CN101132756B - Personal care composition containing hydrophobically modified polymers - Google Patents

Personal care composition containing hydrophobically modified polymers Download PDF

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Publication number
CN101132756B
CN101132756B CN2006800065245A CN200680006524A CN101132756B CN 101132756 B CN101132756 B CN 101132756B CN 2006800065245 A CN2006800065245 A CN 2006800065245A CN 200680006524 A CN200680006524 A CN 200680006524A CN 101132756 B CN101132756 B CN 101132756B
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cosmetic
hair
acceptable composition
polymer
hydrophobically modified
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CN101132756A (en
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劳拉雷·勃兰特
杰弗里·克拉姆
丹姆岩蒂·帕特尔
伊恩·Z·海塞弗特
韦恩·M·卡尔森
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Lubrizol Advanced Materials Inc
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/88Polyamides
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/10Washing or bathing preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/02Preparations for cleaning the hair
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/04Preparations for permanent waving or straightening the hair
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/06Preparations for styling the hair, e.g. by temporary shaping or colouring
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/12Preparations containing hair conditioners

Abstract

A cosmetically acceptable composition comprising one or more hydrophobically modified polyacrylamides prepared by incorporating hydrophobic moieties into a polymer composed acrylamide, one or more cationic monomers and optionally one or more anionic monomers. The composition may be incorporated into products for treating hair, skin and nails and also into household products such as household cleaners and laundry detergents.

Description

The personal care composition that contains hydrophobically modified polymers
Technical field
Upward (cosmetically the present invention relates to make up) acceptable composition; Said compositions contains polyacrylamide; Said polyacrylamide is by acrylamide, one or more cationic monomers and choose any one kind of them or multiple anionic monomer is formed (composed of); Wherein said polyacrylamide is modified through mixing of hydrophobic group, the invention still further relates to use said compositions to be used for treatment of hair, skin and fingernail (nails) method.
Background of invention
20 years in the past, if personal care industry has developed the hydrophobically modified (modified that becomes owner of in the thickening field) scope of polymer.This composition comprises the hydroxyethyl-cellulose and the acrylic ester (acrylates of modification)/behenyl alcohol polyethers-25 methacrylate (Beheneth-25Methacrylate).
The principle of novel polymer that preparation contains various alkyl be introduce can not be separately through unmodified acrylates (acrylate) or the character of acrylamide polymer realization.Although constantly introduce new polymerization product, monomeric quaternary salt (quaternaries), fatty amine and aliphatic alcohol and softening agent (emollients) continue in the personal care product, to play important effect.Many products contain a spot of at least these materials.Yet, these regulators (conditioning agents) and can go up accumulation in substrate (for example hair) in time, thereby reduce the intensity (volume of hair).Therefore, just have the demand to new product, said new product has the character that can not pass through the conventional polymer acquisition and does not have the shortcoming relevant with the monomer material of present use.
Summary of the invention
The present invention make up to go up acceptable compositions, and said compositions comprises one or more hydrophobically modified polyacrylamides, and wherein said polyacrylamide is by acrylamide, one or more cationic monomers and choose any one kind of them or multiple anionic monomer is formed.
According to the type of the hydrophobic part that mixes polymer, the character that said hydrophobically modified polyacrylamide has improved for example creaminess, slip, sensation, viscosity and preserved moisture.
Detailed Description Of The Invention
" anionic monomer " expression is like the monomer of this paper definition, and it has the net negative charge that is higher than a certain pH value.Representational anionic monomer comprises: acrylic acid base addition salts; The base addition salts of methacrylic acid; The base addition salts in itaconic acid; The base addition salts of 2-acrylamido (acrylamido)-2-methyl-1-propane sulfonic acid; Sulfopropyl acrylic ester or sulfopropyl methacrylate (sulfopropyl acrylateor methacrylate) base addition salts; Perhaps these or other polymerizable (polymerizable) base addition salts of the acrylamide base addition salts of other water-soluble forms of carboxylic acid or sulfonic acid, sulfomethylated (sulphomethylated); Allylsulfonate (allyl sulphonate) base addition salts; The base addition salts of styrene sulfonic acid; Sodium vinyl sulfonate and analog.The preferred anionic surfactants monomer is acrylic acid and 2-acrylamido-2-methyl-1-propane sulfonic acid.
" base addition salts " expression salt that reactions generated: carboxylic acid (-CO < > 2 <> H) the suitable alkali of hydroxide, carbonate or the bicarbonate of group and for example metal cation or tetraalkylammonium cation, or with ammonia or fully organic primary amine, secondary amine or the reactive tertiary amine of alkalescence, have the salt of hydroxy-acid group with generation.Representational alkali metal or alkali salt comprise sodium, lithium, potassium, calcium, magnesium and analog.The representational organic amine that is used to generate base addition salts comprises ethamine, diethylamine, ethylenediamine, ethanolamine, diethanolamine, piperazine and analog.Preferred base addition salts comprises sodium salt and ammonium salt.
" cationic monomer " expression is adapted at also can be at the vinyl monomer of the clean positive charge of commentaries on classics acylamino-reaction back maintenance as described herein with the acrylamide copolymerization under the free radical formation condition.Representational cationic monomer includes but not limited to have the monomer of following formula
R wherein < > 1 <>-R < > 13 <> Independently be selected from H ,-CH < > 3 <> With-CH < > 2 <> CH < > 3 <> And n is 2 or 3.
" IV " representing characteristic viscosity (intrinsic viscosity), it is the RSV that is extrapolated to the infinite dilution limit, and infinite dilution is that polymer concentration is when equalling zero.
" hydrophobic alkyl (Hydrophobic alkyl group) " expression about 4 alkyl (alkyl), alkenyl, cycloalkyl, aryl or aryl (arylalkyl group) to about 22 carbon atoms.Alkyl and alkenyl can be straight or brancheds, and can be interrupted by one or more-OSi(R ')(R ")-with-Si(R ')(R ")-group, and wherein R ' and R " are C < > 1 <>-C < > 4 <> Alkyl.
The such chemical compound of " hydrophobic amine " expression: contain at least one hydrophobic alkyl and at least one amino hydrogen atom, its can with the amide (-C(O of the polyacrylamide of this paper definition) NH < > 2 <> ) reaction of group generation commentaries on classics acylamino-, to generate the polyacrylamide of hydrophobically modified.The hydrophobic amine that contains-OSi(R ')(R ")-with-Si(R ')(R ")-group also is called as " silane of aminofunctional ".Representational hydrophobic amine comprises benzylamine, cyclohexylamine, hexylamine, tuaminoheptane, phenethylamine, octylame, oleyl amine, decyl amine, lauryl amine, octadecylamine and analog.
Representational aminofunctional silane comprises: the amine of following formula
Wherein p is from about 5 to about 500, available from Aldrich, Milwaukee, WI; amino ethyl propyl siloxane (silicone) compound, available from Noveon, Cleveland, OH (trade name Ultrasil) and Siltech Corporation, Toronto, Ontario, Canada (tradename Silamine); and amine functional siloxane, including all obtained from Dow Corning, Midland, MI for DowCorning
Figure G200680006524501D00042
8220, Dow Corning
Figure G200680006524501D00043
939, Dow Corning
Figure G200680006524501D00044
949, Dow Corning
Figure G200680006524501D00045
2-8194, and obtained from the General Electric, Waterford, NY is Silicone SM 253.
The polyacrylamide of " hydrophobically modified polymers " and " hydrophobically modified polyacrylamide " expression this paper definition is wherein along polymer backbone (backbone) a part of amide groups (-C(O) NH < > 2 <> ) transamidation of group through the hydrophobic amine (modified that is modified).Therefore; Except repetitive from cationic monomer and any anionic monomer; Said hydrophobically modified polymers comprises the repetitive with following structure, and wherein RaRb represents the hydrophobic group that generates with the hydrophobic amine transamidation, and M is H or base addition salts.
Figure G200680006524501D00046
" polyacrylamide " expression is by acrylamide defined herein, one or more cationic monomers and any anionic monomer polymerization and the polymer that generates under the free radical formation condition.Suitable polyacrylamide can commercial obtain to be emulsion (emulsion), dispersion (dispersion), solution and powder type, the standard method of radical polymerization that perhaps can be through being used for vinyl monomer prepares.
" RSV " represents reduced viscosity.Or in a series of substantially linear polymers with a good solvent of Homologue in the dilute polymer solution of the "viscosity (RSV)" measurements indicate the polymer chain length and average molecular weight, according to Paul J. Flory, in "Principles of Polymer Chemistry (polymer chemistry)", Cornell University Press, Ithaca, NY.,
Figure G200680006524501D00051
1953, Chapter VII, "Determination of Molecular Weights (molecular weight determination) "on pages 266-316.Under given polymer concentration and temperature, measure RSV and calculating as follows:
RSV = [ ( &eta; / &eta; o ) - 1 ] c
The viscosity of η=polymer solution
η < > 0 <> The viscosity of solvent under the=uniform temp
The concentration of polymer in the c=solution
Concentration unit " c " is (gram/100ml or a g/ decilitre).Therefore, the unit of RSV is dL/g.In present patent application, except as otherwise noted, use 1.0 moles sodium chloride solution to be used to measure RSV.Polymer concentration is 0.100g/dL in this solvent.Measure RSV down at 30 ℃.Use CannonUbbelohde semimicro dilution viscometer (size 75) to measure viscosities il and viscosities il < > 0 <> The complete plumbness of said viscometer places the constant temperature bath that transfers to 30 ± 0.02 ℃.Inherent error is about 2dL/g in RSV calculates.Two polymer homologs have similar RSV in a series of, then indicate them to have similar molecular weight.
Nontoxic, the non-stimulated material of " acceptable excipient in the cosmetic " expression, when mixing with hydrophobically modified polymers of the present invention, it makes said polymer be more suitable for being applied to hair or skin.
In one embodiment, through heating under the temperature and pressure that raises, use about 0.1 one or more about 10% mole hydrophobic amines to carry out the amide (-C(O of PAMC) NH < > 2 <> ) transamidation of group prepares hydrophobically modified polymers of the present invention.Can add alkali to keep hydrophobic amine in its alkalescence but not protonated form.Suitable alkali comprises the hydroxide and the carbonate of ammonia and alkali metal and alkaline-earth metal.
In one embodiment, said PAMC with from sodium pyrosulfite (sodiummetabisulfite) and the sulfite solution processed of sodium hydroxide under the about 9-10 of pH, in the stainless steel pressure reaction vessel, mix.Add said hydrophobic amine, use the air in the nitrogen substitution reaction device.Said mixture heated about 0.5 hour to about 8 hours down at about 120 ℃ to about 180 ℃.In one embodiment, said mixture heated about 5 hours down at about 140 ℃.Make water that the hydrophobically modified polymers that is generated is diluted to the concentration of hope then, and choose wantonly and use one or more antiseptic to handle at elevated temperatures.In one embodiment, use methyl parahydroxybenzoate and propyl p-hydroxybenzoate to handle said hydrophobically modified polymers solution 1 hour down at 5-90 ℃.Through viscosity, < > 13 <> C NMR, GC and GPC method characterize (characterize) product.
In one embodiment, said PAMC is by forming at least about 50% mole acrylamide.
In one embodiment, the RSV of said hydrophobically modified polymers about 0.1 is to about 8dL/g.
In one embodiment, said cationic monomer is selected from chlorination diallyl dimethyl ammonium (diallyldimethylammonium chloride) and methyl chloride acrylamido oxypropyl trimethyl ammonium (methacrylamidopropyltrimethylammonium chloride).
In one embodiment, said hydrophobic amine is selected from C < > 6 <>-C < > 22 <> Alkylamine (alkyl amines) and the group formed of the siloxanes of aminofunctional.
In one embodiment, the RSV of said hydrophobically modified polymers is about 1 to about 5.
In one embodiment, said PAMC is acrylamide/chlorination diallyl dimethyl ammonium copolymer.
In one embodiment, said PAMC is acrylamide/chlorination diallyl dimethyl ammonium/acrylic ternary copolymer.
In one embodiment, said alkylamine is selected from the group that octylame, lauryl amine and hexadecylamine are formed.
In one embodiment, said compositions further comprises one or more upward acceptable excipient of making up.
In one embodiment, acceptable composition comprises based on polymer solids about 0.01 hydrophobically modified polymers to about 40% weight in the said cosmetic.
In one embodiment, acceptable excipient is selected from saccharide, surfactant (surface-active agents in the said cosmetic), wetting agent, vaseline, mineral oil, aliphatic alcohol, fatty ester softening agent, wax and contain wax, silicone oil, the siloxanes liquid (silicone fluid of siloxanes), silicone surfactant (silicone surfactants), volatility hydrocarbon ils, quaternary nitrogen chemical compound, amine-functionalized siloxanes, telomerized polymer, rheology modifier, antioxidant, sunscreen actives agent, from about C < > 10 <> To C < > 22 <> Two long-chain amines, from about C < > 10 <> To C < > 22 <> Long-chain fat amine, aliphatic alcohol, the aliphatic alcohol and the two tail phospholipid (di-tail phospholipid of ethoxylation) group formed.
