CA2062293C - Oxidative hair dyeing process with catalytic pretreatment - Google Patents

Oxidative hair dyeing process with catalytic pretreatment Download PDF

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Publication number
CA2062293C
CA2062293C CA002062293A CA2062293A CA2062293C CA 2062293 C CA2062293 C CA 2062293C CA 002062293 A CA002062293 A CA 002062293A CA 2062293 A CA2062293 A CA 2062293A CA 2062293 C CA2062293 C CA 2062293C
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CA
Canada
Prior art keywords
hair
transition metal
oxidative
complex
composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA002062293A
Other languages
French (fr)
Other versions
CA2062293A1 (en
Inventor
Gottfried Wenke
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
P&G Hair Care Holding Inc
Original Assignee
Bristol Myers Squibb Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bristol Myers Squibb Co filed Critical Bristol Myers Squibb Co
Publication of CA2062293A1 publication Critical patent/CA2062293A1/en
Application granted granted Critical
Publication of CA2062293C publication Critical patent/CA2062293C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/10—Preparations for permanently dyeing the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/4906—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom
    • A61K8/4926—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having six membered rings
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/51—Chelating agents

Abstract

In a method for oxidatively dyeing hair, a pretreatment which comprises contacting hair with an aqueous solution of an effective amount of particular metal/chelate complexes followed by treatment with oxidative dye mixtures is disclosed. The process serves to conform the oxidative dyeing rate of virgin hair to that of the normally noncongruent rate of nonvirgin hair, so as to enhance the efficiency of thw oxidative dyeing process, without reducing the intensity or variety of color available.

Claims (18)

1. A method for dyeing hair having virgin and nonvirgin hair portions in an oxidative hair dyeing process, comprising:
(a) contacting the hair with an aqueous solution of a transition metal ion complexed with a chelating agent selected from the group consisting of 2,2'-dipyridyl and o-phenanthroline, present at a concentration sufficient to effect deposition of the complex on the hair, said contact being for a period of time to deposit a noncoloring, catalytically effective amount of said complex on the hair:
and (b) contacting the catalytically treated hair with an oxidative hair dye mixture comprising dye precursors and an oxidant for a period of from 5 to 30 minutes, whereby the time to produce a desired shade of color in the hair is substantially reduced and the color imparted to the virgin and nonvirgin hair portions is substantially uniform.
2. The method of Claim 1 wherein the transition metal is copper-II.
3. The method of Claim 1 wherein the amount of metal deposited onto the hair is from about 100 to about 1000 ppm.
4. The method of Claim 2 wherein the amount of copper deposited on the hair is from about 100 to about 1000 ppm.
5. The method of Claim 1 wherein the concentration of metal/chelate complex in aqueous solution required to effect a catalytic effective deposition onto the hair is from about 0.001 to about 0.1% by weight of the solution.
6. The method of Claim 5 wherein the transition metal is copper II.
7. The method of Claim 6 wherein the concentration is about 0.01%.
8. The method of Claim 1 wherein step (b) is conducted at a pH of about 6 to about 8.5.
9. The method of Claim 1 wherein the oxidant is hydrogen peroxide.
10. The method of Claim 9 wherein the concentration of hydrogen peroxide may be as low as 0.1%.
11. The method o! Claim 1 wherein the period for contacting the hair with the oxidative hair dye composition is from 5.0 to 15.0 minutes.
12. The method of Claim 1 wherein only virgin hair is treated.
13. A pretreatment composition for stabilizing human hair against oxidation of cystine to cysteic acid comprising; an aqueous solution of a transition metal ion complexed with a noncoloring but catalytically effective amount of a chelating agent selected from the group consisting of 2,2'-dipyridyl and o-phenanthroline, whereby the subsequent steps for oxidative dyeing of hair are less damaging to the hair.
14. The composition of Claim 13 comprising from about 0.001 to about 0.1% of the complex by weight of the solution.
15. The composition of Claim 13 further comprising a hair shampoo as a cosmetically acceptable vehicle for the transition metal complex.
16. The composition of Claim 13 and 14 wherein the transition metal is copper-II.
17. A hair treatment package in kit form comprising;
(a) a pretreatment solution comprising an aqueous solution of a transition metal ion complexed with a non-coloring but catalytically effective amount of a chelating agent selected from the group consisting of 2,2'-dipyridyl and o-phenanthroline: and (b) an oxidative hair dye mixture.
18. The package of Claim 17 wherein the pretreatment solution further comprises a shampoo as a cosmetically acceptable vehicle.
CA002062293A 1991-03-07 1992-03-04 Oxidative hair dyeing process with catalytic pretreatment Expired - Fee Related CA2062293C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/666,108 US5100436A (en) 1991-03-07 1991-03-07 Oxidative hair dyeing process with catalytic pretreatment
US666,108 1991-03-07

