DE10056266B4 - Method of dyeing human hair - Google Patents

Method of dyeing human hair Download PDF

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Publication number
DE10056266B4
DE10056266B4 DE2000156266 DE10056266A DE10056266B4 DE 10056266 B4 DE10056266 B4 DE 10056266B4 DE 2000156266 DE2000156266 DE 2000156266 DE 10056266 A DE10056266 A DE 10056266A DE 10056266 B4 DE10056266 B4 DE 10056266B4
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oil
hair
scalp
fat
stearate
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DE10056266A1 (en
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Mustafa Dr. Grit
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Kao Germany GmbH
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KPSS Kao Professional Salon Services GmbH
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A61K8/064—Water-in-oil emulsions, e.g. Water-in-silicone emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
    • A61K8/585—Organosilicon compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86—Polyethers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A61Q5/065—Preparations for temporary colouring the hair, e.g. direct dyes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/10—Preparations for permanently dyeing the hair

Abstract

Verfahren zum Färben von menschlichem Haar ohne Anfärben der Haut, gekennzeichnet durch die Kombination der folgenden Verfahrensschritte:
a) Aufbringen einer Wasser-in-Öl-Emulsion, enthaltend 5 bis 50 Gew.-% hydrophobe sowie Fett- und/oder Ölkomponenten, bestehend aus mindestens einem Fettsäureester als hydrophobe Komponente, ausgewählt aus Isopropylmyristat, -palmitat, -stearat und -isostearat, Oleyloleat, Isocetylstearat, Hexyllaurat, Dibutyladipat, Dioctyladipat, Myristylmyristat, Oleylerucat und Cetylpalmitat, und Fett- und/oder Öl, ausgewählt aus natürlichen Ölen ausgewählt aus Avocadoöl, Kokosöl, Palmöl, Sesamöl, Erdnussöl, Spermöl, Sonnenblumenöl, Mandelöl, Pfirsichkernöl, Weizenkeimöl, Macadamianussöl, Nachtkerzenöl, Jojobaöl, Ricinusöl, Oliven- oder Sojaöl, Lanolin und dessen Derivate, Mineralölen ausgewählt aus Paraffinöl und Vaseline und synthetischen Ölen, ausgewählt aus Silikonölen und 2 bis 40 Gew.-% mindestens eines nichtionischen Emulgators auf die Kopfhaut und die benachbarten Hautbereiche;
b) Behandeln des Haares mit einer mindestens einen direktziehenden Haarfarbstoff oder mindestens ein Oxidationsfarbstoff-Vorprodukt und mindestens ein Oxidationsmittel enthaltenden Färbezusammensetzung,
c) Einwirken lassen und gegebenenfalls Spülen und/oder Waschen des gefärbten Haares, der Kopfhaut...Process for dyeing human hair without staining the skin, characterized by the combination of the following process steps:
a) applying a water-in-oil emulsion containing 5 to 50 wt .-% hydrophobic and fat and / or oil components, consisting of at least one fatty acid ester as a hydrophobic component selected from isopropyl myristate, palmitate, stearate and isostearate , Oleyl oleate, isocetyl stearate, hexyl laurate, dibutyl adipate, dioctyl adipate, myristyl myristate, oleyl erucate and cetyl palmitate, and fat and / or oil selected from natural oils selected from avocado, coconut, palm, sesame, peanut, sperm, sunflower, almond, peach kernel, wheat germ , Macadamia nut oil, evening primrose oil, jojoba oil, castor oil, olive or soybean oil, lanolin and its derivatives, mineral oils selected from paraffin oil and vaseline and synthetic oils selected from silicone oils and 2 to 40% by weight of at least one nonionic emulsifier on the scalp and the adjacent ones skin areas;
b) treating the hair with a dyeing composition containing at least one substantive hair dye or at least one oxidation dye precursor and at least one oxidizing agent,
c) Allow to act and optionally rinse and / or wash the dyed hair, scalp ...

