CA2549725A1 - A base composition for preparing multi-functional formulations for care and protection of the skin and hair - Google Patents

Abstract

The present invention relates to a cosmetic composition comprising a filmogenic system constituted by at least dimethicone, trimethylsiloxysilicate, stearyl dimethicone, cyclopentasiloxane and dimethiconol, and an emulsifying system constituted by at least PEG-8 dimethicone. This composition imparts to the skin a high resistance to water and to sweat, as well as provides prolonged hydration. In addition, it imparts to user's hair a long time of curl retention, as well as a significant increase in brightness and strengthening of the individual hairs.

Description

Title: "A BASE COMPOSITION FOR PREPARING MULTI-FUNCTIONAL FORMULATIONS FOR CARE AND PROTECTION OF THE
SKIN AND HAIR"
This application claims the priority of Brazilian patent case No.
P10303051-0 filed on December 15, 2003 which is hereby incorporated by reference.
The present invention relates to a cosmetic composition compri-sing a filmogenic system and an emulsifying system. This composition im-parts to the skin high resistance to water and to sweat and provides prolon-ged hydration. Further, it imparts to the hair long retention of curls, as well as significant increase on brightness and strengthening of the hair.
Description of the Prior Art In many western cultures having a tanned body is synonym of status and beauty, and voluntary exposure to the sunlight, in general associ-ated to physical activities, beach or swimming pool, is a quite common prac-tice. However, although the sunlight is fundamental to health, there are num-berless deleterious effects on the skin and hair.
With a view to make exposure to the sunlight safer, a number of preparations to be used topically and on hair, known as sunscreens, have been developed. These preparations have, in their formulations, molecules that are generically classified as sun filters, which act by basically two diffe-rent mechanisms: absorption or reflection of diverse wave lengths present in the sunlight, as those found in the spectral ranges known as UVA and UVB.
In order to have the sunscreens with an adequate performance in real conditions of use, that is to say, associated to physical activities and baths in swimming pools or in the sea, their capability of remaining on the skin or hair should be increased. This increase can be obtained by the pre-sence of polymeric macromolecules with high substantivity and by the filmo-genic action or else by the selection of adequate emulsifiers.
Polyvinyl pyrrolidones, polyvinyl alcohols and some classes of silicones constitute the main known categories of substances that exhibit fil-mogenic action.

However, in general, the utilization of these substances guaran-tees only a period of resistance to water and varies from 40 to 80 minutes, proven through known international protocols, and come from the obtaining of preparations that, in general, exhibit the following characteristics:
1 - undesirable levels of oiliness and stickiness;
2 - low spreading degree;

3 - difficult absorption of the composition by the skin;

4 - possibility of raising the degree of oiliness of the skin;

5 - occurrence of possible cases of comedogenicity by occlusive action on the skin;

6 - incapability of forming a homogeneous film on the skin, re-sulting in an unsatisfactory performance with respect to resistance to water and to sweat, and resulting in "rolling" (areas of accumulation of the product, because it does not spread adequately);

7 - they do not have adequate resistance to moisture, and con-sequently do not provide a satisfactory retention of curls;

8 - due to the constitution of the known compositions, the po lymer comprised therein, which is deposited onto the hair, soon gets loose from it, thus causing the "flake effect" (scaling of the polymer particles that were covering the hair);

9 - they do not provide brightness, besides not increasing the resistance of the hair.
Some patent documents describe silicone compositions, as for example:
Document BR 0013874 describes a cosmetic composition for care of the skin without oil, which comprises emollients such as dimethicone, dimethicone copolyol and trimethylsiloxysilicate. In addition to these compo-nents, said composition contains water, moistener and a keratolytic agent. The function of this composition is to provide softening to the skin due to the presen-ce of emollients and also to retain moisture in order to prevent loss thereof.
The presence of the keratolytic agent in the described cosmetic composition promotes the weakening of the hair.

Document US 5,478,552 describes a liquid cosmetic material comprising a volatile silicone type and trimethylsiloxysilicic acid. It further comprises silicic anhydride, fatty acid ester and mineral clay. This cosmetic exhibits resistance to water, among other properties.
Mineral clay renders the application of the composition onto the hair and the skin of men very difficult, which naturally has much hair. The presence of silicic anhydride and mineral clay promotes astringent actions, which impairs the action of silicones and of fatty acid ester.
Document US 6,387,382 describes preparations for the skin with multiple functionalities in the form of oil-in-water emulsions. Theses prepara-tions comprise a siloxane polymer such ad dimethicone, a cyclic silicone and emollient. These preparations are resistant to water by virtue of a protecting barrier formed.
The combination dimethicone, a cyclic silicone and emollients provide an inadequate time of resistance to water in comparison with which is expected by the users.
Summary of the Invention The invention relates to a cosmetic composition, particularly indi-cate for use in tanning formulations, sunscreens or cosmetic preparations for use on the hair, which comprise a filmogenic system comprising at least cyclopentasiloxane, dimethiconol, dimethicone, trimethylsiloxysilicate and stea-ryl dimethicone, and an emulsifying system comprising at least PEG-8 dimethi-cone. This cosmetic composition may further contain various components known in the cosmetology area, such as moisteners, conditioning agents, pho-toprotecting agents, skin and hair toning agent, fragrance, among others.
Brief Description of the Figures The present invention will now be described in greater detail with reference to the figures that illustrate the tests of performance of the present invention.
- Figure 1 is a graph representing numerically the appraisal of the loss of curl shaping (LGS) over time;
- Figure 2 is a graph representing numerically the appraisal of the increase in tension in maximum load (TML) on the treated hair in comparison with untreated hair (control); and - Figure 3 is a graph representing numerically the appraisal of the energy at the rupture point on treated hair in comparison with untreated hair (control).
Detailed Description of the Invention The present invention describes a cosmetic composition compri-sing a filmogenic system that comprises at least cyclopentasiloxane, dimethi-conol, dimethicone, trimethylsiloxysilicate and stearyl dimethicone, and an emulsifying system comprising at least PEG-8 dimethicone. In addition to the cited components, it may further comprise photoprotecting agents, skin and hair toning agent and, optionally, other agents that have specific functions required for each composition necessary for each situation, such as, chela-ting agents, thickening agents, pH-adjusting agents, preservative agents, moistening agents, conditioning agents, emollients, optional silicones, optio-nal filmogenic agents, oiliness absorbing agents, skin and hair toning agents, optical diffusion agents, skin tensioning agents, sunscreens and filters against ultraviolet rays or active ones, as bacteriostatic, bacterial or antimi-crobial, anti-radical, anti-aging, anti-inflammatory, among others. This com-position may be called a cosmetic base, since it may receive a number of optional components in its constitution.
This cosmetic composition, when applied onto the skin, provides mainly a high resistance to water and to sweat, as well as prolonged hydrati-on. When applied to the hair, its filmogenic action on the hairs provides high retention of curls, a significant increase in brightness and strengthening of the individual hairs.
Further, according to the optional components added to the composition, the latter can provide softness, smoothness, protection against the sunlight, with good spreading and without increasing the oiliness.
The cosmetic composition of the present invention comprises the association of specific filmogenic agents and emulsifying agents to obtain a variety of formulations with diverse functionalities for the care of the skin and the hair. Each of the components, either alone or in combination, of this base has a quite advantageous purpose for the care of the skin or hair, namely:
- the combination of dimethicone and trimethylsiloxysilicate pro-vides repellence to water and also imparts to the product containing them 5 good spreading and does not cause occlusive effects;
- with the present invention, PEG-8 dimethicone acts as an agent that promotes homogeneity of the emulsions and further imparts good condi-tinning to the skin;
- with the present cosmetic composition, stearyl dimethicone has the function of providing hydration to the skin due to the fact of forming a smooth film on the surface of the skin;
- the combination of cyclopentasiloxane and dimethiconol acts on the skin as a film forming system, further providing smoothness and softness;
- the combination of dimethicone, trimethylsiloxysilicate and PEG-8 dimethicone, at the concentrations indicated in this invention, which will be described later, imparts to the formulations in which it is contained a period of 80 minute of resistance to water;
- the combination of dimethicone, trimethylsiloxysilicate, cyclo-pentasiloxane, dimethiconol, stearyl dimethicone, PEG-8 dimethicone provi-des high resistance to water and to sweat, as well as prolonged hydration, when applied to the skin. It also provides a long time of retention of curls, a significant increase in brightness and strengthening of the individual hairs, when applied thereto.
Although described as being particularly useful for formulations for sunscreens, the cosmetic composition of the present invention has a vari-ety of advantages and desired characteristics in a cosmetic product for the skin or hair, some of which are listed below.
1 - it is stable for a period of at least two years;
2 - it has an adequate texture during application, non-sticky, non-oily;
3 - it is easy to spread;
4 - it exhibits an ideal time relative to absorption and drying of the cosmetic composition on the skin;
- it does not cause oiliness on the skin after application;
6 - it has high capacity of maintaining hydration of the skin;
7 - it does present comedogenicity;
5 8 - it does not present photoxoxicity;
9 - it does not present allergicity;
- it has resistance to water, even after a period of immersion of 360 minutes;
11 - it has resistance to sweat, even after a period of forced su-10 doresis of 120 minutes;
12 - it does not cause any type of adverse reaction or lesion, on the skin or in the eye, whether in normal conditions of use or in conditions of forced sudoresis;
13 - it is compatible with agents that protect against the sunlight .(sunscreens) at concentrations that guarantee sunscreen protection factors (SPF) between 2 and 100, preferably from 4 to 60;
14 - it is compatible with agents that protect against the sunlight (sunscreens) at concentrations that guarantee blocking of over 50% of the UVA rays, preferably over 80% of these rays;
15 - it is associable with emollients so as to provide a degree of hydration of the skin significantly higher than that measured for the control area for more than 24 hours after a single application, preferably for more than 8 hours;
16 - it guarantees a significant increase in brightness of the hair;
17 - it provides retention of curls significantly longer than the re-tention measured in control areas (without application of product), for more than 8 hours, after a single application in conditions of high relative moisture;
18 - it promotes an increase by 35% in the tension verified in the maximum load applied to the hair and 53% in the energy necessary to break the hair thread, which results in the strengthening of the individual hairs.
The cosmetic composition of the present invention can serve as a base for any other composition that may contain some type active principle for the skin other than designed only for protection against the sunlight. A
few examples of products that can be prepared from the cosmetic composition of the present invention are:
- sunscreens for adults or children, either for concomitant use in practicing sports or not;
- body or face hydrating products;
- products against spots on the body or face;
- body or face firming products;
- self-tanning products;
- insect repellent products;
- body or face hydrating agents that enlighten the skin;
- pharmaceutical preparations of topical application, that require protection against solar radiation at the application place;
- cosmetic preparations for the body or face intended for children;
- localized-action cosmetic preparations, specific for periocular re-gion, around the lips, on the lips, antispots, against shadows un-der the eye, among others;
- non-rinsable hair conditioners;
- sunscreens for hair;
- pharmaceutical preparations having action on the hair that req ui-re, at the place of application, high resistance to water, as for example pharmaceutical shampoos;
- rinsable or non-rinsable hair preparations that aim at an increase in brightness and /or a long time of retention of curls and/flr the strengthening of the individual hairs.
Filmoaenic S sy tem The filmogenic system is constituted by at least dimethicone, tri-methylsiloxysilicate, stearyl dimethicone, cyclopentasiloxane and dimethico-nol. The amount of this system in the composition ranges from 0.3% to 92%
by weight, preferably from 0.5% to 50.0% by weight, based on the total weight of the cosmetic composition. Silicone agents might be added to this system, which will be described later.

