DE102004002168A1 - Cosmetic, useful as e.g. a shampoo and a shower gel, comprises a foam dispenser with two chambers comprising preparations containing cosmetic and/or dermatological active substances and surfactants - Google Patents

Abstract

Cosmetic (I) comprises a foam dispenser with two separate chambers comprising two cosmetic preparations (1 and 2) that can be simultaneously taken, with the help of two coupled conveyor pumps, to a common outlet where the foaming occurs in an air medium; and where at least one of (1 or 2) contains one or more cosmetic and/or dermatological active substances and one or more surfactants. An independent claim is also included for use of a foam dispenser to mix the cosmetic and/or dermatological preparations containing the active agents in air such that the two phases form foam and after foaming, the two preparations cannot be viewed as separate domains with naked eye.

Description

The The present invention relates to a cosmetic from a foam dispenser and two cosmetic partial preparations as well as the use of the Foam dispenser.

Of the Wish, nice and looking attractive, is inherently rooted in man. Even if the ideal of beauty has undergone changes over time, so is the pursuit of a flawless appearance, always been the goal of the people. A substantial portion of one beautiful and attractive looks as well as the condition and appearance of the skin and the appendages.

In order to the skin and the appendages of the skin, these include especially the hair and nails, they must fulfill their biological functions to the full extent regular cleaning and care and protection against UV radiation. The cleaning serves doing so the removal of dirt, sweat and remains of dead Body cells the ideal breeding ground for pathogens and parasites of all kinds. Become a cosmetic cleaning products usually in the form of gels, lotions and solids (soap bars, washing synthetics) offered. Skin care products, usually creams, ointments or lotions, serve usually moistening and refatting the skin, because the job of skin care is through the daily Washing to compensate for fat and water loss of the skin. This is especially important when the natural regenerative ability is not sufficient. Furthermore should skin care products against environmental influences, especially from the sun and wind, protect and delay skin aging.

The Type of composition of cosmetic preparations finds its natural Limits caused by the compatibility the individual components together and the stability of individual components in the carrier medium be determined. For example, skin regenerating enzymes and vitamins in cosmetic preparations can not last indefinitely. The combination of differently charged polymers or surfactants leads in cosmetic formulations to clumping and precipitation.

There has been no lack of attempts to make such preparations available to the consumer. Most sub-components of the formulations are then packaged and stored separately. As a rule, so-called two-chamber packagings (dual chamber) are used for this purpose, in which the part preparations can be stored in separate storage vessels and taken out of the packaging container at the same time via a common opening. Such two-chamber packaging are described for example in WO 96/02230, WO 96/37420, WO 98/33477 and EP 048703 described.

• • Es lassen sich mit diesen Systemen keine gleichmäßig aufgeschäumten feinporigen Schäume herstellen.
• • Es lassen sich keine stark aufgeschäumten, ein großes Schaumvolumen aufweisende Schäume herstellen.
• • Zur Herstellung von Produkten mit akzeptablem Schaumvermögen sind hohe Mengen an hautreizenden Tensiden notwendig, was dem Effekt von Wirkstoffen, die den Hautzustand verbessern sollen, entgegenwirkt.

Conventional two-chamber packaging, however, have a number of disadvantages that limited their use in the field of cosmetics so far.

• • It is not possible to produce uniformly foamed fine-pored foams with these systems.
• • It is not possible to produce foams which are highly foamed and have a large foam volume.
• • For the production of products with acceptable foaming power, high levels of skin-irritating surfactants are necessary, which counteracts the effect of active ingredients intended to improve the skin condition.

It Therefore, the object of the present invention, the shortcomings of Prior art to eliminate. Furthermore, it was the task of present invention to develop a cosmetic which the simultaneous use of incompatible ingredients of cosmetics and dermatics allows.

Active substance Preparations are taken from the prior art from two-chamber packaging without foaming to become. You will, if any, only on the body frothed by trituration. Did you want one for would reach the consumer appealing foaming power would have to usual 2-chamber products high levels of irritating, mostly anionic Surfactants are used. This is the skin-care effect of active ingredients. By using small quantities most skin-friendly, but only slightly foaming surfactants is indeed the Skin irritation reduced, however, it comes, due to the low foaming (and thus the lower surface the preparation), to a small mass transfer between Preparation and skin (hair, nails etc.) with the result that Only small amounts of active substances are absorbed by the body.

The Efficiency of the active ingredients, i. the physiological action triggered by their use Effect is by means of conventional 2-chamber systems applied preparations on top of that at a high proportion on washing-active substances (surfactants) impaired, since these are the (se desired) Property also have per se water-insoluble compounds by micelle formation "water-soluble" to make Surfactants also keep the active ingredients in the water phase, their Absorption hindered by the washing-active substances, so that in particular in cleaning preparations, the absorption of active ingredients through the skin, Hair, nails is minimal.