Representational saccharide comprises non-ionic or cationic saccharide; Agarose for example; Amylopectin; Amylose; ARABINANS (arabinans); Arabinogalactan; WU-AX Arabinoxylan (arabinoxylens); Antler glue; Radix Acaciae senegalis; Carboxymethyl guar glue; Carboxymethyl (hydroxypropyl) guar gum; The ethoxy guar gum; Carboxymethyl cellulose; Cation guar gum comprises the cellulose ether of methylcellulose; Chrondroitin; Chitin (chitins); Chitosan; Chitosan pyrrolidone carboxylic acid salt (chitosan pyrrolidone carboxylate); Chitosan oxyacetate (chitosan glycolate) chitosan lactate (chitosan lactate); Cocoyl Dimethyl Ammonium (cocodimonium) hydroxypropyl oxygen ethyl cellulose; Colominic acid (gathers-N acetyl-neuraminic acid); Corn starch; Curdlan; Dermatan sulfate (dermatin sulfate); Glucosan; Furcellaran (furcellarans); Glucosan; Crosslinked glucosan; Dextrin; Emulsion adhesive (emulsan); Ethylhydroxyethylcellulose; Semen Lini sugar (tart); Galactoglucomannan; Galactomannan; Glucomannan; Glycogen; Guar gum; Hetastarch; Hydroxypropyl emthylcellulose; Hydroxyethyl-cellulose; Hydroxypropyl cellulose; Hydroxypropyl starch; The guar gum of hydroxypropylation; Gel sugar natural gum (gellan gum); Gel sugar (gellan); Ficus elastica; Karaya; Gum tragacanth (tragacanthin); Heparin; Hyaluronic acid; Inulin (inulin); Keratin sulfate (keratin sulfate); Konjacmannan (konjac mannan); Modified starch; Laminariose (laminarans); Lauryl dimethyl ammonium (laurdimonium) hydroxypropyl oxygen ethyl cellulose; Flos abelmoschi manihot natural gum (okra gum); Oxytarch; Pectic acid; Pectin; Polydextrose; Polyquaternary ammonium salt (polyquaternium)-4; Polyquaternary ammonium salt-10; Polyquaternary ammonium salt-28; Potato starch; Pectin, proto; Psyllium seed natural gum (psylliumseed gum); Pullulan (pullulan); Hyaluronate sodium; Starch diethyllaminoethyl ether; Starch Hydroxyproyl Trimethyl ammonium chloride (starch hydroxypropyltrimonium chloride); Hydroxypropyl starch phosphate (hydroxyproyl starch phosphate); Stearyl Dimethyl Ammonium (steardimonium) hydroxyethyl-cellulose; Raffinose; Rhamnosan (rhamsan); Tapioca; Levan; Scleroglucan (scleroglucan); Sodium alginate; Stachyose (stachylose); Succinoglycan; Wheaten starch; Xanthan gum; Xylan; Xyloglucan and composition thereof.The microorganism saccharide can be referring to Kirk-Othmer < > Encyclopedia of ChemicalTechnology <> (chemical industry technology encyclopedia), the 4th edition, the 16th volume, John Wiley and Sons, NY 578-611 page or leaf (1994), its by reference mode all incorporate into.Compound saccharide (Complexcarbohydrates) can be referring to Kirk-Othmer < > Encyclopedia of Chemical Technology <> (chemical industry technology encyclopedia), the 4th edition, the 4th volume, John Wiley and Sons, NY 930-948 page or leaf, 1995, its this by reference mode incorporate into.
Acceptable composition can comprise surfactant in the cosmetic of the present invention.Surfactant comprises surfactant (surfactants), it typically is preparation provides dirt-removing functions property perhaps only to work as wetting agent.Surfactant generally is divided into anion surfactant, cationic surfactant, non-ionic surface active agent, amphoteric surfactant and zwitterionic surfactant.
The anion surfactant that this paper uses comprises United States Patent (USP) 5,573,709 those disclosed anion surfactants, its this by reference mode incorporate into.Instance comprises alkyl sulfate salt and alkyl ether sulphate salts (alkyl and alkyl ether sulfates).Can be used for concrete alkyl ether sulphate salts instance of the present invention is following sodium salt and ammonium salt: lauryl sulfate ester (lauryl sulfate), lauryl ether sulfuric ester (lauryl ether sulfate), Cortex cocois radicis alkyl 2,2'-ethylenedioxybis(ethanol). ether sulfuric ester (coconut alkyltriethylene glycol ether sulfate); Tallow alkyl 2,2'-ethylenedioxybis(ethanol). ether sulfuric ester (tallow alkyltriethylene glycol ether sulfate) and tallow alkyl hexaoxyethylene sulfuric ester (tallow alkylhexaoxyethylene sulfate).Preferred alkyl ether sulphate salts is those alkyl ether sulphate salts that comprise the mixture of single chemical compound; The mean alkyl chain of said mixture is long for from about 12 to about 16 carbon atoms, average ethoxylation (ethoxylation) degree is to about 6 moles of ethylene oxide from about 1.
The anion surfactant of another suitable classification is alkyl sulfate (alkyl sulfuric acidsalts).Important instance according to known method of sulfonating (comprise bleaching and hydrolysis) obtain, methane series hydrocarbon (comprise have about 8 to about 24 carbon atoms, preferred about 12 to about 18 carbon atoms different-, new-, ineso-and n-paraffin (paraffins)) and sulfonating agent (SO for example < > 3 <> , H < > 2 <> SO < > 4 <> , oleum) the salt of organic sulfur acid reaction product.The Sulfated C of alkali metal and ammonium preferably < > 12-38 <> N-paraffin.
Other synthetic anion surface active agent comprises alkene sulfonate, β-alkoxyl alkyl sulfonate and through the product of isethionic acid esterification and the neutral fatty acid of sodium hydroxide, and succinamate (succinamates).The instantiation of succinamate comprises: N-octadecyl sulfosuccinamic acid disodium; N-(1,2 dicarboxyl ethyl)-N-octadecyl sulfosuccinamic acids, four sodium; The diamyl ester of sodium sulfosuccinate; The dihexyl ester of sodium sulfosuccinate; The dioctyl ester of sodium sulfosuccinate.
The preferred anionic surfactant that is used for acceptable composition in the cosmetic of the present invention comprises ammonium lauryl sulfate (ammonium lauryl sulfate); Laureth ammonium sulfate (ammonium laureth sulfate); Lauryl sulfate triethylamine (trlethylamine laurylsulfate); Laureth sulphuric acid triethylamine; Triethanolamine lauryl sulfate; Laureth sulphuric acid triethanolamine; Lauryl sulfate monoethanolamine; Laureth sulphuric acid MEA; Lauryl sulfate diethanolamine; Laureth sulphuric acid diethanolamine; Laurel monoglyceride sodium sulfate (lauricmonoglyceride sodium sulfate); Sodium lauryl sulfate; Sodium laureth sulfate; Lauryl potassium sulfate; The laureth potassium sulfate; Sodium lauryl sarcosinate; Sodium lauroyl sarcosine; The lauryl sarcosine; The cocoyl sarcosine; Cocoyl ammonium sulfate; Lauroyl ammonium sulfate; Cocoyl sodium sulfate; Lauroyl sodium sulfate; The cocoyl potassium sulfate; Lauryl potassium sulfate; Triethanolamine lauryl sulfate (trlethanolamine); Triethanolamine lauryl sulfate; Cocoyl sulphuric acid MEA; Lauryl sulfate monoethanolamine; Tridecyl benzene sulfonic acid sodium salt and dodecylbenzene sodium sulfonate.
Can be used for the derivant that the amphoteric surfactant in the acceptable composition in the cosmetic of the present invention comprises secondary aliphatic amine and tertiary amine, wherein the aliphatic substituent contains have an appointment 8 to 18 carbon atoms and for example carboxyl, sulfonate (sulfonate), sulfate (sulfate), phosphate (phosphate) or phosphonate (phosphonate) the anionic water solubilizing group.Representative example comprises 3-dodecyl-alanine sodium, 3-dodecyl amino propane sulfonic acid sodium, sodium lauryl sarcosinate, N-alkyltaurate (for example describe among United States Patent (USP) 2 pass through lauryl amine and the prepared salt of sodium isethionate reaction), N-senior alkyl aspartic acid (like United States Patent (USP) 2, describing in 091) and with trade name MIRANOL < > TM <> The product of selling (, describing in 378) like United States Patent (USP) 2,528.Other sarcosinates and sarcosinate derivant can be referring to CTFA CosmeticIngredient Handbook(CTFA cosmetic composition handbooks), the 5th edition, 1988, the 42 pages, its this by reference mode incorporate into.
Cationic surfactant generally comprises but is not limited to contain the 8 fatty quaternary ammonium compounds to about 18 carbon atoms of having an appointment.The anion of quaternary ammonium compound can be a conventional ion, for example chloride ion, etherosulfuric acid root, methyl-sulfuric acid root, acetate, bromide ion, lactate, nitrate anion, phosphate radical or tosylate and composition thereof.Chain alkyl can comprise additional or substituted carbon or hydrogen atom or ehter bond.Other replacements on the quaternary nitrogen can be hydrogen, hydrogen, benzyl or short-chain alkyl or hydroxyalkyl group, for example methyl, ethyl, methylol or ethoxy, hydroxypropyl or its combination.The structure of representational quaternary ammonium compound is provided in CTFA Cosmetic Ingredient Handbook(CTFA cosmetic composition handbook), the 5th edition, 1988, the 40 pages.
The instance of quaternary ammonium compound includes but not limited to: chlorination Shan Yu base trimethyl ammonium (behentrimonium chloride); Chlorination cocoyl trimethyl ammonium (cocotrimoniumchloride); Bromination cetyl ethyl Dimethyl Ammonium (cethethyldimonium bromide); Chlorination Er Shan Yu base Dimethyl Ammonium (dibehenyldimonium chloride); Chlorination dihydro Adeps Bovis seu Bubali benzyl ammonium methyl (dihydrogenated tallow benzylmonium chloride); Chlorination two soybean-based Dimethyl Ammonium (disoyadimonium chloride); Chlorination two Adeps Bovis seu Bubali Dimethyl Ammonium (ditallowdimoniumchloride); Chlorination hydroxyl cetyl hydroxyethyl dimethyl ammonium (hydroxycetyl hydroethyldimonium chloride); Chlorination ethoxy Shan Yu amido propyl Dimethyl Ammonium (hydroxyethylbehenamidopropyl dimonium chloride); Chlorination ethoxy cetyl Dimethyl Ammonium (hydroxyethyl cetyldimonium chloride); Chlorination ethoxy Adeps Bovis seu Bubali Dimethyl Ammonium (hydroxyethyl tallowdimonium chloride); Chlorination myristyl dimethyl benzyl ammonium (myristalkonium chloride); Chlorination EG-2 oil base ammonium methyl (PEG-2 oleamoniumchloride); Chlorination EG-5 stearyl ammonium methyl (stearmonium chloride) cocoyl quaternary ammonium salt (cocoyl quaternium)4 stearyl dimethyl benzyl ammonium (stearalkonium) 4; Trimethyllaurylammonium chloride (lauryltrimonium chloride); Quaternary ammonium salt-16; Quaternary ammonium salt-18; Chlorination lauryl dimethyl hexadecyldimethyl benzyl ammonium (lauralkonium chloride); Chlorination oil base dimethyl benzyl ammonium (olealkmonium chloride); Cetyl pyridinium chloride (cetylpyridinium chloride); Polyquaternary ammonium salt-5; Polyquaternary ammonium salt-6; Polyquaternary ammonium salt-7; Polyquaternary ammonium salt-10; Polyquaternary ammonium salt-22; Polyquaternary ammonium salt-37; Polyquaternary ammonium salt-39; Polyquaternary ammonium salt-47; Polyquaternary ammonium salt-55; Chlorination cetyl trimethyl ammonium (cetyl trimonium chloride); Chlorination dilauryl Dimethyl Ammonium (dilauryldimonium chloride); Cetyl dimethyl benzyl ammonium chloride (cetalkoniumchloride); Chlorination two cetyl Dimethyl Ammonium (dicetyldimonium chloride); Chlorination Semen sojae atricolor trimethyl ammonium (soyatrimonium chloride); Stearyl octyldimethyl ammonium methyl sulfate (stearyl octyldimonium methosulfate) and composition thereof.Other quaternary ammonium compounds are listed in CTFA Cosmetic Ingredient Handbook(CTFA cosmetic composition handbook), front page, the 41-42 page or leaf, its this by reference mode incorporate into.
Acceptable composition can comprise from about C in the cosmetic < > 10 <> To C < > 22 <> Two long-chain amines, from about C < > 10 <> To C < > 22 <> Long-chain fat amine and composition thereof.Instantiation comprises two palmityl amine (dipalmitylamine), dodecanamide propyl dimethyl, stearamidopropyldime.hylamine (stearamidopropyl dimethylamine).
