CN102665658A - Water in oil type cosmetic composition for improving skin - Google Patents
Water in oil type cosmetic composition for improving skin Download PDFInfo
- Publication number
- CN102665658A CN102665658A CN2010800532696A CN201080053269A CN102665658A CN 102665658 A CN102665658 A CN 102665658A CN 2010800532696 A CN2010800532696 A CN 2010800532696A CN 201080053269 A CN201080053269 A CN 201080053269A CN 102665658 A CN102665658 A CN 102665658A
- Authority
- CN
- China
- Prior art keywords
- water
- skin
- polysaccharide
- ceramide
- oil type
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
- A61K8/66—Enzymes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/68—Sphingolipids, e.g. ceramides, cerebrosides, gangliosides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
Abstract
The present invention relates to a water-in-oil type cosmetic composition, which improves the skin to be smooth and keeps the skin free from troubles, and more particularly to a water-in-oil cosmetic composition which has a short-term skin improvement effect, caused by a ceramide-like amino acid derivative and a stabilized papain enzyme, and a long-term skin improvement effect caused by a polysaccharide having a prebiotic effect of selectively controlling bacteria.
Description
Technical field
The present invention relates to a kind of water-in-oil type cosmetic compositions of skin of improving to become smooth and can prevent skin problem; And relate more specifically to a kind of short-term skin improvement effect that produces by ceramide type amino acid derivativges (ceramide-like amino acid derivative) and stable papain (stabilized papain enzyme) that has, and the water-in-oil type cosmetic compositions of the long-term skin improvement effect that produces by the polysaccharide of the prebiotic effect with Selective Control antibacterial (prebiotic effect).
Background technology
Horny layer is the outermost layer of skin, is made up of dead cell.Healthy skin has the update cycle about 28 days, during this period, sloughs old keratin and forms the new cell of one deck.But if (comprise aging, pressure, ultraviolet and environmental pollution) because inherent and extrinsic factor, this renewal becomes slowly, and unnecessary keratin can accumulate and not slough, and causes skin to become slightly thick, and the generation melanin pigmentation makes skin darkening.In addition, this also can cause the formation of acne and wrinkle.
Epidermis is the outermost layer of skin, is the organ that contacts and provide the protection barrier all the time with external environment.The skin barrier that is present in keratodermatitis helps to suppress the loss that power and water is separated matter, and the protection human body is avoided the damage of extraneous and chemicals, and prevents antibacterial and virus infiltration skin (Feingold KR.Cosmet.Toilet.112:49-59,1997).Horny layer is made up of two parts: form the protein that cell is formed by dead angle matter; And be present in the lipid (people such as Elias PM, Adv.Lipid Res.24:1-26,1991) between keratinocyte.Wherein, the lipid between keratinocyte is considered in safeguarding skin barrier, bringing into play most important effect.Lipid between said keratinocyte is the lipid mixture of ceramide, cholesterol, free fatty etc., and contains intercellular lamella (intercellular lamellae).Especially; The ceramide that accounts for epidermis hydrated lipidic thin film (hydrolipid film) 40-50% have comprise sphingol, amido link non--labyrinth of hydroxy acid (amide-linked non-hydroxy acid), 'alpha '-hydroxy acids, ω-hydroxy acid or ester bond fatty acid (ester-linked fatty acid); And through the polarity that these structural elements form is important (people such as Choi MJ in keeping hydrated lipidic thin film laminated structure; Am.J.Clin.Dermatol.6:215-223,2005).
The health skin surface is rich in the required nutrition of growth of microorganism, and therefore skin surface exists many antibacterials usually.These antibacterials are divided into the pathogenic bacterium that cause human body diseases substantially, like staphylococcus or streptococcus, and the non-pathogenic bacteria that can not cause disease.Non-pathogenic bacteria also is called as normal flora and is found on the normal skin.Can non-pathogenic bacteria be divided into two types: even even can not remove when skin applied friction or skin carried out partly sterilised live antibacterial for a long time, be temporary on the skin and through partly sterilised or apply the antibacterial of staying temporarily that friction is easy to remove.