It Therefore, the object of the present invention was this lack of Prior art and to develop a cosmetic, with which active ingredients can be applied in high efficiency. Also It was the object of the present invention to provide a cosmetic develop, with which active ingredient-containing preparations in the foamed state be applied with a high active ingredient efficiency gentle on the skin can.

• a) einem Schaumspender mit zwei von einander getrennten Vorratskammern, deren Inhalt mit Hilfe zweier gekoppelter Förderpumpen gleichzeitig über eine gemeinsame Austrittsöffnung entnommen werden kann und welche die Zubereitungen mittels Luft aufschäumt, sowie
• b) zwei kosmetischen Zubereitungen 1 und 2, die sich jeweils in einer der beiden Vorratskammern des Schaumspenders befinden und dadurch gekennzeichnet sind, dass i) mindestens eine der beiden Zubereitungen einen oder mehrere kosmetische und/oder dermatologische Wirkstoffe enthält und ii) mindestens eine der beiden Zubereitungen ein oder mehrere Tenside enthält.

The objects are surprisingly achieved by a cosmetic, which is formed from

• a) a foam dispenser with two separate pantries, the contents of which can be removed by means of two coupled feed pumps simultaneously via a common outlet opening and which foams the preparations by means of air, and
• b) two cosmetic preparations 1 and 2, which are each located in one of the two storage chambers of the foam dispenser and are characterized in that i) at least one of the two preparations contains one or more cosmetic and / or dermatological active ingredients and ii) at least one of the two Preparations contains one or more surfactants.

The Tasks are also solved by using a foam dispenser with two of each other separate pantries whose contents are coupled by means of two feed pumps at the same time over one common outlet can be removed and which the preparations by means of air foams, for mixing and foaming active ingredient-containing cosmetic and / or dermatological preparations.

Especially the tasks are solved by using a foam dispenser with two of each other separate pantries whose contents are coupled by means of two feed pumps simultaneously over a common outlet can be removed and which foams the preparations by means of air, for Mixing and frothing active ingredient-containing cosmetic and / or dermatological preparations, wherein both phases are preferably mixed and foamed together, that a complete Mixing takes place and the two preparations with the naked eye no more than separate domains be perceived.

For the foam dispenser according to the invention can be advantageous according to the invention a donor system whose pumping and foaming mechanism following the teachings of the foam dispenser disclosed in WO 93/13829. According to the invention advantageous can for example, two-chamber foam dispenser the company Airspray be used.

According to the invention advantageous these are from the two cosmetic preparations 1 and 2 formed cosmetic (or dermatological) total preparation in order to obtain a cleaning preparation which, according to the invention, is preferred after application, wash off the skin with water again.

According to the invention advantageous Cosmetics or the foam dispenser advantageously used according to the invention are characterized in that the preparation in the first Chamber one or more ingredients selected from the group anionic Surfactants, nonionic surfactants, amphoteric surfactants, polymers, perfume oils, emulsifiers, Enzyme substrates, contains.

According to the invention advantageous Cosmetics or the foam dispenser advantageously used according to the invention are characterized in that the preparation in the second Chamber one or more ingredients selected from the group water, cationic surfactants, polymers, emulsifiers, dyes, cosmetic and / or dermatological agents.

Cosmetics which are advantageous according to the invention or the foam dispenser advantageously used according to the invention are characterized in that one or more active substances are selected from among Group of UV photoprotective filters, vitamins, vitamin derivatives, antioxidants, anti-wrinkle agents, self-tanning, depigmenting agents, repellents, plant extracts, enzymes, anhydrous polyols, dyes, effect substances.

When advantageous according to the invention UV sunscreen filters can For example, the following compounds are used:

Inorganic pigments

Preferred inorganic pigments are metal oxides and / or other water-insoluble or insoluble metal compounds, in particular oxides of titanium (TiO ₂ ), zinc (ZnO), iron (eg Fe ₂ O ₃ ), zirconium (ZrO ₂ ), silicon ( SiO ₂ ), manganese (for example MnO), aluminum (Al ₂ O ₃ ), cerium (for example Ce ₂ O ₃ ), mixed oxides of the corresponding metals and mixtures of such oxides, and the barium sulfate (BaSO 4) ₄ ).

The Titanium dioxide pigments can in both the rutile and anatase crystal modifications and can Advantageously treated superficially in the sense of the present invention ("Coated"), for example a hydrophilic, amphiphilic or hydrophobic character formed should be or should be preserved.

These surface treatment may be that the Pigments according to known methods with a thin hydrophilic and / or hydrophobic inorganic and / or organic layer be provided. The different surface coatings can be used in the According to the present invention also contain water.

described Coated and uncoated titanium dioxides may be used in the context of the present invention Invention also in the form of commercially available oily or aqueous predispersions come into use. These predispersions may advantageously dispersing agents and / or solubilization promoters may be added.

The Titanium dioxides according to the invention are characterized by a primary particle size between 10 nm to 150 nm.

in the The meaning of the present invention are particularly preferred titanium dioxides the MT-100 Z and MT-100 TV from Tayca Corporation, Eusolex T-2000 and Eusolex TS from Merck and the titanium dioxide T 805 from Degussa.