Description

Das Hauptpatent DE 100 28 723 betrifft ein Verfahren zum Färben menschlicher Haare, bei dessen Anwendung die ansonsten auftretende Anfärbung der das Haar umgebenden Haut, insbesondere der Gesichts- und Kopfhaut, verhindert wird.The main patent DE 100 28 723 relates to a process for dyeing human hair, the application of which prevents the otherwise occurring staining of the skin surrounding the hair, especially the face and scalp.

Dieses Verfahren besteht darin, daß auf die Kopfhaut bzw. die benachbarten Hautbereiche vor dem Haarefärben zunächst eine Wasser-in-Öl-Emulsion aufgebracht wird, die 5 bis 50 Gew.-% mindestens einer Fett- und/oder Ölkomponenten, bestehend aus mindestens einem Fettsäureester als hydrophobe Komponente, ausgewählt aus Isopropylmyristat, -palmitat, -stearat und -isostearat, Oleyloleat, Isocetylstearat, Hexyllaurat, Dibutyladipat, Dioctyladipat, Myristylmyristat, Oleylerucat und Cetylpalmitat, und Fett- und/oder Öl, ausgewählt aus natürlichen Ölen ausgewählt aus Avocadoöl, Kokosöl, Palmöl, Sesamöl, Erdnussöl, Spermöl, Sonnenblumenöl, Mandelöl, Pfirsichkernöl, Weizenkeimöl, Macadamianussöl, Nachtkerzenöl, Jojobaöl, Ricinusöl, Oliven- oder Sojaöl, Lanolin und dessen Derivate, Mineralölen ausgewählt aus Paraffinöl und Vaseline und synthetischen Ölen ausgewählt aus Silikonölen und 2 bis 40 Gew.-% mindestens eines nichtionischen Emulgators enthält, und anschließend das Haar entweder mit einer mindestens einen direktziehenden Haarfarbstoff oder mindestens ein Oxidationsfarbstoff-Vorprodukt und mindestens ein Oxidationsmittel enthaltenden Färbezusammensetzung gefärbt wird.This Method is that on the scalp or the adjacent skin areas before hair coloring first one Water-in-oil emulsion is applied, the 5 to 50 wt .-% of at least one fat and / or oil components, consisting of at least one fatty acid ester as hydrophobic component, selected from isopropyl myristate, palmitate, stearate and isostearate, oleyl oleate, Isocetylstearate, hexyl laurate, dibutyl adipate, dioctyl adipate, myristyl myristate, Oleyl erucate and cetyl palmitate, and fat and / or oil selected from natural oils selected from Avocado oil, Coconut oil, Palm oil, Sesame oil, Peanut oil, sperm oil, Sunflower oil, Almond oil, Peach kernel oil, Wheat germ oil, macadamia nut oil, Evening primrose oil, jojoba oil, Castor oil, olive or soybean oil, Lanolin and its derivatives, mineral oils selected from paraffin oil and Vaseline and synthetic oils selected from silicone oils and 2 to 40 wt .-% of at least one nonionic emulsifier, and subsequently the hair either with at least one substantive hair dye or at least one oxidation dye precursor and at least one Oxidizing agent-containing dyeing composition colored becomes.

Nach erfolgter Einwirkung wird das Haar vorzugsweise gespült (beispielsweise bei direktziehenden Farbstoffen) oder auch gewaschen und gespült, insbesondere, wenn es sich um eine Oxidationsfärbung handelt.To the action is preferably rinsed the hair (for example with substantive dyes) or also washed and rinsed, in particular, if it is an oxidation dye is.

Die vorliegende Erfindung betrifft eine Verbesserung dieses Verfahrens durch Zusatz von 0,5 bis 15, vorzugsweise 1 bis 10 Gew.-%, insbesondere 2,5 bis 7,5 Gew.-% eines flüchtigen Silikons ausgewählt aus Cyclosiloxan der allgemeinen Formel

Figure 00020001
worin n im Durchschnitt 3 bis 6 bedeutet, zu der in der ersten Verfahrensstufe aufgebrachten W/O-Emulsion.The present invention relates to an improvement of this process by addition of 0.5 to 15, preferably 1 to 10 wt .-%, in particular 2.5 to 7.5 wt .-% of a volatile silicone selected from cyclosiloxane of the general formula
Figure 00020001
where n is 3 to 6 on average, to the W / O emulsion applied in the first step.