By preference, combinations of dimethicone and trimethylsilo-xysilicate are used, which have the following properties (measured at a tem-perature of 25° C):
- refraction index: 1.408 to 1.410 - viscosity: 400 -1020 cP.
Further, preferably combinations of cyclopentasiloxane and di-methiconol which have the following properties are used (measu-red at a temperature of 25°C):
- viscosity: 4500 - 8000 cP
- relative density: 0.945 - 0.965 g/cm3.
Emulsif~ng System The emulsifying system is constituted by at least PEG-8 dimethi-cone. The amount of this system in the composition ranges from 0.1 % to 28.0% by weight, preferably from 0.3% to 12.0% by weight, based on the total weight of the composition. Like the preceding system, this system may further receive optional emulsifying agents, which will be defined later.
Constitution of the Cosmetic Composition In the following table, the preferred proportions of the agents that constitute the filmogenic and emulsifying systems described above are given.
These systems combined, in the amounts corresponding to the proportions defined in the following table, in the form of products for topical use or for use on the hair, enable to obtain preparations that exhibit significant improve-ments in comparison with the known preparations of topical use that, which provides resistance to water and sweat. Further, these improvements are noted in the sensorial aspects related with the safety and effectiveness of use of this composition on the skin:
Component Preferred range of proportions arts b wei ht Dimethicone and trimeth Isilox 8 -12 silicate Stea I dimethicone 7 -11 PEG-8 dimethicone 4 - 7 C clo entasiloxane and dimethiconol 3 - 7 Silicone Agent The types of silicone agents that, in the present invention, act as filmogenic agents exhibit emollient, solvent and skin conditioning properties.
A few examples of silicone that may be added to the cosmetic compositions of the present invention as optional filmogenic agents are volatile and non-volatile silicone oils such as, for example, cyclomethicone, alkyldimethicones, dimethicone-copolyols, dimethiconols, phenyl trimethicones, caprilyl trimethi-cones, aminofunctional silicones, silicones modified with phenyl, phenyl tri-methicones, alkyl modified silicones; dimethyl and diethyl polysiloxane, mixed C~-C3o alkyl polysiloxane, dimethyl siloxanes, polymethylsiloxane, alpha-methyl-omega-metoxypropymethylsiloxane, polyoxidimethylsilylene, polydi methyl silicone and combinations thereof or silicone elastomer such as cyclomethicone and dimethicone crospolymer, vinyl dimethicone and di methicone crospolymer, dimethicone and dimethicone crospolymer and cyclopentasiloxane and dimethicone crospolymer.
Further, as optional filmogenic agents, some polymers such as polyvinyl pyrrolidones and polyvinyl alcohols can be added.
In the preferred embodiments of the present invention, preferably cyclomethicone or dimethicone copolyol or a combination thereof is used as an optional filmogenic agent.
Optional Emulsifying Agent As optional emulsifying agents, anionic emulsifiers, ~uiterionic emulsifiers, non-ionic emulsifiers and polymeric emulsifiers can be used.
A few examples of emulsifying agents may be added to those which make part of the described emulsifying system, such as soybean leci-tin, nonyl phenol ethoxylate, sodium or potassium alkyl phosphates, dietano-lamine cetyl phosphate, dimethicone copolymers such as modified polyo-xyalkylene dimethylpolysiloxanes, methyl glucose, propylglyceryl glucose, ethoxylated glycols, non-ethoxilated glycols, ethoxylated fatty acids, non-ethoxylated fatty acids, ethoxylated sucrose, non-ethoxylated sucrose, etho-xilated pentaeritritol, non-ethoxilated pentaeritritol, ethoxilated alkyl glycosi-des, non-ethoxylated alkyl glycosides, ethoxylated alkyl polyglycosides, etho-xylated alkyl polyglycosides, alkyl phosphates and derivatives thereof and mixtures thereof.
Other alternatives of compounds that can act as emulsifying agents are esters such as potassium cetylphosphate, glyceryl stearate, etho s xylated sorbitan esters, non-ethoxylated sorbitan esters, such as sorbinate stearate, ethoxylated sorbitan stearate, polysorbate 80, polysorbate 65, po-lysorbate 60, polysorbate 40, polysorbate 20, polyquaternium 37, glycol stea-rate, PEG-2 stearate, PEG-10 stearate, PEG-30 stearate, PEG-40 stearate, PEG-100 stearate, PEG-150 stearate, PEG-1000 stearate, sorbitan palmita-10 te, propylene glycol stearate, propylene glycol stearate PEG-25, sorbitane oleate, methyl glycose sesquistearate, among others.
Further, fatty acids such as cetyl alcohol, stearyl alcohol, cet~earyl alcohol can be used. Propoxylated and/or ethoxylated fatty alcohols, among others.
Moreover, there are other options as synthetic polymers, which, besides having the function of a thickening agent, also have the function of a polymeric emulsifying agent, which are formed by carboxyvinyl polymers and copolymers, acrylates, methacrylates, alkyl acrylates, acrylate l Coo-C3o alkyl acrylate crospolymer, acrylamides, taurates and/or combinations thereof, in addition of ethylene oxide and propylene oxide copolymers.
Further, sterols such as ethoxylated or non-ethoxylated animal sterols, ethoxilated vegetable sterols, lanolin and derivatives, for example, lanolin alcohol, cholesterol, soybean sterol, hydrogenated lanolin, hydro-xylated lanolin and derivatives thereof should be considered.
Preferably, non-ionic emulsifiers, polymeric emulsifiers and alkyl phosphates should be used, more preferably potassium cetyl phosphate at a concentration ranging from 0.1 % to 15.0% by weight, preferably from 0.5 to 3.0% by weight, based on the total weight of the composition of the invention.
The choice of an optional emulsifying agent should ~e made with extreme care, since it may significantly alter the effectiveness and safety of the cosmetic composition.
In addition to the above-mentioned components, the compositi-ons of the invention may further comprise compounds conventionally used in cosmetic compositions of this time, which will be detailed hereinafter.
Chelatina Agent The use of a sequestering agent or chelating agent is due to the fact it has the property of sequestering ions from the solution; they are-capa-ble of sequestering calcium and magnesium atoms, but preferably they exhi-bit selectivity for linking to ions such as iron, manganese and copper. Their function is to control a possible oxidation action that may occur and further to promote stability in stocking the cosmetic compositions of the present inven-tion.
A few examples of chelating agents that may be added to the compositions of the present invention include etiodronic acid, nitrite acetic acid, polyaminocarboxylic acid such as ethylenediaminotetracetic acid (EDTA) and salts thereof, pentaacetic ethylenetriamine acid, ethylenediamine disuccinic acid, amono phosphanates, nitrite acetates, hydroxyethylethylene triamines, organic phosphates such as sodium hexamethaphosphate, sodium tripolyphosphate, sodium gluconate, stilbene, ethylene diamine diglutaric acid, EGTA and salts thereof, solvates, isomers and derivative.
In the preferred embodiments of the present invention, preferably disodic EDTA is used to act as a chelating agent in an amount ranging pre-ferably from about 0.05% to about 0.20% by weight, preferably about 0.10%
by weight, based on the total weight of the composition of the invention.
Thickening Agent The function of the thickening agent in cosmetic compositions is to maintain in suspension other components present therein, besides ~provi-ding consistency to the compositions.
A few examples of thickening agents that may by used in the present invention are: natural polymers, carbomer, or-preferably types of gum such as acacia gum, agar, tars gum, gum arabic, ~Igin,alginic acid and deri-vatives such as ammonium or sodium alginate, amilopectin, calcium alginate, gelatin, gelan gum, guar gum, sodium hyalurionate, guar hydroxypropyl, Ka-rays gum, carob bean oil, natto gum, potassium alginate, potassium carrage-enin, sclerotium gum, sodium carrageenin, dragantum gum, xanthan gum and mixtures thereof.
Xanthan gum exhibits excellent thickening properties, in addition to adequate suspending and pseudoplastic properties. These characteristics allow the cream to spread easily over the skin. In this regard, xanthan gum is the preferred gum for addition to the present invention.
Further, polysaccharides may be used, as thickening agents, in the compositions of the present invention. These polysaccharides have a structure with repeated sugar units such as, for example, a carbohydrate.
Among various examples, the following may be cited: cellulose and derivati-ves thereof such as hydroxyethyl cellulose, carboxymethyl hydroxyethyl ce-llulose, ethyl cellulose, hydroxyethyl ethyl cellulose, hydroxypropyl cellulose, hydroxypropyl methyl cellulose, methyl hydroxyethyl cellulose, microcrystali-ne cellulose, sodium sulfate cellulose, hydroxypropyl cellulose and mixtures thereof. Other examples of polysaccharides that may be added are celluloses with alkyl substituted as for example: stearyl, isostearyl, lauryl, miristil, cetyl;
isocetyl, cocoyl, palmityl, oleyl, linoleyl and mixtures thereof, in addition to scleroglucanes and derivatives thereof.
Other alternatives are the synthetic polymers that also act as polymeric emulsifying agents formed by carboxyvinyl polymers and copo-lymers acrylates such as alkyl Coo-so acrylate, methacrylates, alkyl acrylates, acrylamides, taurates, acrylate crospolymers and/or combinations thereof.
In the preferred embodiments of the present invention, preferably a thickening system composed by carbomer and xanthan gum is used in an amount ranging from 0.01 % to 5.00% by weight, prefersbly from 0.10% to about 1.00% by weight, based on the total weight of the cosmetic compositi-ons.
Ph Adjusting Agent In order to obtain a final composition with neutral pH values or suitable for the skin, the following may be added to the composition of the present invention: inorganic hydroxides such as sodium hydroxide, calcium carbonate, citric acid, phosphoric acid, lactic acid, sodium citrate, succinic acid, potassium acetate, sodium chloride, amines such as tertiary.amine, tri-ethanolamine and mixtures thereof.
In the preferred embodiments of the present invention, trietha-nolamine is used as a pH adjusting agent in an amount ranging from 0.01 to 5.00% by weight, preferably 0.1 % to 1.0% by weight, based on the total weight of the composition.
Preserving Agent A preserving agent, as its name indicates, provides preservation of the composition to which it is added, that is to say, it provides the compo-sition with effective protection against attack by microbial agents, prolonging its useful life or shelf life.
There are a number of preserving agents suitable for cosmetic compositions, and all the agents that have this function may be added to the cosmetic composition of the present invention, either alone or in combination.
A few preferred examples of preserving agents for addition to the composition. of the present invention are: sodium acetate, .boric acid, sorbic acid, benzalkonium chloride, sodium metalbisulfite, potassium sorbate, so-dium sulfite, calcium propionate, glutaraldehyde, cream of tartar, sodium benzoate, organic acids, lactic acid, benzoic acid, hydroxymethylglycinates, parabens such as methylparaben and propylparaben, phytic acid, PEG-5 cocoate, PEG-8 dicocoate, iodopropinyl PEG-4 buthyl carbamate, pheno xyetanol, formaldehyde solution, pentanediol, phenol alcohol, benzyl alcohol, iodo alkyl carbamates, imidazoleidinyl, 1,3-bis(hydroxymethyl)-5,5-dimethyl 2,3-imidazolidione, methylchloroisothiazolidione, methylisothazolinone and derivatives thereof and/or combinations thereof.
In the preferred embodiments of the present invention, phenoxi ethanol or 3-iodo-propynylbutyl carbamate or a combination thereof is used as a preserving agent in an amount ranging from 0.01 % to 2.00% by weight, preferably from 0.10% to 1.00% by weight, based on the total weight of the composition.
Moistening Agent The function of the moistening agent in the cosmetic composition of the present invention is to promote retention of water on the user's skin, that is to say, to provide the skin with water and prevent loss of water from it.
The moistening agent further helps in increasing the effectiveness of the emollient, reduces scaling of the skin and improves the sensorial capacity of the skin.
A few examples of moistening agents that may be added to the cosmetic compositions of the present invention are: PEG-4 dilaurate, po-lyhydroxyl alcohols, alkylene polyols and derivatives thereof, Glycerol, etho-xylated glycerol, propoxylated glycerol, sorbitol, hyroxypropyl sorbitol, among others, glycerin, lactic acid and lactate salts, diols and C3-C6 triols, Aloe very extract, butylenes glycol, sugars and amides and derivatives thereof as for example alkoxylated glucose, hyaluronic acid, glycolic acid, lactic acid, glyco-lic acid and salicylic acid, panteol, urea, ethoxilated nonbyl phenol, natural oils such as pine oil, oils and waxes and mixtures thereof.
In the preferred embodiments of the present invention, at least one glycol or Aloe vera extract, or a combination thereof is used as a moiste-ning agent in an amount ranging from 0.01 % to 30.00% percent, preferably from 0.05% to 15.00% by weight, based on the total weight of the compositi-on.
Emollient The function of the emollients in cosmetic compositions is to add and replace lipids and natural oils to the skin. They also act as solubilizers of sunscreens.
As emollients for addition to the composition of the present in-vention, conventional lipids may be added such as, for example, oils, lipids and other water-insoluble components and polar lipids that are modified lipids so as to increase its water solubility by esterifying a lipid in a hydrophilic unit such as for example hydroxyl groups, carbonyl groups, among others. A few compounds that may be used as emollients are natural oils such as essential oils and derived from plants, esters, silicone oils, polyunsaturated fatty acids, lanolin and derivatives. A few natural oils that may be used are derived from damask seed, sesame seed, soybean, peanut, coco-nut, olive, cocoa butter, almond, avocado, carnauba, cotton seed, rice flour, peach stone, mango sto-ne, jojoba, macadamia nut, coffee beans, grape seeds, pumpkin seeds, among others and mixtures thereof.
A few ethers and esters may also be used in the function of emo-5 Ilients, such as, for example, C$-C3o alkyl esters of C$-C3o carboxylic acids, C~-C6 diol monoesters and C~-C3o careboxylic acid diesters, C~o-C2o alcohol monoester sucrose and combinations thereof. Examples of these compounds are dicaprylic ether, cetyl lactate, isopropyl palmitate, dicarprylyl carbonate, C~2-C~5 alkyl benzoate, isopropyl miristate, isopropyl isononate, sucrose pal-10 mitate, sucrose oleate, isostearyl lactate, glyceryl behenate, triglycerol-isostearate, lauryl pyrrolidone carboxylic acid, pantenyl triacetate and combi-nations thereof.
Also, other fatty alcohols may be used as mono-, di- or triclyceri-de esters that have a lipophilic nature, such as dicraprylylic ether, in addition 15 to synthetic and natural hydrocarbons, organic carbonates such as dicaprylyl carbonate, a few types of silicones such as cyclomethicone and mixtures the-reof.
In addition, different natural compounds may be used as emolli-ents, such as microcrystalline wax, carnauba wax, Shea butter, bee wax, ozokerite wax, among others.
In the preferred embodiments of the present invention, C~~-C~5 alkyl benzoate, dicaprylyl carbonate or a combination thereof is used as an emollient agent in an amount ranging from 0.01 % to 2.00% by weight, pre-ferably from 0.10% to 1.00% by weight, based on the total weight of the composition.
Oiliness Absorbing Agent As an agent for modifying the sensorial capacity, that is to say, to promote adsorption of the oiliness, various compounds may be added to the composition of the present invention, such as: polyethylene, polymethyl acrylates such as polymethylmethacrylate, acrylate polymers, salicyficate ester, niacinamide, aluminum silicate, magnesium silicate, calcium silicate, magnesium carbonate, calcium carbonate, magnesium oxide, magnesium hydroxide, titanium dioxide, zinc laurate, zinc miristate, polyacrylamide, po-lysaccharides, modified polysaccharides, cellulose, microcrystalline cellulose maize starch, glyceryl starch, maltodextrin, borates, nitrates such as boron nitrate, silicas such as colloidal silica, hydrated silica, talc, Nylon such as Nylon 12, mica such as titanated mica, chlorides such as bismuth chloride, modified starch such as octenylsuccinate aluminum starch and derivatives thereof, bentonites, besides mixtures thereof.
In the preferred embodiments of the present invention, Nylon 12 or octenylsuccinate aluminum starch or a combination thereof is used as a sensorial capacity modifying agent in an amount ranging from 0.1 % to 40.0%
by weight, preferably from 1.0% to 10.0% by weight, based on the total weight of the composition.
Skin-toning Aaent Optionally, skin-toning agents may be added for imparting this characteristic to the cosmetic composition of the present invention. The types of skin-toning agents suitable for the composition in question are those that react with the proteins of the skin or those that only dye it, such as those constituted by ultrafine dispersions of inorganic pigments and oxide nano-pigments or still those constituted by vegetable substances.
A few examples of skin-toning agents indicated for the present composition are: erythrulose and dihydroxyacetone (DHA), iron oxide, dita-nium dioxide, zinc oxide, those mono or poly carbonyl compounds such as isatin, aloxane, ninidrin, glyceraldehydes, mesotartaric aldehyde, glutaral-dehyde, derivatives of pyrazolin-4,5-dione or of 4,4-dihydroxypyrazolin-5-one, methylglyoxal, 2,3-dihydroxysuccinic dialdehyde, 2-amino-3-hydroxysuccinic dialdehyde and 2-benzylamino-3-hydroxysuccinic dialdehyde.
In the preferred embodiments of the present invention, Erythrulo-se or dihydroxyacetone (DHA) or a combination thereof is used as skin-toning agent in an amount ranging from 0.5% to 20.0% by weight, preferably from 1.5% to 6.0% by weight, based on the total weight of the composition.
Sunscreens In order to filter -the sun rays, sunscreens may be added, which may be water-soluble or liposoluble A few examples of sunscreens that absorb ultraviolet rays, which are indicated for addition to the cosmetic composition of the present invention are: benzilidene camphor and derivatives thereof, isophthalilidene camphor and derivatives thereof, cinnamic acid and esters thereof, salicylic acid and esters thereof, benzoic acid and esters thereof, p-aminobenzoic acid and derivatives thereof such as its esters, substituted hydrozibenzophenones, substituted dibenzoylmethane, benzotriazol and a few derivatives such as 2-arylbenzotriazol, 2-arylbenzimidazol, 2-arylbenzofuranes, 2-arylbenzoxazol, 2-arylindol, mono-phenylcyanoacrylates, diphenylcyanoacrylates, among other sunscreens against ultraviolet rays known from the prior art.
A few examples of sunscreens indicated for the present invention are organic compounds which often have low water-solubility such as triazine derivatives (for example, hydroxyphenyltriazine compounds or benzotriazol derivatives), some amides such as those that contain a vinyl group, cinnamic . acid derivatives, sulfonated benzimidazoles, diphenylmalonitryls, oxalylami-des, camphor derivatives, salicylic acid derivatives such as 2-ethylhexyl saii-cylates, homosalates and isopropyl salicylates, benzophenone derivatives such as benzophenone-2, benzophenone-3 and benzophenone-4, PABA
such as 2-ethylhexyl 4-dimethylamino-benzoate and other sunscreens usu-ally added to the compositions of products for protection against the sunlight.
In addition to the examples cited above, there are other preferred components for performing this function, namely: anillino N,N-trimethyl-4-(2-oxoborn-3-ilidenomethyl) methyl sulfate; 3,3'-(1,4-phenylenodimethylene) bis (7,7-dimethyl-2-oxo-bicyclo-(2.2.2) 1-heptylmetanosulfonic acid and derivati-ves thereof; 1-(4 terc-butylphenyl)3-(4-methoxyphenyl) propane-1, 3, dione;
alpha-(2-oxoborn-3-ilidene) toluene-4-sulfonic acid and salts of potassium, sodium and triethanolamine; 2-cyano-3, 2-ethylexyl 3'-diphenylacrylate; 2-ethoxyethyl 4-methoxycynnamate; methyl anthraninate; Triethanolamine sali-cylate; 2, 2', 4, 4' tetrahydroxybenzophenone; 2-phenylbenzimidazol-5-sulfonic acid and its salts of potassium, sodium and triethanolamine; 2-ethylhexyl 4-methoxicynnamate; 2-hydroxy-4-methoxybenzophenone (oxybenzone); 2-hydroxy-4-methoxybenzophenone 5-sulfonic acid and its sodic salt (suliso-benzone and sodic sulisobenzone); aminobenzoic PABA acid; homomethyl salicylate; N-{(2 and 4) [(2 oxoborn-3-ilidene) methyl] benzyl} acrylamide po-lymer; titanium dioxide (with or without a lipophilic coating); ethyl N-ethoxy-aminobenzoate; 2-ethylhexyl 4-dimethylaminobenzoate; 2-ethylhexyl sali-cylate; isopentyl 4-methoxycinnamate; 3-(4'-methylbenzilide-no)-d-1 camphor;
camphor 3-benzilidene; 2, 4, 6-trianilin-(p-carbo-2'ethyl-hexyl-I'-oxy)-1,3,5-tria-zine octyl; zinc ozide (with or without lipophilic coating); 2-(2H-benzotriazol-2-yl)-4-methyl-6-{2-methyl-3-(1,3,3,3-tetramethyl-1-((trimethylsilyl)oxy) disiloxa-nyl) propyl) phenol; benzoic acid; 4,4'-[[6-[[4-[[1,1-diomoethyl-ethyl]
carbonyl]
amino]-1,3-5-triazine-2,4-diyl] diimino] bis, bis (2 ethylhexyl); 2,2'-methylene-bis-6-(2H-benzotriazol-2-yl)-4-(tetramethyl butyl)-1,1,3,3-phenol; methylene bis-benzotriazolyl tetraethyl butyl phenol; monosodic salt of 2,2'-bis-(1,4-phenylene)-IH-benzimidazol-4,6 6 disulfonic acid; (1,3,5)-triazine-2,4-bis {[4-(2-ethyl-hexyloxy)-2-hydroxy]-phenyl]-6-(4-methoxyphenyl); bis-ethylexyloxy-phenol methoxyphenyl triazine; methylene bis-benzotriazolyl tetramethylbutyl phenol; butyl methoxydibenzoyl methane, 2-ethylexyl p-methoxycinnamate, methylene bis-benzotriaolyl tetramethylbutyl phenol, 4-butyl-4-methoxy-dimenziolmethane, benzophenone 3, bis-ethylhezyloxyphenol methoxyphe-nyl trazine, octhyl triazone, titanium dioxide, cinnamidopropyltrimonium chlo-ride, dimethylpabamidopropyl laurdimonium tosylate and still other non-men-tioned sunscreens.
In the preferred embodiments of the present invention, for pro-ducts of topical application, the mixture of benzophenone 3, butyl methoxydi-benzoylmethane, 2-ethylexyl p-methoxydibenzoylmethane and bis-ethylhexy-loxyphenol methoxyphenyl triazine is used as a sunscreen system, in an amount ranging from 0.10% to 50.0% by weight, preferably from 1.0% to 25.0% by weight, based on the total weight of the composition. On the other hand, for products intended to be used on the hair, the mixture of cinnamido-propyltrimonium chloride and dimethylpabamidopropyl laurdimonium tosylate is used as a sunscreen system in an amount ranging from 0.1 % to 30.0% by weight, preferably from 0.5% to 15.0% by weight, based on the total weight of the composition.
Antioxidant Aaent The antioxidant agents act to protect the topical composition and the skin against oxidation action.
Compounds that have antioxidant properties and may be added to the compositions of the present invention are: sulfites, ascorbates, amino acids (for example, glycine, histidine, tyrosine and triptofane), amidazoles, urocanic acid and derivatives thereof, peptides (for example, D, L-carnosine, D-canosine and L-carnosine), anserine, carotenoids, carotenes and derivati-ves thereof (for example, alpha-carotene and beta-carotene), licopene and derivatives thereof, chlorogenic acid and derivatives thereof, lipoic acid and derivatives thereof, dihydrolipoic acid, aurothioglycose, propylthiouracyl, thio-redoxyne, glutathione, cisteine, cistine, cistamine, dilauryl thiodipropionate, diestearyl thiodipropionate, thiodipropyonic acid, salts of sulfoximine com-pounds, palmitic acid, phytic acid, citric acid, lactic acid, malic acid, pholic acid, vitamin C, tocopherols, vitamin A, vitamin E, vitamin E acetate, lipophilic substances such as butyl hydroxytoluene (BHT), butyl hydroxyanisol (BHA), tetradibutyl pentaeritryl hydroxyhidrocinnamate, benzylalconium chloride, hydrophilic substances such as penoxyethanol, benzyl alcohol, metyl para-ben, propyl paraben, imidazolidinyl urea, hidantoines, polyvinyl alcohol, ethyl alcohol., octyl methoxycinnamate, sunflower-seed extract, lycopene extrac-ted from tomato, OPC (Palmitoyl hydroxypropyl triomonium amilopecti-ne/glycerin crospolymer, lecitin, grape-seed extract) glycospheres and deri-vatives thereof.
In the preferred embodiments of the cosmetic compositions of the present invention, butyl hydroxy toluene is used as an antioxidant agent in an amount ranging from 0.01 % to 1.00% by weight, preferably from 0.01 to 0.20% by weight, based on the total weight of the composition.
Fragrance It is optional to add perfume or fragrance selected from a variety of possible substances to compositions of this kind. The amount of fragrance to be added to the cosmetic compositions of the present invention, preferably ranges from about 0.01 % to about 30.0D%, more preferably from about 0.05% to about 5.00% by weight, based on the total weight of the compositi-on.
Vehicle 5 Water is the base of several possibilities of cosmetic compositi-ons prepared from the already-described base cosmetic composition, acting as a vehicle for the other components. The compositions of the present in-vention comprise water, preferably deminerali~ed or distilled at an adequate percentage (q.s.p.) to reach 100% of the formula, based on the total weight 10 of the present composition. Of course, other cosmetically acceptable vehicles may be used in the present invention. In the examples of the composition that are described later, ethyl alcohol, cyclomethicone and dicaprylyl carbo-nate are also used as a vehicle,.
Other Optional Components 15 In order to impart to the cosmetic compositions of the present invention some desirable characteristic that is not achieved with the cited components, optional components that are compatible with their properties may be added. Some of these compounds that may be added to the compo-sition are:

20~ active principles (either encapsulated or not): they may be lipophilic or hydrophilic such as seaweed extract, combination of palmitoyl hydroxypropyl triomonium aminopectine, glycerin crospolymer, lecitin and grape-seed ex-tract, bisabolol (anti-inflammatory active), D-pantenol (conditioning active), tocopherol (vitamin E), preferably in talaspheres, combination of retinol (vi-tamin A) and tocopherol (vitamin E) preferably in talaspheres, ascorbic acid (vitamin C) preferably ion talaspheres, ergocalcipherol (vitamin D), biosac-charide gum 2 and biosaccharid gum 3 and other active sunscreen com-monly added to compositions of products to be used topically or on the hair;
~ bacteriostatics, bactericidal or antimicrobicidal;
~ stabilising agents such as sodium chloride;
~ dyes;
~ plant extracts: chamomile, rosemary, thyme, calendula, carrot extract, common juniper extract, gentian extract, cucumber ex-tract;
~ skin or hair conditioning agents; .
~ hair dyes;
~ optical diffusers; and ~ other cosmetically acceptable components that are compatible with the base composition.
Examples of Composition Example 1 - Sport SPF 15 Protecting Hydrating Emulsion The composition exemplified below has been prepared by fo-Ilowing these steps:
1 - add disodic EDTA (Phase B) to demineralized water (Phase A) and stir until complete solubilization is achieved;
2 - add carbomer and xanthan gum (Phase C) and stir until complete dispersion is achieved;
3 - add glycerin (Phase D) and stir until complete solubilization is achieved;
4 - heat the mixture under constant stirring up to the temperature of 85°C;
5 - separately, mix dicaprilyl carbonate, C~2-C~5 alkyl benzoate, dimethicone, trimethylsiloxysilicate, PEG-8 dimethicone, stearyl dimethicone, 2-ethylhexyloxyphenol methoxyphenyl triazine benzophenone 3, BHT (Phase E) and heat under constant stirring up to the temperature of 85°C;
6 - at the temperature of 85°C, add the Phase E to the mixture;
7 - add potassium cetylphosphate (Phase F) and triethanolamine previously solubilized in demineralized water (Phase G);
8 - stir until the emulsion is formed;
9 - cool the mixture down to the temperature of 25°C;
10 - add cyclomethicone, cyclopentasiloxane and dimethiconol (Phase H) and vitamin E acetate and lycopene extracted from tomato (Phase I) previously solubilized;
11 - add glycospheres of OPC (Palmitoyl hydroxypropyl triomo-nium amilopectine/glycerin crospolymer, lecitin, grape-seed extract), sun-flower-seed extract, mixture of PEG-5 cocoate, PEG-8 dicocoate and iodo-propinyl butyl carbamate and PEG-4 and phenoxyethanol one by one (Phase J); and 12 - stir until complete homogenization is achieved.
Component Amount % b wei ht A Demineralized water 61.8280 B Disodic EDTA 0.10 C Carbomer 0.35 C Xanthan um 0.2,0 D GI cerin 5.00 E Dica ril I carbonate 2.00 E C~2-C15 alk I benzoate 5.00 E Dimethicone and trimeth Isilox 2.00 silicate E PEG-8 dimethicone 1.00 E Dimethicone stea I ~ 1.00 E 2-eth Ihex I p-methox cinnamate 7.00 E 4-but I-4-methox dibenzo (methane1.00 E Benzo henone 3 1.50 E Bis-ethylhexyloxyphenol methoxyphenyl1.00 triazine E BHT 0.05 F Potassium cet I hos hate 2.00 G Demineralized water 3.00 G Triethanolamine 0.50 H C clomethicone 2.00 H C clo entasiloxane and dimethiconol1.00 I Vitamin E acetate 0.50 I L co ene extracted from tomato 0.002 J Glycospheres of OPC ((Palmitoyl 0.02 hydro-' x ro I triomonium amilo ectine/
I cerin cros of mer, lecitin, ra e-seed extract J Sunflower-seed extract 0.25 J PEG-5 cocoate, PEG-8 dicocoate 0.20 and io-do ro in I but Icarbamate and J Phenox ethanol 1.fl0 Component Function Demineralized water Vehicle Dlsodic EDTA Se uesterina ent Carbomer Thickenin ent a Xanthan um Thickenin ent a GI cerin Moistenin ent a Dicapril I carbonate Emollient C~2-C~5 alk I benzoate Emollient Dimethicone and trimeth Isilox silicateEmollient PEG-8 dimethicone Co-emulsifier Stea I dimethicone Emollient 2-eth Ihex I -methoxicinnmamate Sunscreen 4-but I-4-methox dibenzo (methane Sunscreen Benzo henone 3 Sunscreen Bis-eth (hex lox henol methox hen I Sunscreen triazine BHT Antioxidantent a Potassium cet I hos hate Emulsi ent in a Demineralized water Vehicle Triethanolamine pH ad'uster C clomethicone Emollient C clo entasiloxane and dimethiconol Emollient Vitamin E acetate Antioxidantent a L co ene extracted from tomato Antioxidantent a Glycospheres of QPC (Palmitoyl hydroxypropylAntioxidant triomonium amilo ectine/ I cerin cros agent of mer, le-citin, ra e-seed extract Sunflower-seed extract Antioxidant a ent PEG-5 cocoate, PEG-8 dicocoate and PEG-4Preserving agent io-do ro in Ibut Icrbamate Phenox ethanol Preservin a ent Tests of the cosmetic composition of the present invention The composition used in the tests described hereinafter is that defined in example 1 - Body Hydrating Emulsion with SPF 15.
I. TESTS FOR SAFETY
1 - A clinical double-blind, randomized, controlled study of the comedoaenic potential The objective of this test is to evaluate the comedogenicity of the above-cited cosmetic composition.
For this test, 10 volunteers between 24 and 45 years of age were selected (average 36 years). The volunteers with a history of chronic syste-mic diseases, generalized dermatological diseases, presence of nevus in the dorsal region, pregnancy or nursing were excluded. The test chosen for the cited purpose was the occlusive pacht test (known also as contact test of epicutaneous text).
The procedure of the test is as follows:
- 0.2 ml of the product was applied to the backs of the volunteers with the help of a syringe in a 8 cm2 area;
- occlusion of this area was then made with non-absorbent cotton fabric and sticking plaster;
- an equivalent area was occluded, but without application of pro-duct, to serve as a control area.
This procedure was repeated 12 times in 4 weeks. After this pe-riod, follicular biopsies with the help of cyanocrylate glue, and the removed material was analyzed.
Result: the sample tested proved to ~be non-comedogenic.