For the purposes of the present invention, zinc oxides can also be used in the form of commercially available oily or aqueous predispersions. Zinc oxide particles and predispersions of zinc oxide particles which are suitable according to the invention are distinguished by a primary particle size of <300 nm and can be obtained from the following companies under the following trade names:

special Preferred zinc oxides in the context of the invention are the Z-Cote HP1 from BASF and the zinc oxide NDM from Haarmann & Reimer.

The Total amount of one or more inorganic pigments in the Finished cosmetic preparation will be beneficial in the field 0.1% by weight to 25% by weight, preferably 0.5% to 18% by weight.

Organic pigments

Advantageous organic pigment in the context of the present invention is the 2,2'-methylene-bis (6- (2N-benzotriazol-2-yl) -4- (1,1,3,3-tetramethylbutyl) phenol) [INCI :, which is available under the trade name Tinosorb ^® M from CIBA-Chemikalien GmbH Bisoctyltriazol].

Further UV sunscreen filters

Advantageous UV-A filter substances for the purposes of the present invention are dibenzoylmethane derivatives, in particular 4- (tert-butyl) -4'-methoxydibenzoylmethane (CAS-Nr. 70356-09-1), marketed by Givaudan under the trade name Parsol ^® 1789 and is sold by Merck under the trade name Eusolex ^® 9020th

Further advantageous UV-A filter substances are the phenylene-1,4-bis (2-benzimidazyl) -3,3'-5,5'-tetrasulfonic acid and their salts, especially the corresponding sodium, potassium or Triethanolammonium salts, especially the phenylene-1,4-bis (2-benzimidaryl) -3,3'-5,5'-tetrasulfonic acid bis-sodium salt with the INCI name Bisimidarylate, which, for example, under the trade name Neo Heliopan AP at Haarmann & Reimer available is.

Further advantageous are 1,4-di (2-oxo-10-sulfo-3-bornylidenemethyl) benzene and its salts (especially the corresponding 10-sulfato compounds, in particular the corresponding sodium, potassium or triethanolammonium salt), also referred to as benzene-1,4-di (2-oxo-3-bomylidenemethyl-10-sulfonic acid) becomes.

worin

• • R¹ und R² unabhängig voneinander Wasserstoff, C₁-C₂₀-Alkyl, C₃-C₁₀-Cycloalkyl oder C₃-C₁₀-Cycloalkenyl bedeuten, wobei die Substituenten R¹ und R² gemeinsam mit dem Stickstoffatom, an das sie gebunden sind, einen 5- oder 6-Ring bilden können und
• • R³ einen C₁-C₂₀-Alkyl Rest bedeutet.

Further advantageous UV-A filter substances are hydroxybenzophenones, which are distinguished by the following structural formula:

wherein

• • R ¹ and R ² independently of one another are hydrogen, C ₁ -C ₂₀ -alkyl, C ₃ -C ₁₀ -cycloalkyl or C ₃ -C ₁₀ -cycloalkenyl, where the substituents R ¹ and R ² together with the nitrogen atom to which they are bound to form a 5- or 6-ring and
• • R ^{3 is} a C ₁ -C ₂₀ -alkyl radical.

One particularly advantageous hydroxybenzophenone in the sense of the present invention Invention is 2- (4'-diethylamino-2'-hydroxybenzoyl) -benzoic acid hexyl ester (Also: Aminobenzophenone), which under the trade name Uvinul A Plus available from BASF is.

advantageous UV filter substances in the context of the present invention are further so-called broadband filters, i. Filter substances containing both UV-A as well as UV-B radiation absorb.

wobei R¹, R² und R³ unabhängig voneinander gewählt werden aus der Gruppe der verzweigten und unverzweigten Alkylgruppen mit 1 bis 10 Kohlenstoffatomen bzw. ein einzelnes Wasserstoffatom darstellen. Insbesondere bevorzugt sind das 2,4-Bis-{[4-(2-Ethyl-hexyloxy)-2-hydroxy]-phenyl}-6-(4-methoxyphenyl)-1,3,5-triazin (INCI: Aniso Triazin), welches unter der Handelsbezeichnung Tinosorb^® S bei der CIBA-Chemikalien GmbH erhältlich ist.Advantageous broadband filters or UV-B filter substances are, for example, bis-resorcinyl triazine derivatives having the following structure:

wherein R ¹ , R ² and R ^{3 are} independently selected from the group of branched and unbranched alkyl groups having 1 to 10 carbon atoms or represent a single hydrogen atom. Especially preferred are 2,4-bis - {[4- (2-ethyl-hexyloxy) -2-hydroxy] -phenyl} -6- (4-methoxyphenyl) -1,3,5-triazine (INCI: aniso triazine , which is available under the trade name Tinosorb ^® S from CIBA-Chemikalien GmbH).