Live in other pathogenic bacterium that cause disease when normal flora on the skin helps to suppress to get into skin usually.Therefore, it is very useful and be that human body is necessary to human body to live in normal flora on the skin.If if if the quantity of skin damage or non-pathogenic bacteria reduces or the quantity of pathogenic bacterium increases sharply, human body will produce disease.Therefore, it is believed that if control the antibacterial that lives on the skin to make the rate of rise of nonpathogenic normal flora be higher than the rate of rise of pathogenic bacterium, can improve skin.
Summary of the invention
Therefore, improve the material that skin becomes smooth and can prevent skin problem in order to seek, inventor of the present invention has carried out repeatedly research.The result; Inventor of the present invention finds; With the ceramide type amino acid derivativges with papain capsule and polysaccharide use can provide improve keratodermatitis with the protection skin barrier direct effect; And can optionally reduce the antibacterial that the meeting that is present on the skin causes skin problem, thereby accomplish the present invention.
Therefore, the purpose of this invention is to provide a kind of skin that improves becomes smooth and water-in-oil type cosmetic compositions that can prevent skin problem.
To achieve these goals, the present invention provides a kind of water-in-oil type cosmetic compositions that contains ceramide type amino acid derivativges, papain capsule and polysaccharide.
Water-in-oil type cosmetic compositions of the present invention contains buffer agent, in the foreign minister of said cosmetic composition, has the structure similar with skin phospholipid, thereby provides the lipid components with stable quantity of preserving moisture that helps skin lubrication.In addition; Cosmetic composition of the present invention contains the capsule that obtains through the proteic protease of encapsulation molt, moult; Said capsule is applicable to cosmetics; Therefore use back protease capsule not play a role immediately, but softening keratin and when cleaning cosmetic composition, remove unnecessary keratin in can the special time after use, thus skin is polished.In addition, compare with useful normal flora, cosmetic composition of the present invention can optionally reduce the content of pathogenic bacterium, thereby secular skin nursing effect is provided.At last, water-in-oil type cosmetic compositions of the present invention makes skin not have keratin also moistening smooth and can prevent skin problem, is easy to make up thereby promote skin to become.
Description of drawings
Fig. 1 is one group and has shown the photo of measuring cosmetic composition preparation stability result;
Fig. 2 has shown and has measured cosmetic composition of the present invention in the result of content with the effect that reduces the keratin amount that moisturize;
Fig. 3 is one group and has shown to measure and use behind the cosmetic composition of the present invention the result's of keratin amount photo on each time point skin;
Figure 4 and 5 are for having shown figure and the photo that utilizes image analyzer to measure face degree of irregularity (irregularity) result.
The specific embodiment
The invention provides a kind of water-in-oil type cosmetic compositions that contains ceramide type amino acid derivativges, papain capsule and polysaccharide.
Hereinafter, the present invention will be described in further detail.
The said ceramide type amino acid derivativges that is used as active component in the cosmetic composition of the present invention is plant sterol/behenyl alcohol/octyl group decanol lauroyl glutamate (phytosteryl/behenyl/octyldodecyl/lauroyl glutamate); Said plant sterol/behenyl alcohol/octyl group decanol lauroyl glutamate is the emollient derived from glutamic acid, and is the paste material.It helps to prevent the water loss of skin and makes skin form the protection barrier of environment to external world.Said ceramide type amino acid derivativges dissolving also is scattered in the oil phase of said water-in-oil type cosmetic compositions.
Being used for said ceramide type amino acid derivativges of the present invention can make according to any conventional method known in the art, and limits method for preparing is not special.For example, can utilize natural acid, higher alcohol and plant sterol to synthesize said ceramide type amino acid derivativges.
Gross weight with said compositions is a benchmark, and the content that is used for said ceramide type amino acid derivativges of the present invention is 0.1-5.0 weight %.If the content of said ceramide type amino acid derivativges is lower than 0.1 weight %, the moisturizing effects of ceramide is very little, and if content be higher than 5 weight %, will make said compositions become sticky, make that the cosmetics usability is poor.
The said papain that is used as active component in the cosmetic composition of the present invention is the fruit juice of fruit Fructus Caricae and is a kind of protease.Known this protease helps the treatment and the blood circulation promoting of inflammation and has cleaning skin or remove keratic effect under the situation that does not produce skin irritation.