2 - A clinical, mono-blind, randomized, controlled study of the phototoxicity potential and cutaneous photoallergy The objective of this test is to evaluate whether the above-cited cosmetic composition exhibits phototoxicity and/or cutaneous photoallergy.
5 For this test, 25 volunteers of both sexes, befirveen 18 and 66 years of age were selected. Volunteers with localized or generalized derma-tological diseases, presence of lesions or nevus in the dorsal region, derma-toses triggered by light, use of medicament that induce photosensitivation, pregnancy and nursing were excluded.
10 In order to evaluate photoallergy, a filter-paper disc A with the sample of the product of 0.05 g/cm2 was applied in a determined region of the back of the volunteers, this region and their eyes being protected. This procedure was repeated over 5 times. The disc was removed and the expo-sed region was irradiated with UVA and UVB ultraviolet lamp. The area adja-15 cent the place of application served as a control area and was irradiated as well.
Qn the other hand, to evaluate phototoxicity, the procedure was equivalent, with the difference that the application took place only once and the irradiation was performed with UVA ultraviolet lamp.
20 Result: the cosmetic composition did not cause either phototoxi-city or photoallergy, being considered approved for topical use.
3 - A clinical, open study of the cutaneous tolerability and of the ocular regii-on in real conditions of use The objective of this test is to determine the prevalence of adver-25 se reactions in real conditions of use of the above-cited cosmetic compositi-on.
For this purpose, 28 volunteers between 21 and 43 years of age were selected (average 36 years). Volunteers with a history of chronic sys-temic diseases, corneal eye diseases and dermatological conjunctive disea-ses either generalized or in the periocular region, participation in tests for ocular irritability on the 7 days preceding the test, occurrence of ocular irrita-tion or ocular infection in the 48 hours preceding the test, use of contact len-ses and spectacles, systemic arterial hypertension, intolerance to heat, ha-ving undergone treatment with antihistaminics, anti-inflammatories, corticos-teroids or sympathomimetic medications within the period of 7 days prece-ding the test were excluded.
A frontal region of the face of 24 cm2 area was demarcated on each of the volunteers, and the cosmetic composition was applied in an amount of 2 mg/cm2 homogeneously. After application, the volunteers had a dry sauna to induce diaphoresis in two stages. Thereafter the volunteers used the cosmetic composition for 3 weeks, under supervision of a dermato logist and an ophthalmologist.
Result: in real conditions of use, no volunteer presented any cu-taneous or ocular lesion related to the use of the cosmetic composition. In conditions of diaphoresis, no volunteer presented any kind of adverse ocular reaction or ocular lesion.
4 - A clinical, open, comparative, randomized study of the ocular irritability potential The objective of this test is to evaluate comparatively the ocular irritability potential of the above-cited cosmetic composition, after diaphoresis and of a physiologic solution NaCI 0.9%.
For this test, 29 volunteers between 21 and 44 years of age were selected (average 32 years). Volunteers with a history of chronic systemic diseases, corneal and conjunctive ocular diseases, dermatological diseases either generalized or in the periocular region, participation in tests for ocular irritability in the 7 days preceding the test, occurrence of ocular irritation or ocular infection in the 48 hours preceding the test, use of contact lenses and spectacles, systemic arterial hypertension, intolerance to heat, having under-gone treatment with antihistaminics, anti-inflammatories, cordicosteroids or sympafihomimetic medications within the period of 7 days preceding the test were excluded.
A frontal region of the face of 24 cm~ area was demarcated on each volunteer and the product was applied in an amount of 2 mg/cm2 ho-mogeneously. Several products were applied, randomly choosing the volun-teer who would receive each of them. After application, the volunteers had a dry sauna to induce diaphoresis. Thereafter the volunteers were evaluated by an ophthalmologist.
Result: no volunteer presented ocular ardency or irritation when exposed to the conditions of intense diaphoresis. So, there is no difference between the products used in the test.
II - TESTS FOR EFFICACY
1 - Evaluation of the percentage of UVA protection The objective of this test is to determine spectrophotometrically the percentage of radiation blocking in the region of the UVA ray, according to an Australian methodology.
The cosmetic composition is applied on a tape of the Transpore type, which is kept fiixed on the metallic support of the spectrophotometer. 9 different positions of the tape are read. With the data chosen, the transmi-ttance and the blocking were calculated.
Result: the cosmetic composition exhibited a percentage of blo-eking higher than 90% in the 320 - 360 nm range. Therefore, it is considered to be of a broad protection spectrum.
2 - Evaluation of the Hydration Kinetics The objective of this test is to analyze the kinetics of the cited cosmetic composition in order to evaluate its hydration potential.
The areas of 2.5 x 4 cm of the forearms of 10 volunteers are de-marcated for application of 2 mg/cm2 onto each of them. One of the areas is kept as non-treated (control area). The measurements are made with the help of an apparatus of the Corneometer CM 820 model from the company Courage and Khazaka. The measurements show that the cosmetic composi-tion of the present invention exhibits a 22.2% higher hydration in comparison with the hydration provided by the control area.
Result: the skin hydration values remain at levels significantly higher than the control area for over 8 hours after a single application.

