CA2546350A1 - Small-diameter resin twisted brush - Google Patents

Small-diameter resin twisted brush Download PDF

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Publication number
CA2546350A1
CA2546350A1 CA002546350A CA2546350A CA2546350A1 CA 2546350 A1 CA2546350 A1 CA 2546350A1 CA 002546350 A CA002546350 A CA 002546350A CA 2546350 A CA2546350 A CA 2546350A CA 2546350 A1 CA2546350 A1 CA 2546350A1
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CA
Canada
Prior art keywords
resin
brush
stem
rods
twisted
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002546350A
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French (fr)
Other versions
CA2546350C (en
Inventor
Atsushi Takahashi
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Individual
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Individual
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Filing date
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Publication of CA2546350A1 publication Critical patent/CA2546350A1/en
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Publication of CA2546350C publication Critical patent/CA2546350C/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61CDENTISTRY; APPARATUS OR METHODS FOR ORAL OR DENTAL HYGIENE
    • A61C17/00Devices for cleaning, polishing, rinsing or drying teeth, teeth cavities or prostheses; Saliva removers; Dental appliances for receiving spittle
    • A61C17/16Power-driven cleaning or polishing devices
    • A61C17/22Power-driven cleaning or polishing devices with brushes, cushions, cups, or the like
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46BBRUSHES
    • A46B3/00Brushes characterised by the way in which the bristles are fixed or joined in or on the brush body or carrier
    • A46B3/18Brushes characterised by the way in which the bristles are fixed or joined in or on the brush body or carrier the bristles being fixed on or between belts or wires
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46BBRUSHES
    • A46B15/00Other brushes; Brushes with additional arrangements
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46BBRUSHES
    • A46B2200/00Brushes characterized by their functions, uses or applications
    • A46B2200/10For human or animal care
    • A46B2200/1066Toothbrush for cleaning the teeth or dentures
    • A46B2200/108Inter-dental toothbrush, i.e. for cleaning interdental spaces specifically

Abstract

A resin twisting brush, wherein the material of the shaft part of an interdental brush (the twisting brush) is formed of a resin material having shape restorability and elasticity to provide the brush with proper elasticity, shape restorability, and flexibility and prevent the shaft part from being deformed nor broken so that the shaft part can be deformed and easily inserted when the interdental brush (the twisting brush) is inserted into a narrow portion such as a hourglass-shaped interdental space. Thus, an interdental cleaning assisting tool well matching the three-dimensional shape of an interdental part, capable of maintaining straightness without causing permanent deformation when the shaft part is bent despite the fact that the tool can be inserted into the interdental part restricted in the inserting direction, providing less pain and less uncomfortable feeling and providing comfortable feeling when the tool comes into contact with a tooth and a gum during the cleaning operation, and not damaged also by repeated bending can be provided.