Dadurch wird insbesondere die Konsistenz der Emulsion verbessert, sie ist leichter auftragbar, jedwede Klebrigkeit wird verhindert.Thereby In particular, the consistency of the emulsion is improved, it is easier to apply, any stickiness is prevented.

Geeignete flüchtige Cyclosiloxane sind beispielsweise die unter dem Trivialnamen „Cyclomethicone” bekannten Dodecamethylcyclohexasiloxane und Octamethylcyclotetrasiloxane.suitable volatile Cyclosiloxanes are, for example, those known by the common name "cyclomethicone" Dodecamethylcyclohexasiloxane and Octamethylcyclotetrasiloxane.

Auch niedermolekulare Dimethicon-Copolyole und substituierte niedermolekulare Siloxane können im Rahmen der Erfindung mitverwendet werden.Also low molecular weight dimethicone copolyols and substituted low molecular weight Siloxanes can be used in the invention.

Die genannten Silikone werden insbesondere von der Dow Corning Co. vertrieben und sind in deren Firmenschriften, auf die hier Bezug genommen wird, ausführlich beschrieben.The The silicones mentioned are in particular sold by the Dow Corning Co. and are in their company publications, which are referred to here, in detail described.

Im übrigen wird auf die Beschreibung des Hauptpatents Bezug genommen.Otherwise, will to the description of the main patent reference.

Das folgende Ausführungsbeispiel charakterisiert die Erfindung:
Auf Kopfhaut und angrenzende Hautregionen einer Probandin mit zu färbendem naturbraunen Haar wurde vor der Färbung eine W/O-Emulsion der Zusammensetzung Glyceryltristearat 3,0 (Gew.-%) Polyglyceryl-3-diisostearat 5,0 Glycerylstearat 2,0 Paraffinöl 20,0 Magnesiumsulfat 1,0 Cyclomethicone (DC 344; Viskosität etwa 5,0 3 mPa·s (Brookfield, 25°C) Parfum 0,2 Glycerin 3,0 1,2-Propylenglykol 2,0 Konservierungsmittel 0,3 Wasser ad 100,0 aufgebracht.The following embodiment characterizes the invention:
On the scalp and adjacent skin regions of a subject with natural brown hair to be dyed, a W / O emulsion of the composition was prepared before staining glyceryl 3.0 (wt%) Polyglyceryl-3 diisostearate 5.0 glyceryl stearate 2.0 paraffin oil 20.0 magnesium sulfate 1.0 Cyclomethicone (DC 344, viscosity approx 5.0 3 mPa.s (Brookfield, 25 ° C) Perfume 0.2 glycerin 3.0 1,2-propylene glycol 2.0 preservative 0.3 water ad 100.0 applied.

Das Mittel hatte eine angenehme, nicht klebrige Konsistenz und war leicht auftragbar.The Medium had a pleasant, non-sticky consistency and was light coatable.

Danach wurde das nasse Haar mit einem direktziehenden Färbemittel der Zusammensetzung Dimethicone Copolyol 1,50 (Gew.-%) Ethanol 5,00 Propylencarbonat 25,00 Milchsäure, 90%-ig 5,00 Natriumhydroxid, 32%-ig 0,20 Xanthan Gum (KeltrolR) 2,00 Acid Orange 7 (C. I.-No. 15510) 0,15 Acid Yellow 3 (C. I.-No. 47005) 0,10 Acid Violet 43 (C. I.-No. 60 730) 0,25 Wasser ad 100,00 behandelt.Thereafter, the wet hair was treated with a substantive colorant of the composition Dimethicone Copolyol 1.50 (wt%) ethanol 5.00 propylene carbonate 25,00 Lactic acid, 90% 5.00 Sodium hydroxide, 32% 0.20 Xanthan gum (Keltrol R ) 2.00 Acid Orange 7 (CI No. 15510) 0.15 Acid Yellow 3 (CI No. 47005) 0.10 Acid Violet 43 (CI No. 60 730) 0.25 water ad 100.00 treated.

Nach etwa zwanzigminütiger Einwirkung wurde gewaschen, gespült und getrocknet.To about twenty minutes Action was washed, rinsed and dried.