4. A clinical, open, randomized, study, parallel contr~I over the determination of the sunscreen protection factor (SPF) before and after immersion in water The objective of this test is to determine the sunscreen protection factor (SPF) after and before immersion into water of the above-cited cosme-tic composition.
volunteers between 21 and 49 years of age (average of 29 years) of phototypes I, II and III were selected. Volunteers with a history of phototoxic and photoallergic reactions, use of medicaments liable to product abnormal cutaneous response, presence of sunburns, suntan, uneven skin 10 tone, spots, nevus, seborrhoeic keratosis or excess hair on the site of the test, pregnancy or nursing were excluded.
Areas of 50 cm2 were demarcated in the infrascapular region of the volunteers. Standard sunscreen and the cosmetic composition were applied in adjacent regions in amounts of 0.1 ml or 0.1g homogeneously.
Thereafter, the areas were irradiated and dipped into water. This procedure was then repeated, with measurements right after application of the product of 240 minutes after immersion into water and 360 minutes of immersion into water. With the data obtained, the SPF was calculated.
Result: the product is approved as SPF 15Ø
2fl 5. A clinical, open, randomized study, parallel control over the determination of the sunscreen protection factor ~SPF) before and after diaphoresis The objective of this test is to determine the sunscreen protection factor before and after diaphoresis of the above-cited cosmetic composition.
10 volunteers between 27 and 42 years of age (average 33 ye-ars) of I, II, and III phototypes were selected. Volunteers with a history of phototoxic and photoallergic reactions, use of medicaments liable to product abnormal cutaneous response, .presence of sunburns, suntan, uneven skin tone, spots, nevus, seborrhoeic keratosis or excess hair on the site of the test, pregnancy or nursing were excluded.
Three areas of 50 cm2 were demarcated in the infrascapular re-gion of the volunteers. A standard sunscreen and the cosmetic composition were applied in adjacent regions in the amount of 0.1 ml or 0.1g homoge-nously. Thereafter, the areas were irradiated and exposed to heat (diaphore-sis). This procedure was then repeated, with the measurements immediately after application of the product and after 120 minutes of exposure to heat.
With the results obtained, the SPF was calculated.
Result: the product is approved as SPF 15Ø
III - SENSORIAL EVALUATION
These studies aim at evaluating the acceptance by the consumer of the cosmetic composition of the present invention. 78 male and female volunteers, between 16 and 50 years of age, phototypes I, II, III and IV, being users of photoprotectors were selected. Volunteers who had dermatological diseases or were pregnant or nursing were excluded.
The questionnaire for evaluation of performance and acceptance of the product was answered during the period of test. These evaluations were carried out in parallel with a cosmetic composition from the market, also with the appeal of resistance to water for 6 hours and resistance to sweat without definite time.
The results of the evaluations show that, during application, the consumers considered the texture of the product adequate, that is to say, non-sticky or non-oily, considered the product to be easy to spread and with ideal time of absorptionldrying, and indicated that it, after application, did not leave the skin too oily.
These conclusions are reached from the following results:
- 85% of the volunteers indicated that the product exhibits an ade-quate texture during application, value of 16.5% better than the market composition;
- in hedonic evaluation, the acceptance index for the attribute sti-ckiness was of 83%, value 48% better than the market composi-tion;
- in hedonic evaluation, the acceptance index for the attribute oili-ness was of 81 %, value ~68% better than the market composition;
- 90% of the volunteers considered the product easy or very easy to spread, value 45% better than the market composition;

