Summary of the invention
The present invention make up to go up acceptable compositions, and said compositions comprises one or more hydrophobically modified polyacrylamides, and wherein said polyacrylamide is by acrylamide, one or more cationic monomers and choose any one kind of them or multiple anionic monomer is formed.
According to the type of the hydrophobic part that mixes polymer, the character that said hydrophobically modified polyacrylamide has improved for example creaminess, slip, sensation, viscosity and preserved moisture.
Detailed Description Of The Invention
" anionic monomer " expression is like the monomer of this paper definition, and it has the net negative charge that is higher than a certain pH value.Representational anionic monomer comprises: acrylic acid base addition salts; The base addition salts of methacrylic acid; The base addition salts in itaconic acid; The base addition salts of 2-acrylamido (acrylamido)-2-methyl-1-propane sulfonic acid; Sulfopropyl acrylic ester or sulfopropyl methacrylate (sulfopropyl acrylateor methacrylate) base addition salts; Perhaps these or other polymerizable (polymerizable) base addition salts of the acrylamide base addition salts of other water-soluble forms of carboxylic acid or sulfonic acid, sulfomethylated (sulphomethylated); Allylsulfonate (allyl sulphonate) base addition salts; The base addition salts of styrene sulfonic acid; Sodium vinyl sulfonate and analog.The preferred anionic surfactants monomer is acrylic acid and 2-acrylamido-2-methyl-1-propane sulfonic acid.
" base addition salts " expression salt that reactions generated: carboxylic acid (-CO < > 2 <> H) the suitable alkali of hydroxide, carbonate or the bicarbonate of group and for example metal cation or tetraalkylammonium cation, or with ammonia or fully organic primary amine, secondary amine or the reactive tertiary amine of alkalescence, have the salt of hydroxy-acid group with generation.Representational alkali metal or alkali salt comprise sodium, lithium, potassium, calcium, magnesium and analog.The representational organic amine that is used to generate base addition salts comprises ethamine, diethylamine, ethylenediamine, ethanolamine, diethanolamine, piperazine and analog.Preferred base addition salts comprises sodium salt and ammonium salt.
" cationic monomer " expression is adapted at also can be at the vinyl monomer of the clean positive charge of commentaries on classics acylamino-reaction back maintenance as described herein with the acrylamide copolymerization under the free radical formation condition.Representational cationic monomer includes but not limited to have the monomer of following formula
R wherein < > 1 <>-R < > 13 <> Independently be selected from H ,-CH < > 3 <> With-CH < > 2 <> CH < > 3 <> And n is 2 or 3.
" IV " representing characteristic viscosity (intrinsic viscosity), it is the RSV that is extrapolated to the infinite dilution limit, and infinite dilution is that polymer concentration is when equalling zero.
" hydrophobic alkyl (Hydrophobic alkyl group) " expression about 4 alkyl (alkyl), alkenyl, cycloalkyl, aryl or aryl (arylalkyl group) to about 22 carbon atoms.Alkyl and alkenyl can be straight or brancheds, and can be interrupted by one or more-OSi(R ')(R ")-with-Si(R ')(R ")-group, and wherein R ' and R " are C < > 1 <>-C < > 4 <> Alkyl.
The such chemical compound of " hydrophobic amine " expression: contain at least one hydrophobic alkyl and at least one amino hydrogen atom, its can with the amide (-C(O of the polyacrylamide of this paper definition) NH < > 2 <> ) reaction of group generation commentaries on classics acylamino-, to generate the polyacrylamide of hydrophobically modified.The hydrophobic amine that contains-OSi(R ')(R ")-with-Si(R ')(R ")-group also is called as " silane of aminofunctional ".Representational hydrophobic amine comprises benzylamine, cyclohexylamine, hexylamine, tuaminoheptane, phenethylamine, octylame, oleyl amine, decyl amine, lauryl amine, octadecylamine and analog.
Representational aminofunctional silane comprises: the amine of following formula
Wherein p is from about 5 to about 500, available from Aldrich, Milwaukee, WI; amino ethyl propyl siloxane (silicone) compound, available from Noveon, Cleveland, OH (trade name Ultrasil) and Siltech Corporation, Toronto, Ontario, Canada (tradename Silamine); and amine functional siloxane, including all obtained from Dow Corning, Midland, MI for DowCorning
8220, Dow Corning
939, Dow Corning
949, Dow Corning
2-8194, and obtained from the General Electric, Waterford, NY is Silicone SM 253.
The polyacrylamide of " hydrophobically modified polymers " and " hydrophobically modified polyacrylamide " expression this paper definition is wherein along polymer backbone (backbone) a part of amide groups (-C(O) NH < > 2 <> ) transamidation of group through the hydrophobic amine (modified that is modified).Therefore; Except repetitive from cationic monomer and any anionic monomer; Said hydrophobically modified polymers comprises the repetitive with following structure, and wherein RaRb represents the hydrophobic group that generates with the hydrophobic amine transamidation, and M is H or base addition salts.
" polyacrylamide " expression is by acrylamide defined herein, one or more cationic monomers and any anionic monomer polymerization and the polymer that generates under the free radical formation condition.Suitable polyacrylamide can commercial obtain to be emulsion (emulsion), dispersion (dispersion), solution and powder type, the standard method of radical polymerization that perhaps can be through being used for vinyl monomer prepares.
" RSV " represents reduced viscosity.Or in a series of substantially linear polymers with a good solvent of Homologue in the dilute polymer solution of the "viscosity (RSV)" measurements indicate the polymer chain length and average molecular weight, according to Paul J. Flory, in "Principles of Polymer Chemistry (polymer chemistry)", Cornell University Press, Ithaca, NY.,
1953, Chapter VII, "Determination of Molecular Weights (molecular weight determination) "on pages 266-316.Under given polymer concentration and temperature, measure RSV and calculating as follows:
The viscosity of η=polymer solution
η < > 0 <> The viscosity of solvent under the=uniform temp
The concentration of polymer in the c=solution
Concentration unit " c " is (gram/100ml or a g/ decilitre).Therefore, the unit of RSV is dL/g.In present patent application, except as otherwise noted, use 1.0 moles sodium chloride solution to be used to measure RSV.Polymer concentration is 0.100g/dL in this solvent.Measure RSV down at 30 ℃.Use CannonUbbelohde semimicro dilution viscometer (size 75) to measure viscosities il and viscosities il < > 0 <> The complete plumbness of said viscometer places the constant temperature bath that transfers to 30 ± 0.02 ℃.Inherent error is about 2dL/g in RSV calculates.Two polymer homologs have similar RSV in a series of, then indicate them to have similar molecular weight.
Nontoxic, the non-stimulated material of " acceptable excipient in the cosmetic " expression, when mixing with hydrophobically modified polymers of the present invention, it makes said polymer be more suitable for being applied to hair or skin.
In one embodiment, through heating under the temperature and pressure that raises, use about 0.1 one or more about 10% mole hydrophobic amines to carry out the amide (-C(O of PAMC) NH < > 2 <> ) transamidation of group prepares hydrophobically modified polymers of the present invention.Can add alkali to keep hydrophobic amine in its alkalescence but not protonated form.Suitable alkali comprises the hydroxide and the carbonate of ammonia and alkali metal and alkaline-earth metal.