Acceptable composition can also comprise the aliphatic alcohol and the two tail phospholipid of aliphatic alcohol (being generally monohydric alcohol), ethoxylation in the cosmetic of the present invention, and it can be in order to acceptable composition in the cosmetic of stable emulsion or dispersion form.It also provides to make up goes up acceptable viscosity.The selection of aliphatic alcohol is not crucial, has C although generally use those to be characterized as < > 10 <> To C < > 32 <> , preferred C < > 14 <> To C < > 22 <> Aliphatic chain be the alcohol of roughly saturated alkanol.Instance comprises stearyl alcohol (stearyl alcohol), spermol (cetyl alcohol), cetearyl alcohol (cetostearyl alcohol), cardanol (myristylalcohol) 、 behenyl alcohol, arachidic alcohol, isooctadecanol (isostearyl alcohol) and different spermol (isocetyl alcohol).Spermol is preferred, and can use separately or be used in combination with other aliphatic alcohol, preferably is used in combination with stearyl alcohol.During use, be included in aliphatic alcohol concentration range in the preparation of the present invention and be preferably from about 1 to about 8% weight, more preferably from about 2 to about 6% weight.Said aliphatic alcohol can also be ethoxylation.Instantiation comprises ceteareth (cetereth)-20, stearyl alcohol polyethers (steareth)-20, stearyl alcohol polyethers (steareth)-21 and composition thereof.Also can comprise phospholipid, for example Phosphatidylserine and phosphatidylcholine and composition thereof.
The ionic surfactant pack that can be used for acceptable composition in the cosmetic of the present invention is drawn together the chemical compound that extensively is defined as through using organic hydrophobic compound (character can be aliphatic or alkyl aromatic) condensation alkylene oxide group (character is hydrophilic) to be generated.The instance of the non-ionic surface active agent of preferred classes is: the long chain alkanol amide; The polyethylene oxide condensation compound of alkyl phenol; Have straight or branched configuration (configuration) from about 8 to the aliphatic alcohol of about 18 carbon atoms and the condensation product of oxirane; The long chain tertiary amine oxide; The long chain tertiary phosphine oxide; Contain one from about 1 short-chain alkyl or hydroxyalkyl radical (radical to about 3 carbon atoms) the long-chain dialkyl sulphoxide; And alkyl polysaccharide (APS) surfactant, for example alkyl polyglycoside (alkyl polyglycosides); Polyethylene Glycol (PEG) glycerin fatty ester.
Zwitterionic surfactant (for example betanin) also can be used for acceptable composition in the cosmetic of the present invention.The instance that is used for the betanin of this paper comprises the senior alkyl betanin, for example coco dimethyl carboxymethyl betaine (coco dimethyl carboxymethyl betaine); Cocamido propyl betaine; Coco betaine (cocobetaine); The dodecanamide propyl betanin; Oil-based betaine; The lauryl dimethyl carboxymethyl betaine; Lauryl dimethyl α-carboxyethyl betanin; Cetyl dimethyl carboxymethyl betaine; The two-(2-ethoxys of lauryl) carboxymethyl betaine; The two-(2-hydroxypropyls of stearyl) carboxymethyl betaine (stearyl bis-(2-hydroxypropyl)carboxymethyl betaine); Oil base dimethyl γ-carboxylic CAB; With the two-(2-hydroxypropyls of lauryl) α-carboxyethyl betanin.Sulfobetaines (sulfobetaines) representative can be coco dimethyl azochlorosulfonate propyl lycine (cocodimethyl sulfopropyl betaine), stearyl dimethyl methyl CAB (stearyldimethyl sulfopropyl betaine), the two-(2-ethoxys of lauryl dimethyl sulfoethyl betanin, lauryl) azochlorosulfonate propyl lycine and analog; Amide betaine (amidobetaines) and amide sulfo betaine (amidosulfobetaines), RCONH(CH wherein < > 2 <> ) < > 3 <> It also is the nitrogen-atoms of useful betanin in the present invention that free radical is connected to.
The common consumption of anion, cation, nonionic, both sexes or zwitterionic surfactant that is used for acceptable composition in the cosmetic of the present invention is from about 0.1 to 50% weight, preferably from about 0.5 to about 40% weight, more preferably from about 1 to about 20% weight.
Acceptable composition can comprise wetting agent in the cosmetic of the present invention, and it works as hygroscopic agent, the water yield that has increased absorption, keeps and kept.The suitable wetting agent that is used for preparation of the present invention includes but not limited to: acetamide MEA; DL-Lactic acid ammonium salt.; Chitosan and derivant thereof; The colloidal state Herba bromi japonici; Arabinogalactan (galactoarabinan); Glutamic acid glucose; Glycerin polyether (glycereth)-26; Glycerol; Lactamide MEA; Lactamide DEA; Lactic acid; Methyl glucose polyethers (methyl gluceth)-10; Methyl glucose polyethers-20; Pantothenylol; Propylene glycol; Sorbitol; Polyethylene Glycol; 1; 3-butanediol; 2; The 6-hexanetriol; Hydrogenated starch hydrolysates; Inositol; Mannitol tetramethylolmethane ether (ether); The polyglyceryl Sorbitol; Xylitol, sucrose; Hyaluronate sodium sodium and combination thereof.Glycerol is special preferred humectants.Wetting agent be present in the compositions concentration for from about 0.5 to about 40% weight, preferably from about 0.5 to about 20% weight and more preferably from about 0.5 to about 12% weight.
Acceptable composition can comprise vaseline or mineral oil component in the cosmetic of the present invention, and it is generally USP or NF grade when selecting.Vaseline can be white or yellow.The viscosity of vaseline or denseness grade are not very crucial.Vaseline can partly be replaced by the mixture of hydrocarbon materials, and this mixture can be mixed with on outward appearance and denseness and be similar to vaseline.For example, can make up the vaseline with different waxes and analog or the mixture of mineral oil.Preferred wax comprises Fructus Lauri nobilis wax (bayberry wax); Candelilla wax; Ceresine (ceresin); The Jojoba ester; Lanolin wax; Montan wax; Ceresine (ozokerite); Polyglyceryl-3-Cera Flava; Polyglyceryl-6-the five kinds of stiffness in infant fat acid ester (polyglyceryl-6-pentastearate); Microwax; Paraffin; Isoparaffin (isoparaffin); The vaseline hard paraffin; Squalene; Oligomer alkene; Cera Flava; Synthetic candelilla wax; The synthetic wax Petiolus Trachycarpi; Synthetic bees wax and analog may be combined in together.Having substituted in various degree alkyl methyl siloxanes can be in order to increase the water that skin keeps.Silicones such as stearyl dimethicone (stearyldimethicone) (referred 2503Wax), C30-45 alkyl methyl silicone oil (called AMS-C30 wax) and stearyl trimethyl silane (and) stearyl alcohol (called 580Wax), all available from DowCorning
Figure G200680006524501D00131
, Midland, MI, USA.Other alkyl and phenyl siloxane can be in order to the raising character of preserving moisture.Resins such as dimethicone (and) trimethylsiloxysilicate silicate (trimethylsiloxysilicate) (referred to as Dow Corning
Figure G200680006524501D00132
593) or ring A silicone oil (cyclomethicone) (and) trimethylsiloxysilicate silicate (called Dow Corning
Figure G200680006524501D00133
749fluid), skin care products can be used to improve film formation.When using, vaseline, wax or hydrocarbon or oil ingredient are with about 1 to about 20% weight, 1 concentration to about 12% weight more preferably from about, are included in the said preparation.When using, silicone resin can about 0.1 be comprised to about 10.0% weight.
Softening agent is defined as the material that help to keep soft, the smooth and slick and sly outward appearance of skin.Softening agent remains on ability and functionating on the skin surface or in horny layer through it.Acceptable composition can comprise the fatty ester softening agent on the present invention made up, and it lists in the international cosmetic composition dictionary of International CosmeticIngredient Dictionary(), English edition, 2000, the 1768 to 1773 pages.The instantiation that is used for the suitable fatty ester of preparation of the present invention comprises the isopropyl alcohol myristate; The isopropyl alcohol cetylate; Caprylic/capric triglyceride; Spermol lactate (cetyl lactate); Spermol cetylate (cetyl palmitate); Castor oil hydrogenated; Glyceride; Hydroxyl spermol isostearate (hydroxycetyl isostearate); The hydroxyl Phosphoric acid monohexadecyl ester; The isopropyl alcohol isostearate; Isooctadecanol isostearate (isostearyl isostearate); Diisopropanol decanedioic acid spermol polyethers-20(PPG-5-Ceteth-20); The different pelargonate (2-ethylhexyl of 2-Ethylhexyl Alcohol isononoate); 2-Ethylhexyl Alcohol stearate < > 12 <> To C < > 16 <> Aliphatic alcohol lactate, isopropyl alcohol wool grease (lanolate), 2-ethyl-hexanol salicylate and composition thereof.At present preferred fatty ester is isopropyl alcohol myristate, isopropyl alcohol cetylate, PPG-5-spermol polyethers-20 and caprylic/capric triglyceride.When using, the fatty ester softening agent preferably with about 1 to about 8% weight, 2 concentration to about 5% weight more preferably from about, is included in the preparation of the present invention.
Compositions of the present invention can also comprise silicone compounds.Preferably, the viscosity of silicone components under 25 ℃ is from about 0.5 to about 12,500cps.Suitably the instance of material is dimethyl polysiloxane, diethyl polysiloxanes, dimethyl polysiloxane-diphenyl polysiloxanes, cyclomethicone, trimethyl polysiloxanes, diphenyl polysiloxanes and composition thereof.Simethicone (with the dimethyl polysiloxane of trimethyl cell end block) is a preferred examples.Viscosity is between 50 and 1, and the simethicone between the 000cps is preferred especially.When using, silicone oil preferably with 0.1 to 5% weight, the more preferably concentration of 1 to 2% weight, is included in the preparation of the present invention.
Acceptable composition can comprise volatilization and nonvolatile silicone oil or fluid in the cosmetic of the present invention.Silicone compounds can be viscosity from about 0.5 to about 100 centistoke (centistrokes) wire or annular dimethyl polysiloxane.The range of viscosities of most preferred wire polydimethylsiloxane chemical compound from about 0.5 to about 50 centistokes.A linear, low molecular weight volatile polydimethylsiloxane One example is octamethyltrisiloxane, tradename Dow Corning
Figure G200680006524501D00141
200fluid obtain a viscosity of about 1 centistokes.When using, silicone oil preferably with 0.1 to 30% weight, the more preferably concentration of 1 to 20% weight, is included in the preparation of the present invention.
Acceptable composition can comprise volatile cyclic low-molecular-weight polydimethylsiloxane (cyclomethicone) in the cosmetic of the present invention.Preferred ring-type volatile siloxane can be average repetitive be 4 to 6 and viscosity from about 2.0 to polydimethylcyclosil.xane of about 7.0 centistokes and composition thereof.The ring is preferably a silicone available from Dow Corning, Midland, MI, USA, tradename DowCorning 244fluid, Dow Corning
Figure G200680006524501D00143
245fluid, Dow Corning
Figure G200680006524501D00144
246, DowCorning
Figure G200680006524501D00145
344fluid and Dow Corning 345fluid, and obtained from General Electric, Waterford, NY, USA's Silicone SF-1173 and Silicone SF-1202.When using, silicone oil preferably with 0.1 to 30% weight, the more preferably concentration of 1 to 20% weight, is included in the preparation of the present invention.
The silicone surfactant (siliconesurfactants that has polyoxyethylene or polyoxypropylene side chain) or emulsifying agent also can be used for compositions of the present invention.Preferred examples include: dimethicone copolyol (dimethicone Copolyols), Dow Corning 3225C and 5225C Formulation Aids, available from Dow Corning, Midland, MI, USA; and SiliconeSF-1528, available from General Electric, Waterford, NY.USA.Side chain can also comprise alkyl, for example lauryl or cetyl.A preferred silicone copolymer lauryl alcohol (called DowCorning 5200Formulation Aid) and cetyl dimethicone copolyol (called AbilEM-90, available from Goldschmidt Chemical Corporation, Hopewell, VA).Further preferably the lauryl simethicone is called Belsil LDM 3107VP, can be available from acker-Chemie, and Munchen, GER.When using, silicone surfactant preferably with 0.1 to 30% weight, the more preferably concentration of 1 to 15% weight, is included in the preparation of the present invention.
Amine functional siloxane and emulsion can be used for the present invention.Preferred examples include DowCorning
Figure G200680006524501D00152
8220, Dow Corning
Figure G200680006524501D00153
939, Dow Corning
Figure G200680006524501D00154
949, Dow Corning
Figure G200680006524501D00155
2-8194, all available from Dow Corning, Midland, MI, USA.Further preferably SiliconeSM 253, can be available from General Electric, Waterford, NY, USA.When using, the amine functional siloxane preferably with 0.1 to 5% weight, the more preferably concentration of 0.1 to 2.0% weight, is included in the preparation of the present invention.
Acceptable composition can comprise the volatility hydrocarbon ils in the cosmetic of the present invention.Volatile hydrocarbon comprises about C < > 6 <> To C < > 22 <> Atom.The preferred volatile hydrocarbon is that chain is about C < > 6 <> To C < > 16 <> The aliphatic hydrocarbon of individual carbon atom.This examples for compounds comprises 2-Methylpentadecane, and commodity are called Permethyl 101A, can be available from Presperse, and South Plainfield, NJ, USA.The instance of another preferred volatile hydrocarbon is C < > 12 <> To C < > 14 <> Isoparaffin, commodity are called Isopar M, can be available from xxon, Baytown, TX, USA.When using, volatile hydrocarbon preferably with 0.1 to 30% weight, the more preferably concentration of 1 to 20% weight, is included in the preparation of the present invention.