Normally, contain multiple oiliness composition in the cosmetic formulations, said oiliness composition with emulsifying agent can destructive enzyme three dimensional structure because can be, can be the technology that enzyme is introduced cosmetic formulations essential with the enzyme direct activation.In the present invention, the papain capsule makes through the encapsulation papain, and the capsule that makes is added into the oil phase of said Water-In-Oil cosmetic composition and is dispersed in the preparation.
Being used for said papain capsule of the present invention can make according to any conventional method known in the art, and limits method for preparing is not special.For example; Said papain capsule can be through under papain stable p H; Preparation contains the papain solution of papain and stabilizing agent; Said papain solution and the liposome that comprises lecithin are formed composition mix, and mixture is made through high pressure homogenisers.
Gross weight with said compositions is a benchmark, and the capsular content of said papain is 0.1-2.0 weight %.If the capsular content of said papain is lower than 0.1 weight %, it is very little that it removes the keratin effect, and if content be higher than 2.0 weight %, can make the usability difference of cosmetics in use and cause skin irritation.
The said polysaccharide that is used as active component in the cosmetic composition of the present invention has the prebiotic effect of anti-staphylococcus epidermidis (Staphylococcus epidermidis) and propionibacterium acnes (Propionibacterium acnes).
Can be used for polysaccharide of the present invention for being selected from one or more of the group formed by Herba Orostachyos Flos Camelliae Japonicae (Orostachys japonicas) polysaccharide, green tea polysaccharide and Herba Artemisiae Scopariae (Artemisia capillaries) polysaccharide.
Being used for polysaccharide of the present invention can make according to any conventional method known in the art, and limits method for preparing is not special.For example, said polysaccharide can make in such a way.With Herba Orostachyos Flos Camelliae Japonicae polysaccharide, green tea polysaccharide or the crushing of Herba Artemisiae Scopariae polysaccharide, add pure water, and at 95 ℃ of following heating extraction 3h.The extract that the obtains filter of warp 250 holes, 3 μ m, 1 μ m and 0.5 μ m successively filters, and through being heated to 60 ℃ filtrating is concentrated, and uses 95% ethanol precipitation then.Precipitate is centrifugal, and the precipitate that obtains is dissolved in the pure water.Solution filters through the filter of 0.5 μ m and 0.2 μ m successively, and vacuum drying filtrating, thereby obtains polysaccharide.
Gross weight with said compositions is a benchmark, and the content that is used for said polysaccharide of the present invention is 0.0001-1.0 weight %.If the content of said polysaccharide is lower than 0.0001 weight %, can not obtain desired effects, and if content be higher than 1.0 weight %, can cause skin irritation.
Cosmetic composition of the present invention can be processed the form of making up foremilk, foundation cream, facial cream, emulsion or concealer, but limits the preparation of said cosmetic composition is not special.
Hereinafter, will combine embodiment and test case that the present invention is described in further detail, but scope of the present invention is not limited in these embodiment.
Preparation example 1: dissolved ceramide material
Pure water, emulsifying agent, solubilizing agent and ceramide combination are made dissolved ceramide material.Here, the dissolved amount of said ceramide is 3-5 weight %.
Preparation example 2: the ceramide material of encapsulation
Liposome technology (Lipid technology) is the key of the cosmetic product of research and development and skin function coordination.Prepare different encapsulating materials through the accurate simulation of liposome structure in the skin and the effective supply of active component.Utilize multicoating technology (multilayer coating process) and fluidization (fluidized bed technique), obtain intercellular lamella and liposomal body (lipid envelops) simultaneously.
Utilize the ceramide material and the last process after preparation emulsifying of the said encapsulation that the multicoating prepared is made up of ceramide, lecithin and fatty acid to add.Carry out capsular stabilisation and softening process (at 45 ℃ of following 3h) to reduce the foreign body sensation of the ceramide material that encapsulates.Make capsule break naturally in the said capsule of oil infiltration and carry out softening process in order to reduce said capsular impurity content and to allow.The advantage that the ceramide material of said encapsulation has is: be easier to introduce in the Water-In-Oil preparation and can strengthen the moisturizing activity with respect to traditional solubilizing agent.
Embodiment 1 and 2 and Comparative Examples 1-3
According to composition and the content that following table 1 shows, preparation embodiment 1 and 2 and preparation (the unit: weight %) of Comparative Examples 1-3.In the table 1, said ceramide type amino acid derivativges is plant sterol/behenyl alcohol/octyl group decanol lauroyl glutamate (CAS 245443-09-8; Purchase company limited) in Ajinomoto.
