CN102665663A - Composition for relieving stimulus of skin caused by dye - Google Patents

Composition for relieving stimulus of skin caused by dye Download PDF

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Publication number
CN102665663A
CN102665663A CN201080052525XA CN201080052525A CN102665663A CN 102665663 A CN102665663 A CN 102665663A CN 201080052525X A CN201080052525X A CN 201080052525XA CN 201080052525 A CN201080052525 A CN 201080052525A CN 102665663 A CN102665663 A CN 102665663A
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Prior art keywords
compositions
carbohydrate
dyestuff
composition
derivatives
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Pending
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CN201080052525XA
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Chinese (zh)
Inventor
朴葰星
郑京美
朱璟美
金王基
金德熙
金汉坤
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Amorepacific Corp
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Amorepacific Corp
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60—Sugars; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/732—Starch; Amylose; Amylopectin; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P17/00—Drugs for dermatological disorders
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/10—Preparations for permanently dyeing the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/74—Biological properties of particular ingredients
    • A61K2800/75—Anti-irritant
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A61Q5/065—Preparations for temporary colouring the hair, e.g. direct dyes

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Engineering & Computer Science (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • Organic Chemistry (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Cosmetics (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Saccharide Compounds (AREA)

Abstract

The present invention relates to a composition containing a carbohydrate or a derivative thereof as an active ingredient. The composition relieves stimulus of the skin caused by dye and prevents inflammation caused by dye. In addition, the present invention relates to a hair dye composition comprising a composition containing a carbohydrate or a derivative thereof as an active ingredient. The hair dye composition reduces stimulus of the skin and inflammation caused by dye.

