CA2598350A1 - Enhanced efficacy aluminum or aluminum-zirconium antiperspirant salt compositions containing calcium salt(s) and betaine - Google Patents

Enhanced efficacy aluminum or aluminum-zirconium antiperspirant salt compositions containing calcium salt(s) and betaine Download PDF

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Publication number
CA2598350A1
CA2598350A1 CA002598350A CA2598350A CA2598350A1 CA 2598350 A1 CA2598350 A1 CA 2598350A1 CA 002598350 A CA002598350 A CA 002598350A CA 2598350 A CA2598350 A CA 2598350A CA 2598350 A1 CA2598350 A1 CA 2598350A1
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CA
Canada
Prior art keywords
composition
weight
calcium
antiperspirant
total weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002598350A
Other languages
French (fr)
Other versions
CA2598350C (en
Inventor
Xiaozhong Tang
Marian N. Holerca
Donghui Wu
Christine Popoff
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Colgate Palmolive Co
Original Assignee
Colgate-Palmolive Company
Xiaozhong Tang
Marian N. Holerca
Donghui Wu
Christine Popoff
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Colgate-Palmolive Company, Xiaozhong Tang, Marian N. Holerca, Donghui Wu, Christine Popoff filed Critical Colgate-Palmolive Company
Publication of CA2598350A1 publication Critical patent/CA2598350A1/en
Application granted granted Critical
Publication of CA2598350C publication Critical patent/CA2598350C/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/28—Zirconium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/26—Aluminium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q15/00—Anti-perspirants or body deodorants

Abstract

An antiperspirant composition comprising an antiperspirant salt selected from an aluminum antiperspirant salt, an aluminum-zirconium antiperspirant salt, and a mixture thereof; a betaine component selected from betaine, betaine hydrochloride, and a mixture thereof; a calcium salt; and water.

Claims (45)

1. An antiperspirant composition comprising:
(a) an antiperspirant salt selected from the group consisting of an aluminum antiperspirant salt, an aluminum-zirconium antiperspirant salt, and a mixture thereof;