Table 1
< method for preparing of embodiment 1 and 2 preparation >
1) the ceramide type amino acid derivativges is added in oil-phase component and the emulsifying agent, and make the mixture dissolving through being heated to 50-60 ℃.Past then wherein the adding and dispersion flows controlling agent, pigment and papain capsule, thus make outer oil phase.
2) comprise water-phase component intermingling in independent container of pure water and polyhydric alcohol, thereby make interior water.
3) with 2) interior water be added into 1) outer oil phase in, thereby obtain the Water-In-Oil preparation.
< method for preparing of the preparation of Comparative Examples 1 >
1) through being heated to 50-60 ℃ of dissolved oil phase constituent and emulsifying agent, past then wherein the adding and dispersion flows controlling agent and pigment, thus make outer oil phase.
2) comprise water-phase component intermingling in independent container of pure water and polyhydric alcohol,, thereby make interior water then toward wherein adding dissolved ceramide material.
3) with 2) interior water be added into 1) outer oil phase in, thereby obtain the Water-In-Oil preparation.
< method for preparing of the preparation of Comparative Examples 2 >
1) through being heated to 50-60 ℃ of dissolved oil phase constituent and emulsifying agent, past then wherein the adding and dispersion flows controlling agent and pigment, thus make outer oil phase.
2) will comprise the water-phase component intermingling of pure water and polyhydric alcohol, thereby make interior water.
3) with 2) interior water be added into 1) outer oil phase in, thereby obtain the Water-In-Oil preparation.
4) with the encapsulation the ceramide material be added into 3) the Water-In-Oil preparation in and utilize the Agi-blender that it is uniformly dispersed.
Test case 1: according to the evaluation of the Water-In-Oil preparation of ceramide kind
In order to estimate stability of formulation according to the kind of ceramide, in thermostatic chamber, measure embodiment 1 with 2 and the thermostability of the preparation of Comparative Examples 1-3 and in the greenhouse of cycle variation according to the variations in temperature measurement stability.Same time of every day in room temperature, 30 ℃, 45 ℃ and 55 ℃ of thermostabilitys of measuring down in thermostatic chamber, and to stablize 7 days as standard.In the stability of measuring under the vibration condition of 170rpm in the cycle chamber 7 days, be benchmark with a circulation/sky, under-10 ℃, 30 ℃ and 45 ℃, keep each sample 7h respectively, the variations in temperature stage, (temperature change stage) was 1h.The result who measures is as shown in table 2 below.
In 7 days, altogether through from observing 5 definite preparation stabilities of stability of emulsion and pigment dispersibility in appearance.Estimate based on following standard: O=5 observation all is stable; Δ=3-4 observation is stable; And observation is stable below X=2 time.
Table 2
| Stability | Embodiment 1 | Embodiment 2 | Comparative Examples 1 | Comparative Examples 2 | Comparative Examples 3 |
| Stability of emulsion | O | O | X | Δ | O |
| The pigment dispersibility | O | O | Δ | X | O |
Can find out that from Fig. 1 and table 2 oil phase material except that ceramide type amino acid derivativges material has bad stability.Can find out, contain the preparation of the Comparative Examples 1 of dissolved ceramide material, oil separates with preparation gradually in the several hrs after the emulsifying.In addition, the preparation existence that contains the Comparative Examples 2 of ceramide capsule material is shifted to the problem of said capsule before the consumer at 55 ℃ of following swelling fractures.In addition, about Comparative Examples 2,, when said capsule is dispersed in the said preparation, can opaque layer occur and produce foreign body sensation unlike basic product.On the other hand, the ceramide type amino acid derivativges can add with the form of pasty state in the said oil-phase component, thereby can add in the said preparation easily and do not influence preparation stability, has shown that the preparation of embodiment 1 and 2 has good stable property.
Test case 2: the clinical trial of skin moisturizing activity and keratin amount
In order to confirm to improve the skin slick effect that becomes, the active and keratin amount of the skin moisturizing of the preparation of embodiment 2 was carried out clinical measurement before and after preparation was used.Measured for 2 weeks on one's body 10 people altogether.The papain that uses in this test is purchased the company limited in AT Lab..