Description

TITLE OF THE INVENTION: SMALL-DIAMETER RESIN TWISTED BRUSH
TECHNICAL FIELD
The present invention [relates to the fact] that the plaque which adheres to the tooth surface and periodontal tissues provides a breeding ground for bacteria which cause tooth decay and pyorrhea, two main causes for the loss of teeth. The present invention is directed to an oral cleaning device optimum for controlling plaque between adjacent teeth, a particular cause of periodontal disease, a mascara brush used for making up eyelashes (cilia), and the like, as well as a small size twisted brush optimum for cleaning or polishing a curved complicated shaped small-diameter pipe or the like.
[Background Technology]
In general, the two major diseases causing the loss of teeth are caries and pyorrhea; in particular, for cases of gingival recession due to periodontal disease are not susceptible to interdental plaque contra! by a common toothbrush, resulting in the need for extensive use of an oral cleaning device such as an interdental brush. A typical cleaning device, an interdental brush, is a twisted brush with nylon bristles arranged concentrically around a twisted metal filament, but these types have been plagued with numerous problems which limit their habitual adoption for oral care: when the tip [of the brush] hits the gum during an interdental insertion, it often injures the gum; it causes a discomfort when the metal tip touches the tooth;
repeated use during cleaning causes a high of breakage of the twisted metal filament due to metal fatigue. When a cleaning is performed between three-dimensionally concaved, complicated teeth, such as in a root branching site, the metal which constitutes the interdental brush stem not only resists insertion causing problems, but also suffers from the risk of leaving un-cleaned sections if the cleaning brush is pre-curved to accommodate its insertion. The use of a shape memory nickel titanium alloy is conceivable for avoiding this problem, but if a shaping method similar to that used for a twisted brush is involved, the de-twisting of the metal filament will end up causing nylon bristles to fall out. Therefore, resin materials have been studied as materials to constitute the stem; but since (he interdental brush requires the brush section to penetrate through a O.Smm diameter space for cleaning interdentally, it has been difficult to injection mold so as to insert nylon bristles into a resin material of this diameter. Other methods include electrostatically implanting nylon piles in the radial direction into a shape memory metal filament rod or a resin filament rod, but it is necessary for the diameter of the stem for penetration of the brush section into a 0.8mm diameter space to be about 0.4 mm or less. It has been difficult to uniformly implant nylon bristles about 2mm to about 4mm in total length into a filament rod of this diameter and, in addition, to find an adhesive with no biological hazard so as to prevent the loss of bristles.
Applications for such smalt twisted brushes also includes cosmetic tools such as cosmetic mascara brushes and the like, where basically the stem material has been a metal material.
In addition, this type of twisted shape brush is also used for polishing or cleaning various pipe-shaped items, but use in a complex curved section gave no choice but to connect a supple material to the handle if made of metal because the depth of penetration was limited.
PROBLEMS TO BE SOLVED BY THE INVENTION
As described above, interdental plaque control is very useful. It is [an object of the present invention] to replace the conventional metal stem material with a material that gives an image of a soft sensation for providing an interdental auxiliary cleaning device, which, when used to insert the interdental cleaning device between drum[saddle]-shaped teeth for interdental oral cleaning, will not injure the gum with the tip of the cleaner of the core portion, which permits easy insertion without causing pain or discomfort simultaneously, permits insertion with no resistance between teeth having restriction in the insertion direction, like a maze or having a complicated root shape, maintains straightenability without any permanent deformation when the stem section is bent, allows close fitting to the three-dimensional interdental configuration so as to leave no nnclcaned sections in the root interstices, causes little discomfort when coming into contact with the tooth or the gum during the cleaning operation, undergoes minimal breakdown upon repeated bending; and also for use in a cosmetic mascara brush without fear when used near the eyeball.
Other applications include replacing the stems themselves with a resilient, shape recoverable, anil supple material for use in polishing and cleaning various pipe shaped goods with a complicated curved structure so as to permit a longer penetration depth.
MEANS TO SOLVE THE PROBLEMS