In one embodiment, said PAMC with from sodium pyrosulfite (sodiummetabisulfite) and the sulfite solution processed of sodium hydroxide under the about 9-10 of pH, in the stainless steel pressure reaction vessel, mix.Add said hydrophobic amine, use the air in the nitrogen substitution reaction device.Said mixture heated about 0.5 hour to about 8 hours down at about 120 ℃ to about 180 ℃.In one embodiment, said mixture heated about 5 hours down at about 140 ℃.Make water that the hydrophobically modified polymers that is generated is diluted to the concentration of hope then, and choose wantonly and use one or more antiseptic to handle at elevated temperatures.In one embodiment, use methyl parahydroxybenzoate and propyl p-hydroxybenzoate to handle said hydrophobically modified polymers solution 1 hour down at 5-90 ℃.Through viscosity, < > 13 <> C NMR, GC and GPC method characterize (characterize) product.
In one embodiment, said PAMC is by forming at least about 50% mole acrylamide.
In one embodiment, the RSV of said hydrophobically modified polymers about 0.1 is to about 8dL/g.
In one embodiment, said cationic monomer is selected from chlorination diallyl dimethyl ammonium (diallyldimethylammonium chloride) and methyl chloride acrylamido oxypropyl trimethyl ammonium (methacrylamidopropyltrimethylammonium chloride).
In one embodiment, said hydrophobic amine is selected from C < > 6 <>-C < > 22 <> Alkylamine (alkyl amines) and the group formed of the siloxanes of aminofunctional.
In one embodiment, the RSV of said hydrophobically modified polymers is about 1 to about 5.
In one embodiment, said PAMC is acrylamide/chlorination diallyl dimethyl ammonium copolymer.
In one embodiment, said PAMC is acrylamide/chlorination diallyl dimethyl ammonium/acrylic ternary copolymer.
In one embodiment, said alkylamine is selected from the group that octylame, lauryl amine and hexadecylamine are formed.
In one embodiment, said compositions further comprises one or more upward acceptable excipient of making up.
In one embodiment, acceptable composition comprises based on polymer solids about 0.01 hydrophobically modified polymers to about 40% weight in the said cosmetic.
In one embodiment, acceptable excipient is selected from saccharide, surfactant (surface-active agents in the said cosmetic), wetting agent, vaseline, mineral oil, aliphatic alcohol, fatty ester softening agent, wax and contain wax, silicone oil, the siloxanes liquid (silicone fluid of siloxanes), silicone surfactant (silicone surfactants), volatility hydrocarbon ils, quaternary nitrogen chemical compound, amine-functionalized siloxanes, telomerized polymer, rheology modifier, antioxidant, sunscreen actives agent, from about C < > 10 <> To C < > 22 <> Two long-chain amines, from about C < > 10 <> To C < > 22 <> Long-chain fat amine, aliphatic alcohol, the aliphatic alcohol and the two tail phospholipid (di-tail phospholipid of ethoxylation) group formed.
Representational saccharide comprises non-ionic or cationic saccharide; Agarose for example; Amylopectin; Amylose; ARABINANS (arabinans); Arabinogalactan; WU-AX Arabinoxylan (arabinoxylens); Antler glue; Radix Acaciae senegalis; Carboxymethyl guar glue; Carboxymethyl (hydroxypropyl) guar gum; The ethoxy guar gum; Carboxymethyl cellulose; Cation guar gum comprises the cellulose ether of methylcellulose; Chrondroitin; Chitin (chitins); Chitosan; Chitosan pyrrolidone carboxylic acid salt (chitosan pyrrolidone carboxylate); Chitosan oxyacetate (chitosan glycolate) chitosan lactate (chitosan lactate); Cocoyl Dimethyl Ammonium (cocodimonium) hydroxypropyl oxygen ethyl cellulose; Colominic acid (gathers-N acetyl-neuraminic acid); Corn starch; Curdlan; Dermatan sulfate (dermatin sulfate); Glucosan; Furcellaran (furcellarans); Glucosan; Crosslinked glucosan; Dextrin; Emulsion adhesive (emulsan); Ethylhydroxyethylcellulose; Semen Lini sugar (tart); Galactoglucomannan; Galactomannan; Glucomannan; Glycogen; Guar gum; Hetastarch; Hydroxypropyl emthylcellulose; Hydroxyethyl-cellulose; Hydroxypropyl cellulose; Hydroxypropyl starch; The guar gum of hydroxypropylation; Gel sugar natural gum (gellan gum); Gel sugar (gellan); Ficus elastica; Karaya; Gum tragacanth (tragacanthin); Heparin; Hyaluronic acid; Inulin (inulin); Keratin sulfate (keratin sulfate); Konjacmannan (konjac mannan); Modified starch; Laminariose (laminarans); Lauryl dimethyl ammonium (laurdimonium) hydroxypropyl oxygen ethyl cellulose; Flos abelmoschi manihot natural gum (okra gum); Oxytarch; Pectic acid; Pectin; Polydextrose; Polyquaternary ammonium salt (polyquaternium)-4; Polyquaternary ammonium salt-10; Polyquaternary ammonium salt-28; Potato starch; Pectin, proto; Psyllium seed natural gum (psylliumseed gum); Pullulan (pullulan); Hyaluronate sodium; Starch diethyllaminoethyl ether; Starch Hydroxyproyl Trimethyl ammonium chloride (starch hydroxypropyltrimonium chloride); Hydroxypropyl starch phosphate (hydroxyproyl starch phosphate); Stearyl Dimethyl Ammonium (steardimonium) hydroxyethyl-cellulose; Raffinose; Rhamnosan (rhamsan); Tapioca; Levan; Scleroglucan (scleroglucan); Sodium alginate; Stachyose (stachylose); Succinoglycan; Wheaten starch; Xanthan gum; Xylan; Xyloglucan and composition thereof.The microorganism saccharide can be referring to Kirk-Othmer < > Encyclopedia of ChemicalTechnology <> (chemical industry technology encyclopedia), the 4th edition, the 16th volume, John Wiley and Sons, NY 578-611 page or leaf (1994), its by reference mode all incorporate into.Compound saccharide (Complexcarbohydrates) can be referring to Kirk-Othmer < > Encyclopedia of Chemical Technology <> (chemical industry technology encyclopedia), the 4th edition, the 4th volume, John Wiley and Sons, NY 930-948 page or leaf, 1995, its this by reference mode incorporate into.
Acceptable composition can comprise surfactant in the cosmetic of the present invention.Surfactant comprises surfactant (surfactants), it typically is preparation provides dirt-removing functions property perhaps only to work as wetting agent.Surfactant generally is divided into anion surfactant, cationic surfactant, non-ionic surface active agent, amphoteric surfactant and zwitterionic surfactant.