Particularly; After washing face, let the experimenter in thermostatic constant wet chamber, adapt to the constant temperature and humidity condition (temperature: 22 ± 2 ℃, relative humidity: 40 ± 2%) 15min; Gather the face's optical photograph that uses preparation preceding then, measure water content, keratin amount and skin surface roughness before preparation uses.After the experimenter uses preparation and adapts to constant temperature and humidity condition 15min, measure above-mentioned several once more.Use every day preparation after the week and two weeks once, measure above-mentioned several once more.After the measurement, definite significant difference with respect to the value that obtains before the use preparation (paired t-test, P 0.05).In addition, utilize image analyzer to measure the degree of irregularity of face.Measurement result is shown in Fig. 2-5.
Can find out from Fig. 2-5, when on skin, using cosmetic composition of the present invention, can increase the skin water content, reduce keratin amount and skin surface roughness, thereby make skin smooth moistening.
Test case 3: the test of giving birth to the water bag water formulation effect of amount according to benefit
Prebiotic substance is a water-soluble material, and the foreign minister is a water in the oil-in-water preparation, makes active component and contact skin.Therefore, the effect of preparation can be shifted, and during in-vitro measurements, the active component of the aqueous phase that is easy to take a sample.On the other hand, about the Water-In-Oil preparation of describing among the present invention, said water is present in the said inner phase, thereby is difficult to the effect of the said preparation of prediction.For this reason, carry out test according to the Water-In-Oil preparation effect of prebiotic substance content.Preparation contains the Comparative Examples 4 of the compositions that shows in the following table 3 and the base formulation of embodiment 3-5 respectively.Polysaccharide is added into the water portion of base formulation here, with the amount of 0,2,0.1 and 0.005 weight %.For the polysaccharide of said prebiotic substance obtains from weight ratio is green tea, Herba Artemisiae Scopariae and the Herba Orostachyos Flos Camelliae Japonicae polysaccharide of 60: 30: 10 weight %, and polysaccharide used herein is purchased the company limited in Korea S Bio-Land respectively.
Table 3
< method for preparing of the preparation of embodiment 3-5 and Comparative Examples 4 >
1) the ceramide type amino acid derivativges is added in oil-phase component and the emulsifying agent, and makes the mixture dissolving through being heated to 50-60 ℃.Then, past wherein the adding and dispersion flows controlling agent, pigment and papain capsule, thus make outer oil phase.
2) comprise water-phase component intermingling in independent container of pure water and polyhydric alcohol and prebiotic substance, thereby make interior water.
3) with 2) interior water be added into 1) outer oil phase in, thereby obtain the Water-In-Oil preparation.
In test, prepare the Water-In-Oil basis preparation of embodiment 3-5 and Comparative Examples 4 respectively as stated, dilution is 10 times in distilled water.Diluent stores 5min in 50 ℃ of water-baths, vortex (vortexed) is 5 times then, each 1min.Through filter paper filtering vortex solution, filter through 0.2 μ m filter then, thereby make sample filtrating.
<bacterial cell method of counting >
1. dissolve pretreated sample filtrating toward the peptone that wherein adds 1 weight % respectively, through 0.2 μ m filter paper sample solution is sterilized then.
2. the test bacterial solution of inoculation 10 μ l/ml in each disinfectant sample solution is confirmed initial cell quantity then.(here, water suitably dilutes said bacterial solution, then the diluent of 1ml is applied to the surface of culture medium, and calculates the quantity of bacterial cell through final clump count and extension rate are multiplied each other).
3. every kind of sample solution will having inoculated bacterial solution is cultivated 1 day (situation of propionibacterium acnes) in 32 ℃ of following shaken cultivation 1 day (situation of staphylococcus epidermidis) with 35 ℃ of following anaerobism respectively.
4. suitably dilute the bacterial solution of cultivating respectively, and get the diluent of 1ml.The diluent of staphylococcus epidermidis is coated on the TS agar, coated on the BHI agar and then 35 ℃ of following cultivations 1 day, and with the diluent of propionibacterium acnes and cultivated 3 days 35 ℃ of following anaerobism.Then, measure cell quantity in each bacterial solution.
