CN104768523B - 10℃下具有0.30或更大损耗角正切值的个人护理组合物 - Google Patents

10℃下具有0.30或更大损耗角正切值的个人护理组合物 Download PDF

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CN104768523B
CN104768523B CN201380056196.XA CN201380056196A CN104768523B CN 104768523 B CN104768523 B CN 104768523B CN 201380056196 A CN201380056196 A CN 201380056196A CN 104768523 B CN104768523 B CN 104768523B
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G·J·古斯基
S·周
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    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
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Abstract

本发明提供了一种个人护理组合物，所述个人护理组合物在约10℃下表现出约0.30或更大的损耗角正切值，所述个人护理组合物包含主要表面活性剂、第二表面活性剂、和多元醇。还提供了方法以改善个人护理组合物的稳定性。

Description

10℃下具有0.30或更大损耗角正切值的个人护理组合物
技术领域
本公开一般涉及包含多元醇的个人护理组合物及与其相关的方法。
背景技术
个人护理组合物的适宜性可受多种因素的影响。例如，消费者可能期望个人护理组合物表现出适宜的清洁和发泡特征、不造成皮肤干燥、并且显示出有利的流变性。另外，其它因素如环境温度可影响个人护理组合物的适宜性，因为温度波动可影响个人护理组合物的粘度和/或弹性；潜在地影响消费者对个人护理组合物是否显示有利流变性的观点。平衡这些品质可能是具有挑战性的，因为个人组合物中一种或多种表面活性剂和其它物质的选择可能影响这些因素中的一个或多个。因此，市场上需要表现出适宜清洁和发泡特征、不造成皮肤干燥、并且显示有利流变性的个人护理组合物。
发明内容
个人护理组合物包含主要表面活性剂、第二表面活性剂、和多元醇。所述主要表面活性剂包括不是月桂基硫酸钠或月桂基硫酸铵的阴离子表面活性剂。所述第二表面活性剂包括两性离子表面活性剂、两性表面活性剂、非离子表面活性剂、或它们的组合。所述个人护理组合物在约10℃下表现出约0.30或更大的损耗角正切值。
一种个人护理组合物，其包含：主要表面活性剂，所述主要表面活性剂包含月桂基聚氧乙烯醚(3)硫酸钠；第二表面活性剂，所述第二表面活性剂包括两性离子表面活性剂、两性表面活性剂、非离子表面活性剂、或它们的组合；粘度调节剂；和山梨醇，所述山梨醇构成所述个人护理组合物的约0.5重量％至少于10重量％；其中所述个人护理组合物在约10℃下表现出约0.35或更大的损耗角正切值，并且基本上不含月桂基硫酸钠。
具体实施方式
本申请要求于2012年10月29日提交的美国临时申请61/719,738的优先权，将所述文献以引用方式并入本文。
虽然本说明书通过具体指出并清楚地要求保护本发明的权利要求书作出结论，但据信通过以下说明将更好地理解本发明。
本发明的装置、设备、方法、组分、和/或组合物可包含、由或基本上由本发明的组分以及本文所述的其它成分组成。
除非另外指明，本文使用的所有百分比和比率均按个人护理组合物的总重量计，并且所有测量均在25℃下进行。