Acceptable composition can comprise cation and both sexes telomerized polymer in the cosmetic of the present invention.Such instance includes but not limited to the international cosmetic composition dictionaries of following listed those :International CosmeticIngredient Dictionary() Cosmetic Association(cosmetics, cosmetic product and the)(CTFA of aromatic association) publish 17th Street, N.W., Suite 300, D.C.20036.General example comprises the season derivant (quaternary derivatives of cellulose ether), the season derivant of guar gum, homopolymer and copolymer, the homopolymer of MAPTAC and the season derivant of copolymer and starch of DADMAC.Use the CTFA name, instantiation includes but not limited to polyquaternary ammonium salt-10; Guar gum Hydroxyproyl Trimethyl ammonium chloride (Guar hydroxypropyltrimonium chloride); Starch Hydroxyproyl Trimethyl ammonium chloride (starch hydroxypropyltrimonium chloride); Polyquaternary ammonium salt-4; Polyquaternary ammonium salt-5; Polyquaternary ammonium salt-6; Polyquaternary ammonium salt-7; Polyquaternary ammonium salt-14; Polyquaternary ammonium salt-15; Polyquaternary ammonium salt-22; Polyquaternary ammonium salt-24; Polyquaternary ammonium salt-28; Polyquaternary ammonium salt-32; Polyquaternary ammonium salt-33; Polyquaternary ammonium salt-36; Polyquaternary ammonium salt-37; Polyquaternary ammonium salt-39; Polyquaternary ammonium salt-45; Polyquaternary ammonium salt-47 and chlorination PMAm base oxypropyl trimethyl ammonium (polymethacrylamidopropyltrimoniumchloride); Polyquaternary ammonium salt-55 and composition thereof.When using, telomerized polymer is preferably with from 0.1 to 10% weight, preferably from 0.2 to 6% weight, and the concentration of from 0.2 to 5% weight most preferably, is included in the cosmetic of the present invention in the acceptable composition.
Acceptable composition can comprise one or more rheology modifiers in the cosmetic of the present invention.Can be used in the present invention, rheology modifiers include, but are not limited to: a high molecular weight cross-linked acrylic acid (crosslinked) homopolymer, and an acrylate / C10-30 alkyl acrylate cross-linked polymer (Acrylates/C10-30 Alkyl Acrylates Crosspolymer), for example Carbopol
Figure G200680006524501D00161
and Pemulen
Figure G200680006524501D00162
series, both available from Noveon, Inc., Cleveland, OH, USA; such Salcare
Figure G200680006524501D00163
AST anionic acrylate (anionic acrylate) polymers and such Salcare
Figure G200680006524501D00164
SC96 cationic acrylate (cationic acrylate) polymer, available from Ciba Specialties, High Point, NC, USA; chloride, trimethyl ammonium propyl acrylamide / acrylamide; hydroxyethyl methacrylate ( hydroxyethyl methacrylate) polymer, Steareth -10 allyl ether / acrylate copolymer (Steareth-10 Allyl Ether / Acrylate Copolymer); acrylate / behenyl alcohol polyether methacrylate -25 ester copolymer (Acrylates/Beheneth-25MetacrylateCopolymer), called Aculyn
Figure G200680006524501D00165
28, available from Rohm andHaas / InternationalSpecialties, Wayne, NJ, USA; glyceryl polymethacrylate (glycerylpolymethacraylate), acrylates / behenyl alcohol polyethylene -20 ether methacrylate copolymer (Acrylates/Beheneth-20 Metacrylate Copolymer); bentonite; gums, such as alginates, carrageenan, gum arabic (gum acacia), gum arabic (gum arabic), Indian gum, karaya gum, tragacanth gum, guar gum; guar hydroxypropyl trimethyl ammonium chloride, sugar, xanthan gum or gelatin; cellulose derivatives, such as carboxymethylcellulose sodium, hydroxyethyl cellulose, carboxyethyl cellulose, hydroxymethyl, hydroxymethyl carboxypropyl cellulose, ethyl cellulose, sulfated cellulose, hydroxypropyl cellulose, methyl cellulose, hydroxypropyl methylcellulose, , microcrystalline cellulose; agar; pectin; gelatin; starch and derivatives thereof; chitosan and its derivatives, e.g., hydroxyethyl chitosan sugar; PVA, PVM / MA copolymer, PVM / MA decadiene cross-linked polymer, based on poly (ethylene oxide) thickeners, carbomer sodium (sodium carbomer) and mixtures thereof.When using, rheology modifier is preferably with from 0.01 to 12% weight, preferably from 0.05 to 10% weight and the concentration of from 0.1 to 6% weight most preferably, is included in the cosmetic of the present invention in the acceptable composition.
Acceptable composition can comprise one or more antioxidants in the cosmetic of the present invention, and it includes but not limited to ascorbic acid, BHT, BHA, arabo-ascorbic acid, bisulfite (bisulfite), thioglycolate salt (thioglycolate), tocopherol, sodium metabisulfite, Vitamin E acetate and ascorbyl palmitate (ascorbyl palmitate).Antioxidant will account for acceptable composition 0.01 to 5% weight in the said cosmetic, preferred 0.1 to 3% weight and 0.2 to 2% weight most preferably.
Acceptable composition can comprise one or more sunscreen actives agent in the cosmetic of the present invention.The instance of sunscreen actives agent includes but not limited to octyl group methoxy cinnamate, and (ethyl hexanol is to methoxy cinnamate); Octyl group salicylate oxybenzone (benzophenone-3(benzophenone-3)); Benzophenone-4(benzophenone-4); Antisolaire; The dihydroxyphenyl ketone; Amino benzoic Acid; Amyl group dimethyl PABA; Diethanolamine p-methoxycinnamic acid ester; Two (hydroxypropyl) Aminobenzoates of ethyl 4-; 2-ethylhexyl 1-2-cyanic acid-3; 3-diphenylacrylate ester (2-ethylhexyl-2-cyano-3); The high menthyl ester of salicylic acid; Glyceryl aminobenzoate; Dihydroxy acetone; Octyldimethyl PABA; 2-Phenylbenzimidazole-5-sulfonic acid; Triethanolamine salicylate; Zinc oxide and titanium oxide, and composition thereof.The amount that is used for the sunscreen of acceptable composition in the cosmetic of the present invention will change according to the certain UV absorbing wavelength of employed concrete sunscreen actives agent, and can be from 0.1 to 10% weight, from 2 to 8% weight.
Acceptable composition can comprise one or more antiseptic in the cosmetic of the present invention.Examples of preservatives include, but are not limited to: 1,2 - dibromo-2 ,4 - dicyanobutane (methyl dibromo glutaronitrile, known MERGUARD
Figure G200680006524501D00171
, Ondeo Nalco Company, Naperville, IL, USA ), benzyl alcohol, imidazolidinyl urea, 1,3 - bis (hydroxymethyl) -5,5 - dimethyl-2 - imidazolidinone (imidazolidinedione) (e.g., DMDM hydantoin, called GLYDANT
Figure G200680006524501D00172
, Lonza, Fairlawn, NJ, USA.), methyl chloride isothiazolin-ketone and methyl isobutyl thiazolidinone (eg, Kathon
Figure G200680006524501D00173
, Rohm & Haas Co., Philadelphia, PA, USA), on the methyl paraben, propyl paraben, phenoxyethanol and sodium benzoate, and mixtures thereof.
Acceptable composition can comprise any other composition that just is being usually used in the cosmetics in the cosmetic of the present invention.The instance of this composition includes but not limited to: buffer agent, fragrance ingredient, chelating agen, available so that color additive that compositions itself or horny layer are painted or dyestuff, screening agent, softening agent (softener), foaming booster, foam stabiliser, sunlight filtering agent and peptizer.
Pigment (pigments)(is titanium dioxide, zinc oxide, Talcum, calcium carbonate or Kaolin for example) surface can handle and be used for acceptable composition in the cosmetic of the present invention then through anionic polymer described herein.Treated pigment is then more effectively as the sunscreen actives thing and be used for for example making up and dye the colored cosmetic of eyebrow.
Acceptable composition can contain water and also can contain acceptable solvent in any cosmetic in the cosmetic of the present invention.The instance of acceptable solvent includes but not limited to: monohydric alcohol, and the alkanol that for example has 1 to 8 carbon atom is (as ethanol, isopropyl alcohol, benzyl alcohol and phenylethyl alcohol); Polyhydric alcohol, for example alkylene glycol (alkylene glycols)(is as glycerol, ethylene glycol and propylene glycol); And glycol ether, for example one-, two-and three-ethylene glycol monoalkyl ether, for example glycol monomethyl methyl ether and diglycol monotertiary methyl ether use separately or mix and use.These solvents can exist more than 70% weight with respect to reaching of total composition weight, for example from 0.1 to 70% weight.
Acceptable composition can also contain electrolyte in the cosmetic of the present invention; Aluminium chlorhydroxide, alkali metal salt (for example sodium salt, potassium salt or lithium salts for example; These salt are preferably halogenide (for example chloride or bromide) and sulfate or acylate (for example acetate (acetates) or lactate (lactates))); And alkali salt, carbonate, silicate, nitrate, acetate, gluconate, pantothenate and the lactate of the preferred calcium of said alkali salt, magnesium and strontium.
The compositions that is used to handle skin comprises aftershave lotion, sunscreen, lotion, hands and health cream (hand and body creams), liquid soap, soap slab, bath oil rod (bath oil ars), shaving cream, dishwashing liquid, shower gels, bubble bath and analog.
Skin care compositions and methods of the present invention can be processed oil-in-water, water in oil emulsion, triple emulsion or dispersion.
The preparation of preferred oil-in-water emulsion is added water-msoluble ingredients then through at first forming the aqueous mixture of water solublity (for example, undersaturated quaternary ammonium compound, wetting agent, waterborne-type preservation) component.Water-msoluble ingredients comprises emulsifying agent, water-insoluble antiseptic, vaseline or mineral oil component, aliphatic alcohol component, fatty ester softening agent and silicone oil components.The input of mixed tensor is high and will continues to be enough to form the time of the water-in-oil emulsion with smooth appearance (show and have relative small particles in the emulsion).Generally through forming the aqueous mixture of water-soluble component, interpolation has the thickening agent that is used for the water-insoluble materials suspending power then in the preparation of preferred dispersion.
Acceptable composition can also be packaged as aerosol in the cosmetic of the present invention, and wherein, the form that it can aerosol spray or the form of aerosol foam are used.As these aerocolloidal propelling gass, especially, possibly use dimethyl ether, carbon dioxide, nitrogen, nitrous oxide, air and volatile hydrocarbon, said volatile hydrocarbon is butane, iso-butane and propane for example.
The compositions that is used for treatment of hair comprises the shower goods, for example bubble bath, soap and oil, shampoo, regulator, hair depigmenting agent, hair-dyeing agent, interim and long lasting hair color agent, color adaptation agent, hair brightening agent, dyeing and non-painted hair conditioner, hair dye, curly hair fixative (hairwave sets), long-acting setting lotion, setting lotion, hair straighten, haircut adjuvant, hair oil, hair modify (hair dressings) and oxygenated products.Said hydrophobically modified polymers also can be used for the resident type (leave-in that finalizes the design) product; Example gel, mousse (mosses), spray (spritzes), typing cream, typing wax, brilliantine, balsam etc.; Use separately or with other polymer or structural agent (structuring agent) be used in combination; Control and the hair compliance to provide, and have cleaning, nature, inviscid sensation.
Hair care composition of the present invention provides level and smooth sensation; And it can be washed off from hair easily, because exist said hydrophobically modified polymers, volatile siloxane, other polymer, surfactant or other can change material at the sedimentary chemical compound of hair.
Under the situation of cleaning agent; Shampoo that for example is used to have one's hair wash or liquid hand soaps or the bath gels that is used to clean skin; Said compositions contains anion, cation, nonionic, amphion or amphoteric surfactant; Said surfactant usually amount for from about 3 to about 50% weight, preferably from about 3 to about 20% weight, and its pH usually from about 3 to about 10 scope.
The preferred shampoo of the present invention contains the combination of anion surfactant and zwitterionic surfactant and/or amphoteric surfactant.Preferred especially shampoo contains from about 0 to about 16% active alkyl sulfate salt (alkyl sulfates), from 0 to the alkyl sulfate salt of the ethoxylation of about 50% weight with from 0 option list surface-active agent to about 50% weight; This surfactant is selected from nonionic, both sexes and zwitterionic surfactant; And be at least 5% weight of alkyl sulfate salt or its mixture of alkyl sulfate salt, ethoxylation; And the total surfactant level is from about 10% weight to about 25% weight.