Especially advantageous preparations according to the present invention, which are characterized by a high or very high UV-A protection, preferably contain a plurality of UV-A and / or broadband filters, in particular Dibenzoylmethane derivatives [for example, 4- (tert-butyl) -4'-methoxydibenzoylmethane], Benzotriazole derivatives [for example, the 2,2'-methylenebis (6- (2H-benzotriazol-2-yl) -4- (1,1,3,3-tetramethylbutyl) phenol)], Phenylene-1,4-bis (2-benzimidazyl) -3,3'-5,5'-tetrasulfonic acid and / or their salts, the 1,4-di (2-oxo-10-sulfo-3-bomylidenemethyl) benzene and / or its salts and / or the 2,4-bis - {[4- (2-ethyl-hexyloxy) -2-hydroxy] -phenyl} -6- (4-methoxyphenyl) -1,3,5-triazine . each individually or in any combination with each other.

aufweisen, sind vorteilhafte UV-Filtersubstanzen im Sinne der vorliegenden Erfindung, beispielsweise die in der Europäischen Offenlegungsschrift EP 570 838 A1 beschriebenen s-Triazinderivate, deren chemische Struktur durch die generische Formel

wiedergegeben wird, wobei
R einen verzweigten oder unverzweigten C₁-C₁₈-Alkylrest, einen C₅-C₂₀-Cycloalkylrest, gegebenenfalls substituiert mit einer oder mehreren C₁-C₄-Alkylgruppen, darstellt,
X ein Sauerstoffatom oder eine NH-Gruppe darstellt,
R₁ einen verzweigten oder unverzweigten C₁-C₁₈-Alkylrest, einen C₅-C₁₂-Cycloalkylrest, gegebenenfalls substituiert mit einer oder mehreren C₁-C₄-Alkylgruppen, oder ein Wasserstoffatom, ein Alkalimetallatom, eine Ammoniumgruppe oder eine Gruppe der Formel

bedeutet, in welcher
A einen verzweigten oder unverzweigten C₁-C₁₈-Alkylrest, einen C₅-C₁₂-Cycloalkyl- oder Arylrest darstellt, gegebenenfalls substituiert mit einer oder mehreren C₁-C₄-Alkylgruppen,
R₃ ein Wasserstoffatom oder eine Methylgruppe darstellt,
n eine Zahl von 1 bis 10 darstellt,
R₂ einen verzweigten oder unverzweigten C₁-C₁₈-Alkylrest, einen C₅-C₁₂-Cycloalkylrest, gegebenenfalls substituiert mit einer oder mehreren C₁-C₄-Alkylgruppen, darstellt, wenn X die NH-Gruppe darstellt, und einen verzweigten oder unverzweigten C₁-C₁₈-Alkylrest, einen C₅-C₁₂-Cycloalkylrest, gegebenenfalls substituiert mit einer oder mehreren C₁-C₄-Alkylgruppen, oder ein Wasserstoffatom, ein Alkalimetallatom, eine Ammoniumgruppe oder eine Gruppe der Formel

bedeutet, in welcher
A einen verzweigten oder unverzweigten C₁-C₁₈-Alkylrest, einen C₅-C₁₂-Cycloalkyl- oder Arylrest darstellt, gegebenenfalls substituiert mit einer oder mehreren C₁-C₄-Alkylgruppen,
R₃ ein Wasserstoffatom oder eine Methylgruppe darstellt,
n eine Zahl von 1 bis 10 darstellt,
wenn X ein Sauerstoffatom darstellt.Other UV filter substances, which are the structural motif

have advantageous UV filter substances in the sense of the present invention, for example, those in the European published patent application EP 570 838 A1 described s-triazine derivatives, their chemical structure by the generic formula

is reproduced, wherein
R is a branched or unbranched C ₁ -C ₁₈ -alkyl radical, a C ₅ -C ₂₀ -cycloalkyl radical, optionally substituted by one or more C ₁ -C ₄ -alkyl groups,
X represents an oxygen atom or an NH group,
R _{1 is} a branched or unbranched C ₁ -C ₁₈ alkyl radical, a C ₅ -C ₁₂ cycloalkyl radical optionally substituted with one or more C ₁ -C ₄ alkyl groups, or a hydrogen atom, an alkali metal atom, an ammonium group or a group of formula

means in which
A is a branched or unbranched C ₁ -C ₁₈ -alkyl radical, a C ₅ -C ₁₂ -cycloalkyl or aryl radical, optionally substituted by one or more C ₁ -C ₄ -alkyl groups,
R _{3 represents} a hydrogen atom or a methyl group,
n represents a number from 1 to 10,
R _{2 is} a branched or unbranched C ₁ -C ₁₈ alkyl radical, a C ₅ -C ₁₂ cycloalkyl radical optionally substituted with one or more C ₁ -C ₄ alkyl groups, when X represents the NH group, and a branched one or straight-chain C ₁ -C ₁₈ -alkyl radical, a C ₅ -C ₁₂ -cycloalkyl radical optionally substituted by one or more C ₁ -C ₄ -alkyl groups, or a hydrogen atom, an alkali metal atom, an ammonium group or a group of the formula

means in which
A is a branched or unbranched C ₁ -C ₁₈ -alkyl radical, a C ₅ -C ₁₂ -cycloalkyl or aryl radical, optionally substituted by one or more C ₁ -C ₄ -alkyl groups,
R _{3 represents} a hydrogen atom or a methyl group,
n represents a number from 1 to 10,
when X represents an oxygen atom.