除非另外指明，本文所用的所有量度均为公制单位。
定义
“ALS”是指月桂基硫酸铵。
“CAPB”是指椰油酰胺基丙基甜菜碱。
“SLS”是指月桂基硫酸钠。
“SLES”是指月桂基聚氧乙烯醚(n)硫酸钠。
如本文所用，术语“个人护理组合物”是指旨在用于局部施用到皮肤和/或毛发的组合物。
除非另外指明，如本文所用，短语“基本上不含”是指个人护理组合物包含少于约2％，少于约1％，和少于约0.1％的所述成分。如本文所用，术语“不含”是指个人护理组合物包含0％的所述成分，即所述成分尚未被加入个人护理组合物中。然而，这些成分可作为个人护理组合物的其它组分的副产物或反应产物而附带地形成。
除非另外指明，“稳定”是指如由本文所述方法所测量，个人护理组合物在10℃下具有大于约0.30、约0.31、约0.32、约0.33、约0.34、或约0.35的损耗角正切值。
个人护理组合物
所述个人护理组合物可为洗去型制剂，其可被局部施用到皮肤和/或毛发，并且在数分钟内用水从皮肤和/或毛发上洗去。如本文所述方法所测量，所述个人护理组合物在约25℃下可表现出约1,000厘泊(cP)至约1,000,000cP，约1,500厘泊(cP)至约1,000,000cP，约5,000厘泊(cP)至约1,000,000cP，约6,000厘泊(cP)至约1,000,000cP，或约8,000厘泊(cP)至约1,000,000cP的粘度。所述个人护理组合物也可被用作剃刮助剂。所述个人护理组合物可从包装件中挤出或分配。所述个人护理组合物可为例如液体、半液体霜膏、洗剂、或凝胶的形式，并且可旨在用于局部施用到皮肤和/或毛发。个人护理组合物的例子可包括但不限于洗发剂、调理洗发剂、沐浴剂、保湿沐浴剂、沐浴凝胶、洁肤剂、清洁乳、毛发和沐浴剂、沐浴保湿剂、宠物香波、剃刮制剂、以及与一次性清洁布一起使用的清洁组合物。
个人护理组合物的适宜性可受多种因素的影响，包括存在于个人护理组合物中的表面活性剂的量和类型。许多消费者使用个人护理组合物，因为个人护理组合物可从皮肤和/或毛发上移除污垢、汗液、皮脂、以及其它物质。然而，除了被个人护理组合物所显示的清洁特性以外，个人护理组合物的适宜性也可受其它因素的影响。
例如，个人护理组合物的适宜性可根据个人护理组合物制剂中包含的表面活性剂的类型和量而变化。就这一点而言，当个人护理组合物包含促使皮肤干燥的表面活性剂时，消费者可将所述个人护理组合物视为不适宜的。另外，由于使用具体个人护理组合物时，许多消费者将清洁效率等同于生成的泡沫水平，因此消费者可能不期望所含表面活性剂不发泡至所期望水平的个人护理组合物。也可能影响消费者对个人护理组合物看法的是个人护理组合物所显示的流变性。例如，温度波动可引起个人护理组合物的流变性变化，使得消费者认为产品过稠和/或不可分配。在保持个人护理组合物的清洁特性的同时，平衡前述因素可能是具有挑战性的尝试。
除了上文的复杂因素以外，一些消费者还期望稠厚的产品。可通过增大个人护理组合物的粘度，产生稠厚的产品。然而，粘度可与个人护理组合物的弹性行为相关联，所以增大粘度可对产品感觉具有负面效应。一种此类负面效应为弹性或凝胶状特征的发展，这可能是消费者不喜欢的。
个人护理组合物的流变行为可由其损耗角正切值来表征。增大个人护理组合物的粘度可使其损耗角正切值降至不可接受的水平，从而赋予个人护理组合物非期望的凝胶状稠度。因此，可平衡个人护理组合物的粘度和损耗角正切值，以向消费者赋予更加可接受的产品。例如，消费者可能认为10℃下具有高于约0.30，高于约0.31，高于约0.32，高于约0.33，高于约0.34，或高于约0.35损耗角正切值的个人护理组合物具有足够的粘度以在皮肤之上流动，但又不过于凝胶状，或换句话讲难以铺展在皮肤上或从包装中分配。相比之下，10℃下具有低于约0.30损耗角正切值的个人护理组合物可被认为是过于凝胶状，并且难以铺展在皮肤上以及从容器中分配。另外，约25℃下具有低于5000cP稠度的个人护理组合物可被认为过稀。相比之下，约25℃下具有高于5000cP稠度的个人护理组合物可被认为具有足够的稠度。个人护理组合物可具有至多约20的损耗角正切值。