The anion surfactant that this paper uses comprises United States Patent (USP) 5,573,709 those disclosed anion surfactants, its this by reference mode incorporate into.Instance comprises alkyl sulfate salt and alkyl ether sulphate salts (alkyl and alkyl ether sulfates).Can be used for concrete alkyl ether sulphate salts instance of the present invention is following sodium salt and ammonium salt: lauryl sulfate ester (lauryl sulfate), lauryl ether sulfuric ester (lauryl ether sulfate), Cortex cocois radicis alkyl 2,2'-ethylenedioxybis(ethanol). ether sulfuric ester (coconut alkyltriethylene glycol ether sulfate); Tallow alkyl 2,2'-ethylenedioxybis(ethanol). ether sulfuric ester (tallow alkyltriethylene glycol ether sulfate) and tallow alkyl hexaoxyethylene sulfuric ester (tallow alkylhexaoxyethylene sulfate).Preferred alkyl ether sulphate salts is those alkyl ether sulphate salts that comprise the mixture of single chemical compound; The mean alkyl chain of said mixture is long for from about 12 to about 16 carbon atoms, average ethoxylation (ethoxylation) degree is to about 6 moles of ethylene oxide from about 1.
The anion surfactant of another suitable classification is alkyl sulfate (alkyl sulfuric acidsalts).Important instance according to known method of sulfonating (comprise bleaching and hydrolysis) obtain, methane series hydrocarbon (comprise have about 8 to about 24 carbon atoms, preferred about 12 to about 18 carbon atoms different-, new-, ineso-and n-paraffin (paraffins)) and sulfonating agent (SO for example < > 3 <> , H < > 2 <> SO < > 4 <> , oleum) the salt of organic sulfur acid reaction product.The Sulfated C of alkali metal and ammonium preferably < > 12-38 <> N-paraffin.
Other synthetic anion surface active agent comprises alkene sulfonate, β-alkoxyl alkyl sulfonate and through the product of isethionic acid esterification and the neutral fatty acid of sodium hydroxide, and succinamate (succinamates).The instantiation of succinamate comprises: N-octadecyl sulfosuccinamic acid disodium; N-(1,2 dicarboxyl ethyl)-N-octadecyl sulfosuccinamic acids, four sodium; The diamyl ester of sodium sulfosuccinate; The dihexyl ester of sodium sulfosuccinate; The dioctyl ester of sodium sulfosuccinate.
The preferred anionic surfactant that is used for acceptable composition in the cosmetic of the present invention comprises ammonium lauryl sulfate (ammonium lauryl sulfate); Laureth ammonium sulfate (ammonium laureth sulfate); Lauryl sulfate triethylamine (trlethylamine laurylsulfate); Laureth sulphuric acid triethylamine; Triethanolamine lauryl sulfate; Laureth sulphuric acid triethanolamine; Lauryl sulfate monoethanolamine; Laureth sulphuric acid MEA; Lauryl sulfate diethanolamine; Laureth sulphuric acid diethanolamine; Laurel monoglyceride sodium sulfate (lauricmonoglyceride sodium sulfate); Sodium lauryl sulfate; Sodium laureth sulfate; Lauryl potassium sulfate; The laureth potassium sulfate; Sodium lauryl sarcosinate; Sodium lauroyl sarcosine; The lauryl sarcosine; The cocoyl sarcosine; Cocoyl ammonium sulfate; Lauroyl ammonium sulfate; Cocoyl sodium sulfate; Lauroyl sodium sulfate; The cocoyl potassium sulfate; Lauryl potassium sulfate; Triethanolamine lauryl sulfate (trlethanolamine); Triethanolamine lauryl sulfate; Cocoyl sulphuric acid MEA; Lauryl sulfate monoethanolamine; Tridecyl benzene sulfonic acid sodium salt and dodecylbenzene sodium sulfonate.
Can be used for the derivant that the amphoteric surfactant in the acceptable composition in the cosmetic of the present invention comprises secondary aliphatic amine and tertiary amine, wherein the aliphatic substituent contains have an appointment 8 to 18 carbon atoms and for example carboxyl, sulfonate (sulfonate), sulfate (sulfate), phosphate (phosphate) or phosphonate (phosphonate) the anionic water solubilizing group.Representative example comprises 3-dodecyl-alanine sodium, 3-dodecyl amino propane sulfonic acid sodium, sodium lauryl sarcosinate, N-alkyltaurate (for example describe among United States Patent (USP) 2 pass through lauryl amine and the prepared salt of sodium isethionate reaction), N-senior alkyl aspartic acid (like United States Patent (USP) 2, describing in 091) and with trade name MIRANOL < > TM <> The product of selling (, describing in 378) like United States Patent (USP) 2,528.Other sarcosinates and sarcosinate derivant can be referring to CTFA CosmeticIngredient Handbook(CTFA cosmetic composition handbooks), the 5th edition, 1988, the 42 pages, its this by reference mode incorporate into.
Cationic surfactant generally comprises but is not limited to contain the 8 fatty quaternary ammonium compounds to about 18 carbon atoms of having an appointment.The anion of quaternary ammonium compound can be a conventional ion, for example chloride ion, etherosulfuric acid root, methyl-sulfuric acid root, acetate, bromide ion, lactate, nitrate anion, phosphate radical or tosylate and composition thereof.Chain alkyl can comprise additional or substituted carbon or hydrogen atom or ehter bond.Other replacements on the quaternary nitrogen can be hydrogen, hydrogen, benzyl or short-chain alkyl or hydroxyalkyl group, for example methyl, ethyl, methylol or ethoxy, hydroxypropyl or its combination.The structure of representational quaternary ammonium compound is provided in CTFA Cosmetic Ingredient Handbook(CTFA cosmetic composition handbook), the 5th edition, 1988, the 40 pages.
The instance of quaternary ammonium compound includes but not limited to: chlorination Shan Yu base trimethyl ammonium (behentrimonium chloride); Chlorination cocoyl trimethyl ammonium (cocotrimoniumchloride); Bromination cetyl ethyl Dimethyl Ammonium (cethethyldimonium bromide); Chlorination Er Shan Yu base Dimethyl Ammonium (dibehenyldimonium chloride); Chlorination dihydro Adeps Bovis seu Bubali benzyl ammonium methyl (dihydrogenated tallow benzylmonium chloride); Chlorination two soybean-based Dimethyl Ammonium (disoyadimonium chloride); Chlorination two Adeps Bovis seu Bubali Dimethyl Ammonium (ditallowdimoniumchloride); Chlorination hydroxyl cetyl hydroxyethyl dimethyl ammonium (hydroxycetyl hydroethyldimonium chloride); Chlorination ethoxy Shan Yu amido propyl Dimethyl Ammonium (hydroxyethylbehenamidopropyl dimonium chloride); Chlorination ethoxy cetyl Dimethyl Ammonium (hydroxyethyl cetyldimonium chloride); Chlorination ethoxy Adeps Bovis seu Bubali Dimethyl Ammonium (hydroxyethyl tallowdimonium chloride); Chlorination myristyl dimethyl benzyl ammonium (myristalkonium chloride); Chlorination EG-2 oil base ammonium methyl (PEG-2 oleamoniumchloride); Chlorination EG-5 stearyl ammonium methyl (stearmonium chloride) cocoyl quaternary ammonium salt (cocoyl quaternium)4 stearyl dimethyl benzyl ammonium (stearalkonium) 4; Trimethyllaurylammonium chloride (lauryltrimonium chloride); Quaternary ammonium salt-16; Quaternary ammonium salt-18; Chlorination lauryl dimethyl hexadecyldimethyl benzyl ammonium (lauralkonium chloride); Chlorination oil base dimethyl benzyl ammonium (olealkmonium chloride); Cetyl pyridinium chloride (cetylpyridinium chloride); Polyquaternary ammonium salt-5; Polyquaternary ammonium salt-6; Polyquaternary ammonium salt-7; Polyquaternary ammonium salt-10; Polyquaternary ammonium salt-22; Polyquaternary ammonium salt-37; Polyquaternary ammonium salt-39; Polyquaternary ammonium salt-47; Polyquaternary ammonium salt-55; Chlorination cetyl trimethyl ammonium (cetyl trimonium chloride); Chlorination dilauryl Dimethyl Ammonium (dilauryldimonium chloride); Cetyl dimethyl benzyl ammonium chloride (cetalkoniumchloride); Chlorination two cetyl Dimethyl Ammonium (dicetyldimonium chloride); Chlorination Semen sojae atricolor trimethyl ammonium (soyatrimonium chloride); Stearyl octyldimethyl ammonium methyl sulfate (stearyl octyldimonium methosulfate) and composition thereof.Other quaternary ammonium compounds are listed in CTFA Cosmetic Ingredient Handbook(CTFA cosmetic composition handbook), front page, the 41-42 page or leaf, its this by reference mode incorporate into.