Es wurde ein glänzend braun gefärbtes Haar, das leicht kammbar war, einen vollen Griff und Spannkraft aufwies, erhalten. Die Färbung blieb über vier Haarwäschen haltbar.It became a shiny one browned Hair that was easy to comb, a full grip and resilience had received. The coloring stayed over four washes durable.

Es trat keinerlei Verfärbung der Kopfhaut und der angrenzenden Hautbereiche auf.It no discoloration occurred scalp and adjacent skin areas.

Claims (2)

Verfahren zum Färben von menschlichem Haar ohne Anfärben der Haut, gekennzeichnet durch die Kombination der folgenden Verfahrensschritte: a) Aufbringen einer Wasser-in-Öl-Emulsion, enthaltend 5 bis 50 Gew.-% hydrophobe sowie Fett- und/oder Ölkomponenten, bestehend aus mindestens einem Fettsäureester als hydrophobe Komponente, ausgewählt aus Isopropylmyristat, -palmitat, -stearat und -isostearat, Oleyloleat, Isocetylstearat, Hexyllaurat, Dibutyladipat, Dioctyladipat, Myristylmyristat, Oleylerucat und Cetylpalmitat, und Fett- und/oder Öl, ausgewählt aus natürlichen Ölen ausgewählt aus Avocadoöl, Kokosöl, Palmöl, Sesamöl, Erdnussöl, Spermöl, Sonnenblumenöl, Mandelöl, Pfirsichkernöl, Weizenkeimöl, Macadamianussöl, Nachtkerzenöl, Jojobaöl, Ricinusöl, Oliven- oder Sojaöl, Lanolin und dessen Derivate, Mineralölen ausgewählt aus Paraffinöl und Vaseline und synthetischen Ölen, ausgewählt aus Silikonölen und 2 bis 40 Gew.-% mindestens eines nichtionischen Emulgators auf die Kopfhaut und die benachbarten Hautbereiche; b) Behandeln des Haares mit einer mindestens einen direktziehenden Haarfarbstoff oder mindestens ein Oxidationsfarbstoff-Vorprodukt und mindestens ein Oxidationsmittel enthaltenden Färbezusammensetzung, c) Einwirken lassen und gegebenenfalls Spülen und/oder Waschen des gefärbten Haares, der Kopfhaut und der benachbarten Hautbereiche nach Patent Nr. 100 28 723, dadurch gekennzeichnet, daß die in der Verfahrensstufe a) aufgebrachte W/O-Emulsion zusätzlich 0,5 bis 15 Gew.-% mindestens eines flüchtigen Silikons ausgewählt aus Cyclosiloxan der allgemeinen Formel
Figure 00050001
worin n im Durchschnitt 3 bis 6 bedeutet, enthält.A process for dyeing human hair without staining the skin, characterized by the combination of the following process steps: a) applying a water-in-oil emulsion containing 5 to 50 wt .-% hydrophobic and fat and / or oil components consisting of at least one fatty acid ester as a hydrophobic component selected from isopropyl myristate, palmitate, stearate and isostearate, oleyl oleate, isocetyl stearate, hexyl laurate, dibutyl adipate, dioctyl adipate, myristyl myristate, oleyl erucate and cetyl palmitate, and fat and / or oil selected from natural oils selected from Avocado oil, coconut oil, palm oil, sesame oil, peanut oil, sperm oil, sunflower oil, almond oil, peach kernel oil, wheat germ oil, macadamia nut oil, evening primrose oil, jojoba oil, castor oil, olive or soybean oil, lanolin and its derivatives, mineral oils selected from paraffin oil and vaseline and synthetic oils selected from Silicone oils and 2 to 40 wt .-% of at least one nonionic emulsifier rs on the scalp and the adjacent skin areas; b) treating the hair with a dyeing composition comprising at least one substantive hair dye or at least one oxidation dye precursor and at least one oxidizing agent, c) allowing to act and optionally rinsing and / or washing the dyed hair, scalp and adjacent skin areas of Patent No. 100 No. 28 723, characterized in that the W / O emulsion applied in process stage a) additionally contains 0.5 to 15% by weight of at least one volatile silicone selected from cyclosiloxane of the general formula
Figure 00050001
wherein n means on average 3 to 6 contains. Verfahren nach Anspruch 1, dadurch gekennzeichnet, daß die W/O Emulsion 1 bis 10 Gew.-% eines Cyclosiloxans enthält.Method according to claim 1, characterized in that that the W / O emulsion 1 to 10 wt .-% of a cyclosiloxane.
DE2000156266 2000-06-09 2000-11-14 Method of dyeing human hair Expired - Fee Related DE10056266B4 (en)