个人护理组合物的损耗角正切值不仅可随粘度变化而波动，而且可在温度跨度内波动。例如，虽然个人护理组合物可具有室温(例如25℃)下可接受的损耗角正切值，但是在更低的温度如约10℃下，损耗角正切值可能过低。为了具有可在所有季节运输、储存和使用的组合物，在约10℃下所测量的约0.30或更大的损耗角正切值是期望的。
现已发现，包含某些类型的表面活性剂如月桂基硫酸钠(SLS)和其它非乙氧基化烷基硫酸盐，可负面地影响个人护理组合物在低温下的损耗角正切值。不受理论的限制，据信这至少部分地归因于个人护理组合物中由表面活性剂所形成的胶束可堆积的程度。SLS为更小的表面活性剂分子，并且趋于允许更刚性的胶束堆积。据信该更刚性的堆积可造成组合物在低温下的不稳定性，从而导致更低的损耗角正切值。因此，个人护理组合物在低温下的稳定性可通过从个人护理组合物中移除SLS而增大。
令人惊奇的是，还已发现，将特定的多元醇加入某些不含或基本上不含SLS的个人护理组合物中，可增加某些个人护理组合物的粘度和/或改善流变性。令人惊奇的是，还已发现，即使按所述个人护理组合物的重量计少于约10％或更少含量的多元醇也可增加不含或基本上不含非乙氧基化烷基硫酸盐的某些个人护理组合物的粘度和/或改善流变性。
向不含或基本上不含非乙氧基化烷基硫酸盐的某些个人护理组合物加入特定的多元醇可增加个人护理组合物的粘度和/或改善流变性的发现是令人惊奇的，例如考虑到个人护理组合物中多元醇不可预知的性质。就这一点而言，已示出，在包含磺基琥珀酸单酯表面活性剂的某些个人护理组合物中包含高含量的多元醇如甘油，可能造成某些个人护理组合物的不稳定。
主要表面活性剂
所述个人护理组合物可包含可含有阴离子表面活性剂的主要表面活性剂。所述主要表面活性剂可构成所述个人护理组合物的约5重量％至约10重量％，约6.4重量％至约10重量％，和约6.4重量％至约8.4重量％。所述阴离子表面活性剂可为月桂基聚氧乙烯醚(n)硫酸钠(下文为SLEnS)，其中n定义了乙氧基化的平均摩尔数。阴离子表面活性剂也可为月桂基聚氧乙烯醚(n)硫酸铵(下文为ALEnS)，其中n定义了乙氧基化的平均摩尔数。例如，n可在大于约0至约3，或者约0.5至约2.7，或者约1.1至约2.5，或者大于约0至约2.5，或者约1.8至约2.2，或者约2的范围内。应当理解，材料如SLE3S可包含例如显著量的分子，所述分子以一定分布不具有乙氧基化物，具有1摩尔乙氧基化物，具有4摩尔乙氧基化物等，所述分布可以是广阔的、狭窄的或截短的，同时仍包含其中平均分布为约3的SLE3S。应当理解，材料如SLE2S可包含例如显著量的分子，所述分子以一定分布不具有乙氧基化物，具有1摩尔乙氧基化物，具有4摩尔乙氧基化物等，所述分布可以是广阔的、狭窄的或截短的，同时仍包含其中平均分布为约2的SLE2S。应当理解，材料如SLE1S可包含例如显著量的分子，所述分子以一定分布不具有乙氧基化物，具有1摩尔乙氧基化物，具有4摩尔乙氧基化物等，所述分布可以是广阔的、狭窄的或截短的，同时仍包含其中平均分布为约1的SLE2S。
所述阴离子表面活性剂也可为十三烷基聚氧乙烯醚(n)硫酸钠(下文为STnS)和/或十三烷基聚氧乙烯醚(n)硫酸铵(下文为ATnS)，其中n定义了乙氧基化的平均摩尔数。例如，n可在大于0至3，或者0.5至2.7，或者1.1至2.5，或者大于0至2.5，或者1.8至2.2，或者约2的范围内。应当理解，材料如ST2S可例如包含显著量的分子，所述分子以一定分布不具有乙氧基化物，具有1摩尔乙氧基化物，具有3摩尔乙氧基化物等，所述分布可以是广阔的、狭窄的或截短的，同时仍包含其中平均分布为约2的ST2S。