Acceptable composition can comprise from about C in the cosmetic < > 10 <> To C < > 22 <> Two long-chain amines, from about C < > 10 <> To C < > 22 <> Long-chain fat amine and composition thereof.Instantiation comprises two palmityl amine (dipalmitylamine), dodecanamide propyl dimethyl, stearamidopropyldime.hylamine (stearamidopropyl dimethylamine).
Acceptable composition can also comprise the aliphatic alcohol and the two tail phospholipid of aliphatic alcohol (being generally monohydric alcohol), ethoxylation in the cosmetic of the present invention, and it can be in order to acceptable composition in the cosmetic of stable emulsion or dispersion form.It also provides to make up goes up acceptable viscosity.The selection of aliphatic alcohol is not crucial, has C although generally use those to be characterized as < > 10 <> To C < > 32 <> , preferred C < > 14 <> To C < > 22 <> Aliphatic chain be the alcohol of roughly saturated alkanol.Instance comprises stearyl alcohol (stearyl alcohol), spermol (cetyl alcohol), cetearyl alcohol (cetostearyl alcohol), cardanol (myristylalcohol) 、 behenyl alcohol, arachidic alcohol, isooctadecanol (isostearyl alcohol) and different spermol (isocetyl alcohol).Spermol is preferred, and can use separately or be used in combination with other aliphatic alcohol, preferably is used in combination with stearyl alcohol.During use, be included in aliphatic alcohol concentration range in the preparation of the present invention and be preferably from about 1 to about 8% weight, more preferably from about 2 to about 6% weight.Said aliphatic alcohol can also be ethoxylation.Instantiation comprises ceteareth (cetereth)-20, stearyl alcohol polyethers (steareth)-20, stearyl alcohol polyethers (steareth)-21 and composition thereof.Also can comprise phospholipid, for example Phosphatidylserine and phosphatidylcholine and composition thereof.
The ionic surfactant pack that can be used for acceptable composition in the cosmetic of the present invention is drawn together the chemical compound that extensively is defined as through using organic hydrophobic compound (character can be aliphatic or alkyl aromatic) condensation alkylene oxide group (character is hydrophilic) to be generated.The instance of the non-ionic surface active agent of preferred classes is: the long chain alkanol amide; The polyethylene oxide condensation compound of alkyl phenol; Have straight or branched configuration (configuration) from about 8 to the aliphatic alcohol of about 18 carbon atoms and the condensation product of oxirane; The long chain tertiary amine oxide; The long chain tertiary phosphine oxide; Contain one from about 1 short-chain alkyl or hydroxyalkyl radical (radical to about 3 carbon atoms) the long-chain dialkyl sulphoxide; And alkyl polysaccharide (APS) surfactant, for example alkyl polyglycoside (alkyl polyglycosides); Polyethylene Glycol (PEG) glycerin fatty ester.
Zwitterionic surfactant (for example betanin) also can be used for acceptable composition in the cosmetic of the present invention.The instance that is used for the betanin of this paper comprises the senior alkyl betanin, for example coco dimethyl carboxymethyl betaine (coco dimethyl carboxymethyl betaine); Cocamido propyl betaine; Coco betaine (cocobetaine); The dodecanamide propyl betanin; Oil-based betaine; The lauryl dimethyl carboxymethyl betaine; Lauryl dimethyl α-carboxyethyl betanin; Cetyl dimethyl carboxymethyl betaine; The two-(2-ethoxys of lauryl) carboxymethyl betaine; The two-(2-hydroxypropyls of stearyl) carboxymethyl betaine (stearyl bis-(2-hydroxypropyl)carboxymethyl betaine); Oil base dimethyl γ-carboxylic CAB; With the two-(2-hydroxypropyls of lauryl) α-carboxyethyl betanin.Sulfobetaines (sulfobetaines) representative can be coco dimethyl azochlorosulfonate propyl lycine (cocodimethyl sulfopropyl betaine), stearyl dimethyl methyl CAB (stearyldimethyl sulfopropyl betaine), the two-(2-ethoxys of lauryl dimethyl sulfoethyl betanin, lauryl) azochlorosulfonate propyl lycine and analog; Amide betaine (amidobetaines) and amide sulfo betaine (amidosulfobetaines), RCONH(CH wherein < > 2 <> ) < > 3 <> It also is the nitrogen-atoms of useful betanin in the present invention that free radical is connected to.
The common consumption of anion, cation, nonionic, both sexes or zwitterionic surfactant that is used for acceptable composition in the cosmetic of the present invention is from about 0.1 to 50% weight, preferably from about 0.5 to about 40% weight, more preferably from about 1 to about 20% weight.
Acceptable composition can comprise wetting agent in the cosmetic of the present invention, and it works as hygroscopic agent, the water yield that has increased absorption, keeps and kept.The suitable wetting agent that is used for preparation of the present invention includes but not limited to: acetamide MEA; DL-Lactic acid ammonium salt.; Chitosan and derivant thereof; The colloidal state Herba bromi japonici; Arabinogalactan (galactoarabinan); Glutamic acid glucose; Glycerin polyether (glycereth)-26; Glycerol; Lactamide MEA; Lactamide DEA; Lactic acid; Methyl glucose polyethers (methyl gluceth)-10; Methyl glucose polyethers-20; Pantothenylol; Propylene glycol; Sorbitol; Polyethylene Glycol; 1; 3-butanediol; 2; The 6-hexanetriol; Hydrogenated starch hydrolysates; Inositol; Mannitol tetramethylolmethane ether (ether); The polyglyceryl Sorbitol; Xylitol, sucrose; Hyaluronate sodium sodium and combination thereof.Glycerol is special preferred humectants.Wetting agent be present in the compositions concentration for from about 0.5 to about 40% weight, preferably from about 0.5 to about 20% weight and more preferably from about 0.5 to about 12% weight.