in hedonic evaluation, the acceptance index for the attribute drying time was ~of 87%, value 30% better than the market com-position;
- 92% of the volunteers indicated that the product does not leave 5 the skin too oily after application, value 33% better than the ma-rket composition.
IV - TESTS FOR STABILITY
Semi-pilot scale and industrial bench batches were analyzed for determination/evaluation of their physical-chemical parameters, as well as 10 organoleptic parameters:
- viscosity: the samples subjected to conditions of 37°C, 5°C, 25°C, sunlight and 45°C for 1 month kept the viscosity within the specified range;
- pH: the samples subjected to the conditions of 37°C, 5°C, 25°C, 15 sunlight and 45°C for 1 month kept the viscosity within the speci-fled range;
- appearance: 37°C, 5°C, 25°C, sunlight and 45°C
for 1 month did not present significant variations;
- color: 37°C, 5°C, 25°C, sunlight and 45°C for 1 month did not 20 present significant variations;
- odor: 37°C, 5°C, 25°C, sunlight and 45°C for 1 month did not present significant variations.
Example 2 - Definition and Volume Cream: Crisp Hair This composition was prepared in a similar way as the composi-25 tion of example 1 above. The difference lies in the constitution of Phase E, which in the case of example 2 comprises these compounds: mixture of di-caprilyl carbonate, C~~-C~5 alkyl benzoate, dimethicone, trimethylsiloxysilica-te, PEG-8 dimethicone, stearil dimethicone and BHT.
Phase Com onent Arnount % b wei ht A Demineralized water 56.83 B Disodic EDTA 0.10 C Carbomer 0.35 C Xanthan um 0.20 D GI cerin 5.fl0 E Dica I I carbonate 2.00 E E C12-C15 dimethicone benzoate5.00 E Trimeth Isilox silicate 2.00 E PEG-8 dimethicone 1.00 E Stea I dimethicone 1.00 E BHT 0.05 F Potassium cet I hos hate 2.00 G Demineralized water 3.00 G Triethanolamine 0.50 H C clomethicone 2.00 H C clo entasiloxane and dimethiconol1.00 I Vitamin E acetate 0.50 1 L co ene extracted from tomato0.002 J Glycospheres of OPC (Palmitoyl0.02 hydroxypropyl trimonium amilopecti-. ne/glycerin crospoiymer, lecitin, grape-seed extract J Sunflower-seed extract 0.25 J PEG-5 cocoate, PEG-8 dicocoate0.20 and iodopropinyl butylcarbamate and PET-J Phenox ethanol 1.00 Com onent Function Demineralized water Vehicle Dlsodic EDTA Se uesterina ent Carbomer Thickenin ent a Xanthan um Thickenin ent a GI cerin Moistenin ent a Dica ril I carbonate Emollient C12-C15 alk I benzoate Emollient Dimethicone and trimeth Isilox silicateEmollient PEG-8 dimethicone Co-emulsifier Stea I dimethicone Emollient BHT Antioxidantent a Potassium cet (phosphate Emulsi in ent a Demineralized water Vehicle Triethanolamine H ad'uster C clomethicone Emollient C clo entasiloxane and dimethiconol Emollient Vitamin E acetate Antioxidantent a L co ene extracted from tomato Antioxidantent a ~Glycospheres of (Palmitoyl hydroxypropylAntioxidant trimo- agent nium amilopectine/glycerin crospolymer, lecitin, ra e-seed extract Sunflower-seed extract Antioxidantent a PEG-5 cocoate, PET-8 dicocoate and iodopropinylPreserving but Icarbamate PEG-4 agent Phenox ethanol Preservin ent a Test of the Cosmetic Composition of Example 2 The composition used in the tests described below is that defined in example 2 - Definition and Volume Cream: Crisp Hair I -TEST FOR EFFICACY
1 - Eval nation of Curl Retention The objective of this test is to evaluate the curl retention potential of the compositions in a long-term study and in conditions of high relative humidity.
The measurement of the capacity of retaining curls is based ~on the analysis of the image (.photographs) of previously treated and modeled locks of hair that remain under high relative humidity. The photos are registe-red every hour (#otalizing 8 hours) and then the lengths of the locks are mea-sured. The product capable of maintaining the shortest length of the hair, with respect to both the initial lock size (expression A) and the initial curl size (ex-pression B) over time will have the greatest power of retaining curls, that is to say, it will have the least loss of hair shaping (in percentage).
For this test, control locks (without application of product), locks with application of placebo (components of the filmogenic and emulsifying systems: cyclopentasiloxane, dimethiconol, dimethicone, trimethylsiloxysili-cate and stearyl dimethicone and PEG-8 dimethicone) and locks with appli-cation of the complete formula, described in Example 2 have been used.
Note: Figure 1: A graph illustrating the values of loss of curl shaping (LCS) over time.
Result: As can be concluded from Figure 1, the best product for retaining curls is the cosmetic composition of the present invention, descri-bed in Example 2, which provides retention of curls significantly greater than the retention achieved in the control or that provided by placebo, for over 8 hours after a single application in conditions of high relative humidity (URm;~.
= 85%).
Example 3 - Hair Protection Fluid The cosmetic composition exemplified below has been prepared according to the following steps:
1 - heating dimethicone, trimethylsiloxysilicate, PEG-8 dimethi-cone, stearyl dimethicone (Phase A) up to the temperature of 75°C;
2 - cooling the mixture down to the temperature of 50°C;
3 - adding cyclopentasiloxane and dimethiconol (Phase B) and stirring until complete solubilization is reached.
Phase Com onent Amount % b wei ht A Dimethicone and trimeth Isilox 2.00 silicate A PEG-8 dimethicone 1.00 A Stea I dimethicone 1.00 B C clo entasiloxane and dimethiconol1.00 Phase Function Dimethicone and trimeth Isilox Emollient silicate PEG-8 dimethicone Co-emulsifier Stea I dimethicone Emollient C clo entasiloxane and dimethiconol Emollient Test of the Cosmetic Composition of the Present Invention The composition used in the tests described below is that defined in Example 3 - Hair Protection Fluid.
I - TEST FOR EFFICACY
1 - Measurement of the Mechanical Properties of Hair The objective of this test is to obtain values of parameters rela-ting to the mechanical properties of individual hairs by applying a known for-mula for obtaining the applied tension curve versus deformation/lengthening undergone by.the hair. Control individual hairs (without treatment) and hairs treated with the products of .combination of silicones (composition of Example 3), Sport formula .(Example 1 without the sunscreen agents) and placebo of this same formulation have been used.
The individual hairs were subjected to the adequate treatments.
The equipment Instron was used for obtaining the measurements of tension versus deformation.
The hairs were conditioned in a room with controlled humidity between 55 and 65% of relative humidity.

30 individual hairs were treated with the cosmetic composition of the present invention, constituted by the base composition at defined con-centrations, and 30 control hairs.
The final results are expressed in energy at the breaking point (J) and in the tension on the maximum load (MPa), as can be seen in the graphs of Figures 2 and 3. With the values of the graph, the decrease or increase in energy and tension for breaking an individual hair was calculated (in percen-tage).
Locks of hair were separated for each treatment to be evaluated.
In the application, a proportion of 1 g of product for 6 g of lock was used.