Measure the quantity of bacterial cell according to above-mentioned count of bacteria method, and calculate the rate of rise of bacterial cell quantity in each sample according to following formula 1.Result of calculation is as shown in table 4 below.
[formula 1]
The quantity of bacterial cell in the blank behind the quantity/0h of bacterial cell in the blank behind the quantity ÷ 24h of bacterial cell in the sample behind the quantity/0h of bacterial cell in the sample behind the rate of rise=24h of bacterial cell quantity in the sample
Calculate the K value of the rate of rise that is used for staphylococcic rate of rise of comparative sample mesocuticle and sample propionibacterium acnes according to following formula 2.High K value shows relative the increasing of rate of rise of beneficial bacteria and has given prebiotic effect.
[formula 2]
The rate of rise of propionibacterium acnes in the staphylococcic rate of rise/sample of K=sample mesocuticle
Table 4
Can find out that from last table 4 polysaccharide in the embodiment 3-5 preparation has prebiotic effect, and when having diluted 10 times in the consideration pre-treatment step, similarly surpass content range 0.2-0.0005 weight % basically.Therefore, can find,, also can show prebiotic effect even when only being added into polysaccharide in the water-in-oil type cosmetic compositions with the amount of 0.0005 weight %.
Therefore, Water-In-Oil cosmetic composition of the present invention has good prebiotic effect, thereby can optionally reduce the content of pathogenic bacterium with respect to useful normal flora.Therefore, it can suppress skin problem and have secular skin nursing effect.
Though described the present invention in conjunction with the embodiment of bright property specifically, the present invention is not limited to embodiment and claims of only limiting to enclose.It is understandable that under the situation that does not depart from the scope of the invention and spirit, those skilled in the art can change or modify these embodiments.
Claims (6)
1. water-in-oil type cosmetic compositions that contains ceramide type amino acid derivativges, papain capsule and polysaccharide.
2. water-in-oil type cosmetic compositions according to claim 1, wherein, said ceramide type amino acid derivativges is plant sterol/behenyl alcohol/octyl group decanol lauroyl glutamate.
3. water-in-oil type cosmetic compositions according to claim 1 wherein, is a benchmark with the gross weight of said compositions, and the content of said ceramide type amino acid derivativges is 0.1-5.0 weight %.
4. water-in-oil type cosmetic compositions according to claim 1 wherein, is a benchmark with the gross weight of said compositions, and the capsular content of said papain is 0.1-2.0 weight %.
5. water-in-oil type cosmetic compositions according to claim 1; Wherein, said polysaccharide is for being selected from least a in the group of being made up of Herba Orostachyos Flos Camelliae Japonicae (Orostachys japonicas) polysaccharide, green tea polysaccharide and Herba Artemisiae Scopariae (Artemisia capillaries) polysaccharide.
6. water-in-oil type cosmetic compositions according to claim 1 wherein, is a benchmark with the gross weight of said compositions, and the content of said polysaccharide is 0.0001-1.0 weight %.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020090116446A KR101640857B1 (en) | 2009-11-30 | 2009-11-30 | Water in Oil type make-up cosmetic composition for improving skin |
| KR10-2009-0116446 | 2009-11-30 | ||
| PCT/KR2010/008428 WO2011065772A2 (en) | 2009-11-30 | 2010-11-26 | Water in oil type cosmetic composition for improving skin |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102665658A true CN102665658A (en) | 2012-09-12 |
| CN102665658B CN102665658B (en) | 2013-09-25 |
Family
ID=44067115
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201080053269.6A Expired - Fee Related CN102665658B (en) | 2009-11-30 | 2010-11-26 | Water in oil type cosmetic composition for improving skin |
Country Status (3)
| Country | Link |
|---|---|
| KR (1) | KR101640857B1 (en) |