Acceptable composition can comprise vaseline or mineral oil component in the cosmetic of the present invention, and it is generally USP or NF grade when selecting.Vaseline can be white or yellow.The viscosity of vaseline or denseness grade are not very crucial.Vaseline can partly be replaced by the mixture of hydrocarbon materials, and this mixture can be mixed with on outward appearance and denseness and be similar to vaseline.For example, can make up the vaseline with different waxes and analog or the mixture of mineral oil.Preferred wax comprises Fructus Lauri nobilis wax (bayberry wax); Candelilla wax; Ceresine (ceresin); The Jojoba ester; Lanolin wax; Montan wax; Ceresine (ozokerite); Polyglyceryl-3-Cera Flava; Polyglyceryl-6-the five kinds of stiffness in infant fat acid ester (polyglyceryl-6-pentastearate); Microwax; Paraffin; Isoparaffin (isoparaffin); The vaseline hard paraffin; Squalene; Oligomer alkene; Cera Flava; Synthetic candelilla wax; The synthetic wax Petiolus Trachycarpi; Synthetic bees wax and analog may be combined in together.Having substituted in various degree alkyl methyl siloxanes can be in order to increase the water that skin keeps.Silicones such as stearyl dimethicone (stearyldimethicone) (referred 2503Wax), C30-45 alkyl methyl silicone oil (called AMS-C30 wax) and stearyl trimethyl silane (and) stearyl alcohol (called 580Wax), all available from DowCorning
, Midland, MI, USA.Other alkyl and phenyl siloxane can be in order to the raising character of preserving moisture.Resins such as dimethicone (and) trimethylsiloxysilicate silicate (trimethylsiloxysilicate) (referred to as Dow Corning
593) or ring A silicone oil (cyclomethicone) (and) trimethylsiloxysilicate silicate (called Dow Corning
749fluid), skin care products can be used to improve film formation.When using, vaseline, wax or hydrocarbon or oil ingredient are with about 1 to about 20% weight, 1 concentration to about 12% weight more preferably from about, are included in the said preparation.When using, silicone resin can about 0.1 be comprised to about 10.0% weight.
Softening agent is defined as the material that help to keep soft, the smooth and slick and sly outward appearance of skin.Softening agent remains on ability and functionating on the skin surface or in horny layer through it.Acceptable composition can comprise the fatty ester softening agent on the present invention made up, and it lists in the international cosmetic composition dictionary of International CosmeticIngredient Dictionary(), English edition, 2000, the 1768 to 1773 pages.The instantiation that is used for the suitable fatty ester of preparation of the present invention comprises the isopropyl alcohol myristate; The isopropyl alcohol cetylate; Caprylic/capric triglyceride; Spermol lactate (cetyl lactate); Spermol cetylate (cetyl palmitate); Castor oil hydrogenated; Glyceride; Hydroxyl spermol isostearate (hydroxycetyl isostearate); The hydroxyl Phosphoric acid monohexadecyl ester; The isopropyl alcohol isostearate; Isooctadecanol isostearate (isostearyl isostearate); Diisopropanol decanedioic acid spermol polyethers-20(PPG-5-Ceteth-20); The different pelargonate (2-ethylhexyl of 2-Ethylhexyl Alcohol isononoate); 2-Ethylhexyl Alcohol stearate < > 12 <> To C < > 16 <> Aliphatic alcohol lactate, isopropyl alcohol wool grease (lanolate), 2-ethyl-hexanol salicylate and composition thereof.At present preferred fatty ester is isopropyl alcohol myristate, isopropyl alcohol cetylate, PPG-5-spermol polyethers-20 and caprylic/capric triglyceride.When using, the fatty ester softening agent preferably with about 1 to about 8% weight, 2 concentration to about 5% weight more preferably from about, is included in the preparation of the present invention.
Compositions of the present invention can also comprise silicone compounds.Preferably, the viscosity of silicone components under 25 ℃ is from about 0.5 to about 12,500cps.Suitably the instance of material is dimethyl polysiloxane, diethyl polysiloxanes, dimethyl polysiloxane-diphenyl polysiloxanes, cyclomethicone, trimethyl polysiloxanes, diphenyl polysiloxanes and composition thereof.Simethicone (with the dimethyl polysiloxane of trimethyl cell end block) is a preferred examples.Viscosity is between 50 and 1, and the simethicone between the 000cps is preferred especially.When using, silicone oil preferably with 0.1 to 5% weight, the more preferably concentration of 1 to 2% weight, is included in the preparation of the present invention.
Acceptable composition can comprise volatilization and nonvolatile silicone oil or fluid in the cosmetic of the present invention.Silicone compounds can be viscosity from about 0.5 to about 100 centistoke (centistrokes) wire or annular dimethyl polysiloxane.The range of viscosities of most preferred wire polydimethylsiloxane chemical compound from about 0.5 to about 50 centistokes.A linear, low molecular weight volatile polydimethylsiloxane One example is octamethyltrisiloxane, tradename Dow Corning
200fluid obtain a viscosity of about 1 centistokes.When using, silicone oil preferably with 0.1 to 30% weight, the more preferably concentration of 1 to 20% weight, is included in the preparation of the present invention.
Acceptable composition can comprise volatile cyclic low-molecular-weight polydimethylsiloxane (cyclomethicone) in the cosmetic of the present invention.Preferred ring-type volatile siloxane can be average repetitive be 4 to 6 and viscosity from about 2.0 to polydimethylcyclosil.xane of about 7.0 centistokes and composition thereof.The ring is preferably a silicone available from Dow Corning, Midland, MI, USA, tradename DowCorning
244fluid, Dow Corning
245fluid, Dow Corning
246, DowCorning
344fluid and Dow Corning
345fluid, and obtained from General Electric, Waterford, NY, USA's Silicone SF-1173 and Silicone SF-1202.When using, silicone oil preferably with 0.1 to 30% weight, the more preferably concentration of 1 to 20% weight, is included in the preparation of the present invention.
The silicone surfactant (siliconesurfactants that has polyoxyethylene or polyoxypropylene side chain) or emulsifying agent also can be used for compositions of the present invention.Preferred examples include: dimethicone copolyol (dimethicone Copolyols), Dow Corning
3225C and 5225C Formulation Aids, available from Dow Corning, Midland, MI, USA; and SiliconeSF-1528, available from General Electric, Waterford, NY.USA.Side chain can also comprise alkyl, for example lauryl or cetyl.A preferred silicone copolymer lauryl alcohol (called DowCorning
5200Formulation Aid) and cetyl dimethicone copolyol (called AbilEM-90, available from Goldschmidt Chemical Corporation, Hopewell, VA).Further preferably the lauryl simethicone is called Belsil LDM 3107VP, can be available from acker-Chemie, and Munchen, GER.When using, silicone surfactant preferably with 0.1 to 30% weight, the more preferably concentration of 1 to 15% weight, is included in the preparation of the present invention.
Amine functional siloxane and emulsion can be used for the present invention.Preferred examples include DowCorning
8220, Dow Corning
939, Dow Corning
949, Dow Corning
2-8194, all available from Dow Corning, Midland, MI, USA.Further preferably SiliconeSM 253, can be available from General Electric, Waterford, NY, USA.When using, the amine functional siloxane preferably with 0.1 to 5% weight, the more preferably concentration of 0.1 to 2.0% weight, is included in the preparation of the present invention.