There was no rinsing. .
Each individual hair, having its diameter measured with the help of a micrometer, was kept suspended by two pneumatic claws separated by a distance of 5 cm. The constant velocity applied in the upper claw for stre-5 tching the hair was of 10 mm/min. After rupture, the equipment was pro-grammed for causing the upper claw to return to the initial position.
The software registered various parameters for each individual hair, such as young module, rupture energy, tension in function of the defor-mation undergone by the individual hair. The values measured are shown in 10 the graphs of figures 2 and 3.
Notes: Figure 2 shows a graph that evaluates the Increase in maximum load tension (MLT) on individual hairs treated in comparison with untreated ones (control hairs);
Figure 3 shows a graph that evaluates the energy at the rupture 15 point on treated hairs in comparison with untreated hairs (control hairs).
Results:
The treatment with the Hair Protection Fluid (composition of Example 3) has provided an increase in the energy necessary for rupture of the individual Hair (35%), which results in a strengthening of the individual 20 hair (greater resistance).
Preferred embodiments having been described, one should un-derstand that the scope of the present invention embraces other possible variations, being limited only by the contents of the accompanying claims, which include the possible equivalents.
25 Other Examples of 'Composition Example 4 - Sport SPF 30 Hydrating Protecting Emulsion Com onent Amount % b wei ht Demineralized water 40.3280 Disodic EDTA 0.10 GI cerin 5.00 Seaweed extract 2.fl0 Cros of mers of ac lates/C~o-so alk 0.30 I ac late Xanthan um 0.05 Stea I dimethicone 1.20 PEG-8 dimethicone 1.20 2-eth (hex I -methox cinnamate 9.00 4-but I-4-methox dibenzo (methane 3.00 Benzo henone 3 4.00 Dica ril I carbonate 6.00 Oct I triazone 3.00 Dimethicone and trimeth Isilox silicate2.70 C clo entasiloxane and dimethiconol 1.50 C clomethicone 3.00 BHT 0.05 Dica lic ether 3.00 Aluminum octen Isuccinate starch 6.00 Potassium cet I hos hate 2.00 N Ion 12 1.00 Demineralized water 3.00 Triethanolamine 0.60 Vitamin E acetate 0.50 L co ene extracted from tomato 0.002 Glycospheres of OPC (Palmitoyl hydroxypropyl0.02 trimonium amilopectine/glycerin crospolymer, lecitin, ra e-seed extract Sunflower-seed extract 0.25 PEG-5 cocoate, PEG-8 dicocoate and 0.20 iodopro-in I but Icarbamate PEG-4 Phenox ethanol 1.00 Com onent Function Demineralized water Vehicle Disodic EDTA Se uesterin a ent GI cerin Moistenin a ent Seaweed extract Active Cros of mers of ac lates/C~ 0-30 alk ThiclCenin a ent ( ac late Xanthan um Thickenin a ent Stea I dimethicone Emollient PEG-8 dimethicone Co-emulsifier 2-eth hex I -rnethox cinnamate Sunscreen 4-but -4-methox dibenzo (methane Sunscreen Benzo henone 3 Sunscreen Dica ril I carbonate Emollient Oct I triazone Sunscreen Dimethicone and trimeth Isilox silicateEmollient C clo entasiloxane and dimethiconol Emollient C clomethicone Emollient BHT Antioxidant a ent Aluminum octen Isuccinate starch Oiliness adsorbin a ent Potassium cet I hos hate Emulsifier N Ion 12 Oiliness adsorbin a ent Demineralized water Vehicle Triethanolamine H ad'uster Vitamin E acetate Antioxidant a ent L co ene extracted from tomato Antioxidant a ent Glycospheres of OPC (Palmitoyl hydroxypropylAntioxidant agent trimonium amilopectine/glycerin crospolymer, lecitin, ra e-seed extract Sunflower-seed extract Antioxidant a ent PEG-5 cocoate, PEG-8 dicocoate and Preserving agent iodopro-in I but Icarbamate PEG-4 Phenox ethanol Preservin a ent Example 5 - SPF 30 Protecting Gel Com onent Amount % b wei ht Neutral 96 eth I alcohol Qs 100 H drox ro (cellulose 1.10 2-eth (hex I -methox cinnamate 9.00 Benzo henone 3 4.00 4-but I-4-methox dibenzo (methane 2.00 Oct I triazone 3.00 BHA 0.05 Cet I lactate 1.00 Stea I dimethicone 1.00 PEG-8 dimethicone 0.80 Dimethicone and trimeth Isilox silicate1.70 C clo entasiloxane and dimethiconol 0.75 Vitamin E acetate 0.50 L co ene extracted from tomato 0.002 Glycospheres of OPC {Palmitoyl hydroxypropylfl.02 trimonium amilopectine/glycerin crospolymer, lecitin, ra e-seed extract Sunflower-seed extract 0.25 PEG-5 cocoate, PEG-8 dicocoate and 0.20 iodopro-in I PEG-4 but Icarbamate Phenox ethanol 1.00 Com onent Function Neutral 96 eth I alcohol Vehicle H drox ro (cellulose Thickenin a ent 2-eth (hex I p-methoxicinnamate Sunscreen Benzo henone 3 Sunscreen 4-but I-4-methox dibenzo (methane Sunscreen Oct I triazone Sunscreen BHA Antioxidant a ent Cet I lactate Emollient Stea I dimethicone emollient PEG-8 dimethicone Co-emulsifier Dimethicone and trimeth Isilox silicateEmollient C clopentasiloxane and dimethiconol Emollient Vitamin E acetate Antioxidant a ent L co ene extracted from tomato Antioxidant a ent Glycospheres of OPC (Palrnitoyl hydroxypropylAntioxidant agent trimonium amilopectine/glycerin crospolymer, lecitin, ra e-seed extract Sunflower-seed extract Antioxidant a ent PEG-5 cocoate, PEGB-dicocoate and Preserving agent iodopro-in I PEG-4 but Icarbamate Phenox ethanol Preservin a ent Example 6 - SPF 30 Lip Protector Com onent Amount % b wei ht Dica ril I carbonate 39.74 Microc stalline wax 16.80 Carnauba wax 5.76 Shea butter 3.50 Vitamin E acetate 0.50 Bee wax 3.40 Ozokerite wax 3.75 GI cerin behenate 1.00 Stea I dimethicone 0.50 PEG-8 dimethicone 0.70 Dimethicone and trimeth Isilox silicate2.30 C clo entasiloxane and dimethiconol 1.20 2-eth Ihex I -methoxicinnamate 7.50 4-but I-4-methoxydibenzo~rl-methane 4.00 Benzo henone 3 6.00 Oct I triazone 3.00 Meth I arabene 0.20 Pro I arabene 0.10 BHT 0.05 Com onent Function Dica ril I carbonate Emollient Microc stalline wax Emollient Carnauba wax Emollient Shea butter Emollient Vitamin E acetate Antioxidantent a Bee wax Emollient Ozokerite wax Emollient GI cerin behenate ~ Emollient Stea I dimethicone Emollient PET-8 dimethicone Co-emulsifier Dimethicone and trimeth Isiilox silicateEmollient C clo entasilocane and dimethiconol Emollient 2-eth (hex I -methox cinnamate . Sunscreen 4-but I-methoxidibenzo (methane Sunscreen Benzo henone 3 Sunscreen Oct I triazone Sunscreen Meth I arabene Preservin ent a Pro I arabene Preservin ent a BHT Antioxidantent a Example 7 - SPF 30 Baby Protecting Emulsion Com onent Amount % b wei ht C clomethicone 24.80 Titanium dioxide 16.00 C clomethicone and dimethicone co of 10.00 of Cet I dimethicone co of of 5.00 Tri I ce I-4 isostearate 2.00 Demineralized water 15.00 Xanthan um 0.1fl Disodic EDTA 0.05 Sodium chloride 1.50 Demineralized water 15.5410 But lane lycol 3.00 Pol sorbate 20 0.10 Triethanolamine 0,.009 Phenox ethanol 1.00 Vitamin E acetate 0.50 PEG-5 cocoate and PEG-8 dicocoate and 0.20 iodopro-in I but Icarbamate and PEG-4 Stearate dimethicone 1.00 PEG-8 dimethicone 0.80 Dimethicone and trimeth Isilox silicate2.20 C clo entasiloxane and dimethiconol 1.20 Component Function C clomethicone Emollient Titanium dioxide Sunscreen C clomethicone and dimethicone co of Emulsifier of Cet I dimethicone co of of Co-emulsifier Tri I ce I-4 isostearate Emollient Demineralized water Vehicle Xanthan um Thickenin a ent Disodic EDTA Se uesterin a ent Sodium chloride Stabilizin a ent Demineralized water Vehicle But lene I col Moistenin a ent Pol sorbate 20 Co-emoulsifier Triethanolamine H ad'uster Phenox ethanol Preservin a ent Vitamin E acetate Antioxidant a ent PEG-5 cocoate and PEG-8 dicocoate and Preserving agent iodopro-in I but Icarbamate and PEG-4 Stea I dimethicone Emollient PEG-8 dimethicone Co-emulsifier Dimethicone and trimeth Isilox silicateEmollient C clo entasiloxane and dimethiconol Emollient Example 8 - Hair Protecting Sunscreen Com onent Amount % b wei ht Demineralized water 61.8280 Disodic EDTA 0.10 Carbomer 0.35 Xanthan um 0.20 GI cerin 5.00 Dica ril I carbonate 2.00 C~2-~5 alk I benzoate 5.00 Dimethicone and trimeth Isilox silicate2.00 PEG-8 dimethicone 1.00 Stea I dimethicone 1.00 BHT 0.05 Cinnamido ro Itrimonium chloride 1.0 Dimeth I abamido ro I Ilaurdimonium 0.5 tos late Pol uaternium 37 and ro lene I col 4.00 Demineralized water 3.00 Triethanolamine 3.00 C clomethicone 2.00 C clo entasiloxane and dimethiconol 1.00 Vitamin E acetate 0.50 L co ene extracted from tomato 0.002 ~Glycospheres of OPC (Palmitoyl hydroxypropyl0.02 trimonium amilopectine/glycerin crospolymer, leci-tin, ra e-seed extract Sunflower-seed extract 0.25 PEG-5 cocoate and PEG-8 dicocoate and 0.20 iodopro-in I but Icarbamate and PEG-4 Phenox ethanol 1.00 Com onent Function Demineralized water Vehicle Disodic EDTA Se uesterina ent Carbomer Thickenin ent a Xanthan um Thickenin ent a GI cerin Moistenin ent a Dica ril I carbonate Emollient C12-15 alk 1 benzoate Emollient Dimethicone and trimeth IsiloxisilicateEmollient PEG-8 dimethicone Co-emulsifier Stea I dimethicone Emollient BHT Antioxidantent a Cinnamido ro Itrimonium chloride Sunscreen Dimeth I abamido ro I laurdimonium Sunscreen tos late Pol uaternium 37 and ro lene I co) Emulsifier Demineralized water Vehicle Triethanolamine H ad'uster C clomethvicone Emollient C clo entasiloxane and dimethiconol Emollient Vitamin E acetate Antioxidant a ent L co ene extracted from tomato Antioxidant a ent Glycospheres of OPC (Palmitoyl hydroxypropylAntioxidant agent trimonium amilopectine/glycerin crospolymer, lecitin, rape-seed extract Sunflower-seed extract Antioxidant a ent PEG-5 cocoate and PEG-8 dicocoate Preserving agent and iodo-ro in I but Icarbamate and PEG-4 Phenox ethanol Preservin a ent

Claims (30)

1. A cosmetic composition characterized by comprising a filmo-genic system containing at least cyclopentasiloxane, dimethiconol, dimethi-cone, trimethylsiloxysilicate and stearyl dimethicone and an emulsifying sys-tem containing at least PEG-8 dimethicone.