wiedergegeben wird, welches im Folgenden auch als Dioctylbutylamidotriazon (INCI: Dioctylbutamidotriazone) bezeichnet wird und unter der Handelsbezeichnung UVA-SORB HEB bei Sigma 3V erhältlich ist.Particularly preferred UV filter substance in the context of the present invention is also an unsymmetrically substituted s-triazine whose chemical structure is represented by the formula

which is also referred to below as Dioctylbutylamidotriazon (INCI: Dioctylbutamidotriazone) and under the trade name UVA-SORB HEB Sigma 3V is available.

Also advantageous in the context of the present invention is a symmetrically substituted s-triazine which comprises 4,4 ', 4 "-silk-1,3-triazine-2,4,6-triyltriimino-tris-benzoic acid tris (2-ethylhexyl ester ), synonym: 2,4,6-tris [anilino- (p-carbo-2'-ethyl-1'-hexyloxy)] - 1,3,5-triazine (INCI: Octyl Triazone), which was obtained from BASF Limited liability company under the trade name UVINUL ^® T 150.

wiedergegeben wird, wobei R₁, R₂ und A₁ verschiedenste organische Reste repräsentieren.Also in the European patent application 775,698 preferred bis-Resorcinyltriazinderivate be described whose chemical structure by the generic formula

is reproduced, wherein R ₁ , R ₂ and A _{1 represent a} variety of organic radicals.

Advantageous For the purposes of the present invention are also the 2,4-bis - {[4- (3-sulfonato) -2-hydroxy-propyloxy) -2-hydroxy] phenyl} -6- (4-methoxyphenyl) -1,3 , triazine-5 Sodium salt containing 2,4-bis - {[4- (3- (2-propyloxy) -2-hydroxy-propyloxy) -2-hydroxy] -phenyl} -6- (4-methoxyphenyl) -1,3,5 triazine, 2,4-bis - {[4- (2-ethyl-hexyloxy) -2-hydroxy] -phenyl} -6- [4- (2-methoxyethylcarboxyl) -phenylamino] -1,3,5-triazine . 2,4-bis - {[4- (3- (2-propyloxy) -2-hydroxy-propyloxy) -2-hydroxy] -phenyl} -6- [4- (2-ethylcarboxyl) -phenylamino] 1,3,5-triazine, 2,4-bis - {[4- (2-ethyl-hexyloxy) -2-hydroxy] -phenyl} -6- (1-methylpyrrol-2-yl) -1,3,5-triazine 2,4-bis - {[4-tris (trimethylsiloxy-silylpropyloxy) -2-hydroxy] phenyl} -6- (4-methoxyphenyl) -1,3,5-triazine, 2,4-bis - {[4- (2 '' - methylpropenyloxy) -2-hydroxy] -phenyl} -6- (4-methoxyphenyl) -1,3,5-triazine and 2,4-bis- [4- (1 ', 1', 1 ', 3', 5 ', 5', 5'-heptamethylsiloxy-2 "-methyl-propyloxy) -2-hydroxy] - phenyl} -6- (4-methoxyphenyl) -1,3,5-triazine.

An advantageous broadband filter for the purposes of the present invention is the 2,2'-methylene-bis (6- (2N-benzotriazol-2-yl) -4- (1,1,3,3-tetramethylbutyl) phenol), which available under the trade name Tinosorb ^® M from CIBA-Chemikalien GmbH.

Advantageous broadband filter according to the present invention is further the 2- (2H-benzotriazol-2-yl) -4-methyl-6- [2-methyl-3- [1,3,3,3-tetramethyl-1 - [( trimethylsilyl) oxy] disiloxanyl] propyl] phenol (CAS No .: 155633-54-8) with the INCI name Drometrizole Trisiloxane.

• • 3-Benzylidencampher-Derivate, vorzugsweise 3-(4-Methylbenzyliden)campher, 3-Benzylidencampher;
• • 4-Aminobenzoesäure-Derivate, vorzugsweise 4-(Dimethylamino)-benzoesäure(2-ethylhexyl)ester, 4-(Dimethylamino)benzoesäureamylester;
• • 2,4,6-Trianilino-(p-carbo-2'-ethyl-1'-hexyloxy)-1,3,5-triazin;
• • Ester der Benzalmalonsäure, vorzugsweise 4-Methoxybenzalmalonsäuredi(2-ethylhexyl)ester;
• • Ester der Zimtsäure, vorzugsweise 4-Methoxyzimtsäure(2-ethylhexyl)ester, 4-Methoxyzimtsäureisopentylester;
• • Derivate des Benzophenons, vorzugsweise 2-Hydroxy-4-methoxybenzophenon, 2-Hydroxy-4-methoxy-4'-methylbenzophenon, 2,2'-Dihydroxy-4-methoxybenzophenon
• • sowie an Polymere gebundene UV-Filter.