Description

Be used to alleviate the skin irritant compositions that dyestuff causes
[technical field]
The present invention relates to alleviating the skin irritation effective composition that dyestuff causes.
[background technology]
Recently, many people, though age and sex, the requirement of using hair dye to cover too early grey hair and poliosis and satisfy the individual character expression.This type of hair dye can be divided into following type according to the persistent period.
First kind, temporary stain is intended to realize temporary transient dyeing, and after water cleans residual color on hair not.This type of temporary dyestuff almost is neutral and comprises dyeing spraying, dyeing mousse, dyeing gel, mascara etc.
Second kind, the semipermanent stain is one-piece type hair dye.It further is divided into basic stain and acid stain.Though acid stain mixes with hydrogen peroxide as the permanent stain agent, it needs the peroxide of relative low concentration, and therefore to compare the extent of damage of hair lower with permanent dyestuff.Basic stain need not mix with peroxide, and therefore hair cuticle and cortex is not caused damage.In addition, basic stain constitutes glossy protecting film, thereby plays the effect that stops ultraviolet and protection hair.This type of semipermanent stain has the persistent period in about 2 week-4 week.They can not dye through chemical bond through ionic bond, and comprise hair dyeing.
At last, the permanent stain agent form by first reagent (dyestuff) and second reagent (oxidant) and can mutually combine through said first reagent and said second reagent time reaction between them dye.This type of permanent stain agent can further be divided into vegetable dyeing agent, rapid dyeing agent and oxidative coloration agent.At present, the most used is the oxidative coloration agent.
In general, the oxidative coloration agent contains oxidative dyestuff and alkaline reagent.For example the dyestuff of m-aminophenol, p-phenylenediamine (PPD), para-aminophenol is used as said oxidative dyestuff.This type of oxidative dyestuff infiltrates through in the hair and plays the effect that changes hair color.Said alkaline reagent plays and makes the expansible effect of hair, so that said oxidative dyestuff is penetrated into wherein.The representative instance of said alkaline reagent comprises MEA and ammonia.The representative instance of said second reagent comprises hydrogen peroxide.
[summary of the invention]
[technical problem]
Have now found that a kind of comprising as the compositions of the carbohydrate or derivatives thereof of active component to the skin irritation and the prevention that alleviate dyestuff and cause or to suppress the inflammation that dyestuff causes effective.The present invention aims to provide the compositions that is used to alleviate the skin irritant compositions that dyestuff causes and is used to prevent or suppress the inflammation that dyestuff causes, wherein said compositions comprises the carbohydrate or derivatives thereof as active component.
[technical scheme]
One general aspect, provide to be used to alleviate the skin irritant compositions that dyestuff causes, it comprises the carbohydrate or derivatives thereof as active component.
Another general aspect, the compositions that is used to prevent or suppress the inflammation that dyestuff causes is provided, it comprises the carbohydrate or derivatives thereof as active component.
Another general aspect, composition for hair dying is provided, it comprises above-mentioned composition.
[beneficial effect]
This paper is disclosed, and to comprise as the compositions of the carbohydrate or derivatives thereof of active component be effective to the skin irritation that alleviates dyestuff and cause.
This paper is disclosed to be comprised as the compositions of the carbohydrate or derivatives thereof of active component to prevention or to suppress the inflammation that dyestuff causes be effective.
This paper is disclosed to be contained and comprises as the composition for hair dying of the compositions of the carbohydrate or derivatives thereof of active component to prevention or to suppress skin irritation and inflammation that dyestuff causes be effective.
[preferred forms]
The term " skin " that this paper uses is meant the tissue that covers the animal body surface.In the most wide in range implication of term " skin ", it has been contained scalp and hair and has covered the for example tissue of face or health of body surface.
Hereinafter will be described embodiment of the present invention in detail.
It is organic dyestuff, surfactant, aromatic, ammonia spirit, hydrogenperoxide steam generator, ammonium mercaptoacetate, fatty acid alcohol etc. that the hair dyeing product that uses at present contains diamidogen.Yet in these compositions, said diamidogen is that organic dyestuff causes skin irritation.In addition, when said diamidogen is that organic dyestuff combines with Skin Cell and when becoming antigen, can on skin, have side effects, for example calcination, erythra, pruritus, urticaria, inflammation, send out bleb or contact dermatitis.Therefore, use when containing diamidogen and being the product of organic dyestuff when having sensitive-skinned people, they just possibly suffer from contact allergic dermatitis etc.When hair dye be applied to since continually permanent stain with stress and on the scalp of sensitization the time, this type of diamidogen is that organic dyestuff is excessively absorbed in the said scalp, to such an extent as to user possibly suffer serious stimulation.In some cases, said user possibly not accepted the hair dyeing process.At present, stimulate palliative and hair dye to unite use to carry out the hair dyeing process.Yet because the low pH value of hair dye product itself and be included in the oxidizing process in the dyeing course, the stimulation palliative that great majority are used for dyeing course is difficult to provide the skin irritation of expectation to alleviate effect.In addition, when excessive stimulation palliative and hair dye product coupling, it possibly influence hair dyeing process itself unfriendly.Therefore, this type of stimulates the application of palliative to be restricted.