In general, small size twisted brushes used for interdental brushes and the like require twisting a stainless filament or like metal which constitutes the stem portion, thereby clamping nylon bristles in place. The present invention, in order to replace the conventional interdental brush stem with a resin material having both optimum suppleness and straighten ability (shape recovery), involves, as in the case of a conventional metal interdental brush manufacturing step, the clamping of nylon bristles in a perpendicular direction between two pieces of resin material and twisting one end, while holding the other, thereby clamping and generating a twisted brush using a resin material. However, it is difficult for the stem resin material to maintain its twisted configuration, and also to provide suppleness and shape recoverability such as straightenabilty and the like which are the desired properties of the initial objective. Therefore, [the present invention is] directed to a smali-diameter resin twisted brush constructed by arraying two pieces of resin filament material and thermally fusible resin filaments in parallel thereto, heat-treating at any stage before, during or after a step of clamping radially-projecting filaments (fibers) in the stem filaments rods and twisting so as to form a twisted brush shape, thereby melting only the thermally fusible resin to mutually fuse the two pieces of resin material themselves that form a stem member with the radially-projectiny filaments (fibers) such as nylon bristles, and fuse-fixating the de-twisting stress of the stem member resin materials, so that the brush can maintain the twisted brush configuration with the radially-projecting filaments (fibers) clamped preventing the bristles from falling out.
The above means provide the functions givsn below.
ADVANTAGEOUS EFFECTS OF THE INVENTION
The small-diameter resin twisted brush as set forth in Claims 1 to 5 reduces any fear when used near the eyeball as in a mascara brush because the stem is not made of metal as in the case of conventional twisted brushes;
there is neither any discomfort due to a galvanic electric current between the saliva and the metal when used orally nor worry of metal-induced allergy when used for a long period of time.
Further, as the brush structure is the same as that of tlic conventional twisted brush, the bristle performance is not lost, and it is possible to take advantage of the features of each resin material, thereby resulting in the excellent effects of imparting suppleness not present in the conventional metal twisted brush, maintaining straightcnability due to the shape recoverability immediately after use under bent and deformed conditions, and providing a soft use comfort.
Similarly, this twisted brush is made of a resilient, shape recoverable, supple, resin material of similar properties for the stem itself, so that the entire brush from the tip to the extended holder section is resilient, shape recoverable (straightenablc), and supple, enabling one to respond to a cleaning or polishing operation of a variety of pipe shaped goods regardless of complicatedly curved shapes at a deeper penetration depth.
The nylon bristles referred to here may not be limited to resin materials, but may be a metal material; the resin material may occlude or be bound with polishing particles, permitting one to make up a twisted brush with a higli polishing capability according to the conditions of the polishing and cleaning objectives, while the stem maintains shape recovery or suppleness.
THE BEST EMBODIMENT FOR CARRYING OUT THE INVENTION
Hereafter, the embodiments of the present invention are explained with reference to the attached drawings.
Figures 1-8 are examples of manufacturing steps and embodiments for working the invention; in these figures, like symbols represent like objects where the baste construction is similar to that of the conventional one shown in the drawings.
As shown m Figure 1, multiple radially-projecting resin filaments (fibers) I are arrayed, parallel to, and clamped by, stem resin filament rods 2 with thermally fusible resin filament rods 3 parallel thereto. Figure 2 sliows the way the assembly is viewed from the stem direction, in this condition, twisting by holding the stem tip portion 4 and tip rear end 5 causes the radially-projecting resin filaments (fibers) 1 to become helically oriented around the stem as the center axis of a concentric circle , as shown in Figure 3 , giving rise to a twisted brash shape. Heat treating the entire assembly while the above state is maintained melts only the thermally fusible resin filament rods 3 as in Figure 4, thereby fusing each of the radially-projecting Resin filaments (fibers) I which constitute the bristles with the two or more resin filament rods 2, generating a small-diameter resin twisted brush as shown in Figure 5 which maintains a twisted brush shape which prevents the bristles from falling out, prevents the resin filament rods that constitute the twisted stem portion from delwisting, and which has helical bristles. In this case, the timing for the heat treatment may be during or before the twisting step. In order to shorten the time required to retain each twisted brush of the stem tip 4 and stem rear end 5 until the heat treated thermally fusible resin filament rods 3 have cooled and solidified, any number of twisted brush [units] may have the radially-projecting resin filaments (fibers) positioned at fixed intervals flanked by sections lacking stem bristles, (Fig. 6) and then be twisted and heat treated, thereby permitting production efficiency to be enhanced.