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US8070831B2 (en) 2008-12-19 2011-12-06 L'oreal S.A. Composition comprising at least one solid fatty alcohol, dyeing or lightening process using same and devices
US8092553B2 (en) 2008-12-19 2012-01-10 L'oreal S.A. Composition for the oxidation dyeing of keratin fibers comprising para-aminophenol, dipropylene glycol and at least one additional dye precursor
US8114170B2 (en) 2009-12-22 2012-02-14 L'oreal S.A. Agent for coloring and/or bleaching keratin fibers comprising composition (A), composition (B), at least one fat and at least one reductone
US8118884B2 (en) 2009-12-22 2012-02-21 L'oreal S.A. Dyeing or lightening compositions comprising at least one fatty substance and at least one amphoteric polymer
US8142518B2 (en) 2009-12-22 2012-03-27 L'oreal Agent for dyeing and/or bleaching keratin fibers in two parts, comprising at least one fatty substance and at least one sequestrant
US8147564B2 (en) 2009-12-22 2012-04-03 L'oreal Agent for dyeing and/or bleaching keratin fibers, comprising composition (A), anhydrous composition (B), and at least one fatty substance
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US7837742B2 (en) 2003-05-19 2010-11-23 The Procter & Gamble Company Cosmetic compositions comprising a polymer and a colorant
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DE102005038771A1 (en) * 2005-08-15 2007-02-22 Henkel Kgaa Hair dyeing and treatment kit with dye and color protectant
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FR2940067B1 (en) 2008-12-19 2011-02-25 Oreal OXIDIZING COMPOSITION FOR THE TREATMENT OF KERATIN FIBERS COMPRISING A CATIONIC POLYMER, A FATTY AMIDE AND AN OXYGEN AGENT
FR2940106B1 (en) 2008-12-19 2013-04-12 Oreal COMPOSITION COMPRISING A FATTY BODY AND A SILICATE, COLORING PROCESS USING THE SAME AND DEVICES
FR2940107B1 (en) 2008-12-19 2011-03-18 Oreal PROCESS FOR LIGHTENING KERATINIC MATERIALS USING AN EMULSION COMPRISING AN ALKALI AGENT AND AN OXIDIZING COMPOSITION
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US9005594B2 (en) 2007-12-21 2015-04-14 L'oreal Method for lightening human keratin fibers using at least one anhydrous composition, at least one organic amine, and at least one oxidizing agent, and device for use thereof
US8070831B2 (en) 2008-12-19 2011-12-06 L'oreal S.A. Composition comprising at least one solid fatty alcohol, dyeing or lightening process using same and devices
US8092553B2 (en) 2008-12-19 2012-01-10 L'oreal S.A. Composition for the oxidation dyeing of keratin fibers comprising para-aminophenol, dipropylene glycol and at least one additional dye precursor
US8114170B2 (en) 2009-12-22 2012-02-14 L'oreal S.A. Agent for coloring and/or bleaching keratin fibers comprising composition (A), composition (B), at least one fat and at least one reductone
US8118884B2 (en) 2009-12-22 2012-02-21 L'oreal S.A. Dyeing or lightening compositions comprising at least one fatty substance and at least one amphoteric polymer
US8142518B2 (en) 2009-12-22 2012-03-27 L'oreal Agent for dyeing and/or bleaching keratin fibers in two parts, comprising at least one fatty substance and at least one sequestrant
US8147564B2 (en) 2009-12-22 2012-04-03 L'oreal Agent for dyeing and/or bleaching keratin fibers, comprising composition (A), anhydrous composition (B), and at least one fatty substance

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