(b) a betaine component selected from the group consisting of betaine, betaine hydrochloride, and a mixture thereof; and (c) a calcium salt.
2. The composition of claim 1, further comprising water.
3. The composition of claim 1, wherein said calcium salt component (c) together with said betaine component (b) is provided in an amount sufficient to increase a first ratio of an HPLC peak 4 area to peak 3 area, said peak 4 area being proportional to a first amount of a polymer of said antiperspirant salt and said peak 3 area being proportional to a second amount of a larger polymer of said antiperspirant salt.
4. The composition of claim 3, wherein said first ratio is increased to at least about 0.5.
5. The composition of claim 4, wherein said first ratio is increased to at least about 1.0
6. The composition of claim 5, wherein said first ratio is increased to at least about 2.
7. The composition of claim 6, wherein said first ratio is increased to at least about 3.
8. The antiperspirant composition of claim 7, wherein said first ratio is increased to at least about 4.
9. The composition of claim 1, wherein said antiperspirant salt is said aluminum-zirconium antiperspirant salt, wherein said calcium salt component (c) together with said betaine component (b) is provided in an amount sufficient to decrease a second ratio of the peak area of HPLC peak 1 to a sum of the peak areas of HPLC peaks 2, 3, 4 and 5.
10. The composition of claim 9, wherein said second ratio is decreased to less than about 0.4.
11. The composition of claim 10, wherein said second ratio is decreased to less than about 0.3.
12. The composition of claim 11, wherein said second ratio is decreased to less than about 0.2.
13. The composition of claim 12, wherein said second ratio is decreased to less than about 0.1
14. The composition of claim 13, wherein said second ratio is 0.
15. The composition of claim 1, wherein said component (b) is provided in an amount from about 0.5 to about 40 wt % based on a total weight of said antiperspirant composition.
16. The composition of claim 1, wherein said component (c) is provided in an amount from about 0.2 to about 80 wt % based on a total weight of said antiperspirant composition.
17. The composition of claim 1, wherein said calcium salt is selected from the group consisting of calcium chloride, calcium bromide, calcium nitrate, calcium citrate, calcium formate, calcium acetate, calcium gluconate, calcium ascorbate, calcium lactate, calcium glycinate, calcium carbonate, calcium sulfate, calcium hydroxide and mixtures thereof.
18. The composition of claim 1, wherein said component (a) is provided in an amount from about 5% by weight to about 85% by weight based on a total weight of said antiperspirant composition.
19. The composition of claim 1, wherein said calcium salt component (c) together with said betaine component (b) is provided in an amount sufficient to increase an peak intensity at 63.5 ppm.
20. The composition of claim 19 wherein said increase in said 27 AI NMR peak intensity is at least about 20%.
21. The composition of claim 20 wherein said increase in s said 27A1 NMR peak intensity is at least about 100%.
22. The composition of claim 21 wherein said increase in said 27A1 NMR peak intensity is at least about 300%.
23. The composition of claim 22 wherein said increase in said 27A1 NMR peak k intensity is at least about 500%.
24. The composition of claim 23 wherein said increase in said 27A1 NMR peak intensity is at least about 700%.
25. The composition of claim 24 wherein said increase in said 27 AI NMR peak intensity is at least about 900%.
26. The composition of claim 1, wherein the antiperspirant salt is in the range from 5 -85 weight % based on a total weight of said antiperspirant composition.
27. The composition of claim 26, wherein the antiperspirant salt is in the range from about 10 - 60 weight % based on the total weight of said antiperspirant composition.
28. The composition of claim 27, wherein the antiperspirant salt is in the range from about 15 - 35 weight % based on the total weight of said antiperspirant composition.
29. The composition of claim 1, wherein the betaine component (b) is present in an amount of at least about 0.1 weight % based on a total weight of said composition.
30. The composition of claim 29, wherein the betaine component (b) is in the range from about 0.5 - 40 weight % based on the total weight of said composition.
31. The composition of claim 30, wherein the betaine component (b) is in the range from about 2.0 - 30 weight % based on a total weight of said composition.
32. The composition of claim 31, wherein the betaine component (b) is in the range from about 4.0 - 20 weight % based on the total weight of said composition.
33. The composition of claim 1, wherein the calcium salt component (c) is present in an amount of at least about 0.1 weight % based on a total weight of said composition.
34. The composition of claim 33, wherein the calcium salt component (c) is in the range from about 0.2 - 80 weight % based on the total weight of said composition.
35. The composition of claim 34, wherein the calcium salt component (c) is in the range from about 0.4 - 40 weight % based on the total weight of said composition.
36. The composition of claim 35, wherein the calcium salt component (c) is in the range from about 0.5 - 10 weight % based on the total weight of said composition.
37. The composition of claim 1, further coinprising a water soluble alcohol.
38. The composition of claim 37, wherein said water soluble alcohol is a C2-C8 alcohol.
39. The antiperspirant composition of claim 38, where said water soluble alcohol is ethanol.
40. The composition of claim 37, wherein said water soluble alcohol is selected from the group consisting of glycol, propylene glycol, dipropylene glycol, tripropylene glycol and mixtures thereof.
41. The composition of claim 1, further comprising glycine in an amount from about 0 - 40 weight % based on a total weight of said composition.
42. The composition of claim 41, wherein said glycine is provided in an amount from about 1- 30 weight % based on the total weight of said composition.
43. The composition of claim 42, wherein said glycine is provided in an amount from about 2- 20 weight % based on the total weight of said composition.
44. The composition of claim 43, wherein said glycine is provided in an amount from about 8 - 10% based on the total weight of said composition.
45. The composition of claim 1, wherein the composition is in the form of a powder, a liquid, a gel, or a solid.
CA2598350A 2005-02-18 2006-02-14 Enhanced efficacy aluminum or aluminum-zirconium antiperspirant salt compositions containing calcium salt(s) and betaine Expired - Fee Related CA2598350C (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US65407005P 2005-02-18 2005-02-18
US60/654,070 2005-02-18
US11/348,499 US7704531B2 (en) 2005-02-18 2006-02-06 Enhanced efficacy aluminum or aluminum-zirconium antiperspirant salt compositions containing calcium salt(s) and betaine
US11/348,499 2006-02-06
PCT/US2006/005054 WO2006091417A1 (en) 2005-02-18 2006-02-14 Enhanced efficacy aluminum or aluminum-zirconium antiperspirant salt compositions containing calcium salt(s) and betaine

Publications (2)

Publication Number Publication Date
CA2598350A1 true CA2598350A1 (en) 2006-08-31
CA2598350C CA2598350C (en) 2011-04-19

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CA2598350A Expired - Fee Related CA2598350C (en) 2005-02-18 2006-02-14 Enhanced efficacy aluminum or aluminum-zirconium antiperspirant salt compositions containing calcium salt(s) and betaine

Country Status (11)

Country Link
US (1) US7704531B2 (en)
EP (1) EP1853222B1 (en)
AR (1) AR053547A1 (en)
AU (1) AU2006216930B2 (en)
BR (1) BRPI0607766A2 (en)
CA (1) CA2598350C (en)
ES (1) ES2476421T3 (en)
MX (1) MX2007010017A (en)
PL (1) PL1853222T3 (en)
RU (1) RU2007134576A (en)
WO (1) WO2006091417A1 (en)

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US7704531B2 (en) 2010-04-27
WO2006091417A1 (en) 2006-08-31
BRPI0607766A2 (en) 2010-03-23
EP1853222B1 (en) 2014-05-28
AU2006216930B2 (en) 2009-08-20
RU2007134576A (en) 2009-03-27
AU2006216930A1 (en) 2006-08-31
AR053547A1 (en) 2007-05-09
ES2476421T3 (en) 2014-07-14
US20060204463A1 (en) 2006-09-14
CA2598350C (en) 2011-04-19
PL1853222T3 (en) 2015-02-27
MX2007010017A (en) 2007-10-04
EP1853222A1 (en) 2007-11-14

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