Since the cut surface is expected to have sharp edges, it is preferred to subject the stem tip section 4 to ultrasonic, radio frequency or machining treatment to remove these edges for gaining a smooth shape.
As shown in Figure 7, construction of the nidi ally-projecting resin filaments (fibers) 1 with thermally fusible resin-coated resin filament rods 7, and heat treating during, before, or after the twisting step, fuses, as shown in Figure 8, only the thermally fusible resin portion of the thermally fusible resin-coated resin filament rods 7, thereby fusing together the radially-projecting resin filament rods (fibers) 1 with the resin filament rods 2 that constitute the core portion of the thermally fusible resin-coated resin filament rods 7, thereby maintaining a twisted brush shape which prevents the bristles from falling out, prevents the resin filament rods which constitute the twisted stem portion from detwisting, and which forms the helical bristles.
The resultant small-diameter resin twisted brush, when used by connecting it to the motion shaft of an electrical interdental cleaning device that generates a sliding motion, a rotating motion, or a rotary-sliding motion as in Japanese Patent Applications 2000-380686 and 2001-230207 or in a manual interdental cleaning device.
. . .[the sentence incomplete.] Incidentally, the small-diameter resin twisted brush of this invention is not limited to the above manufacturing sleps and embodiments so that a variety of modifications may obviously be made within the scope not deviating from the gist of the present invention, as for the resin rods used for the stem, the number of the thermally fusible resin filament rods, the materials and array conditions of the radially-projecting resin filnments( fibers) (in terms of arrays in a bundled state or the array intervals), the inclusion of polishing particles, use of metal, and the like.
POTENTIAL UTILITY IN INDUSTRY
The small-diameter resin twisted brush of this invention which docs not use metal in the stem section, will be free of any discomfort due to a galvanic current between the saliva and metal nor is any concern about metal-induced allergy, when used as un oral cleaning device, as an interdental brush for control of the plaque between teeth which can cause pcriodontal disease; and while structurally it is the same as a conventional twisted tooth brush, the stem is provided with enough suppleness, maintains straightenability (shape recoverabiliry) immediately after use in a bent or deformed situation, suffers only rarely stress fatigue due to repetitious use; thereby there is less chance of breakage, giving rise to a highly durable interdental brush. These feature may be taken advantage of and suitably used as a tip brush for connection to the motion shaft of an electrical interdental cleaning device that generate a sliding motion, a rotating motion, or rotary-sliding motion as in Japanese Patent Applications 2000-380686 and 2001-230207. Furthermore, this metal-free twisted brush permits a cleaning, polishing, or coating operation of a complicated shape site which has been difficult for a conventional metal twisted brush, by making it possible not only to take advantage of the characteristics of the resin stem section, but also to reach a further deeper penetration depth than a conventional metal twist brush, which permits cleaning and polishing operations for parts such as machine parts with a complicates shape that have been impossible to clean, leaving no uncleaned corners.
Unlike a metal twisted brush with the hard sensation image of metal, the resin soft sensation reduces fear and thus provides comfort when used in front of the eye such as a for a mascara brush used for an eyelash cosmetic.
BRIEF DESCRIPTION OF THE DRAWINGS
[Figure [J
A figure showing the way the radially-projecting resin filaments (fibers) uniformly arranged in parallel are clamped in a perpendicular crossing direction with the resin filament rods and thermally fusible resin filament rods.
[Figure 2]
Figure i.
[Figure 3]
A figure showing the B-B' cut stem direction of A C-C* cross-section of Figure 5 showing the way the radially-projecting resin filaments (fibers) uniformly arranged in parallel are clamped in a perpendicular crossing direction with the resin filament rods and thermally fusible resin filament rods.
[Figure 4]