In one aspect, the compositions that is provided for alleviating the skin irritant compositions that dyestuff causes and is used to prevent or suppress the inflammation that dyestuff causes, wherein said compositions comprises the carbohydrate or derivatives thereof as active component.
Said carbohydrate or derivatives thereof generally is meant and contains carbon, hydrogen and oxygen atom, has C n(H 2O) nChemical formula and each molecule in contain one or more alcohol radicals (OH) with an aldehyde radical (CHO) or ketone group (=CO) chemical compound.Yet, said carbohydrate or derivatives thereof also comprise oxygen atomicity than said chemical formula lack 1 chemical compound (for example deoxyribose), further contain the chemical compound (for example diaminourea sugar) of nitrogen-atoms, further contain the chemical compound (for example chondroitin sulfate) etc. of sulphur atom.
According to an embodiment, said carbohydrate or derivatives thereof can be for being selected from least a of monosaccharide, oligosaccharide and polysaccharide.
Especially, term " monosaccharide " is meant the unit of carbohydrate and comprises through the acid hydrolysis of polysaccharide (for example starch or cellulose) or the sugar of enzyme hydrolysis preparation.More particularly, according to an embodiment, said monosaccharide can be rhamnose, glucose, galactose, fructose or xylose.
Rhamnose has C 6H 12O 5Chemical formula.Naturally the rhamnose that exists mainly is a L-type rhamnose, also is called the 6-deoxymannose.
Glucose has C 6H 12O 6Chemical formula, and be the hexose monosaccharide that typically has aldehyde radical.Glucose can be represented by following Chemical formula 1.According to an embodiment, the n in the Chemical formula 1 can equal 1.
Figure BPA00001565293800041
Galactose is a kind of hexose monosaccharide with aldehyde radical, and is a kind of not as the sweet sugar of glucose.Galactose has C 6H 12O 6Chemical formula and can represent by following Chemical formula 2.According to an embodiment, the n in the Chemical formula 2 can equal 1.
Figure BPA00001565293800042
Fructose is not only hexose and is ketose, has C 6H 12O 6Chemical formula and can represent by following chemical formula 3.According to an embodiment, the n in the chemical formula 3 can equal 1.
Xylose is the pentose with aldehyde radical, belongs to the valeral saccharide and has C 5H 10O 5Chemical formula.
Term " oligosaccharide " also is called oligosaccharide, is the sugar through the glycosidic bond formation of monosaccharide.This is a generic term, has covered ten sugar that form from disaccharide to ten monosaccharide of two monosaccharide formation.Saccharic composition great majority in glycoprotein and the glycolipid belong to oligosaccharide.More particularly, according to an embodiment, said oligosaccharide can be lactose, sucrose, maltose.According to another embodiment, said oligosaccharide can comprise as the Raffinose of trisaccharide or as the stachyose of tetrose.
Lactose (lactose) also is called lactose (milk sugar) and is the disaccharide that is formed by galactose and glucose.Lactose has C 12H 22O 11Chemical formula.
Sucrose (sucrose) also is called sucrose (table sugar) and is the disaccharide that is formed by glucose and fructose.
Maltose (maltose) is called maltose (malt sugar) again, is the disaccharide that is formed by two glucose molecules, and has C 12H 22O 11Chemical formula.
Term " polysaccharide " comprises the macromolecular sugar that all glycosidic bonds that pass through two or more monosaccharide form.The molecular weight of polysaccharide can be several thousand to 1000000 or bigger.According to an embodiment, polysaccharide comprises that wherein n is 2 to 100000 by the chemical compound of Chemical formula 1-3 expression.
According to an embodiment, polysaccharide can comprise the homopolysaccharide of the sugar with single kind, and the heteropolysaccharide with at least two kinds of sugar.Especially, polysaccharide comprises starch, glycogen, cellulose, hemicellulose or pectin.More particularly, polysaccharide comprises as the glucosan of glucose polymer or starch, as the xylan of xylose polymer, as the inulin of fructose polymer or levan or as the galactan of galactose polymer.
According to an embodiment, said comprising as the compositions of the carbohydrate or derivatives thereof of active component to the skin irritation and the prevention that alleviate dyestuff and cause or to suppress the inflammation that dyestuff causes effective.According to another embodiment, said dyestuff can be that diamidogen is an organic dyestuff.
In yet another aspect, composition for hair dying is provided, it contains the compositions that comprises as the carbohydrate or derivatives thereof of active component.Because said comprising as the compositions of the carbohydrate or derivatives thereof of active component to the skin irritation and the prevention that alleviate dyestuff and cause or to suppress the inflammation that dyestuff causes effective; Therefore, said composition for hair dying is compared with existing composition for hair dying also alleviating skin irritation and inflammation is effective.More particularly, said dyestuff can be that diamidogen is an organic dyestuff.
According to an embodiment, said composition for hair dying can comprise first reagent and second reagent.For said first reagent, it can be formulated as powder, liquid, emulsifiable paste, washing liquid or gel-type preparation, but is not limited thereto.According to another embodiment, said composition for hair dying can be one-piece type composition for hair dying, and wherein said first reagent and said second reagent are incorporated in the single compositions.Said one-piece type composition for hair dying can be formulated as powder, liquid, emulsifiable paste, washing liquid or gel-type preparation, but is not limited thereto.