The shampoo that is used for having one's hair wash can also contain other adjusting additive that is generally used for shampoo, for example siloxanes and telomerized polymers.United States Patent (USP) 5,573,709 provide a series of non-volatile siloxane regulators that can be used in the shampoo.Be used for telomerized polymer of the present invention and list in Cosmetic, Toiletries and Fragrance Associations(CTFA)dictionary(cosmetics, cosmetic product and the (CTFA of aromatic association) dictionary).Instantiation comprises polyquaternary ammonium salt (for example polyquaternary ammonium salt-1 to polyquaternary ammonium salt-53), guar gum Hydroxyproyl Trimethyl ammonium chloride, starch Hydroxyproyl Trimethyl ammonium chloride and chlorination PMAm base oxypropyl trimethyl ammonium.
Other preferred embodiments comprise with the mainly application of the form of flushing lotion to be used before or after the shampoo hair washing.These lotions are the lotion or the gel of aqueous solution or aqueous solution of alcohol, emulsion, thickening normally.If said compositions occurs with form of emulsion, then said compositions can be nonionic, anion or cationic.Nonionic emulsion mainly consist of oil and/or have polyoxyethyleneization alcohol aliphatic alcohol (for example; The stearyl alcohol (stearyl alcohol of polyoxyethyleneization) or cetyl/stearyl alcohol) mixture, and cationic surfactant can be added into these compositionss.Anion emulsion generates from soap basically.
If said compositions occurs with the lotion or the gel form of thickening, then said compositions contains the thickening agent that exists or do not have solvent.Operable thickening agent especially is: resin, acrylic thickener, and can be available from B.F.Goodrich; Xanthan gum; Sodium alginate; Radix Acaciae senegalis; Cellulose derivative and based on the thickening agent that gathers (oxirane), and it also possibly realize thickening through the mixture of polyglycol distearate or distearate or through the mixture of phosphate ester and amide.The concentration of thickening agent is generally 0.05 to 15% weight.If said compositions is with typing lotion, molding lotion or the fixedly form appearance of lotion, then said compositions generally comprises as above defined Ampholyte polymers in water, alcohol or aqueous solution of alcohol.
Under the situation of hair fixative, said compositions can contain one or more additional hair fixative polymer.When existing, said additional hair fixative polymer is to exist from about 0.25 total amount to about 10% weight.As long as said additional hair fixative resin and given hydrophobically modified polymers are compatible; Then said additional hair fixative resin can be selected from: acrylamide copolymer; Acrylamide/sodium acrylate copolymer; Acrylates (acrylate)/ammonio methacrylate copolymer; The acrylates copolymer; Acrylic acid/acrylates copolymer; Fatty acid/dimethylamino hydroxypropyl diethylenetriamines copolymer; Fatty acid/glycidyl diethylenetriamines copolymer; Pi-allyl stearate/VA copolymer; Amino-ethyl acrylic ester phosphate (aminoethylacrylate phosphate)/the acrylates copolymer; The ammonium acrylate copolymer; Vinylacetic acid ammonium/acrylates copolymer acrylates/biacetone acrylamide copolymer; AMPD acrylates/biacetone acrylamide copolymer; The butyl ester (butyl ester of PVM/MA copolymer) copolymer calcium/sodium salt (calcium/sodium PVM/MA copolymer) of the butyl ester (butyl ester of ethylene/maleic anhydridecopolymer) copolymer of ethylene/copolymer-maleic anhydride; Corn starch/acrylamide/sodium acrylate copolymer; Diethyleneglycolamin/chloropropylene oxide/piperazine-copolymer; Dodecanedioic acid/spermaceti stearyl alcohol (cetearyl alcohol)/the isopropyl ester (isopropyl ester of PVM/MA copolymer) of the ethyl ester (ethyl ester of PVM/MA copolymer) copolymer of glycol copolymer copolymer; Karaya; Methacryl ethyl betanin/methacrylic acid salt copolymer (methacryloyl ethyl betaine/methacrylatecopolymer); Octyl acrylamide/acrylates/butyl ethylaminoethanol methacrylate copolymer (octylacrylamide/acrylate/butylaminoethyl methacrylate copolymer); Octyl acrylamide/acrylates copolymer; Phthalic anhydride/glycerol/capric acid glycidyl ester copolymer (phthalic anhydride/glycerin/glycidyl decanoate copolymer); Phthalic acid/benzenetricarboxylic acid/glycol copolymer; Polyacrylamide; The polyacrylamide base methyl propane sulfonic acid; Polybutylene terephthalate (PBT) (polybutylene terephthalate); Polyethyl acrylate (polyethylacrylate); Polyethylene; Polyquaternary ammonium salt-1; Polyquaternary ammonium salt-2; Polyquaternary ammonium salt-4; Polyquaternary ammonium salt-5; Polyquaternary ammonium salt-6; Polyquaternary ammonium salt-7; Polyquaternary ammonium salt-8; Polyquaternary ammonium salt-9; Polyquaternary ammonium salt-10; Polyquaternary ammonium salt-11; Polyquaternary ammonium salt-12; Polyquaternary ammonium salt-13; Polyquaternary ammonium salt-14; Polyquaternary ammonium salt-15; Polyquaternary ammonium salt-39; Polyquaternary ammonium salt-47; Polyvinyl acetate; Polyvinyl butyral resin; Polyvinyl imidazol quinoline acetate (polyvinylimidazolinium acetate); Polyvinyl methyl ether (polyvinyl methyl ether) copolymer; PVP/ DMAE methacrylate (dimethylaminoethylmethacrylate) copolymer; PVP/ eicosylene copolymer; PVP/ EMA (ethyl methacrylate)/EUDRAGIT S100; PVP/ hexadecene (hexadecene) copolymer copolymer; PVP/ vinyl acetate/itaconic acid copolymer; Lac; Acrylic compounds sodium salt copolymer (sodium acrylates copolymer); Acrylic compounds sodium salt/acryloyl nitrogen class (Acrylnitrogens) copolymer; PAA (sodium acrylate)/ethenol copolymer; Carrageenin sodium; Starch diethyllaminoethyl ether (starchdiethylaminoethyl ether); Stearyl vinyl ether/maleic anhydride copolymer; Sucrose benzoate (sucrose benzoate)/Sucrose acetoisobutyrate (sucrose acetate isobutyrate)/BBP(Butyl Benzyl Phthalate (butyl benzyl phthalate) copolymer; Sucrose benzoate/Sucrose acetoisobutyrate/BBP(Butyl Benzyl Phthalate/methylmethacrylate copolymer; Sucrose benzoate/Sucrose acetoisobutyrate copolymer; Vinyl acetate/cronate copolymer (vinylacetate/crotonate copolymer); Vinyl acetate/.beta.-methylacrylic acid copolymer; Vinyl acetate/.beta.-methylacrylic acid/methacryloxy benzophenone-1(methacryloxybenzophenone-1) copolymer; Vinyl acetate/.beta.-methylacrylic acid/vinyl neodecanoate copolymer, and composition thereof.The synthetic polymer that is used to generate the typing adjuvant is in " history of The History of Polymers in Haircare(hair care polymer) ", and Cosmetics and Toiletries describes in 103(1988), its this by reference mode incorporate into.Other can be used for synthetic polymer of the present invention can be with reference to CTFA Dictionary(CTFA dictionary), the 5th edition, 2000, its this by reference mode incorporate into.
If compositions contemplated of the present invention is used for keratin fiber and particularly human hair's dyeing, then except said hydrophobically modified polymers, contain at least a oxidation dye precursors and/or a kind of direct dyes as the one of which.It can also contain any other adjuvant that just is being usually used in such compositions.
The pH of said dye composite is generally 7 to 11, and can be through adding basifier (alkalizing agent) transfer to the value of hope.
Can also be used for curling or hair straightening according to compositions of the present invention.In this case, except said hydrophobically modified polymers, said compositions generally contains other adjuvants that one or more Reducing agents and (if suitably) just are being usually used in such compositions; This compositions contemplated is used in combination with neutralization composition.
In one embodiment; The present invention is for handling the method for the substrate that is selected from hair, skin and fingernail; It comprises that acceptable composition is gone up in cosmetic is applied to said substrate; Said compositions contains one or more hydrophobically modified polyacrylamides, and wherein said polyacrylamide is made up of acrylamide and one or more cationic monomers.
In another embodiment, said substrate is hair.
In another embodiment; The present invention is household cleaners or laundry detergent; Said household cleaners or laundry detergent comprise one or more hydrophobically modified polyacrylamides, and wherein said polyacrylamide is by acrylamide, one or more cationic monomers and choose any one kind of them or multiple anionic monomer is formed.
Through understanding aforementioned content better with reference to following embodiment, proposing following embodiment is for describing purpose, do not expect the scope of the present invention that limits.
Embodiment 1 uses the modification of hexadecylamine to acrylamide-chlorination diallyl dimethyl ammonium copolymer.
Add aqueous solution (the polymer actives) of 69.5: 30.5% moles of of acrylamide-chlorination diallyl dimethyl ammonium copolymer solution to the Parr reaction vessel; Add sodium hydrate aqueous solution (50%) and metabisulfite solution (15%, mixture 19.2g) and deionized water (200g).Add the hexadecylamine of fine gtinding then, and fully stir the mixture.Seal said reaction vessel then, stir and be made as maximum the setting, and use the nitrogen pressurized reactor and discharge (repeating 5 times).Seal said reaction vessel then, be heated to 140 ℃ and kept 5 hours down at 140 ℃.Stop heating then, cool off said reaction vessel to ambient temperature, so that the aqueous solution of hydrophobically modified polymers to be provided.The character of representational hydrophobically modified polymers is shown in table 1.In table 1, AcAm represents acrylamide, and DADMAC represents the chlorination diallyl dimethyl ammonium, and MAPTAC represents methyl chloride acrylamido oxypropyl trimethyl ammonium.
Table 1
Figure G200680006524501D00231
< > 1 <> The siloxanes of the aminofunctional of following formula
H < > 2 <> N(CH < > 2 <> ) < > 3 <> [Si(CH < > 3 <> ) < > 2 <> O] < > p <> Si(CH < > 3 <> ) < > 2 <> (CH < > 2 <> ) < > 3 <> NH < > 2 <> , wherein p is about 50, Aldrich, Milwaukee, WI
2Ultrasil TM A-23,Noveon,Cleveland,OH。
The preparation of embodiment 2 hydrophobically modified polymers solution.
The aqueous solutions of polymers (445g of embodiment 1) is transferred to flask, and is heated to 85 ℃, follow stirring.Nipagin (0.6g), propyl parabene (0.12g) and the mixture of deionized water (30g) be heated with the dissolving p-Hydroxybenzoate, be added into the polymer solution of heat then.Stirred said mixture 1 hour down at 85 ℃, be cooled to ambient temperature then, so that said hydrophobically modified polymers solution to be provided.
In following embodiment, the chlorination diallyl dimethyl ammonium copolymer of acrylamide/30.5% mole that " C8 polymer " expression is 69.5% mole, this copolymer is through the octylame modification.The chlorination diallyl dimethyl ammonium copolymer of acrylamide/30.5% mole that " C12 polymer " expression is 69.5% mole, this copolymer is through the lauryl amine modification.The chlorination diallyl dimethyl ammonium copolymer of acrylamide/30.5% mole that " C16 polymer " expression is 69.5% mole, this copolymer is through the hexadecylamine modification.
The preparation of embodiment 3 representative shampoos.
Component shown in the table 2 is added according to listed order, behind each the interpolation, mixes fully.This batch (batch) be heated to 55 ℃ to 65 ℃, with fusing coconut oleoyl amine (cocamide) MIPA, and use lactic acid to regulate this pH to 5.5 in batches to 6.5.Be lower than interpolation antiseptic under about 40 ℃.The said polymer of dilute with water to be generating the total lot amount of about 200g, and stirs said mixture about 15 minutes.Before viscosity test, said shampoo is outgased, to remove the air of any parcel.
Table 2
Basic shampoo preparation (formulation)
Compositions C-8 is polymer-modified C-12 is polymer-modified
Composition Weight % Weight %
Deionized water (DI water) 50.166 48.166
Ammonium lauryl sulfate, 28% 20.00 20.00
Sodium lauryl sulfate, 29% 20.00 20.00
Cocamido propyl betaine, 30% 3.00 3.00
Coconut oleoyl amine MIPA 3.00 3.00
The C8 polymer, 8% 3.125 0.00
< > < > [0109] <> <>
The C12 polymer, 5% 0.00 5.00
Lactic acid 0.059 0.059
Sodium chloride 0.300 0.300
The EDTA disodium 0.10 0.10
Kathon CG 0.05 0.05
The DMDM glycolylurea 0.10 0.10
Aromatic (Fragrance) 0.10 0.10
Embodiment 4 contains the evaluation of basic shampoo of the hydrophobically modified polymers of varying level.
Test is according to the foam stability and the viscosity of the representative shampoo preparation of the method preparation of embodiment 3.Use Brookfield DV-I+Viscometer(Middleboro, MA) obtain viscosity test.The result is described in table 3.Clearly, representative polymer has shown the viscosity potentiation of using the shampoo system.Viscosity plays a part important relatively in hair care product, can is luxurious or enrich by consumers' perceptions because viscosity is thick.Also tested the character that spumes that contains and do not contain the shampoo of polymer.Polymer, particularly telomerized polymer play detrimental effect to the character that spumes of shampoo usually.The interpolation of representative polymer in shampoo increased the foam time of sending out near 3 times.