Acceptable composition can comprise the volatility hydrocarbon ils in the cosmetic of the present invention.Volatile hydrocarbon comprises about C < > 6 <> To C < > 22 <> Atom.The preferred volatile hydrocarbon is that chain is about C < > 6 <> To C < > 16 <> The aliphatic hydrocarbon of individual carbon atom.This examples for compounds comprises 2-Methylpentadecane, and commodity are called Permethyl 101A, can be available from Presperse, and South Plainfield, NJ, USA.The instance of another preferred volatile hydrocarbon is C < > 12 <> To C < > 14 <> Isoparaffin, commodity are called Isopar M, can be available from xxon, Baytown, TX, USA.When using, volatile hydrocarbon preferably with 0.1 to 30% weight, the more preferably concentration of 1 to 20% weight, is included in the preparation of the present invention.
Acceptable composition can comprise cation and both sexes telomerized polymer in the cosmetic of the present invention.Such instance includes but not limited to the international cosmetic composition dictionaries of following listed those :International CosmeticIngredient Dictionary() Cosmetic Association(cosmetics, cosmetic product and the)(CTFA of aromatic association) publish 17th Street, N.W., Suite 300, D.C.20036.General example comprises the season derivant (quaternary derivatives of cellulose ether), the season derivant of guar gum, homopolymer and copolymer, the homopolymer of MAPTAC and the season derivant of copolymer and starch of DADMAC.Use the CTFA name, instantiation includes but not limited to polyquaternary ammonium salt-10; Guar gum Hydroxyproyl Trimethyl ammonium chloride (Guar hydroxypropyltrimonium chloride); Starch Hydroxyproyl Trimethyl ammonium chloride (starch hydroxypropyltrimonium chloride); Polyquaternary ammonium salt-4; Polyquaternary ammonium salt-5; Polyquaternary ammonium salt-6; Polyquaternary ammonium salt-7; Polyquaternary ammonium salt-14; Polyquaternary ammonium salt-15; Polyquaternary ammonium salt-22; Polyquaternary ammonium salt-24; Polyquaternary ammonium salt-28; Polyquaternary ammonium salt-32; Polyquaternary ammonium salt-33; Polyquaternary ammonium salt-36; Polyquaternary ammonium salt-37; Polyquaternary ammonium salt-39; Polyquaternary ammonium salt-45; Polyquaternary ammonium salt-47 and chlorination PMAm base oxypropyl trimethyl ammonium (polymethacrylamidopropyltrimoniumchloride); Polyquaternary ammonium salt-55 and composition thereof.When using, telomerized polymer is preferably with from 0.1 to 10% weight, preferably from 0.2 to 6% weight, and the concentration of from 0.2 to 5% weight most preferably, is included in the cosmetic of the present invention in the acceptable composition.
Acceptable composition can comprise one or more rheology modifiers in the cosmetic of the present invention.Can be used in the present invention, rheology modifiers include, but are not limited to: a high molecular weight cross-linked acrylic acid (crosslinked) homopolymer, and an acrylate / C10-30 alkyl acrylate cross-linked polymer (Acrylates/C10-30 Alkyl Acrylates Crosspolymer), for example Carbopol
and Pemulen
series, both available from Noveon, Inc., Cleveland, OH, USA; such Salcare
AST anionic acrylate (anionic acrylate) polymers and such Salcare
SC96 cationic acrylate (cationic acrylate) polymer, available from Ciba Specialties, High Point, NC, USA; chloride, trimethyl ammonium propyl acrylamide / acrylamide; hydroxyethyl methacrylate ( hydroxyethyl methacrylate) polymer, Steareth -10 allyl ether / acrylate copolymer (Steareth-10 Allyl Ether / Acrylate Copolymer); acrylate / behenyl alcohol polyether methacrylate -25 ester copolymer (Acrylates/Beheneth-25MetacrylateCopolymer), called Aculyn
28, available from Rohm andHaas / InternationalSpecialties, Wayne, NJ, USA; glyceryl polymethacrylate (glycerylpolymethacraylate), acrylates / behenyl alcohol polyethylene -20 ether methacrylate copolymer (Acrylates/Beheneth-20 Metacrylate Copolymer); bentonite; gums, such as alginates, carrageenan, gum arabic (gum acacia), gum arabic (gum arabic), Indian gum, karaya gum, tragacanth gum, guar gum; guar hydroxypropyl trimethyl ammonium chloride, sugar, xanthan gum or gelatin; cellulose derivatives, such as carboxymethylcellulose sodium, hydroxyethyl cellulose, carboxyethyl cellulose, hydroxymethyl, hydroxymethyl carboxypropyl cellulose, ethyl cellulose, sulfated cellulose, hydroxypropyl cellulose, methyl cellulose, hydroxypropyl methylcellulose, , microcrystalline cellulose; agar; pectin; gelatin; starch and derivatives thereof; chitosan and its derivatives, e.g., hydroxyethyl chitosan sugar; PVA, PVM / MA copolymer, PVM / MA decadiene cross-linked polymer, based on poly (ethylene oxide) thickeners, carbomer sodium (sodium carbomer) and mixtures thereof.When using, rheology modifier is preferably with from 0.01 to 12% weight, preferably from 0.05 to 10% weight and the concentration of from 0.1 to 6% weight most preferably, is included in the cosmetic of the present invention in the acceptable composition.
Acceptable composition can comprise one or more antioxidants in the cosmetic of the present invention, and it includes but not limited to ascorbic acid, BHT, BHA, arabo-ascorbic acid, bisulfite (bisulfite), thioglycolate salt (thioglycolate), tocopherol, sodium metabisulfite, Vitamin E acetate and ascorbyl palmitate (ascorbyl palmitate).Antioxidant will account for acceptable composition 0.01 to 5% weight in the said cosmetic, preferred 0.1 to 3% weight and 0.2 to 2% weight most preferably.
Acceptable composition can comprise one or more sunscreen actives agent in the cosmetic of the present invention.The instance of sunscreen actives agent includes but not limited to octyl group methoxy cinnamate, and (ethyl hexanol is to methoxy cinnamate); Octyl group salicylate oxybenzone (benzophenone-3(benzophenone-3)); Benzophenone-4(benzophenone-4); Antisolaire; The dihydroxyphenyl ketone; Amino benzoic Acid; Amyl group dimethyl PABA; Diethanolamine p-methoxycinnamic acid ester; Two (hydroxypropyl) Aminobenzoates of ethyl 4-; 2-ethylhexyl 1-2-cyanic acid-3; 3-diphenylacrylate ester (2-ethylhexyl-2-cyano-3); The high menthyl ester of salicylic acid; Glyceryl aminobenzoate; Dihydroxy acetone; Octyldimethyl PABA; 2-Phenylbenzimidazole-5-sulfonic acid; Triethanolamine salicylate; Zinc oxide and titanium oxide, and composition thereof.The amount that is used for the sunscreen of acceptable composition in the cosmetic of the present invention will change according to the certain UV absorbing wavelength of employed concrete sunscreen actives agent, and can be from 0.1 to 10% weight, from 2 to 8% weight.
Acceptable composition can comprise one or more antiseptic in the cosmetic of the present invention.Examples of preservatives include, but are not limited to: 1,2 - dibromo-2 ,4 - dicyanobutane (methyl dibromo glutaronitrile, known MERGUARD
, Ondeo Nalco Company, Naperville, IL, USA ), benzyl alcohol, imidazolidinyl urea, 1,3 - bis (hydroxymethyl) -5,5 - dimethyl-2 - imidazolidinone (imidazolidinedione) (e.g., DMDM hydantoin, called GLYDANT
, Lonza, Fairlawn, NJ, USA.), methyl chloride isothiazolin-ketone and methyl isobutyl thiazolidinone (eg, Kathon
, Rohm & Haas Co., Philadelphia, PA, USA), on the methyl paraben, propyl paraben, phenoxyethanol and sodium benzoate, and mixtures thereof.