A C-C "cross-section of Figure 5 illustrating; the way a twisted brush with radially-projecting resin filaments (fibers) is formed by holding the stem tip while twisting the stem rear end.
[Figure 5]
A cross-section in the stem direction showing the way the thermally fusible resin has melted and bonded by super [sic] heating while a twisted brush with radially-projecting resin filaments (fibers) is formed and held by holding the stem tip while twisting the stem rear end.
[Figure 6]
A figure showing the way twisted brushes arc formed continuously at fixed intervals so as to shorten the time for cooling and holding per piece for enhanced production efficiency.
[Figure 7]
A figure showing the way the radially-projecting resin filaments (fibers) uniformly arranged in parallel are clamped in a perpendicular crossing direction the thermally fusible resin-coated resin filament rods.
[Figure 8]
A cross-section in the stem direction showing the way the thermally fusible resin lias melted and bonded by super [sic] heating while a twisted brush wilh radially-projecting resin filaments (fibers) is formed and held by holding the stem tip of the thermally fusible resin-coated resin filament rods while twisting the stem rear sad.

1. Radially-projecting resin filament rods (fibers) 2. Resin filament rod 3. Thermally fusible resin filament rod 4. Stem tip 5. Stem rear end 6. Portions lacking stem bristles 7. Thermally fusible resin-coated resin filament rod 8. Thermally fusible filament resin melt-deformed bonded portion

Claims (5)

1. A small-diameter resin twisted brush, in which tbebmsii is made, with a multiple number of radially-projecting filaments (fibers) mounted on, and kept clamped in, two or more stem rods, by twisting at both ends of said stein rods and shaping helical bristles around the stem; wherein said stem rods of the twisted brush are constituted of resin filament rods (fibers) and thermally fusible resin filament rods (fibers) lined up in parallel; and said thermally fusible resin filament rods are melted during, before, or after a step of keeping the radially-projecting resin" filaments (fibers) damped in the stem rods, holding (he stem rods at both ends thereof, and twisting for forming a twisted brush shape; thereby fusing together the radially-projecting filaments (fibers) that constitute bristles each with the two or more resin filament rods; and maintaining the shape of the twisted brush which prevents the bristles from falling out, prevents the resin filament rods which constitute the twisted stem portion from detwisting, and has helical bristles.
2. A small-diameter resin twisted brush wherein the stem rods as set forth in Claim 1 are constituted of thermally fusible resin-coated resin filament rods which have been pre-coated with a theimally fusible resin material, and heat treated during, before, or after a step of the twisting, for fusing only the thermally fusible resin portion, thereby fusing the radially-projecting resin ** filaments (fibers) with each of the thermally fusible resin-coated resin filament rods; and maintaining the shape of the twisted brush which prevents the bristles from falling out, prevents the resin filament rods which constitute the twisted stem portion from detwisting, and has helical bristles.
3. A small-diameter resin twisted brush in which the brush is made with improved productivity by cutting at llxed intervals, a continuous twisted brush which is generated by twisting white the resin core material or the thermally fusible libers, of any length, as set forth in Claims 1 and 2, hold the radially-projecting fibers thai constitute the bristles clamped at fixed intervals, thereby shortening the time per twisted brush for cooling and holding after the heat treatment.
*[The "thermally fusible fibers" may refer to the thermally fusible resin covered infusible resin filament rods.]
4. A small-diameter resin twisted brush, wherein the bristle size is color coded by using a pre-pigmented resin for the resin filament rods or the thermally fusible fibers as set forth in Claims I and 2.
5. A small-diameter resin twisted brush, wherein the small-diameter metal-free brush stem tips as set forth in Claims 1 and 2 are subjected to ultrasonic, radio frequency, or a machining treatment, thereby removing [sharp] edges generating a smoothened shape, thereby facilitating brush insertion.
CA2546350A 2003-11-18 2004-11-15 Small-diameter resin twisted brush Expired - Fee Related CA2546350C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2003388512A JP3615752B1 (en) 2003-11-18 2003-11-18 Small diameter resin twist brush
JP2003-388512 2003-11-18
PCT/JP2004/016930 WO2005048771A1 (en) 2003-11-18 2004-11-15 Resin twisting brush

Publications (2)

Publication Number Publication Date
CA2546350A1 true CA2546350A1 (en) 2005-06-02
CA2546350C CA2546350C (en) 2013-01-22

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CA2546350A Expired - Fee Related CA2546350C (en) 2003-11-18 2004-11-15 Small-diameter resin twisted brush

Country Status (10)