Table 3
Contain the evaluation of basic shampoo of the hydrophobically modified polymers of varying level
Figure G200680006524501D00251
The preparation of embodiment 5 natural shampoo preparations.
Composition shown in the use table 4 prepares natural shampoo preparation.
Table 4
Natural shampoo preparation
Compositions
Composition The INCI title Weight %
Deionized water Water QS
Geropon SBFA-30 Laureth-3 sulfosuccinate disodiums 3.00
Standapol A Ammonium lauryl sulfate, 30% 30.00
Plantacare 818UP Cocos nucifera oil-glucoside (Coco-Glucoside) 3.00
Glucamate DOE-120 PEG-120 methyl glucoside dioleate 2.10
Velvetex AB-45 Cocos nucifera oil-betanin (Coco-Betaine) 8.00
Methyl parahydroxybenzoate Methyl parahydroxybenzoate 0.20
Propyl p-hydroxybenzoate Propyl p-hydroxybenzoate 0.10
< > < > [0120] <> <>
Polysorbas20 Polysorbate 20 0.00
Polymer Polymer 0.25
Citric acid, 50% Citric acid, 50% QS
Embodiment 6 contains the evaluation of the natural shampoo of representational hydrophobically modified polymers.
Estimate as embodiment 5 described in viscosity, foam elution time and the slip of the natural shampoo preparation for preparing.Said shampoo is owing to glucose/ethoxylate (ethoxyate) be somewhat adherent.The result is shown in table 5.Improve said preparation through adding hydrophobically modified polymers, said hydrophobically modified polymers has reduced contrast substrate (base) stickiness feeling.In a word, the hydrophobically modified polymers that is added into shampoo makes the foam sensation than the contrast substrate that does not have polymer butter slightly more seemingly.
Table 5
Contain the evaluation of the natural shampoo of hydrophobically modified polymers
Sample Viscosity 5/20(cps) Visual observation Foam Elution time (second) Slide
Contrast natural shampoo 9,360 Clarification Like butter 1-2(glues) 4
0.5 mole C16 polymer 11,080 Clarification Like butter 2 4
Embodiment 7 contains the evaluation of the commercialization shampoo of representational hydrophobically modified polymers.
With C < >8 <>And C < >12 <>Alkyl (0.25% weight) representative polymer of the present invention of modification is put into Suave
Figure G200680006524501D00261
Shampoo keeps clarification with confirmatory sample.Also investigate Suave Natural Strawberry shampoo, can be added into the principle of existing preparation with the proof hydrophobically modified polymers later on.Usually, be added into the telomerized polymer generation muddiness of these systems.Be added into the C of these systems < > 8 <> And C < > 12 <> Slip and butyrous that polymer keeps said preparation better to clarify and increase.After 3 months, contain C < >8 <>And C < >12 <>The Suave of polymer
Figure G200680006524501D00262
Mountain Strawberry shampoo substrate keeps clarification.After be added into the instance of the polyquaternary ammonium salt of said preparation-7(typical case telomerized polymer) keep muddy.The introducing of said hydrophobically modified polymers is used to increase the compatibility of the ALS/ALES surfactant system of potential surfactant and Suave shampoo substrate.
Embodiment 8 contains the evaluation of the character that spumes of the shampoo of representative hydrophobically modified polymers.
Use the representative shampoo Compositions that contains composition shown in the table 6 of the alkyl-modified polymer manufacture of C12 to be produced and in the experiment of Hart de George foam, to be estimated.This tests demonstration; It is 23 seconds for the shampoo preparation of the polymer manufacture of using the modification of C12 hydrophobic group that hydrophobically modified polymers has produced more stable shampoo foam and longer thus efflux time (drain time)(, is 8.3 seconds and use the shampoo preparation of unmodified polymer preparation).
Table 6
The shampoo preparation that uses in the experiment of Hart de George foam
Composition Weight %
Deionized water 48.266
Sodium lauryl sulfate, 29% 10.00
Sodium laureth sulfate, 28% 30.00
Cocamido propyl betaine, 30% 3.00
Coconut oleoyl amine MIPA 1.00
The C12 polymer 5.00
Citric acid, 100%(s)
Sodium chloride
The EDTA disodium 0.10
Methylchloroisothiazandnone Methylisothiazolinone 0.05
The DMDM glycolylurea 0.10
The instrument of the embodiment 9 hydrophobically modified polymers combing (Instrumental wet combing that wets) estimates.
Wet combing is the common method of testing in order to the accommodation property of describing the material that adds the hair nursing preparation.Use 0.5% living solution treatment of hair bundle, clean then.Then at DiaStronTensile Tester(MTT 160, Hampshire, UK) in the carding force (combing force of the treated bundle of hair of test).The carding force in a small amount that in test, needs representes that said bundle of hair is by well-tuned.Below table 7 and 8 shows that the bundle of hair of using representative polymer to handle has outstanding combing character.
Table 7
The statistic that combing is analyzed
Level Number Average Standard error Be lower than 95% Be higher than 95%
The C-8 polymer 4 215.000 79.174 21.27 408.73
Contrast 4 551.250 79.174 357.52 744.98
Table 8
The statistic that combing is analyzed
Level Number Average Standard error Be lower than 95% Be higher than 95%
The C-12 polymer 6 64.117 33.822 -11.2 139.48
< > < > [0141] <> <>
Contrast 6 512.333 33.822 437.0 587.69
The wet combing (sensory wet combing of sensation in the embodiment 10 regulator preparations) and lubricity (lubricity properties) evaluation.
The adjusting formulation preparation that contains composition shown in the table 9 is following.
Spray in the entry hydroxyethyl-cellulose (HEC) and mixing 30 minutes under the medium speed.Heat this solution to 40 ℃, to guarantee said solution clarification and homogenizing.Add the stearamide propyl dimethyl amine then, use Fructus Citri Limoniae acid for adjusting pH to 4.0, add chlorination two cetyl Dimethyl Ammonium then.The mixture of this thickening is heated to 70 ℃, and adds cetyl, stearyl and Promulgen G(with Shan Yu base) admixture.Said mixture is heated to 0-85 ℃ and kept 30 minutes.Begin to cool down then, and slowly add cold deionized water.Said mixture is mixed and cooling, and be lower than 55 ℃ of interpolation silicone blends down.Be lower than the 40 ℃ of slow down EDTA of interpolation 0.05/30 diluents, and be lower than 35 ℃ of interpolation antiseptic down at last.
Table 9
Regulate preparation
Compositions PEG-2/DCQ PEG-2/DCQ
1%C16 1%C8
Composition
Deionized water 45.00 45.00
Hydroxyethyl-cellulose (HEC) 0.20 0.20
Citric acid, 50% 0.12 0.12
The stearamide propyl dimethyl amine 0.50 0.50
Chlorination two cetyl Dimethyl Ammonium, 67% 2.00 2.00
Chlorination EG-2 oil base ammonium methyl, 69% 0.50 0.50
Shan Yu base trimethyl ammonium Methylsulfate salt (Behentrimonium Methosulfate)(50%) and spermol and 1,3 butylene glycol 0.00 0.00
Spermol (C95) 3.00 3.00
Stearyl alcohol (S95) 2.00 2.00
Stearyl alcohol (70%) and ceteareth (Ceteareth)-20(30%) 1.00 1.00
Siloxanes 0.50 0.00
Be cooled to 0-55 ℃ deionized water 21.03 21.93
The EDTA disodium 0.05 0.05
Deionized water 2.90 3.00
DBDCB(with) dipropylene glycol 0.10 0.10
< > < > [0148] <> <>
The DMDM glycolylurea 0.10 0.10
Deionized water *(using the DI diluted polymer) 20.00 20.00
Deionized water 0.00 0.00
The C16 polymer 1.00 0.00
The C8 polymer 0.00 1.00
Wet combing of sensation in the embodiment 11 regulator preparations and lubricity evaluation.
The (wet detangling that tangles wets) wet combing and the (lubricity panel of lubricity group) test, press the regulator preparation of embodiment 10 preparations with following evaluation.
1. can reliably distinguish the said test of housebroken evaluation Shi Jinhang of impaired topknot and treated topknot.
2. with every group of totally three parts of same sample (replicate) test.
3. each test, the topknot that the topknot of untreated black decolouring and regulator are handled as a reference.
4. each topknot is through the 1ml product treatment, and rubs into topknot and continued for 60 seconds, cleans for 30 seconds at 38 ℃ of following tap waters subsequently.
5. topknot is gone to tangle and the setting group.Each topknot soaks three times to introduce entanglement once more in the 500ml deionized water.Remove unnecessary water with glove hands then.
6. group member (Panelists) use the wide end of black plastics ally comb to go to tangle twice.
7. next, the group member uses the said topknot of the wet comb of little toothed portion twice.
Through cocycle under the said topknot of combing four times to estimate fibre-fibre friction, estimate lubricity.
9. after each test, topknot soaks three times with introducing entanglement once more in deionized water, and removes unnecessary water with glove hands.
Five said topknots of the common grading of group members (the 1=height rubs to the low friction of 5=).The result is shown in table 10-12.Higher go to tangle wet combing and lubricity numeral preferable performance.
Table 10
Wet the going of containing the C16 hydrophobically modified polymers of regulator tangled and combing
Compositions Wet going tangled Wet combing Lubricity
Untreated 1.94 1.56 1.49
The C16 polymer 4.07 3.73 3.57
< > < > [0164] <> <> Table 11
Wet the going of containing the C8 hydrophobe of regulator tangled and combing
Compositions Wet going tangled Wet combing Lubricity
Untreated 2.13 1.71 1.50
The C8 polymer 4.26 3.96 3.79
Table 12
Wet the going of containing the C12 hydrophobe of regulator tangled and combing
Compositions Wet going tangled Wet combing Lubricity
Untreated 2.29 2.04 1.63
The C12 polymer 3.67 3.37 3.27
As show to show among the 10-12, hydrophobically modified polymers of the present invention provides the good moist matter that significantly is better than untreated black decolouring hair.
The preserve moisture smoothness (smoothness of smoothie gel of embodiment 12) estimates and the thin film evaluation
Use following group test, carry out smoothness and thin film evaluation according to the Smoothie gel preparation of table 13.
Table 13
The Smoothie gel of preserving moisture
Compositions Contrast The C-8 polymer The C-12 polymer Polyquaternary ammonium salt-7
Composition Weight % Weight % Weight % Weight %
Water Qs Qs qs qs
Hydroxyethyl-cellulose 0.53 0.53 0.53 0.53
Polyquaternary ammonium salt-4 0.17 0.17 0.17 0.17
C8 polymer (8%) 0.00 4.00 0.00 0.00
C12 polymer (5%) 0.00 0.00 4.00 0.00
Polyquaternary ammonium salt-7 0.00 0.00 0.00 4.00
Bai Manghua seed oil 0.025 0.025 0.025 0.025
The DMDM glycolylurea 0.20 0.20 0.20 0.20
Aromatic 0.10 0.10 0.10 0.10
Oleth-20(Oleth-20) 0.20 0.20 0.20 0.20
The group test of level and smooth sensation and thin film.
1. prepare 1 gram sample, length is each former hair (International HairImporters of 6 inches, Bellerose, and New York, USA).
2. application 1 gram polymer is on topknot.Pushing away the topknot 25 times of rubbing covers guaranteeing.
3. each topknot of wide terminal combing that uses ally typing comb is to go entanglement.
4. make sample air dry.
5. at random group member makes its finger slip over said topknot from top to bottom, and according to density (1=is unsmooth very level and smooth to 5=) and film hardness (1=is not stone to the 5=firmly) topknot of grading.
Smooth feeling is felt can help the aesthetics of product, and hair fiber is slipped over each other.This is the important goal of any adjusting product.Group uses following proposal to estimate the suitable sliding and level and smooth sensation from the preparation of above-mentioned prescription.The result lists in table 14.
Table 14
The preserve moisture working group of Smoothie gel estimates
Preparation Level and smooth sensation (n=4) Film hardness (n=4)
Water 4.0 1.0
Polyquaternary ammonium salt-7 2.9 3.6
Control formulation 2.8 4.3
The C8 polymer 3.0 4.8
The C16 polymer 3.0 4.8
Described in table 14, hydrophobically modified polymers of the present invention has shown that comparison is according to the hardness of preparation raising and the smoothness that improves a little.
Embodiment 13-16
The representative hair nursing preparation that contains hydrophobically modified polymers is prepared shown in embodiment 13-16.
Table 15
The shampoo of preserving moisture
Composition Weight %
Deionized water 49.11
Sodium lauryl sulfate, 29% 20.00
Sodium laureth sulfate, 28% 20.00
Cocamido propyl betaine, 30% 3.00
Lauramide DEA 3.00
Fatty acid/PG-2 0.50
The C8 polymer 3.13
Citric acid, 100%(s) 0.60
Sodium chloride 1.36
The EDTA disodium 0.10
< > < > [0192] <> <>
The DMDM glycolylurea 0.10
Yellow 0.038
Green 0.041
In the axle/viscosity of speed after 5/20 time 30 seconds is 13480cps.Shampoo produces very creamy foam.