Acceptable composition can comprise any other composition that just is being usually used in the cosmetics in the cosmetic of the present invention.The instance of this composition includes but not limited to: buffer agent, fragrance ingredient, chelating agen, available so that color additive that compositions itself or horny layer are painted or dyestuff, screening agent, softening agent (softener), foaming booster, foam stabiliser, sunlight filtering agent and peptizer.
Pigment (pigments)(is titanium dioxide, zinc oxide, Talcum, calcium carbonate or Kaolin for example) surface can handle and be used for acceptable composition in the cosmetic of the present invention then through anionic polymer described herein.Treated pigment is then more effectively as the sunscreen actives thing and be used for for example making up and dye the colored cosmetic of eyebrow.
Acceptable composition can contain water and also can contain acceptable solvent in any cosmetic in the cosmetic of the present invention.The instance of acceptable solvent includes but not limited to: monohydric alcohol, and the alkanol that for example has 1 to 8 carbon atom is (as ethanol, isopropyl alcohol, benzyl alcohol and phenylethyl alcohol); Polyhydric alcohol, for example alkylene glycol (alkylene glycols)(is as glycerol, ethylene glycol and propylene glycol); And glycol ether, for example one-, two-and three-ethylene glycol monoalkyl ether, for example glycol monomethyl methyl ether and diglycol monotertiary methyl ether use separately or mix and use.These solvents can exist more than 70% weight with respect to reaching of total composition weight, for example from 0.1 to 70% weight.
Acceptable composition can also contain electrolyte in the cosmetic of the present invention; Aluminium chlorhydroxide, alkali metal salt (for example sodium salt, potassium salt or lithium salts for example; These salt are preferably halogenide (for example chloride or bromide) and sulfate or acylate (for example acetate (acetates) or lactate (lactates))); And alkali salt, carbonate, silicate, nitrate, acetate, gluconate, pantothenate and the lactate of the preferred calcium of said alkali salt, magnesium and strontium.
The compositions that is used to handle skin comprises aftershave lotion, sunscreen, lotion, hands and health cream (hand and body creams), liquid soap, soap slab, bath oil rod (bath oil ars), shaving cream, dishwashing liquid, shower gels, bubble bath and analog.
Skin care compositions and methods of the present invention can be processed oil-in-water, water in oil emulsion, triple emulsion or dispersion.
The preparation of preferred oil-in-water emulsion is added water-msoluble ingredients then through at first forming the aqueous mixture of water solublity (for example, undersaturated quaternary ammonium compound, wetting agent, waterborne-type preservation) component.Water-msoluble ingredients comprises emulsifying agent, water-insoluble antiseptic, vaseline or mineral oil component, aliphatic alcohol component, fatty ester softening agent and silicone oil components.The input of mixed tensor is high and will continues to be enough to form the time of the water-in-oil emulsion with smooth appearance (show and have relative small particles in the emulsion).Generally through forming the aqueous mixture of water-soluble component, interpolation has the thickening agent that is used for the water-insoluble materials suspending power then in the preparation of preferred dispersion.
Acceptable composition can also be packaged as aerosol in the cosmetic of the present invention, and wherein, the form that it can aerosol spray or the form of aerosol foam are used.As these aerocolloidal propelling gass, especially, possibly use dimethyl ether, carbon dioxide, nitrogen, nitrous oxide, air and volatile hydrocarbon, said volatile hydrocarbon is butane, iso-butane and propane for example.
The compositions that is used for treatment of hair comprises the shower goods, for example bubble bath, soap and oil, shampoo, regulator, hair depigmenting agent, hair-dyeing agent, interim and long lasting hair color agent, color adaptation agent, hair brightening agent, dyeing and non-painted hair conditioner, hair dye, curly hair fixative (hairwave sets), long-acting setting lotion, setting lotion, hair straighten, haircut adjuvant, hair oil, hair modify (hair dressings) and oxygenated products.Said hydrophobically modified polymers also can be used for the resident type (leave-in that finalizes the design) product; Example gel, mousse (mosses), spray (spritzes), typing cream, typing wax, brilliantine, balsam etc.; Use separately or with other polymer or structural agent (structuring agent) be used in combination; Control and the hair compliance to provide, and have cleaning, nature, inviscid sensation.
Hair care composition of the present invention provides level and smooth sensation; And it can be washed off from hair easily, because exist said hydrophobically modified polymers, volatile siloxane, other polymer, surfactant or other can change material at the sedimentary chemical compound of hair.
Under the situation of cleaning agent; Shampoo that for example is used to have one's hair wash or liquid hand soaps or the bath gels that is used to clean skin; Said compositions contains anion, cation, nonionic, amphion or amphoteric surfactant; Said surfactant usually amount for from about 3 to about 50% weight, preferably from about 3 to about 20% weight, and its pH usually from about 3 to about 10 scope.
The preferred shampoo of the present invention contains the combination of anion surfactant and zwitterionic surfactant and/or amphoteric surfactant.Preferred especially shampoo contains from about 0 to about 16% active alkyl sulfate salt (alkyl sulfates), from 0 to the alkyl sulfate salt of the ethoxylation of about 50% weight with from 0 option list surface-active agent to about 50% weight; This surfactant is selected from nonionic, both sexes and zwitterionic surfactant; And be at least 5% weight of alkyl sulfate salt or its mixture of alkyl sulfate salt, ethoxylation; And the total surfactant level is from about 10% weight to about 25% weight.
The shampoo that is used for having one's hair wash can also contain other adjusting additive that is generally used for shampoo, for example siloxanes and telomerized polymers.United States Patent (USP) 5,573,709 provide a series of non-volatile siloxane regulators that can be used in the shampoo.Be used for telomerized polymer of the present invention and list in Cosmetic, Toiletries and Fragrance Associations(CTFA)dictionary(cosmetics, cosmetic product and the (CTFA of aromatic association) dictionary).Instantiation comprises polyquaternary ammonium salt (for example polyquaternary ammonium salt-1 to polyquaternary ammonium salt-53), guar gum Hydroxyproyl Trimethyl ammonium chloride, starch Hydroxyproyl Trimethyl ammonium chloride and chlorination PMAm base oxypropyl trimethyl ammonium.
Other preferred embodiments comprise with the mainly application of the form of flushing lotion to be used before or after the shampoo hair washing.These lotions are the lotion or the gel of aqueous solution or aqueous solution of alcohol, emulsion, thickening normally.If said compositions occurs with form of emulsion, then said compositions can be nonionic, anion or cationic.Nonionic emulsion mainly consist of oil and/or have polyoxyethyleneization alcohol aliphatic alcohol (for example; The stearyl alcohol (stearyl alcohol of polyoxyethyleneization) or cetyl/stearyl alcohol) mixture, and cationic surfactant can be added into these compositionss.Anion emulsion generates from soap basically.