Publications (2)

Publication Number Publication Date
CA2062293A1 CA2062293A1 (en) 1992-09-08
CA2062293C true CA2062293C (en) 2002-02-26

Family

ID=24672861

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002062293A Expired - Fee Related CA2062293C (en) 1991-03-07 1992-03-04 Oxidative hair dyeing process with catalytic pretreatment

Country Status (7)

Country Link
US (2) US5100436A (en)
EP (1) EP0507448B1 (en)
JP (1) JPH05124940A (en)
AU (1) AU655234B2 (en)
CA (1) CA2062293C (en)
DE (1) DE69211045T2 (en)
GR (1) GR3020079T3 (en)

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EP0679078B1 (en) * 1991-12-13 2001-09-05 Vitachlor Corporation Compositions and methods for removing minerals from hair
MX9306352A (en) * 1992-10-13 1995-01-31 Combe Inc COLORING COMPOSITION FOR GRADUAL HAIR DYING THROUGH ATMOSPHERIC DEOXIDATION AND THE PROCESS TO USE IT.
US5368610A (en) * 1993-04-20 1994-11-29 Clairol Incorporated Use of metal salts and chelates together with chlorites as oxidants in hair coloring
US5554197A (en) * 1994-07-19 1996-09-10 Anthony Bernard Incorporated Hair dying system and methods for accurately blending and developing hair dye
DE4438129A1 (en) * 1994-10-27 1996-05-02 Schwarzkopf Gmbh Hans New substituted 2,4-diaminophenols, process for their preparation and hair dye
FR2727314B1 (en) * 1994-11-24 1997-01-03 Oreal PROCESS FOR THE PERMANENT DEFORMATION OF KERATINIC MATERIALS
US6432147B1 (en) 1996-12-23 2002-08-13 The Procter & Gamble Company Hair coloring compositions
GB9626712D0 (en) * 1996-12-23 1997-02-12 Procter & Gamble Hair colouring compositions
GB9626675D0 (en) * 1996-12-23 1997-02-12 Procter & Gamble Hair coloring compositions
GB9626711D0 (en) * 1996-12-23 1997-02-12 Procter & Gamble Hair colouring compositions
GB9626713D0 (en) * 1996-12-23 1997-02-12 Procter & Gamble Hair colouring compositions
US6309426B1 (en) 1996-12-23 2001-10-30 The Procter & Gamble Company Hair coloring compositions
US6398821B1 (en) 1996-12-23 2002-06-04 The Procter & Gamble Company Hair coloring compositions
DE19705875C1 (en) * 1997-02-15 1998-04-02 Wella Ag Oxidative hair colour, giving excellent result under mild conditions
DE19852972A1 (en) * 1998-11-17 2000-05-18 Henkel Kgaa Colorants with transition metal complexes
DE19859681A1 (en) 1998-12-23 2000-06-29 Henkel Kgaa Colorants with transition metals
JP3420143B2 (en) * 1999-12-02 2003-06-23 花王株式会社 Hair treatment agent
US20020042958A1 (en) * 2000-08-29 2002-04-18 Artec Systems Group, Inc. System and method of formulating composition for color-treating hair
WO2002033396A1 (en) * 2000-10-14 2002-04-25 Saunders Alex M Ligand based solution assay for low concentration analytes
US7179302B2 (en) * 2001-03-20 2007-02-20 The Procter & Gamble Company Oxidative treatment of hair with reduced hair damage
US7186275B2 (en) * 2001-03-20 2007-03-06 The Procter & Gamble Company Compositions suitable for the treatment of hair comprising chelants and methods for reducing oxidative hair damage
GB2386068A (en) * 2001-03-20 2003-09-10 Procter & Gamble Oxidative treatment of hair with reduced hair damage
US6695888B2 (en) * 2001-07-30 2004-02-24 Unilever Home & Personal Care, Usa, Division Of Conopco, Inc. Transition metal complexes as dye forming catalysts in hair coloring compositions