Country Link
US (1) US7721379B2 (en)
EP (1) EP1690469B1 (en)
JP (1) JP3615752B1 (en)
KR (1) KR100758553B1 (en)
CN (1) CN100479700C (en)
AU (1) AU2004291010B2 (en)
BR (1) BRPI0416309A (en)
CA (1) CA2546350C (en)
TW (1) TWI257854B (en)
WO (1) WO2005048771A1 (en)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5083932B2 (en) * 2005-02-18 2012-11-28 ユニチカトレーディング株式会社 Method for producing brushes such as interdental brushes
FR2895886B1 (en) * 2006-01-11 2008-05-30 Techpack Int Sa APPLICATOR BRUSH OF A COSMETIC PRODUCT COMPRISING A TWISTED METAL WIRE TEXTURED SOUL
US8517728B2 (en) * 2007-01-24 2013-08-27 Colgate-Palmolive Company Oral care implement having fluid delivery system
SE532467C2 (en) * 2007-12-27 2010-01-26 Numat As Implant cleaning tool for cleaning a metallic implant
JP5229620B2 (en) * 2008-07-31 2013-07-03 フィグラ株式会社 Liquid cosmetic application brush and method of manufacturing the liquid cosmetic application brush
JP5297737B2 (en) * 2008-09-24 2013-09-25 ライオン株式会社 Interdental brush and manufacturing method thereof
US8136536B2 (en) 2008-09-24 2012-03-20 Elc Management Llc Shape memory polymer mascara brush
US8850650B2 (en) * 2009-02-02 2014-10-07 Sanderson-Macleod, Inc. Homogeneous core wire protective cleaning tip
EP2638877B1 (en) 2010-11-11 2016-01-20 Homareproducts Corporation Brush for cleaning inside of implant
CA2829119A1 (en) 2011-03-09 2012-09-13 Colgate-Palmolive Company Interdental cleaning device
US8434185B1 (en) * 2011-05-10 2013-05-07 Charles W. Beaver, Sr. Pipe cleaner assembly
US20130035691A1 (en) * 2011-07-08 2013-02-07 Clint Boylan Surgical brush
JP5731451B2 (en) * 2012-08-09 2015-06-10 大平工業株式会社 Interdental brush
IN2015DN03043A (en) 2012-10-26 2015-10-02 Colgate Palmolive Co
JP5400984B1 (en) * 2013-06-18 2014-01-29 株式会社橋本ブラシ製作所 Brush manufacturing method and brush
DE102013010782A1 (en) * 2013-06-28 2014-12-31 Interbros Gmbh Interdental cleaner and process for its preparation
JP6695073B2 (en) * 2014-06-02 2020-05-20 有限会社メディコム Loop brush
KR102589498B1 (en) * 2015-07-23 2023-10-16 라이온 가부시키가이샤 interdental brush
US20200046475A1 (en) * 2018-08-13 2020-02-13 Prajeshkumar Y. Desai Kite Gum Brush