适用于个人清洁组合物中的其它阴离子表面活性剂为琥珀酸盐，其例子包括N-十八烷基磺基琥珀酸二钠；月桂基磺基琥珀酸二钠；月桂基磺基琥珀酸二铵、N-(1,2-二羧基乙基)-N-十八烷基磺基琥珀酸四钠；磺基琥珀酸钠的二戊基酯；磺基琥珀酸钠的二己基酯；和磺基琥珀酸钠的二辛基酯。
用于个人清洁组合物中的阴离子表面活性剂的其它例子包括月桂基肌氨酸钠、月桂酰肌氨酸钠、肌氨酸月桂酯、椰油基肌氨酸、磷酸烷基酯、乙氧基化磷酸烷基酯、以及它们的组合。
常常，SLE1S、SLE2S和SLE3S与个人护理组合物中的SLS混合。个人护理组合物的例子可包含少于约2％的SLS，或者少于约1％的SLS，或者少于约0.5％的SLS，或者少于约0.1％的SLS，或者少于约0.05％的SLS，或者介于约0.01％SLS和约0.05％SLS之间，或者约0％SLS。
常常，SLE1S、SLE2S和SLE3S，或ALE1S、ALE2S和ALE3S与个人护理组合物中的ALS混合。个人护理组合物的例子可包含少于约2％的ALS，或者少于约1％的ALS，或者少于约0.5％的ALS，或者少于约0.1％的ALS，或者少于约.05％的ALS，或者介于约0.01％ALS和约0.05％ALS之间，或者约0％ALS。
辅助表面活性剂
所述个人护理组合物还可包含辅助表面活性剂。辅助表面活性剂可构成所述个人护理组合物的0.1重量％至20重量％，约2重量％至约10重量％，或约2重量％至约5重量％。辅助表面活性剂也可构成所述个人护理组合物的大于20重量％。辅助表面活性剂可包括两性表面活性剂、两性离子表面活性剂、非离子表面活性剂、以及它们的混合物。
两性/两性离子表面活性剂的例子为甜菜碱表面活性剂。可用于本文的甜菜碱表面活性剂的例子包括高级烷基甜菜碱如椰油基二甲基羧甲基甜菜碱、月桂基二甲基羧甲基甜菜碱、月桂基二甲基α-羧乙基甜菜碱、鲸蜡基二甲基羧甲基甜菜碱、月桂基双-(2-羟乙基)羧甲基甜菜碱、硬脂基双-(2-羟丙基)羧甲基甜菜碱、油基二甲基γ-羧丙基甜菜碱、月桂基双-(2-羟丙基)α-羧乙基甜菜碱等。其它甜菜碱为磺基甜菜碱，其可由椰油基二甲基磺丙基甜菜碱、硬脂基二甲基磺丙基甜菜碱、月桂基二甲基磺乙基甜菜碱、月桂基双-(2-羟乙基)磺丙基甜菜碱等代表；其中RCONH(CH2)x基团附接到甜菜碱的氮原子的酰胺基甜菜碱和酰胺基磺基甜菜碱也可用于本发明中。优选的甜菜碱为椰油酰胺基丙基甜菜碱。
其它可用的表面活性剂包括两性乙酸盐如月桂基两性乙酸钠，和非离子表面活性剂如葡糖苷如癸基葡糖苷、单甘油酯如单月桂酸甘油酯、烷醇酰胺如椰油基单乙醇酰胺、和甘油醚如PEG-80椰油酸甘油酯。
水
本发明的液体个人清洁组合物还可包含按所述组合物的重量计约20％至约95％，约40％至约90％，约60％至约90％，和约70％至约90％的水。
粘度调节剂
所述个人护理组合物还可包含粘度调节剂以调节个人护理组合物的粘度。此类浓度可在例如按所述个人护理组合物的重量计约0.1％至约10％，约0.3％至约5.0％，或0.5％至3％的范围内。
可用于本文的粘度调节剂的非限制性例子包括无机盐。可用于本文的无机盐的例子为硝酸镁、磷酸三镁、氯化钙、碳酸钠、氯化钠、硫酸铝钠、磷酸二钠、聚偏磷酸钠、琥珀酸镁钠、硫酸钠、三聚磷酸钠、硫酸铝、氯化铝、水合氯化铝、水合三氯化铝锆、水合三氯化铝锆甘氨酸配合物、硫酸锌、氯化铵、磷酸铵、硫酸铵、乙酸钙、硝酸钙、磷酸钙、硫酸钙、硫酸铁、氯化镁、硫酸镁、烷基醚硫酸盐、它们的混合物等。