The UV-B and / or broadband filters may be oil-soluble or water-soluble. Advantageous oil-soluble UV-B and / or broadband filter substances are, for. B .:

• 3-benzylidene camphor derivatives, preferably 3- (4-methylbenzylidene) camphor, 3-benzylidene camphor;
• 4-aminobenzoic acid derivatives, preferably 2-ethylhexyl 4- (dimethylamino) benzoate, 4- (dimethylamino) benzoic acid amyl ester;
• 2,4,6-trianilino (p-carbo-2'-ethyl-1'-hexyloxy) -1,3,5-triazine;
• Esters of benzalmalonic acid, preferably di-2-ethylhexyl 4-methoxybenzalmalonate;
• Esters of cinnamic acid, preferably 4-methoxycinnamic acid (2-ethylhexyl) ester, 4-methoxycinnamic acid isopentyl ester;
• Derivatives of benzophenone, preferably 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-methoxy-4'-methylbenzophenone, 2,2'-dihydroxy-4-methoxybenzophenone
• • as well as UV-bound polymers.

• • Salze der 2-Phenylbenzimidazol-5-sulfonsäure, wie ihr Natrium-, Kalium- oder ihr Triethanolammonium-Salz, sowie die Sulfonsäure selbst;
• • Sulfonsäure-Derivate des 3-Benzylidencamphers, wie z. B. 4-(2-Oxo-3-bornylidenmethyl)benzolsulfonsäure, 2-Methyl-5-(2-oxo-3-bornylidenmethyl)sulfonsäure und deren Salze.

Advantageous water-soluble UV-B and / or broadband filter substances are z. B .:

• Salts of 2-phenylbenzimidazole-5-sulphonic acid, such as its sodium, potassium or triethanolammonium salt, and the sulphonic acid itself;
• Sulfonic acid derivatives of 3-Benzylidencamphers, such as. B. 4- (2-oxo-3-bomylidenemethyl) benzenesulfonic acid, 2-methyl-5- (2-oxo-3-bomylidenemethyl) sulfonic acid and salts thereof.

Particularly advantageous UV filter substances which are liquid at room temperature for the purposes of the present invention are homomenthyl salicylate (INCI: homosalates), 2-ethylhexyl 2-hydroxybenzoate (2-ethylhexyl salicylate, octyl salicylate, INCI: octyl salicylates), 4-isopropylbenzyl salicylate and esters of cinnamic acid, preferably 4-Methoxycinnamate (2-ethylhexyl) ester (2-ethylhexyl-4-methoxycinnamate, INCI: octyl methoxycinnamate) and 4-methoxycinnamic acid isopentyl ester (isopentyl 4-methoxycinnamate, INCI: isoamyl p-methoxycinnamate), 3- (4- (2, 2-bis ethoxycarbonylvinyl) phenoxy) propenyl) -methoxysiloxan / dimethylsiloxane copolymer (INCI: dimethicodiethylbenzalmalonate) which is available for example under the trade name Parsol ^® SLX from Hoffmann La Roche.

A further light protection filter substance according to the invention to be used advantageously is ethylhexyl-2-cyano-3,3-diphenylacrylate, obtainable (octocrylene) from BASF under the name Uvinul ^® N 539th

It may also be of considerable advantage, polymer-bound or polymeric UV filters in preparations according to the present invention To use invention, in particular those as described in WO-A-92/20690 to be discribed.

The List of said UV filters, for the purposes of the present invention can be used Of course not limiting.

Advantageous contain the preparations according to the invention the substances, the UV radiation in the UV-A and / or UV-B range, in a total amount from Z. 0.1% to 30% by weight, preferably 0.5 to 20% by weight, in particular 1.0 to 15.0 wt .-%, each based on the total weight preparations to make cosmetic preparations available put the hair or the skin in front of the entire area of the Protect ultraviolet radiation. You can also as a sunscreen for Hair or the skin serve.

Vitamins and vitamin derivatives

These include, among others, vitamins A, B _1-6 , B ₁₂ , C, D, E, F, N, K and PP and their derivatives. These can be used according to the invention advantageously in a concentration of 0.001 to 10 wt .-%, preferably 0.05-7 wt .-%, particularly preferably 0.5-5 wt .-%, each based on the total weight of the part of the preparation in which they are included.

When according to the invention preferred Vitamin derivatives are thereby Retinylpalmitat, Ascorbylglucosid, Tocopheryl acetate, tocopheryl palmitate, niacinamide, panthenol used.