Family Cites Families (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3124823A (en) * 1964-03-17 Stem brush and method for making same
US3817837A (en) 1971-05-14 1974-06-18 Syva Corp Enzyme amplification assay
US3996345A (en) 1974-08-12 1976-12-07 Syva Company Fluorescence quenching with immunological pairs in immunoassays
US4233402A (en) 1978-04-05 1980-11-11 Syva Company Reagents and method employing channeling
CH648465A5 (en) * 1980-10-22 1985-03-29 Esro Ag BRUSH.
CA1223831A (en) 1982-06-23 1987-07-07 Dean Engelhardt Modified nucleotides, methods of preparing and utilizing and compositions containing the same
US5089390A (en) 1987-09-04 1992-02-18 Syntex (U.S.A.) Inc. 2-methyl-4-hexene- and 2-methyl-4-heptene-1,2-diol derivatives
JPH0220969A (en) * 1988-07-08 1990-01-24 Matsushita Electric Ind Co Ltd Luminance signal processing circuit
US5508178A (en) 1989-01-19 1996-04-16 Rose; Samuel Nucleic acid amplification using single primer
US5101015A (en) 1989-04-10 1992-03-31 Abbott Laboratories Reagents for an amphetamine-class fluorescence polarization immunoassay
US4974279A (en) * 1989-07-18 1990-12-04 Mathison Kevin G Back brush apparatus
CA2037804A1 (en) 1990-03-13 1991-09-14 Richard P. Pankratz Polyolefin backside coating for photosensitive reproduction element
US5253386A (en) * 1990-06-28 1993-10-19 Lalonde Anthony F Brush for cleaning interior of a tube or the like
JPH05317338A (en) 1992-05-21 1993-12-03 Lion Corp Interdental brush and its manufacture
JP3110556B2 (en) * 1992-05-21 2000-11-20 ライオン株式会社 Interdental brush and manufacturing method thereof
JP3014235B2 (en) * 1993-02-25 2000-02-28 富士写真フイルム株式会社 Method for forming silver halide grains and method for producing silver halide photographic material
DE4306214A1 (en) * 1993-02-27 1994-09-01 Geka Brush Georg Karl Gmbh Brush with bristles fixed between twisted wire sections
DE9312577U1 (en) * 1993-08-21 1993-11-18 Geka Brush Georg Karl Gmbh Brushes, especially interdental brushes
DE9313034U1 (en) * 1993-08-31 1993-10-28 Geka Brush Georg Karl Gmbh Cleaning device
JP3718264B2 (en) 1995-08-04 2005-11-24 大平工業株式会社 Interdental brush with interdental gauge function
FR2745481B1 (en) * 1996-02-29 1998-04-30 Oreal PROGRESSIVE BRUSH FOR APPLYING A COSMETIC PRODUCT, ESPECIALLY MASCARA
JPH1094429A (en) 1996-09-25 1998-04-14 Taihei Kogyo Kk Interdental brush
JPH10117846A (en) 1996-10-23 1998-05-12 Lion Corp Inter-tooth brush and its production
JPH1137374A (en) * 1997-07-25 1999-02-12 Sekisui Chem Co Ltd Electro-fusion type piping member and manufacture of electro-fusion type piping member
FR2774269B1 (en) * 1998-01-30 2000-04-07 Oreal BRUSH FOR APPLYING A MAKE-UP PRODUCT, DEVICE THUS EQUIPPED AND MANUFACTURING METHOD
US6269514B1 (en) * 1998-06-05 2001-08-07 Du Pont Monofilament bristle assemblies and methods of making brushes using same
JP2990353B1 (en) 1998-06-12 1999-12-13 ナックス株式会社 Interdental brush
JP2000253931A (en) * 1999-03-09 2000-09-19 Mizutani Shoji Kk Brush
US6016815A (en) * 1999-03-12 2000-01-25 Avon Products, Inc. Applicator brush
US20020120995A1 (en) * 2000-10-02 2002-09-05 Brezler Russel A. Low friction toothbrush
JP3434275B2 (en) 2000-12-14 2003-08-04 淳 高橋 Electric interdental brush
JPWO2003011073A1 (en) 2001-07-30 2004-11-18 高橋 淳 Free Angle Electric Mouth Cleaning Equipment
US7169907B2 (en) 2002-03-01 2007-01-30 Roche Diagnostics Operations, Inc. Derivatives, immunogens, and antibodies for detecting ecstasy-class drugs
US20050133056A1 (en) * 2002-08-21 2005-06-23 Antonio Montoli Wire core mascara brush

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TW200526145A (en) 2005-08-16
US7721379B2 (en) 2010-05-25
EP1690469B1 (en) 2017-10-25
TWI257854B (en) 2006-07-11
BRPI0416309A (en) 2007-01-09
AU2004291010B2 (en) 2010-09-02
JP3615752B1 (en) 2005-02-02
JP2006246904A (en) 2006-09-21
CN1882266A (en) 2006-12-20
CA2546350C (en) 2013-01-22
WO2005048771A1 (en) 2005-06-02
AU2004291010A1 (en) 2005-06-02
EP1690469A4 (en) 2012-05-02
KR20060103327A (en) 2006-09-28
CN100479700C (en) 2009-04-22
EP1690469A1 (en) 2006-08-16
US20080034524A1 (en) 2008-02-14
KR100758553B1 (en) 2007-09-13

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