The resident type (Less volume leave in of embodiment 14 low amounts) regulator
Table 16
The resident type regulator of low amount
Compositions
Composition Weight % Weight %
Water
Hydroxyethyl-cellulose 1.00 1.00
Chlorination two cetyl Dimethyl Ammonium (Varisoft 432CG) 3.00 3.00
Amino-terminated dimethyl polysiloxane (Amodimethicone)(with) chlorination cetyl trimethyl ammonium (cetrimonium chloride)(with) nonoxynolum (Nonoxynol)-10 (DC949) 0.25 0.25
The C8 polymer, 8% 12.50 0.00
Fructus Mali pumilae draft aromatic 0.10 0.10
The DMDM glycolylurea 0.40 0.20
When being used for said preparation, the C8 hydrophobically modified polymers to the effect of hair provide smoothly, gloss and stretching hair.When using 1% living polymer, to compare with the control formulation that does not have polymer, hair is stretching and level and smooth by more effectively.
Embodiment 15 ethnic group (ethnic) regulator.
Table 17
The ethnic group regulator
Compositions
Composition Weight % Weight %
Deionized water qs qs
Hydroxyethyl-cellulose 0.30 0.30
The stearamide propyl dimethyl amine 0.50 0.50
Chlorination two cetyl Dimethyl Ammonium (Varisoft 432CG) 3.00 3.00
Spermol 5.00 5.00
< > < > [0203] <> <>
Stearyl alcohol and ceteareth (Ceteareth)-20 2.00 2.00
Citric acid, 50% qs Qs
The C8 polymer 3.00 0.00
The C16 polymer 0.00 3.00
Cyclomethicone 1.00 1.00
Simethicone 10CS 0.20 0.20
The DMDM glycolylurea 0.20 0.20
This ethnic group regulator produces dry good stretching, extension and covering.
Embodiment 16 hair lotions.
Generate hair lotion with level and smooth hair.
Table 16
Hair lotion
Composition Weight % Weight %
Deionized water qs qs
Cocamido propyl betaine 2.00 2.00
Hydroxyethyl-cellulose 0.50 0.50
Acrylamide /DADMAC/ acrylate copolymer 2.00 2.00
The C8 polymer 5.00 0.00
The C12 polymer 0.00 5.00
The PEG-40 castor oil hydrogenated 0.20 0.20
Aromatic 0.10 0.10
The DMDM glycolylurea 0.20 0.20
The evaluation of embodiment 17 hydrophobically modified polymers in hair fixing is used.
Test contains the curling maintenance of the representative formulation of hydrophobically modified polymers, and it is the appraisal tool that typing is used.
6 inches long, topknot decolouring and that wrap in advance are available from International Hair Importesand Products Inc.
6 inches long, the decolouring with the home built topknot, available from DeMeo Brothers Inc.
Through " hair of width prepares the topknot that is used to test to cut 1/8 from the said topknot of wrapping in advance (every bundle 0.4g).This topknot water is moistening, the 0.3g sodium laureth sulfate is pushed away from top to bottom rub on said topknot then, continues 1 minute.Then 40 ± 2 ℃ of following tap water flushings 1 minute.The topknot of washing is soaked in the deionized water and spends the night.
The topknot of cleaning soaked 2 minutes in the aqueous solutions of polymers of 0.5% weight.With glove finger excessive solution is extruded from said topknot.The every topknot of wide terminal combing that uses the ally Shaping comb twists in hair on the roller (diameter 11/16 ") to go entanglement then.This hair is provided at the indoor of 50% relative humidity to spend the night.Second day, launch hair from each roller, and the hair that curls is placed the indoor of 90% relative humidity.Per length (fall-out that measured said volume in 15 minutes), continue 2 hours, and keep through following Equation for Calculating is curling:
Figure G200680006524501D00341
Equation 1: Calculation curl retention
The topknot length of L=full extension wherein
The topknot length of Lo=during on-test
Topknot length when Lt=measures
Following table has been described the curling maintenance of C-16 polymer phase for benchmark (methacrylic acid/acrylamido methyl propane sulfonic acid sodium copolymer).
Table 19
Curl and keep
Time Contrast The C-16 polymer Benchmark
15 51.10 78.24 85.32
30 38.05 68.00 75.30
45 33.41 64.87 71.51
60 32.25 63.29 69.06
75 30.86 62.50 68.18
90 30.38 61.97 67.51
105 30.15 61.45 67.51
120 29.45 60.67 66.17
Data in the table 19 show that the curling maintenance of representational hydrophobically modified polymers is equivalent to benchmark.
The representational hair fixing preparation of embodiment 8-21.
Embodiment 8-21 has shown the representative polymer in the hair fixing preparation.
Use or do not use the typing paste formulation of representative polymer of the present invention and reference polymer preparation to be shown in table 20.
Table 20
The typing cream that contains representative polymer
Compositions
Composition Weight % Weight %
Deionized water qs qs
Polyquaternary ammonium salt-37/ propylene glycol/dicaprylate dicaprate (Dicaprylate Dicaprate) and PPG-1 Trideceth-6 1,50% 4.00 4.00
The C16 polymer 1.00 0.00
Deionized water 10.00 10.00
Polyvinylpyrrolidone 2 0.00 0.25
Encircle penta siloxanes 3 1.00 1.00
1Salcare SC96,Ciba Specialty Chemicals,Highpoint,NC,USA。
2PVP-K30,International Specialties Products,Wayne,NJ,USA。
3DoW Corning
Figure G200680006524501D00351
245fluid,Dow Corning,Midland,MI,USA。
Embodiment 19 hair styling mousses.
Use the hair styling mousse preparation of hydrophobically modified polymers preparation to increase creaminess and level and smooth hair.Representational preparation is shown in table 21.
Table 21
Hair styling mousse
Compositions The C-12 polymer The C-8 polymer
Composition Weight % Weight %
Deionized water Qs Qs
SD alcohol 40 20.00 20.00
The C12 polymer 4.00 0.00
The C8 polymer 0.00 4.00
Chlorination cetyl trimethyl ammonium 1.00 1.00
Antiseptic Qs Qs
< > < > [0239] <> <>
Aromatic Qs Qs
Embodiment 20 mineral oil gels
Use the mineral oil gel of hydrophobically modified polymers preparation that extra adjusting of this gel and compliance are provided.Representational preparation is shown in table 22.
Table 22
Mineral oil gel
Compositions The C-12 polymer The C-8 polymer
Composition Weight % Weight %
Deionized water Qs Qs
The C12 polymer 2.00 0.00
The C8 polymer 0.00 2.00
Mineral oil 10.00 10.00
Oleth (Oleth)-10 21.00 21.00
The PEG-25 castor oil hydrogenated 10.00 10.00
Glycerol 8.00 8.00
Antiseptic Qs Qs
Aromatic Qs Qs
Embodiment 21 resident (Leave-on) or eluting (rinse-off) send out slurry (hair taffy).
The ability that test said preparation deep layer is regulated hair on hair.Allow said preparation dry on hair, rinse out then to produce soft moistening sensation.The interpolation of C12 or C8 polymer allows flushing sensation that more silk is sliding and the adjusting that increases.Representational preparation is shown in table 23.
Table 23
Resident (Leave-on) or eluting (rinse-off) send out slurry
Composition Weight % Weight %
Water 91.04 90.50
Polyacrylamide (with the)C13-14 isoparaffin (with) laureth-7 4.00 4.00
Cyclomethicone 1.00 1.00
The PPG-10 methyl cellulose ether 2.00 2.00
C12 polymer (5%) 1.96 0.00
C8 polymer (8%) 0.00 2.50
Antiseptic qs qs
< > < > [0250] <> <> Embodiment 22 various surfactants and polymer are to the evaluation of the spreading ability of skin nursing Parafilm.
With the rapid screening method that is described below, carry out this research near wetting behavior.
1.50 0.2%, 1.0% solution of μ l or dispersion are moved liquid to 10cm * 10cm ParafilmWax flat board.
2.5 after minute, measure the maximum gauge of drop.Measure three duplicate samples.(room temperature is 23 ℃) carried out in test under environmental condition.
3. invasin is calculated as the average value measured of test solution diameter and distilled water diameter (0.6cm or three drops) ratio.
The result is shown in table 24.
Table 24
Various surfactants are sprawling on the Parafilm surface relatively under environmental condition
System Diameter (cm) Invasin Document surface tension (dyne /cm)
Deionized water 0.58 1.00 72.8
Cyclomethicone, cleaning 3.37 5.81 20-35
The C8 polymer, 0.2% 0.58 1.00 NA
The C12 polymer, 0.2% 0.58 1.00 NA
The C16 polymer, 0.2% 0.58 1.00 NA
The C8 polymer, 1.0% 0.60 1.03 NA
The C12 polymer, 1.0% 0.63 1.05 NA
The C16 polymer, 1.0% 0.70 1.17 NA
Sodium lauryl sulfate, 0.1% 0.70 1.20 44.3
The preparation that discovery contains hydrophobically modified polymers (even having low hydrophobic replacement) is surface-active.The result shows that surface activity increases with alkyl chain length.The C16 polymer has more surface activity than C12 polymer, and the C12 polymer is because of it spumes, heavy-gravity character is than C8 polymer self-association (self-associate more).
Embodiment 23-26 contains the representative skin care formulation of hydrophobically modified polymers.
Polymer of the present invention also can be used for handling skin.Do not receive any theory, polymer of the present invention can form protecting film on skin or fingernail.The skin nursing lotion preparation is shown in embodiment 23-26.
In the level and smooth frost of face, the interpolation of hydrophobically modified polymers, produced only use separately salt the extraordinary viscosity structure (build that can not obtain).Representational prescription is shown in table 25.
Table 25
Face is frost smoothly
Composition Weight % Weight %
Deionized water 80.00 80.00
Aluminium-magnesium silicate 1 1.90 1.90
Xanthan gum 2 1.27 1.27
Glycerol 0.40 0.40
Simethicone copolyol (Dimethicone Copolyol) 3 0.10 0.10
The DMDM glycolylurea 0.20 0.20
Deionized water 6.13 6.13
C8 polymer (5%) 0.00 5.00
Deionized water 10.00 5.00
1Veegum HV,R.T.Vanderbilt Company,Norwalk,CT USA。
2Keltrol CG-F,CP Kelco,Leatherhead,Surrey UK。
< > 3 <> Dow 193 Fluid, simethicone copolyol (Dimethicone Copolyol), DowCorning, Midland, MI USA.
4Glydant,Lonza,Fairlawn,NJ USA。
The level and smooth white substrate [1.27% xanthan gum of face/1.9% aluminium-magnesium silicate (MAS)] viscosity significantly improves through the interpolation of 0.25%C8 polymer.The original viscosity that does not have the substrate of polymer is 6600cps(5/20,30 seconds, and 23.5 ℃).Adding 0.25%C8 polymer viscosity afterwards is 16000cps(6/20).
Said hydrophobically modified polymers can be used as main (primary) or auxiliary (secondary) regulator.It can be used for thickening, moistening, increase foam, form the thin film and the adjuvant (secondary of stable emulsion or dispersion perhaps).
Embodiment 24 bubble baths.
After the sensation, hydrophobically modified polymers produces skin soft and that silk is sliding in the bubble bath preparation.
Representational preparation is shown in table 26
Table 26
Bubble bath
Composition Weight % Weight %
Deionized water qs qs
Ammonium lauryl sulfate, 29% 35.00 35.00
Cocamidopropyl propyl amide hydroxyl sulfo betaine (Cocamidopropyl Hydroxysultaine) 5.00 5.00
Lauramide DEA 4.00 4.00
The laureth disodium sulfosuccinate 8.00 8.00
Hexanediol 2.00 2.00
The C12 polymer 3.00 0.00
The C8 polymer 0.00 3.00
Citric acid, 100%(s) Qs pH 6.0 Qs pH 6.0
Sodium chloride 1.36 1.36
The EDTA disodium 0.10 0.10
The DMDM glycolylurea 0.10 0.10
Aromatic Qs Qs
Embodiment 25 lotion of preserving moisture.
Hydrophobically modified polymers produces soft and smooth after touching skin, and the emulsion spreadability of the lotion preparation that helps to preserve moisture.Representational preparation is shown in table 27.
Table 27
The lotion of preserving moisture
Composition Weight % Weight %
Water qs qs
Hydroxyethyl-cellulose 0.25 0.25
Glycerol 2.00 2.00
Vaseline 2.00 2.00
Mineral oil 4.00 4.00
Spermol 3.00 3.00
Stearyl alcohol 2.00 2.00
Polawax NF 1.00 1.00
Simethicone 100cs 0.50 0.50
Acrylic ester /C10-30 alkyl acrylate cross-linked polymer 0.30 0.30
Triethanolamine 0.25 0.25
C12 polymer (5%) 5.00 0.00
C8 polymer (8%) 0.00 3.125
< > < > [0283] <> <>
Antiseptic qs qs
The representational liquid hand soaps of the evaluation preparation that the viscosity of the liquid hands soap preparation of hydrophobically modified polymers of containing embodiment 26 improves is shown in table 28.Viscosity data is shown in table 29.