According to an embodiment, in the said compositions that comprises as the carbohydrate or derivatives thereof of active component, in the gross weight of said compositions, the amount that said carbohydrate or derivatives thereof can 0.1-80wt% exists.According to another embodiment, in the gross weight of said compositions, the amount that said carbohydrate or derivatives thereof can 0.1-50wt% exists.According to another embodiment, in the gross weight of said compositions, the amount that said carbohydrate or derivatives thereof can 0.1-10wt% exists.When said carbohydrate or derivatives thereof exists with the amount less than 0.1wt%, enough effects can not be provided.When said carbohydrate or derivatives thereof existed with the amount greater than 80wt%, said compositions possibly was a problem aspect stable.
According to an embodiment; In comprising the composition for hair dying that contains as the compositions of the carbohydrate or derivatives thereof of active component; In said composition for hair dying gross weight, said comprise can 0.1-10wt% as the compositions of the carbohydrate or derivatives thereof of active component amount exist.According to another embodiment, in said composition for hair dying, in the gross weight of said composition for hair dying, said comprise can 0.1-5wt% as the compositions of the carbohydrate or derivatives thereof of active component amount exist.According to another embodiment, in said composition for hair dying, in the gross weight of said composition for hair dying, said comprise can 0.1-1wt% as the compositions of the carbohydrate or derivatives thereof of active component amount exist.When the said compositions that comprises as the carbohydrate or derivatives thereof of active component exists with the amount less than 0.1wt%, enough effects can not be provided.When the said compositions that comprises as the carbohydrate or derivatives thereof of active component existed with the amount greater than 80wt%, said compositions possibly was a problem aspect stable.
[embodiment]
Embodiment and Test Example are described at present.Following embodiment and Test Example only are the purposes from illustration, rather than are intended to limit scope of the present invention.
[Test Example 1] assessment alleviates the effect of the inflammation that skin irritation that dyestuff causes and prevention or inhibition dyestuff cause
In order to assess the effect that alleviates skin irritation and the prevention that dyestuff causes or suppress the inflammation that dyestuff causes, implemented to use the mice ear test (MEST) of mice with the method that describes below.
Obtain the mice individual (BALC/c) in 7 ages in week, quarantine and adapt to 10 days time.Then, to the abdominal part depilation of mice, and continue 7 days main components with dyestuff, promptly 3% p-phenylenediamine (PPD) (PPD) is co-administered in this with monosaccharide (glucose, galactose or fructose) or disaccharide (maltose, lactose or sucrose), every day 3 times.The PPD that uses dimethyl sulfoxine (DMSO) and 3% respectively is as contrast.Used the ear of weighing mice the last time back 24 hours.After the weighing, that the ear of mice is fixing and test to carry out histopathology with h and E (H&E) dyeing in formalin.Then, measure the thickness of mouse ear.At this, the weight of mouse ear is measured through using the 6mm card punch that the ear of having used each sample of mice individual (Balb/c) is carried out biopsy.Measure the thickness of mouse ear at the thickness of the ear of the mice individual (Balb/c) of the weight poststaining of weighing mouse ear through using the microscope measurement.The result is presented in the following table 1.
[table 1]
Sample Ear weight (mg) Ear thickness (μ m)
Contrast (DMSO) 8.14±1.11 237.34±19.24
PPD(3％) 14.74±0.23 433.28±11.57
The PPD+ glucose 9.11±1.20 241.22±41.54
The PPD+ galactose 9.09±1.03 243.93±37.48
PPD+ fructose 8.64±1.15 248.43±25.57
PPD+ maltose 9.35±1.32 259.28±21.74
The PPD+ lactose 8.38±1.11 259.52±46.04
PPD+ sucrose 8.22±1.41 243.54±40.01
Can find out that from top result the associating carbohydrate is used p-phenylenediamine (PPD) and caused ear weight and thickness significantly to descend with respect to using p-phenylenediamine (PPD) separately.In other words, this has shown that the carbohydrate or derivatives thereof has alleviated the skin irritation that p-phenylenediamine (PPD) causes, inflammation and edema.Therefore, can find out that the carbohydrate or derivatives thereof is the skin irritation that causes of organic dyestuff and prevention or to suppress diamidogen be that the inflammation that organic dyestuff causes is effective to alleviating diamidogen.Different carbohydrate or derivatives thereofs can be united use.
Can provide some to contain the FORMULATION EXAMPLE that comprises as the composition for hair dying of the compositions of the carbohydrate or derivatives thereof of active component hereinafter.Yet said composition for hair dying can be formulated into the several formulations form except that following FORMULATION EXAMPLE, and these FORMULATION EXAMPLE only are the purposes from illustration, are not intended to limit the scope of the invention.
[FORMULATION EXAMPLE 1] powder-type first reagent composition for hair dying
Figure BPA00001565293800081
[FORMULATION EXAMPLE 2] gel-type first reagent composition for hair dying
Composition Wt％
Glucose 1.0
P-phenylenediamine (PPD) 3.0
Hydroxyethyl-cellulose 0.5
The L-arginine 2.0
Sodium pyrosulfite 1.0
Pure water To 100
[FORMULATION EXAMPLE 3] one-piece type composition for hair dying
Figure BPA00001565293800082