According to the invention, the use of vitamins and their derivatives in a concentration of 0.05 to 1% by weight, preferably in a concentration of 0.01 to 0.5% by weight and very particularly advantageous preferably in a concentration of 0.05 to 0.2% by weight, in each case based on the total weight of the partial preparation.

enzymes

The Cosmetic according to the invention or the invention advantageous used foam dispenser contains beneficial enzymes. As enzymes can advantageous for the purposes of the present invention lipases, esterases, Proteases and other hydrolases are used, with lipases preferred according to the invention are.

When enzymes according to the invention can advantageous enzyme extracts from Alcaligenes sp. (e.g., from the company Amano Enzyme Europe Ltd.), Aspergillus niger (e.g., from the companies Amano Enzyme Europe Ltd. or Fluka), Candida cylindracea (e.g. from the companies Sigma, Aldrich, Fluka, Amano Enzyme Europe Ltd., Boeringer-Mannheim), Candida lipolytica (for example from Amano Enzyme Europe Ltd., Fluka), Chromobacterium viscosium (e.g. Sigma), Humicola laguninosa (e.g., from Amano Enzyme Europe Ltd.), Mucor miehei (e.g., from Amano Enzyme Europe Ltd., Novo), Penecillium roqueforti (e.g., from Fluka), Porcine pancreas (e.g., from Sigma, Aldrich, Fluka, Amano Enzyme Europe Ltd., Boeringer-Mannheim), Pseudomonas agroginosa (e.g., from Amano Enzyme Europe Ltd.), Pseudomonas fluorescens (e.g., from Amano Enzyme Europe Ltd., Fluka), Pseudomonas sp. (e.g., from Sigma, Boeringer-Mannheim), Rhizopus delemar (e.g., from Sigma, Fluka, Boeringer-Mannheim), Rhizopus japonicus (e.g., from Amano Enzyme Europe Ltd.), Rhizopus oryzae (e.g., from Amano Enzyme Europe Ltd.), Rhizopus sp. (e.g., from Amano Enzyme Europe Ltd., Serva) and / or wheat germ (e.g., from Sigma).

there are as enzyme extracts lipases from porcine pancreas (Porcine pancreas), Aspergillus niger, Chromobacterium viscosium, Geotrichum candidum, Penecillium camberti, Penecillium roqueforti preferred according to the invention.

According to the invention very particularly preferably of the species Mucor miehei lipases (eg Liporyme ^® from Novo Nordisk), Humicola laguninosa, Pseudomonas aegruginosa, Pseudomonas fluorescens, Pseudomonas sp., Candida cylindracea and / or Candida lipolyfica.

According to the invention advantageous There are one or more enzymes in the form of an aqueous solution. Their content of one or more enzymes According to the invention advantageous from 0.1 to 5% by weight, preferably from 1 to 5% by weight and most preferably from 1 to 2% by weight, based in each case on the total weight of the part preparation in which they contain are.

antioxidants

Advantageously, the antioxidants are selected from the group consisting of amino acids (eg glycine, lysine, arginine, cysteine, histidine, tyrosine, tryptophan) and their derivatives (as salt, ester, ether, sugar, nucleotide, nucleoside, Peptide and lipid association), imidazoles (eg, urocanic acid) and their derivatives (as a salt, ester, ether, sugar, nucleotide, nucleoside, peptide and / or lipid combination), peptides such as D, L-carnosine, D-carnosine, L-carnosine, anserine and their derivatives (eg as salt, ester, ether, sugar, thiol, nucleotide, nucleoside, peptide and lipid combination), carotenoids, Carotenes (eg .alpha.-carotene, .beta.-carotene, .alpha.-lycopene, phytoene,) and their derivatives (for example as salt, ester, ether, sugar, nucleotide, nucleoside, peptide and / or Lipid association), chlorogenic acid and its derivatives (as a salt, ester, ether, sugar, thiol, nucleotide, nucleoside, peptide and / or lipid combination), aurothioglucose, propylthiouracil and other thiols (eg Thioredoxin, lipases acid, glutathione, cysteine, cystine, cystamine and their glycosyl, N-acetyl, methyl, ethyl, propyl, amyl, butyl and lauryl, palmitoyl, oleyl, γ-linoleyl, cholesteryl and glyceryl esters) and their salts, dilauryl thiodipropionate, distearyl thiodipropionate, thiodipropionic acid and derivatives thereof (as a salt, ester, ether, sugar, thiol, nucleotide, nucleoside, peptide and / or lipid compound) and sulfoximine compounds ( eg Homocysteinsulfoximin, Buthioninsulfone, penta-, hexa-, Neptathioninsulfoximin) in very low tolerated doses (eg pmol to μmol / kg). Also (metal) chelators (eg, apoferritin, desferral, lactoferrin, α-hydroxy fatty acids, palmitic acid, phytic acid) and derivatives thereof (as the salt, ester, ether, sugar, thiol, nucleotide, nucleoside, peptide and or lipid Verbidung), α-hydroxy acids (eg, citric acid, lactic acid, malic acid), humic acid, bile acid, bile extracts, bilirubin, biliverdin, EDTA, EGTA and their derivatives, unsaturated fatty acids and their derivatives (eg γ-linolenic acid, linoleic acid, oleic acid ), Folic acid and its derivatives, furfurylidene sorbitol and its derivatives, ubiquinone, ubiquinol, plastoquinone and their derivatives (as a salt, ester, ether, sugar, thiol, nucleotide, nucleoside, peptide and lipid combination) , Vita min C and derivatives (eg ascorbyl palmitate, Mg ascorbyl phosphate, ascorbyl acetate), tocopherols and derivatives (eg vitamin E acetate), as well as phenolic compounds and plant extracts containing them, such as. Flavonoids (eg, glycosylrutin, ferulic acid, caffeic acid), furfurylidene glucitol, butylhydroxytoluene, butylhydroxyanisole, nordihydroguaiacetic acid, nordihydroguiaretic acid, trihydroxybutyrophenone and their derivatives (as the salt, ester, ether, sugar, nucleotide, nucleoside, peptide and lipid association). Uric acid and its derivatives, mannose and its derivatives (as a salt, ester, ether, sugar, thiol, nucleotide, nucleoside, peptide and lipid combination). Zinc and its derivatives (eg ZnO, ZnSO ₄ ), selenium and its derivatives (eg selenium methionine, Ebselen), stilbenes and their derivatives (eg stilbene oxide, trans-stilbene oxide) and the inventively suitable derivatives (as salt, ester, ether) , Sugar, thiol, nucleotide, nucleoside, peptide and / or lipid Verbidung) of these drugs.