粘度调节剂也可包括聚合物。聚合物的非限制性例子包括纤维素衍生物和改性纤维素聚合物，如甲基纤维素、乙基纤维素、羟乙基纤维素、羟丙基甲基纤维素、硝基纤维素、纤维素硫酸钠、羧甲基纤维素钠、结晶纤维素、纤维素粉末、聚乙烯吡咯烷酮、聚乙烯醇、瓜尔胶、羟丙基瓜尔胶、黄原胶、阿拉伯胶、黄蓍胶、半乳聚糖、长豆角胶、瓜尔胶、刺梧桐树胶、角叉菜胶、果胶、琼脂、温柏树籽(榅桲子)、淀粉(稻、玉米、马铃薯、小麦)、海藻胶(藻类提取物)；微生物聚合物，如葡聚糖、琥珀酰葡聚糖、普鲁兰；淀粉基聚合物，如羧甲基淀粉、甲基羟丙基淀粉；藻酸基聚合物，如藻酸钠、褐藻酸丙二醇酯；丙烯酸酯聚合物，如聚丙烯酸钠、聚丙烯酸乙酯、聚丙烯酰胺、聚乙烯亚胺；以及无机水溶性材料，如膨润土、硅酸铝镁盐、合成锂皂石、锂蒙脱石和无水硅酸。
多元醇
所述个人护理组合物还可包含多元醇。此类浓度可在例如按所述个人护理组合物的重量计约0.1％至约10％，约0.3％至约5.0％，或0.5％至3％的范围内。
可用于本文的多元醇的非限制性例子包括甘油、山梨醇、丙二醇、丁二醇、己二醇、乙氧基化葡萄糖、1,2-己二醇、己三醇、二丙二醇、海藻糖、二甘油、麦芽糖醇、麦芽糖、葡萄糖、果糖、硫酸软骨素钠、透明质酸钠、腺苷磷酸钠、乳酸钠、吡咯烷酮碳酸盐、葡糖胺、环糊精、以及它们的混合物。
其它任选成分
所述个人护理组合物还可包含其它个人护理助剂成分，所述助剂成分可调节所述组合物的物理、化学、美化或美观特征，或在沉积于皮肤上时用作“活性”组分。此类助剂成分的非限制性例子包括防腐剂(例如对羟基苯甲酸丙酯)、除臭剂、抗微生物剂、芳香剂、除臭香料、着色剂或染料、增稠剂、感觉剂、防晒剂、表面活性剂或乳化剂、胶凝剂或其它悬浮剂、pH调节剂、共溶剂或其它附加溶剂、润肤剂、药物活性物质、维生素、以及它们的组合。助剂成分的其它非限制性例子包括：酶、研磨剂、皮屑脱落剂、吸收剂、美观组分(如香料、颜料、染色剂/着色剂)、精油、皮肤感觉剂、收敛剂等(例如丁香油、薄荷醇、樟脑、桉树油、丁子香酚、乳酸薄荷酯、金缕梅馏出液)、抗痤疮剂(如间苯二酚、硫、水杨酸、锌等)、抗结块剂、消泡剂、附加的抗微生物剂(如丁基氨基甲酸碘丙酯)、抗氧化剂、粘合剂、生物添加剂、缓冲剂、膨化剂、螯合剂、化学添加剂、着色剂、化妆收敛剂、化妆品杀虫剂、变性剂、药物收敛剂、外用止痛药、成膜剂或材料(如有助于组合物成膜性和亲和性的聚合物(如二十碳烯与乙烯基吡咯烷酮的共聚物))、湿润剂、遮光剂、pH调节剂、推进剂、还原剂、螯合剂、皮肤漂白剂(或增亮剂)(例如曲酸、抗坏血酸、抗坏血酸磷酸镁、抗坏血酸葡糖胺)、皮肤调理剂(湿润剂，包括混杂的和吸留的)、皮肤抚慰剂和/或愈合剂(如泛醇和衍生物(例如乙基泛醇)、芦荟、泛酸及其衍生物、尿囊素、红没药醇和甘草酸二钾)、皮肤处理剂(包括预防、延迟、抑制和/或逆转皮肤皱纹的试剂(如α-羟基酸例如乳酸和乙醇酸，和β-羟基酸例如水杨酸))、增稠剂、水解胶体(具体为沸石)、和维生素及其衍生物(例如生育酚、生育酚乙酸酯、β-胡萝卜素、视黄酸、视黄醇、类视色素、棕榈酸视黄酯、烟酸、烟酰胺、泛醇等)。
测试方法
可使用具有CPE-41锭子和温度控制的数字式布氏粘度计(RVDVII型)来测量个人护理组合物的粘度。在25℃、1mm间隙(旋转的锭子与RVDVII壁之间的距离)、1RPM(每分钟转数)的剪切速率下测量粘度。每次测量进行两分钟的时间以允许收集足够的数据点，以确定产品的平均粘度(即锭子在1rpm下旋转2分钟)。
将G"与G'的比率(即G"÷G')称为损耗角正切值。为测量个人护理组合物的粘性模量(G")和弹性模量(G')，使用配备有上部具有40mm直径的1度锥形几何体和下部平板几何体的高级流变仪AR G2流变仪(TA Instruments，DE，USA)，所述平板几何体配备有珀耳帖加热/冷却机构，以控制温度。通过将大约1克的个人护理组合物置于下部测试几何体上，并且降低上部几何体至约27微米的所需间隙，擦去任何过量的个人护理组合物以围绕上部和下部几何体的边缘产生均匀的表面，来进行测量。在0.01至100弧度每秒的频率范围内进行测试，每十进收集10个数据点，使用0.1Pa的恒定振动应力和10℃或25℃的设定温度。