Table 28
Liquid hand soaps preparation
Composition Weight %
Deionized water qs
Sodium lauryl sulfate, 29% 10.00
Sodium laureth sulfate, 1 mole of EO, 28% 8.21
The cocoyl sodium isethionate 2.00
The C8 polymer 0.00
The C12 polymer 5.00
Citric acid, 100%(s) 0.006
Sodium chloride qs
The EDTA disodium 0.10
Kathon CG 0.05
The DMDM glycolylurea 0.10
Table 29
Viscosity measurement
Sample Viscosity under 1.0%NaCl, 4/20
The contrast hand soaps 2540
The C12 polymer 3410
Benchmark, hydroxypropyl emthylcellulose 1880
As shown in Table 29, provide comparison to shine and the higher viscosity of benchmark hydroxypropyl emthylcellulose material with the bonded C12 hydrophobic polymer of 1% sodium chloride.
Embodiment 27 contains group's combing evaluation of the silicon of hydrophobically modified polymers.
Use two parts of topknots of two kinds of polymer-modified processing of silicon.Treated topknot washed for 15 seconds under deionized water then.Repeating this handles other twice.Hair setting comprises entanglement and wet combing.Grade from 1 to 5.High representes that hair is easier to tangle and combing.Following table has been summed up the test result from housebroken group member.Its polymer-modified comparison of silicon that shows two types is better according to combing.
Table 30
Group's combing that silicon is polymer-modified
Title Go to tangle The combing grade
Contrast 2 2
Polymer IX 4.4 3.6
Polymer X 4.1 3.0
Embodiment 28 laundry detergent preparations
Hydrophobically modified polymers has shown good and compatibility anion surfactant and viscosity potentiation.These advantages allow representative polymer to be formulated into household cleaners and laundry detergent.Representational laundry detergent formulations is shown in table 31.Through with listed order adding ingredient and use moderate agitation to dissolve each fully to become to assign to prepare said preparation.If desired, can add color and aromatic additive.
Table 31
Laundry detergent performance number
Composition %wt
Water qs
The C12 polymer 2
EDTA four sodium (38%) 0.2
C 12/14Alkyl polyglucoside 4.0
Alkyl ethoxylate (ethoxylate) 3.5
LINER ALKYL BENZENE SULPHONIC ACID SOFT 96 sodium 6.5
Monoethanolamine 1.0
Although described the present invention for the purpose of illustration in detail; But it is to be understood that this details just is used for this purpose; Those skilled in the art can make many adjustment, variation and change therein, and do not break away from the spirit and scope of the present invention, except that right require to be limited.Fall into the implication that is equivalent to this claim and the change within the scope with being included in this claim scope.

Claims (21)

1. acceptable composition in the cosmetic; It comprises one or more hydrophobically modified polyacrylamides; Wherein said polyacrylamide is made up of acrylamide and one or more cationic monomers; Perhaps said polyacrylamide is made up of acrylamide, one or more cationic monomers and one or more anionic monomers; Wherein a part of amide groups group in the amide groups group of polymer backbone is modified through the transamidation of hydrophobic amine, and wherein said hydrophobic amine is selected from C < > 6 <>-C < > 22 <> The group that the siloxanes of alkylamine and aminofunctional is formed; Wherein said one or more cationic monomers are to be adapted at also can changeing the vinyl monomer that acylamino-reaction back keeps clean positive charge with said acrylamide copolymerization under the free radical formation condition, and wherein said hydrophobically modified polymers has 0.1 to 8dL/g reduced viscosity RSV; Wherein said anionic monomer is selected from the base addition salts, 2-acrylamido-base addition salts, sulfopropyl acrylic ester or the base addition salts of sulfopropyl methacrylate of 2-methyl-1-propane sulfonic acid, the base addition salts of sulfomethylated acrylamide, the base addition salts of allylsulfonate, base addition salts, sodium vinyl sulfonate, acrylic acid and the 2-acrylamido-2-methyl-1-propane sulfonic acid of styrene sulfonic acid in base addition salts, the itaconic acid of acrylic acid base addition salts, methacrylic acid; Said cationic monomer is selected from the monomer with following formula:
R wherein < > 1 <>-R < > 13 <> Independently be selected from H ,-CH < > 3 <> With-CH < > 2 <> CH < > 3 <> And n is 2 or 3.
2. acceptable composition in the cosmetic as claimed in claim 1, wherein said polyacrylamide is made up of at least 50% mole acrylamide.
3. acceptable composition in the cosmetic as claimed in claim 2, wherein said polyacrylamide is modified through the transamidation of one or more hydrophobic amines of 0.1 to 10% mole.
4. acceptable composition in the cosmetic as claimed in claim 3, wherein said cationic monomer are selected from chlorination diallyl dimethyl ammonium and methyl chloride acrylamido oxypropyl trimethyl ammonium.
5. acceptable composition in the cosmetic as claimed in claim 4, wherein said hydrophobically modified polymers has 1 to 5 RSV.
6. acceptable composition in the cosmetic as claimed in claim 5, wherein said polyacrylamide are acrylamide/chlorination diallyl dimethyl ammonium copolymers.
7. acceptable composition in the cosmetic as claimed in claim 5, wherein said polyacrylamide are acrylamide/chlorination diallyl dimethyl ammonium/acrylic ternary copolymers.
8. acceptable composition in the cosmetic as claimed in claim 6, wherein said C < > 6 <>-C < > 22 <> Alkylamine is selected from the group of octyl amine, lauryl amine, hexadecylamine composition.
9. acceptable composition in the cosmetic as claimed in claim 6, wherein said C < > 6 <>-C < > 22 <> Alkylamine is selected from the group of the silane composition of aminofunctional.
10. acceptable composition in the cosmetic as claimed in claim 1, it further comprises one or more upward acceptable excipient of making up.
11. acceptable composition in the cosmetic as claimed in claim 10, it comprises the hydrophobically modified polymers based on 0.01 to 40% weight of polymer solids.
12. acceptable composition in the cosmetic as claimed in claim 10, wherein said excipient are selected from water, saccharide, surfactant, wetting agent, vaseline, mineral oil, fatty ester softening agent, wax, silicone oil, siloxanes liquid, volatility hydrocarbon ils, quaternary nitrogen chemical compound, amine-functionalized siloxanes, telomerized polymer, antioxidant, sunscreen actives agent, from C < > 10 <> To C < > 22 <> Long-chain fat amine, aliphatic alcohol, the aliphatic alcohol of ethoxylation and the group that two tail phospholipid are formed.
13. acceptable composition in the cosmetic as claimed in claim 12, wherein said wax are the wax that contains siloxanes.
14. acceptable composition in the cosmetic as claimed in claim 12, wherein said surfactant is a silicone surfactant.
15. acceptable composition in the cosmetic as claimed in claim 12, wherein said telomerized polymer is a rheology modifier.
16. acceptable composition in the cosmetic as claimed in claim 12 is wherein said from C < > 10 <> To C < > 22 <> Long-chain fat amine be from C < > 10 <> To C < > 22 <> Two long-chain amines.
17. acceptable composition in the cosmetic as claimed in claim 1, it is selected from: shampoo; Aftershave lotion; Sunscreen; Lotion; Hands and health cream; Liquid soap; Soap slab; The bath oil rod; Shaving cream; Dishwashing liquid; Regulator; Long-acting setting lotion; Relaxor; The hair depigmenting agent; Hair removes the lotion that tangles; The typing gel; Design-shaping gel; The spraying foam; Typing cream; The typing lotion; Mousse; Spray gel; Brilliantine; Bath gels; Bubble bath; The hair-dyeing agent; Non-painted hair conditioner; The curly hair fixative; Setting lotion; Hair straighten; The haircut adjuvant; Hair oil; Hair is modified and oxygenated products; Spray; The group that typing wax and balsam are formed.
18. acceptable composition in the cosmetic as claimed in claim 17, wherein said hair-dyeing agent are interim or long lasting hair color agent, color adaptation agent, hair brightening agent, painted hair conditioner or hair dye.
19. acceptable composition in the cosmetic as claimed in claim 1, wherein said compositions are household cleaners or laundry detergent.
20. a processing is selected from the method for the substrate of hair, skin or fingernail, it comprises acceptable composition in the described cosmetic of claim 1 is applied to said substrate.
21. method as claimed in claim 20, wherein said substrate is hair.
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Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8241618B2 (en) * 2005-01-27 2012-08-14 Lubrizol Advanced Materials, Inc. Process for producing a hydrophobically modified polymer for use with personal care compositions
US20090069522A1 (en) 2007-09-11 2009-03-12 Hessefort Yin Z Hydrophobically modified polymers
US20110219552A1 (en) * 2007-12-31 2011-09-15 Yan Zhou Method of Protecting Dyed Hair Color from Fading or Wash-Out
KR101441025B1 (en) * 2008-03-05 2014-09-17 주식회사 엘지생활건강 Hair conditioning composition
JP5467672B2 (en) * 2009-01-29 2014-04-09 株式会社マンダム Gel hair conditioner
BRPI1010282B1 (en) * 2009-03-27 2017-05-02 Hercules Inc amino polymers and their use in aqueous compositions
KR101004288B1 (en) * 2010-07-01 2011-01-03 고도윤 Preparing method of composition with enhanced efficacy of blending aromatic oil for improving condition of hair and scalp
ES2393028B1 (en) * 2011-03-24 2013-11-05 Martín BAENA JIMÉNEZ PROCEDURE FOR OBTAINING A HAND CREAM.
ES2395011B1 (en) * 2011-03-25 2013-12-27 Martín BAENA JIMÉNEZ PROCEDURE FOR OBTAINING A BODY MILK
EP2594247A3 (en) * 2011-09-02 2015-01-07 The Procter & Gamble Company Personal care composition comprising butylated hydroxyanisole compound
CN102796222B (en) * 2012-08-28 2014-07-23 山东大学 Synthesis method of hydrophobically associated polyacrylamide
KR101488376B1 (en) * 2012-12-28 2015-02-02 동아대학교 산학협력단 Zizania Bath Bubble Bomb composition and Preparing Method thereof
JP5913475B2 (en) * 2014-08-06 2016-04-27 株式会社 資生堂 Raw materials for cosmetics
JP6715840B6 (en) 2014-11-25 2020-07-29 ダウ グローバル テクノロジーズ エルエルシー Hair care composition containing cationic polymer
WO2016085707A1 (en) 2014-11-25 2016-06-02 The Dow Chemical Company Personal care compositions containing cationic polymers
JP2017002133A (en) * 2015-06-05 2017-01-05 東邦化学工業株式会社 Detergent composition
US10827757B2 (en) * 2015-10-12 2020-11-10 Lubrizol Advanced Materials, Inc. Biocidally active polymer compositions
US20180305636A1 (en) * 2015-10-23 2018-10-25 Basf Se Solid solutions of odoriferous substances and flavoring agents with vinyl lactam polymers
WO2017139765A1 (en) * 2016-02-12 2017-08-17 Rodan & Fields, Llc Moisturizing compositions and uses thereof
BR112019025183A2 (en) * 2017-06-15 2020-06-16 Unilever Nv CONDITIONING COMPOSITION, WATER SAVING METHOD AND ANIONIC POLYMER USE
EP3638197B1 (en) * 2017-06-15 2023-01-18 Unilever IP Holdings B.V. Hair conditioning composition having improved rinsing properties
CN112041418A (en) 2018-05-02 2020-12-04 奈克斯特阿普有限公司 Laundry sheet
EP4037653A1 (en) * 2019-10-04 2022-08-10 Living Proof, Inc. Cosmetic compositions comprising chitosan and hydroxypropyl methylcellulose and their use for improving hair strength and related properties

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0522756A1 (en) * 1991-06-28 1993-01-13 Calgon Corporation Ampholyte terpolymers providing superior conditioning properties in skin and nail care products
US6207778B1 (en) * 1999-05-07 2001-03-27 Isp Investments Inc. Conditioning/styling terpolymers

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3172845D1 (en) * 1980-11-19 1985-12-12 Du Pont Aqueous cleaning emulsion
US4731419A (en) * 1986-02-24 1988-03-15 Nalco Chemical Company Alkoxylated/cationically modified amide-containing polymers
JPH0813938B2 (en) * 1986-06-24 1996-02-14 味の素株式会社 Surface modifiers for inorganic and organic pigments
US5128419A (en) * 1990-08-20 1992-07-07 Nalco Chemical Company Synthesis of tagged polymers by post-polymerization (trans) amidation reaction
CA2072185C (en) * 1991-06-28 2002-10-01 Shih-Ruey T. Chen Ampholyte terpolymers providing superior conditioning properties in shampoos and other hair care products
US5167828A (en) * 1991-10-07 1992-12-01 Nalco Chemical Company Phosphinate-containing polymers for controlling scale in underground petroleum-containing formations and equipment associated therewith
FR2683224A1 (en) * 1991-10-30 1993-05-07 Bristol Myers Squibb Co MODIFIED HYDROPHOBIC COPOLYMERS WITH INTERNAL LOAD.
US6361768B1 (en) * 1998-12-29 2002-03-26 Pmd Holdings Corp. Hydrophilic ampholytic polymer

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0522756A1 (en) * 1991-06-28 1993-01-13 Calgon Corporation Ampholyte terpolymers providing superior conditioning properties in skin and nail care products
US6207778B1 (en) * 1999-05-07 2001-03-27 Isp Investments Inc. Conditioning/styling terpolymers

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