| CN (1) | CN102665658B (en) |
| WO (1) | WO2011065772A2 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105640819A (en) * | 2014-11-13 | 2016-06-08 | 广州十长生化妆品有限公司 | Skin tendering smoothening whitening exfoliating microsphere and application thereof |
| CN107007492A (en) * | 2016-12-26 | 2017-08-04 | 广州市花安堂生物科技有限公司 | A kind of makeup remover and preparation method thereof |
| CN107405285A (en) * | 2014-12-31 | 2017-11-28 | 株式会社爱茉莉太平洋 | Chemical anisotropic particle and the water-in-oil emulsion composition for including it |
| CN111675770A (en) * | 2020-07-15 | 2020-09-18 | 延边大学 | Preparation method and application of orostachys wolfsii polysaccharide |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2013070891A1 (en) | 2011-11-08 | 2013-05-16 | The Procter & Gamble Company | Method of identifying prebiotics and compositions containing the same |
| US20150202136A1 (en) * | 2012-02-14 | 2015-07-23 | The Procter & Gamble Company | Topical use of a skin-commensal prebiotic agent and compositions containing the same |
| JP5690779B2 (en) * | 2012-07-10 | 2015-03-25 | 株式会社 資生堂 | Water-in-oil emulsified cosmetic |
| KR102506973B1 (en) | 2015-09-02 | 2023-03-07 | (주)아모레퍼시픽 | High internal phase Water-in-Oil type emulsified cosmetic composition |
| JP2019510037A (en) | 2016-03-31 | 2019-04-11 | ゴジョ・インダストリーズ・インコーポレイテッド | Antibacterial peptide stimulant cleaning composition |
| JP2019510036A (en) | 2016-03-31 | 2019-04-11 | ゴジョ・インダストリーズ・インコーポレイテッド | A detergent composition comprising probiotic / prebiotic active ingredients |
| CA3043748A1 (en) | 2016-11-23 | 2018-05-31 | Gojo Industries, Inc. | Sanitizer composition with probiotic/prebiotic active ingredient |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5834013A (en) * | 1994-06-08 | 1998-11-10 | L'oreal | Cosmetic or dermatological composition in the form of an aqueous and stable dispersion of cubic gel particles based on phytanetriol and containing a surface-active agent which has a fatty chain, as dispersing and stabilizing agent |
| CN1723872A (en) * | 2004-07-20 | 2006-01-25 | 花王株式会社 | Oil-in-water emulsified composition |
| US20060198800A1 (en) * | 2003-08-14 | 2006-09-07 | Natalie Dilallo | Skin care compositions including hexapeptide complexes and methods of their manufacture |
| US20060246029A1 (en) * | 2005-03-16 | 2006-11-02 | Procyte Corporation | Methods and compositions for preventing and treating aging or photodamaged skin |
| US20070213244A1 (en) * | 2004-09-13 | 2007-09-13 | Ajinomoto Co., Inc | Wash composition |
| CN101283960A (en) * | 2007-04-11 | 2008-10-15 | 味之素株式会社 | Water-in-oil type emulsified compositions |
| EP2044927A1 (en) * | 2006-06-30 | 2009-04-08 | Hakuto Co., Ltd | Cosmetic and method for production thereof |
-
2009
- 2009-11-30 KR KR1020090116446A patent/KR101640857B1/en active IP Right Grant
-
2010
- 2010-11-26 WO PCT/KR2010/008428 patent/WO2011065772A2/en active Application Filing
- 2010-11-26 CN CN201080053269.6A patent/CN102665658B/en not_active Expired - Fee Related
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5834013A (en) * | 1994-06-08 | 1998-11-10 | L'oreal | Cosmetic or dermatological composition in the form of an aqueous and stable dispersion of cubic gel particles based on phytanetriol and containing a surface-active agent which has a fatty chain, as dispersing and stabilizing agent |
| US20060198800A1 (en) * | 2003-08-14 | 2006-09-07 | Natalie Dilallo | Skin care compositions including hexapeptide complexes and methods of their manufacture |
| CN1723872A (en) * | 2004-07-20 | 2006-01-25 | 花王株式会社 | Oil-in-water emulsified composition |
| US20070213244A1 (en) * | 2004-09-13 | 2007-09-13 | Ajinomoto Co., Inc | Wash composition |
| US20060246029A1 (en) * | 2005-03-16 | 2006-11-02 | Procyte Corporation | Methods and compositions for preventing and treating aging or photodamaged skin |
| EP2044927A1 (en) * | 2006-06-30 | 2009-04-08 | Hakuto Co., Ltd | Cosmetic and method for production thereof |
| CN101283960A (en) * | 2007-04-11 | 2008-10-15 | 味之素株式会社 | Water-in-oil type emulsified compositions |
Non-Patent Citations (1)
| Title |
|---|