If said compositions occurs with the lotion or the gel form of thickening, then said compositions contains the thickening agent that exists or do not have solvent.Operable thickening agent especially is: resin, acrylic thickener, and can be available from B.F.Goodrich; Xanthan gum; Sodium alginate; Radix Acaciae senegalis; Cellulose derivative and based on the thickening agent that gathers (oxirane), and it also possibly realize thickening through the mixture of polyglycol distearate or distearate or through the mixture of phosphate ester and amide.The concentration of thickening agent is generally 0.05 to 15% weight.If said compositions is with typing lotion, molding lotion or the fixedly form appearance of lotion, then said compositions generally comprises as above defined Ampholyte polymers in water, alcohol or aqueous solution of alcohol.
Under the situation of hair fixative, said compositions can contain one or more additional hair fixative polymer.When existing, said additional hair fixative polymer is to exist from about 0.25 total amount to about 10% weight.As long as said additional hair fixative resin and given hydrophobically modified polymers are compatible; Then said additional hair fixative resin can be selected from: acrylamide copolymer; Acrylamide/sodium acrylate copolymer; Acrylates (acrylate)/ammonio methacrylate copolymer; The acrylates copolymer; Acrylic acid/acrylates copolymer; Fatty acid/dimethylamino hydroxypropyl diethylenetriamines copolymer; Fatty acid/glycidyl diethylenetriamines copolymer; Pi-allyl stearate/VA copolymer; Amino-ethyl acrylic ester phosphate (aminoethylacrylate phosphate)/the acrylates copolymer; The ammonium acrylate copolymer; Vinylacetic acid ammonium/acrylates copolymer acrylates/biacetone acrylamide copolymer; AMPD acrylates/biacetone acrylamide copolymer; The butyl ester (butyl ester of PVM/MA copolymer) copolymer calcium/sodium salt (calcium/sodium PVM/MA copolymer) of the butyl ester (butyl ester of ethylene/maleic anhydridecopolymer) copolymer of ethylene/copolymer-maleic anhydride; Corn starch/acrylamide/sodium acrylate copolymer; Diethyleneglycolamin/chloropropylene oxide/piperazine-copolymer; Dodecanedioic acid/spermaceti stearyl alcohol (cetearyl alcohol)/the isopropyl ester (isopropyl ester of PVM/MA copolymer) of the ethyl ester (ethyl ester of PVM/MA copolymer) copolymer of glycol copolymer copolymer; Karaya; Methacryl ethyl betanin/methacrylic acid salt copolymer (methacryloyl ethyl betaine/methacrylatecopolymer); Octyl acrylamide/acrylates/butyl ethylaminoethanol methacrylate copolymer (octylacrylamide/acrylate/butylaminoethyl methacrylate copolymer); Octyl acrylamide/acrylates copolymer; Phthalic anhydride/glycerol/capric acid glycidyl ester copolymer (phthalic anhydride/glycerin/glycidyl decanoate copolymer); Phthalic acid/benzenetricarboxylic acid/glycol copolymer; Polyacrylamide; The polyacrylamide base methyl propane sulfonic acid; Polybutylene terephthalate (PBT) (polybutylene terephthalate); Polyethyl acrylate (polyethylacrylate); Polyethylene; Polyquaternary ammonium salt-1; Polyquaternary ammonium salt-2; Polyquaternary ammonium salt-4; Polyquaternary ammonium salt-5; Polyquaternary ammonium salt-6; Polyquaternary ammonium salt-7; Polyquaternary ammonium salt-8; Polyquaternary ammonium salt-9; Polyquaternary ammonium salt-10; Polyquaternary ammonium salt-11; Polyquaternary ammonium salt-12; Polyquaternary ammonium salt-13; Polyquaternary ammonium salt-14; Polyquaternary ammonium salt-15; Polyquaternary ammonium salt-39; Polyquaternary ammonium salt-47; Polyvinyl acetate; Polyvinyl butyral resin; Polyvinyl imidazol quinoline acetate (polyvinylimidazolinium acetate); Polyvinyl methyl ether (polyvinyl methyl ether) copolymer; PVP/ DMAE methacrylate (dimethylaminoethylmethacrylate) copolymer; PVP/ eicosylene copolymer; PVP/ EMA (ethyl methacrylate)/EUDRAGIT S100; PVP/ hexadecene (hexadecene) copolymer copolymer; PVP/ vinyl acetate/itaconic acid copolymer; Lac; Acrylic compounds sodium salt copolymer (sodium acrylates copolymer); Acrylic compounds sodium salt/acryloyl nitrogen class (Acrylnitrogens) copolymer; PAA (sodium acrylate)/ethenol copolymer; Carrageenin sodium; Starch diethyllaminoethyl ether (starchdiethylaminoethyl ether); Stearyl vinyl ether/maleic anhydride copolymer; Sucrose benzoate (sucrose benzoate)/Sucrose acetoisobutyrate (sucrose acetate isobutyrate)/BBP(Butyl Benzyl Phthalate (butyl benzyl phthalate) copolymer; Sucrose benzoate/Sucrose acetoisobutyrate/BBP(Butyl Benzyl Phthalate/methylmethacrylate copolymer; Sucrose benzoate/Sucrose acetoisobutyrate copolymer; Vinyl acetate/cronate copolymer (vinylacetate/crotonate copolymer); Vinyl acetate/.beta.-methylacrylic acid copolymer; Vinyl acetate/.beta.-methylacrylic acid/methacryloxy benzophenone-1(methacryloxybenzophenone-1) copolymer; Vinyl acetate/.beta.-methylacrylic acid/vinyl neodecanoate copolymer, and composition thereof.The synthetic polymer that is used to generate the typing adjuvant is in " history of The History of Polymers in Haircare(hair care polymer) ", and Cosmetics and Toiletries describes in 103(1988), its this by reference mode incorporate into.Other can be used for synthetic polymer of the present invention can be with reference to CTFA Dictionary(CTFA dictionary), the 5th edition, 2000, its this by reference mode incorporate into.
If compositions contemplated of the present invention is used for keratin fiber and particularly human hair's dyeing, then except said hydrophobically modified polymers, contain at least a oxidation dye precursors and/or a kind of direct dyes as the one of which.It can also contain any other adjuvant that just is being usually used in such compositions.
The pH of said dye composite is generally 7 to 11, and can be through adding basifier (alkalizing agent) transfer to the value of hope.
Can also be used for curling or hair straightening according to compositions of the present invention.In this case, except said hydrophobically modified polymers, said compositions generally contains other adjuvants that one or more Reducing agents and (if suitably) just are being usually used in such compositions; This compositions contemplated is used in combination with neutralization composition.
In one embodiment; The present invention is for handling the method for the substrate that is selected from hair, skin and fingernail; It comprises that acceptable composition is gone up in cosmetic is applied to said substrate; Said compositions contains one or more hydrophobically modified polyacrylamides, and wherein said polyacrylamide is made up of acrylamide and one or more cationic monomers.
In another embodiment, said substrate is hair.
In another embodiment; The present invention is household cleaners or laundry detergent; Said household cleaners or laundry detergent comprise one or more hydrophobically modified polyacrylamides, and wherein said polyacrylamide is by acrylamide, one or more cationic monomers and choose any one kind of them or multiple anionic monomer is formed.
Through understanding aforementioned content better with reference to following embodiment, proposing following embodiment is for describing purpose, do not expect the scope of the present invention that limits.