实例
由以下方法制备比较例C-1至C-16和本发明实例I-1至I-15。首先，使用SpeedMixer(DAC 400FVZ型，得自Hauschild)，将每种相应的个人护理组合物的除NaCl以外的所有成分在2000rpm下混合一分钟。一分钟间隔应足以实现均匀的溶液。接着，加入包含NaCl的溶液，并且然后再次混合所有成分。然后对如本文所述的每个实例测量粘度和损耗角正切值。
表1和2中的组合物示出了每种成分或溶液按所述个人护理组合物重量计的百分比。数量表达为所加入成分的百分比，包括成分中所含的任何非活性组分。仅作为例示性实例，包含按所述组合物的重量计约25％月桂基聚氧乙烯醚-3硫酸钠成分的组合物指示包含按所述组合物的重量计约7.0％的活性月桂基聚氧乙烯醚-3硫酸钠(按所述组合物的重量计25％的成分*所述成分中28％的活性组分＝按所述组合物的重量计7.0％的活性月桂基聚氧乙烯醚-3硫酸钠)的组合物。
表1：
表2：
如表1中所示，比较例C-1、C-4至C-6以及C-11至C-13示出了包含SLS与SLE3S(月桂基聚氧乙烯醚(3)硫酸钠)、CAPB(椰油酰胺基丙基甜菜碱)和山梨醇的组合的个人护理组合物。比较例C-2以及C-7至C-9示出了包含SLE3S和CAPB，但无SLS或多元醇的个人护理组合物。比较例C-3、C-10以及C-14至C-16示出了包含SLS、SLE3S和CAPB，但无多元醇的个人护理组合物。
表2中的本发明实例I-1至I-6以及I-10至I-12示出包含SLES、CAPB和山梨醇，但无SLS的个人护理组合物。本发明实例I-7至I-9以及I-13至I-15示出包含SLES、CAPB和甘油，但无SLS的个人护理组合物。本发明实例I-10至I-12示出包含SLES、CAPB和少量山梨醇，但无SLS的个人护理组合物。
将比较例C-3与C-4进行比较，显示向包含SLS、SLE3S和CAPB的个人护理组合物中仅加入山梨醇，未获得稳定的个人护理组合物(即在约10℃下具有大于约0.30损耗角正切值的个人护理组合物)。将C-2与C-3进行比较，还显示从包含SLE3S和CAPB，但无多元醇的个人护理组合物中移除SLS，未获得稳定的个人护理组合物，因为所得组合物未能提供消费者寻求的期望流变性。例如，C-2被认为过于凝胶状，并且难以在皮肤上铺展，并且因此不稳定。
最后，比较例C-4至C-6示出，虽然增加包含SLE3S、SLS、CAPB和山梨醇的个人护理组合物中粘度调节剂NaCl的浓度可增大个人护理组合物的粘度，但是仅包含粘度调节剂不致使个人护理组合物在约10℃下大于0.30的损耗角正切值。
令人惊奇的是，将本发明实例I-1至I-6与比较例C-2以及C-7至C-9进行比较示出，在包含SLE3S和CAPB，但无SLS的个人护理组合物中包含山梨醇，致使个人护理组合物在约10℃下具有大于0.30的损耗角正切值。使包含SLE3和CAPB的个人护理组合物稳定所需的山梨醇的量按所述个人护理组合物重量计可如I-1至I-6中所示低于10％，或甚至如I-10至I-12中所示在仅约1.5％至约4.5％的范围内。例如，将C-2与I-2进行比较，向包含SLE3S和CAPB，但无SLS的个人护理组合物中加入按所述个人护理组合物的重量计大约3％的山梨醇，使约10℃下约0.30的损耗角正切值增大至约10℃下约0.36。