Claims (8)

1. be used to alleviate the skin irritant compositions that dyestuff causes, it comprises the carbohydrate or derivatives thereof as active component.
2. be used to prevent or suppress the compositions of the scytitis that dyestuff causes, it comprises the carbohydrate or derivatives thereof as active component.
3. according to the compositions of claim 1 or 2, wherein said carbohydrate or derivatives thereof is be selected from monosaccharide, oligosaccharide and polysaccharide at least a.
4. according to the compositions of claim 3, wherein said monosaccharide comprises rhamnose, glucose, galactose, fructose or xylose.
5. according to the compositions of claim 3, wherein said oligosaccharide comprises lactose, sucrose or maltose.
6. according to the compositions of claim 3, wherein said polysaccharide comprises as the glucosan of glucose polymer or starch, as the xylan of xylose polymer, as the inulin of fructose polymer or levan or as the galactan of galactose polymer.
7. according to the compositions of claim 1 or 2, wherein said dyestuff is that diamino is an organic dyestuff.
8. composition for hair dying, it comprises like claim 1 or 2 defined compositionss.
CN201080052525XA 2009-11-19 2010-11-18 Composition for relieving stimulus of skin caused by dye Pending CN102665663A (en)

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KR10-2009-0112178 2009-11-19
KR1020090112178A KR20110055237A (en) 2009-11-19 2009-11-19 Composition for relieving skin irritation by dye
PCT/KR2010/008158 WO2011062426A2 (en) 2009-11-19 2010-11-18 Composition for relieving stimulus of skin caused by dye

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JP5977934B2 (en) * 2011-10-14 2016-08-24 株式会社アモーレパシフィックＡｍｏｒｅｐａｃｉｆｉｃ Ｃｏｒｐｏｒａｔｉｏｎ Hair dye composition
KR101523918B1 (en) * 2012-05-03 2015-05-29 코스맥스 주식회사 Temporary hair dye cosmetic composition

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Publication number Priority date Publication date Assignee Title
CN1222849A (en) * 1996-04-30 1999-07-14 海德罗默公司 Composition, barrier film and method for preventing contact dermatitis
CN1321461A (en) * 2000-03-30 2001-11-14 株式会社资生堂 Hair dyeing fixing agent, hair dye and hair dyeing methode
DE102006050984A1 (en) * 2006-10-26 2008-04-30 Henkel Kgaa Cosmetic agent, useful e.g. as hair treating agent, and to increase the elasticity of keratin fibers, preferably human hairs, comprises purine and/or its derivative, coolness producing substances and/or heatness producing substance

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KR20110055237A (en) 2011-05-25
JP2013511512A (en) 2013-04-04
US20130225522A1 (en) 2013-08-29
WO2011062426A2 (en) 2011-05-26
WO2011062426A3 (en) 2011-11-10

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