| E.BERARDESCA等: ""Effects of topical gluco-oligosaccharide and collagen tripeptide F in the treatment of sensitive atopic skin"", 《INTERNATIONAL JOURNAL OF COSMETIC SCIENCE》 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105640819A (en) * | 2014-11-13 | 2016-06-08 | 广州十长生化妆品有限公司 | Skin tendering smoothening whitening exfoliating microsphere and application thereof |
| CN107405285A (en) * | 2014-12-31 | 2017-11-28 | 株式会社爱茉莉太平洋 | Chemical anisotropic particle and the water-in-oil emulsion composition for including it |
| CN107007492A (en) * | 2016-12-26 | 2017-08-04 | 广州市花安堂生物科技有限公司 | A kind of makeup remover and preparation method thereof |
| CN111675770A (en) * | 2020-07-15 | 2020-09-18 | 延边大学 | Preparation method and application of orostachys wolfsii polysaccharide |
Also Published As
| Publication number | Publication date |
|---|---|
| KR101640857B1 (en) | 2016-08-01 |
| WO2011065772A3 (en) | 2011-11-17 |
| KR20110059986A (en) | 2011-06-08 |
| CN102665658B (en) | 2013-09-25 |
| WO2011065772A2 (en) | 2011-06-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102665658B (en) | Water in oil type cosmetic composition for improving skin | |
| KR101912478B1 (en) | Exopolysaccharide for the treatment and/or care of the skin, mucous membranes, hair and/or nails | |
| TW516968B (en) | Dermatological composition | |
| JPWO2004016236A1 (en) | Cosmetics | |
| CN108143702A (en) | A kind of efficient whitening and moisturizing facial mask liquid, facial mask and preparation method thereof | |
| KR20110108686A (en) | Antioxidant containing extracts of natural materials and composition of feed, food or cosmetic | |
| KR101985354B1 (en) | A composition comprising a herbal fermentation extract having preventing and improving acne lesion | |
| KR101595530B1 (en) | Liposome composition having excellent effect of skin wrinkle improvement and skin whitening for accelerating percutaneous absorption | |
| KR20110108687A (en) | Skin whitening agent containing extracts of natural materials and composition of cosmetic | |
| KR102460358B1 (en) | Cosmetic composition comprising fermented herbs mixture extract for preventing or improving of skin whitening, anti-wrinkle, UV-protective, anti-atopic and tinea pedis | |
| CN105705154A (en) | Cosmetic or dermatological use of an extract of hamamelis virginiana | |
| JP2002053428A (en) | Skin care preparation | |
| KR102204932B1 (en) | Cosmetic composition with liposome including acerola extract | |
| KR100708236B1 (en) | Cosmetic composition comprising the flower extract of Camellia japonica L. showing astringent activity | |
| KR100776346B1 (en) | A composition comprising an extract eclipta prostrata l., rehmannia glutinosa liboschtz var. purpurea makino, polygonum multiflorium thunb. and pinellia ternata breit. showing anti-dandruff and anti-inflammatory activity | |
| WO2022013897A1 (en) | Dermatological composition for rebalancing the skin, for increasing its hydration and elasticity and for reducing dynamic disorders | |
| JP2015229655A (en) | Skin external preparation | |
| KR102074384B1 (en) | Cosmetic composition for improving wrinkles and skin elasticity comprising bifidobacterium animalis subsp. lactis lm1017 having immunostimulating activity | |
| JP2001212445A (en) | Emulsifying agent | |
| KR20190098603A (en) | Cosmetic composition comprising microorganism femented produsts with moisturizing effects | |
| KR20190021114A (en) | Composition for anti-inflammation, inhibiting secretion of sebum, or treating acne on the skin comprising plant extract | |
| KR20090075281A (en) | Cosmetic composition with the effect of atopy skins | |
| KR20170095702A (en) | Manufacturing method of cosmetic composition containing nano particle natural materials and cosmetic composition manufactured by the same | |
| KR101448993B1 (en) | Pharmaceutical agent containing the Betula platyphylla Sukatchev var. japonica Hara extract as an effective ingredient and its use | |
| JP2021185879A (en) | Yeast culture extract and skin preparation containing the same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20130925 Termination date: 20211126 |