considerable advantages over that consisting of polyamides, polyvinyl chloride, and the like, which have been used up to now and especially with respect to the chemical requirements during the spinning process. The plastic mentioned is resistant to spinning bath temperatures up to 70 C., sulphuric acid, carbon sulphide and warm chloro-sulphuric acid. It has not been possible to detach or loosen the nozzle bottom inserted into the nozzle body according to this invention at pressures far exceeding 11 atmospheres so that the advantage of the nozzle made according to the present invention is obvious in view of its resistance to chemical attack and the high durability.
While in the foregoing the invention was described for the body portion of the nozzle consisting of plastic as defined, it should be understood that plastic may be used very successfully, which contains additives of materials conventional in this art. Such materials are for instance, metallic oxides.
What we claim is:
1. A composite nozzle for spinning synthetic fibers, said nozzle comprising a bottom portion made of a metallic material selected from the group consisting of noble metals and noble metal alloys, and a body portion consisting of a polymer material having the general formula poly-mon'ochloro trifuoro-ethylene and is several times the size of the bottom 'portion.
References Cited UNITED STATES PATENTS 2,403,476 7/ 1946 :Berry et al. 18-8 2,803,851 8/1957 Baunlich et al. 18-8 2,983,570 '5/ 1.961 LHX.
3;044,155 7/1962 Robinson 18-8 X OTHIER REFERENCES application of Aschenbrenner et al., Ser. No. 349,256, published Apr. 27, 1943.
WILLIAM I. STEPHENSON, Primary Examiner.

Claims (1)

1. A COMPOSIT NOZZLE FOR SPINNING SYNTHETIC FIBERS, SAID NOZZLE COMPRISING A BOTTOM PORTION MADE OF A METALLIC MATERIAL SELECTED FROM THE GROUP CONSISTING OF NOBLE METALS AND NOBLE METAL ALLOYS, AND A BODY PORTION CONSISTING OF A POLYMER MATERIAL HAVING THE GENERAL FORMULA -(CX2)4WHERIN X IS PARTLY SUBSTITUTED BY FLUORINE AND PARTLY BY CHLORINE, SSAID BODY PORTION CONSISTING OF A WALLED SHELL WITH THE RIM OF THE BOTTOM PORTION EMBEDDED IN SAID WALL.
US481371A 1965-08-20 1965-08-20 Nozzle for spinning fibers and method of making such nozzles Expired - Lifetime US3357047A (en)

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US481371A US3357047A (en) 1965-08-20 1965-08-20 Nozzle for spinning fibers and method of making such nozzles
US671172A US3491181A (en) 1965-08-20 1967-07-20 Method of making nozzles for spinning fibers

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US67117267A 1967-07-20 1967-07-20

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4997113A (en) * 1985-05-17 1991-03-05 The Coca-Cola Company Orifice insertion and removal device for a post-mix beverage valve
CN106573134A (en) * 2014-06-20 2017-04-19 美德斯普瑞公司 Aerosol or spray device, spray nozzle unit and method of manufacturing the same

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3969455A (en) * 1970-05-25 1976-07-13 Continental Can Company, Inc. Method for forming, sealing, capping and pasteurization of beverage in plastic container
US3676540A (en) * 1971-03-15 1972-07-11 American Cyanamid Co Wet-spinning shaped fibers
US4143112A (en) * 1974-05-30 1979-03-06 Johnson & Johnson Method for making probe covers for electronic thermometers
US4194059A (en) * 1976-12-20 1980-03-18 Compagnie Generale Des Etablissements Michelin Assembly for an electrochemical device comprising a plate and a support
US4960554A (en) * 1985-10-07 1990-10-02 American Cyanamid Company Method for making helically wound extrudate particles

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2403476A (en) * 1944-08-08 1946-07-09 Du Pont Extrusion apparatus
US2803851A (en) * 1953-03-13 1957-08-27 American Viscose Corp Spinneret assembly
US2983570A (en) * 1958-02-10 1961-05-09 Pirelli Porous moulds for manufacturing plastic articles
US3044155A (en) * 1957-08-02 1962-07-17 Engelhard Ind Inc Spinnerette

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2403476A (en) * 1944-08-08 1946-07-09 Du Pont Extrusion apparatus
US2803851A (en) * 1953-03-13 1957-08-27 American Viscose Corp Spinneret assembly
US3044155A (en) * 1957-08-02 1962-07-17 Engelhard Ind Inc Spinnerette
US2983570A (en) * 1958-02-10 1961-05-09 Pirelli Porous moulds for manufacturing plastic articles

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4997113A (en) * 1985-05-17 1991-03-05 The Coca-Cola Company Orifice insertion and removal device for a post-mix beverage valve
CN106573134A (en) * 2014-06-20 2017-04-19 美德斯普瑞公司 Aerosol or spray device, spray nozzle unit and method of manufacturing the same
US20170281880A1 (en) * 2014-06-20 2017-10-05 Medspray B.V. Aerosol or spray device, spray nozzle unit and method of manufacturing the same
US10632265B2 (en) * 2014-06-20 2020-04-28 Medspray B.V. Aerosol or spray device, spray nozzle unit and method of manufacturing the same
CN106573134B (en) * 2014-06-20 2021-04-06 美德斯普瑞公司 Spraying device and method for producing a spraying device and associated device

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