在包含SLE3S和CAPB，但无SLS的个人护理组合物中包含甘油，也致使个人护理组合物在约10℃下具有大于0.30的损耗角正切值，如本发明实例I-7至I-9至I-13中所示。将I-7至I-9与C-7至C-9进行比较显示，向包含SLE3S和CAPB，但无SLS的个人护理组合物中加入按所述个人护理组合物的重量计仅约1％至约3％的甘油，致使损耗角正切值从0.18至0.24的范围增大至0.36至0.33的范围。
将I-3与I-4进行比较还示出，包含SLE3S和CAPB，但无SLS的稳定个人护理组合物的粘度可通过增大粘度调节剂NaCl的浓度而增加。通过将I-13至I-15与I-7至I-9进行比较还示出，稳定个人护理组合物的粘度可通过增加粘度调节剂而增加，同时仍保持个人护理组合物在10℃下0.30或更大的损耗角正切值。
本文所公开的量纲和值不应被理解为严格限于所引用的确切数值。相反，除非另外指明，每个此类量纲旨在表示所引用的值以及该值附近的函数等同范围。例如，公开为“40mm”的量纲旨在表示“约40mm”。
具体实施方式中的所有引用文献的相关部分均以引用方式并入本文；任何文献的引用不可解释为是对其作为本发明的现有技术的认可。当本文献中术语的任何含义或定义与以引用方式并入本文的相同术语的任何含义或定义冲突时，将以本文献中赋予那个术语的含义或定义为准。
尽管已用具体实施例来说明和描述了本发明，但是对那些本领域的技术人员显而易见的是，在不背离本发明的实质和范围的情况下可作出各种其它的改变和变型。因此，所附权利要求书旨在涵盖本发明范围内的所有此类改变和变型。

Claims (13)

1.一种混合物在制备个人护理组合物中的用途，所述混合物由下列组分组成：
i)5重量％到10重量％的主要表面活性剂，所述主要表面活性剂包括不是月桂基硫酸钠或月桂基硫酸铵的阴离子表面活性剂；
ii)0.1重量％到20％重量的第二表面活性剂，所述第二表面活性剂包括两性离子表面活性剂、两性表面活性剂、或它们的组合；和
iii)0.1重量％到10重量％的选自甘油、山梨醇、丙二醇和丁二醇的多元醇；
其中所述个人护理组合物在10℃下表现出0.30或更大的损耗角正切值；其中所述个人护理组合物不含月桂基硫酸钠。
2.根据权利要求1所述的用途，其中所述个人护理组合物不含非乙氧基化烷基硫酸盐。
3.根据权利要求1所述的用途，所述个人护理组合物还包含粘度调节剂，所述粘度调节剂选自硝酸镁、磷酸三镁、氯化钙、碳酸钠、氯化钠、硫酸铝钠、磷酸二钠、聚偏磷酸钠、琥珀酸镁钠、硫酸钠、三聚磷酸钠、硫酸铝、氯化铝、水合氯化铝、水合三氯化铝锆、水合三氯化铝锆甘氨酸配合物、硫酸锌、氯化铵、磷酸铵、硫酸铵、乙酸钙、硝酸钙、磷酸钙、硫酸钙、硫酸铁、氯化镁、硫酸镁、烷基醚硫酸盐、以及它们的混合物。
4.根据权利要求3所述的用途，其中所述粘度调节剂包括氯化钠。
5.根据权利要求1所述的用途，其中所述第二表面活性剂包括椰油酰胺基丙基甜菜碱。
6.根据权利要求5所述的用途，其中所述椰油酰胺基丙基甜菜碱构成所述个人护理组合物的2重量％至5重量％。
7.根据权利要求1所述的用途，其中所述多元醇构成所述个人护理组合物的0.5重量％至少于10重量％。
8.根据权利要求1所述的用途，其中所述多元醇包括山梨醇、甘油、或它们的混合物。
9.根据权利要求1所述的用途，其中所述多元醇包含按所述个人护理组合物的重量计1％至3％的甘油。
10.根据权利要求1所述的用途，其中所述多元醇包含按所述个人护理组合物的重量计0.5％至5.0％的山梨醇。
11.根据权利要求1所述的用途，其中所述个人护理组合物在25℃下表现出5,000cP或更大的粘度。
12.根据权利要求1所述的用途，其中所述个人护理组合物在10℃下表现出0.33或更大的损耗角正切值。
13.根据权利要求1所述的用途，其中所述个人护理组合物在10℃下表现出0.35或更大的损耗角正切值。
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