WO2003047542A1 (en) * 2001-12-05 2003-06-12 Unilever Plc Hair bleaching and colouring composition which comprise trasition metal catalysts
US6732744B2 (en) 2001-12-07 2004-05-11 The Procter & Gamble Company Method for the ultrasonic treatment of hair and other keratinous fibers
KR100592343B1 (en) * 2002-02-27 2006-06-21 가부시키가이샤 아리미노 Hair dyeing method and hair dye set
US7261744B2 (en) * 2002-12-24 2007-08-28 L'oreal S.A. Method for dyeing or coloring human keratin materials with lightening effect using a composition comprising at least one fluorescent compound and at least one optical brightener
US7195650B2 (en) * 2003-04-01 2007-03-27 L'oreal S.A. Process for dyeing, with a lightening effect, human keratin fibers that have been permanently reshaped, using at least one composition comprising at least one fluorescent dye
US7208018B2 (en) * 2003-04-01 2007-04-24 L'oreal Composition for dyeing human keratin materials, comprising at least one fluorescent dye and at least one associative polymer, process therefor and use thereof
US7736631B2 (en) * 2003-04-01 2010-06-15 L'oreal S.A. Cosmetic dye composition with a lightening effect for human keratin materials, comprising at least one fluorescent dye and at least one aminosilicone, and process of dyeing
US7186278B2 (en) * 2003-04-01 2007-03-06 L'oreal S.A. Composition for dyeing human keratin materials, comprising at least one fluorescent dye and at least one compound comprising an acid functional group and processes therefor
US7204860B2 (en) * 2003-04-01 2007-04-17 L'oreal Composition for dyeing human keratin materials, comprising at least one fluorescent dye and at least one polyol, process therefor and use thereof
US7250064B2 (en) * 2003-04-01 2007-07-31 L'oreal S.A. Dye composition comprising at least one fluorescent dye and a non-associative thickening polymer for human keratin materials, process therefor, and method thereof
US7812163B2 (en) * 2003-07-16 2010-10-12 Hatchtech Pty Ltd. Methods and compositions for controlling ectoparasites
WO2006106366A1 (en) * 2005-04-06 2006-10-12 The Boots Company Plc Improved oxidative hair dyes and related topical compositions
US20070169285A1 (en) * 2006-01-25 2007-07-26 Saroja Narasimhan Method and kit for coloring hair
US7758659B2 (en) 2006-08-10 2010-07-20 Combe Incorporated Catalyzed air oxidation haircolor
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JPH01251139A (en) * 1988-03-31 1989-10-06 Toshiba Corp Knowledge increasing method for knowledge base
CA1333690C (en) * 1988-05-12 1994-12-27 Thomas Matthew Schultz Process for dyeing hair by the sequential treatment with metal ion containing composition and dye composition containing 5,6-dihydroxyindole-2-carboxylic acid
JPH0648926A (en) * 1990-09-11 1994-02-22 Bristol Myers Squibb Co Method for decreasing dirt of head skin

Also Published As

Publication number Publication date
EP0507448B1 (en) 1996-05-29
EP0507448A3 (en) 1993-04-14
DE69211045T2 (en) 1996-10-02
US5316551A (en) 1994-05-31
GR3020079T3 (en) 1996-08-31
AU1213792A (en) 1992-09-10
EP0507448A2 (en) 1992-10-07
DE69211045D1 (en) 1996-07-04
US5100436A (en) 1992-03-31
JPH05124940A (en) 1993-05-21
CA2062293A1 (en) 1992-09-08
AU655234B2 (en) 1994-12-08

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