2. A cosmetic composition according to claim 1, characterized in that the amount of the filmogenic system ranges from 0.3% to 92,0% by weight.

3. A cosmetic composition according to claim 3, characterized in that the amount of the filmogenic system ranges from 0.5% to 50.0% by weight.

4. A cosmetic composition according to claim 1, characterized in that the amount of the emulsifying system ranges from 0.1% to 28.0% by weight.

5. A cosmetic composition according to claim 4, characterized in that the amount of the emulsifying system ranges from 0.3% to 12.0% by weight.

6. A cosmetic composition according to claim 1, characterized in that the filmogenic system comprises a silicone agent selected from the group consisting of cyclomethicone, alkyldimethicone, dimethicone copolyol, dimethiconol, phenyl trimethicone, caprilyl trimethicone, aminofunctional sili-cones, phenyl modified silicones, phenyl trimethicone, alkyl modified silicones, dimethyl and diethyl polysiloxane, mixed C1-C30 alkyl polysiloxane, dimethyl siloxane, o polymethylsiloxane, .alpha.-methyl-.omega.-methoxypolymethylsiloxane, po-lyoxydimethylsilylene, polydimethyl silicone oil, silicone elastomers such as cyclomethicone and dimethicone crospolymer, vinyl dimethicone and dime-thicone crospolymer, dimethicone and dimethicone crospolymer and cyclo-pentasiloxane and dimethicone crospolymer, polymers such as polyvinyl pyr-rolidone and polyvinyl alcohols and combinations thereof.

7. A cosmetic composition according to claim 1, characterized in that the emulsifying system comprises an additional emulsifying system se-lected from the group consisting of: soybean lecitin, nonyl phenol ethoxylate, sodium or potassium alkyl phosphates, diethanolamine cetyl phosphate, di-methicone co-polymers such as modified polyoxyalkylene dimethylpolysilo-xanes, methyl glucose, propylglyceryl glucose, ethoxylated glycols, non-ethoxylated glycols, ethoxylated fatty acids, non-ethoxylated fatty acids, ethoxylated sucrose, non-ethoxylated sucrose, ethoxylated pentaeritritol, non-ethoxylated pentaeritritol, ethoxylated alkyl glycosides, non-ethoxylated alkyl glycosides, ethoxylated alkyl polyglicosides, propyleneglycol, esters such as glyceryl stearate, ethoxylated sorbitan esters, non-ethoxylated sor-bitane esters, such as sorbitan stearate, ethoxylated sorbitan stearate, po-lysorbate 80, polysorbate 65, polysorbate 60, polysorbate 40, polysrobate 20, polyquatemium 37, glycol stearate, PEG-2 stearate, PEG-10 stearate, PEG-30 stearate, PEG-40 stearate, PEG-100 stearate, PEG-150 stearate, PEG-1000 stearate, sorbitane palmitate, propylene glycol stearate, propylene glycol PEG-25 stearate, sorbitan oleate, methyl glucose sesquistearate, fatty alco-hols such as cetyl alcohol, stearyl alcohol, cetearyl alcohol, propoxylated and/or ethoxylated fatty alcohols, synthetic polymers formed by carbo-xyvinylic polymers and copolymers, acrylates, metjacrylates, alkyl acrylates, croacrylates / C10-C30 alkyl crospolymer, acrylamides, taurates, ethylene oxi-de and propylene oxide copolymers, and combinations thereof and derivati-ves thereof.

8. A cosmetic composition according to claim 1, characterized by comprising a sunscreen system in an amount ranging from 0.1% to 50.0% by weight.

9. A cosmetic composition according to claim 8, characterized by comprising a sunscreen system in an amount ranging from 1:0% to 30.0% by weight.

10. A cosmetic composition according to claim 9, characterized in that the sunscreen system is composed of a combination between: ben-zylidene camphor, isophthalylidene camphor, terephthalyllidene camphor, cinnamic acid, salicylic acid, benzoic acid, p-aminobenzoic acid, substituted hydrozibenzophenones, substituted dibenzoylmethane, benzotriazol such as 2-arylbenzotriazol, 2-arylbenzimidazol, 2-arylbenzofuranes, 2-arylbenzoxazol, 2-arylindol, mono-phenylcyanoacrylates, diphenylcyanocarylates, triazine derivatives such as hydroxyphenhyltriazine compounds and benzotriazol de-rivatives, amides containing a vinyl group, cinnamic acid derivatives, sulfo-nated benzimidazoles, diphenylmalonitriles, oxalylamides, canphor derivati-ves, salicylic acid derivatives such as 2-ethylhexyl salicylates, homosalates and isopropyl salicylates, diphenylacrylates, benzophenone derivatives such as benzophenone-2, benzophenone-3 and benzophenone-4, PABA such as 2-ethylhexyl 4-dimethylamminobenzoate, N,N,N-trimethyl-4-(2-oxoborn-3-ylideneomethyl) anilinomethyl sulfate, 3,3'-(1,4-phenylenedimethylene) bis (7,7-dimethyl-2-oxo-bicyclo-(2.2.1) 1-hepthylmethanosulfonic acid; 1-(4-terc-butylphenyl)-3-(4-methoxyphenyl) propane-1, 3-dione; .alpha.-(2 oxobom-3-ylidene) toluene-4-sulfonic acid and its salts of potassium, sodium and trietanolamine;
2-ethylexyl 2-cyano-3, 3'-diphenylacrylate; 2-ethoxyethyl 4-methoxycinnamate;
2,2'-dihydroxy-4-methoxybenzophenone; methyl anthanilate; trietanolamine salicylate; 2,2',4,4' tetrahydroxybenzophenone; 2-phenylbenzimidazol-5 sul-fonic acid and its salts of potassium, sodium and trietanolamine; 2-ethylhexyl 4-methoxycinnamate; 2-hydroxy-4-methoxybenzophenone (oxybenzone); 2-hydroxy-4-methoxybenzophenone sulfonic acid and its salt of sodium .(suli-sobenzone and sodic sulisobenzone); 4 aminobenzoic PABA acid; homo-methyl salicylate; N-{(2 and 4) [(2 oxobom-3-ylidene) methyl] benzyl}
acrylamide polymer; titanium dioxide (with or without lipophilic coating); ethyl N-ethoxy-=aminobenzoate; 2-ethylhexyl 4-dimethyl aminobenzoate; 2-ethylhexyl sali-cylate; isopentyl 4-methoxycinnamate;3-(4'-methylbenzylidene-d-1-camphor;
3-benzylidene camphor; 2,4,6- trianiline-(p-carbo-2-ethyl-hexyl-I'-oxy)-1,2,5-triazine octyl; zinc oxide (with or without lipophilic coating); 2-(2H-benzotri-azol-2-yl)-4-methyl-6-(2-methyl-3-(1,3,3,3-tetramethyl-1-((trimethylsilyl) oxy) disiloxanyl) propyl} phenol; benzoic acid; 4,4'-[[6-[[4-[[(1,1-dimethyl-ethyl]
amino]
carbonyl] phenyl] amino]-1,3k,5-triazine-2,4-diyl] diimino] bis, bis (2 ethylhe-xyl); 2,2'-methylene-bis-6-(2H-benzotriazol-2-yl)-4-(tetramethyl butyl)-1,1,3,3-phenol; methylene bis-benzotriazolyl tetraethyl butyl phenol; monosodic salt of 2,2'-bis-(1,4-phenylene)-IH-benzimidazol-4, 6 disulfonic acid; (1, 3, 5)-triazine-2, 4-bis {[4-(2-ethyl-hexyloxy)-2-hydroxy]-6-(4-methoxyphenyl); bis-ethylexyloxyphenol methoxyphenyl triazine; methylene bis-benzotriazolyl te-tramethylbutyl-phenol; butyl methoxydibenzoylmethane, 2-ethylexyl p-metho-xycinnamate, methylene bis-benzotriazolyl tetramethylbutylphenol, 4-butyl-methoxydibenzolmethane, benzophenone 3, bis-ethylhexyloxyphenol metho-xyphenyl triazine, octhyl triazone, titanium dioxide and derivatives thereof and combinations thereof.

11. A cosmetic composition according to claim 10, characterized in that the sunscreen system is composed of benzophenone-3, butyl metho-xydibenzoylmethane, 2-ethylhexyl p-methoxycinnamate and bis-ethylhexy-phenol methoxyphenyl triazine.

12. A cosmetic composition according to claim 10, characterized in that the sunscreen system is composed of cinnamidopropyltrimonium chlo-ride and dimethylpabamidopropyl laurdimonium tosylate.

13. A cosmetic product characterized in comprising the cosmetic composition as defined in any one of the claims 1 to 12.

14. A cosmetic product according to claim 13, characterized by being a body sunscreen for skin of adults and children.

15. A cosmetic product according to claim 13, characterized by being a body or face hydrating product.

16. A cosmetic product according to claim 13, characterized by being a self-tanning product.

17. A cosmetic product according to claim 13, characterized by being a insect repellent product.

18. A cosmetic product according to claim 13, characterized by being a pharmaceutical preparation.

19. A cosmetic product according to claim 13, characterized by being a sunscreen for hair.

20. A cosmetic product according to claim 13, characterized by being a non-rinsable hair conditioner.

21. A cosmetic product according to claim 13, characterized by being a rinsable hair-preparation.

22. An use of the cosmetic composition as defined in claims 1 to 12, characterized by being for producing a cosmetic product for care or pro-tection of the skin or hair.

23. An use according to claim 22, characterized by the fact that the cosmetic product is a sunscreen for skin of adults and children.

24. An use according to claim 22, characterized by the fact that the cosmetic product is a body or face hydrating product.

25. An use according to claim 22, characterized by the fact that the cosmetic product is a self-tanning product.

26. An use according to claim 22, characterized by the fact that the cosmetic product is an insect repellent product.

27. An use according to claim 22, characterized by the fact that the cosmetic product is a pharmaceutical preparation.

28. An use according to claim 22, characterized by the fact that the cosmetic product is a sunscreen for hair.

29. An use according to claim 22, characterized by the fact that the cosmetic product is a non-rinsable hair conditioner.

30. An use according to claim 22, characterized by the fact that the cosmetic product is a rinsable hair preparation.