The Amount of the aforementioned antioxidants (one or more compounds) in the preparations preferably from 0.001 to 30% by weight, particularly preferably from 0.05 to 20% by weight, in particular 1-10% by weight, based on the total weight of the preparation.

Provided Vitamin E and / or derivatives thereof are the antioxidant (s), is advantageous, their respective concentrations from the field from 0.001-10 Wt .-%, based on the total weight of the formulation to choose.

Provided Vitamin A, or vitamin A derivatives, or carotenes or their derivatives the one or more antioxidants are advantageous, their respective Concentrations in the range of 0.001-10 wt .-%, based on the Total weight of the formulation to choose.

Antiwrinkle active ingredients, Plant extracts and other active substances

Further advantageous active ingredients in the context of the present invention natural Active ingredients and / or their derivatives, such as. Alpha-lipoic acid, phytoene, D-biotin, coenzyme Q10, alpha-glucosylrutin, carnitine, carnosine, natural and / or synthetic isoflavonoids, creatine, creatinine, lignans, Taurine and / or β-alanine.

According to the invention advantageous can but also other pharmaceutically or dermatologically active substances such as the skin soothing and nourishing substances be incorporated. Which includes for example, panthenol, allantoin, tannin and plant active ingredients such as azulene and bisabolol, glycyrrhizin, hamamelin and plant extracts like chamomile, aloe vera, hamazelis, liquorice root.

The Amount of the aforementioned active substances (one or more compounds) in the part preparations preferably from 0.001 to 30% by weight, particularly preferably from 0.05 to 20% by weight, in particular 1-10% by weight, based on the total weight of the part preparation.

Self

When Self become advantageous according to the invention used inter alia: glycerol aldehyde, hydroxymethylglyoxal, γ-dialdehyde, Erythrulose, 6-aldo-D-fructose, Ninhydrin, 5-hydroxy-1,4-naphthoquinone (juglone), 2-hydroxy-1,4-naphthoquinone (Lawson).

Especially For the purposes of the invention, preference is given to 1,3-dihydroxyacetone (DNA). The advantage here is a concentration of 0.5 to 10% by weight 1,3-dihydroxyacetone and especially a concentration of 1 to 7% by weight on the total weight of the part preparation.

Depigmentiermittel

When advantageous according to the invention Depigmenting agents can for example, dicarboxylic acids such as 8-hexadecene-1,16-dicarboxylic acid (Dioic acid, CAS number 20701-68-2), kojic acid, ascorbic acid and azelaic acid and their derivatives are used.

According to the invention advantageous is the total concentration of depigmenting agents in the corresponding Part preparation 0,001-10 Wt .-%, preferably 0.005-8 Wt .-%, in particular 0.05-5 Wt .-%.

repellents

According to the invention can advantageously be used:
N, N-diethyl-3-methylbenzamide (DEET), dimethyl phthalate (Palatinol M, DMP), 2,3; 4,5-bis (2-butylene) -tetrahydro-2-furaldehyde (MGK Repellent 11), butopyronoxyl (Indalone), N, N-caprylic acid diethylamide (Repellent 790), o-chloro-N, N-diethylbenzamide in admixture with N, N-diethylbenzamide (Kik repellent), dimethyl carbate (Dimalone), di-n-propyl isocinchomeronate (MGK). Repellent 326), 2-ethylhexane-1,3-diol (Rutgers 612), N-octylbicycloheptendicarboximide (MGK 264 Insecticidesynergist), piperonyl-butoxide (PBO) and, particularly preferred according to the invention, 3- (Nn-butyl-N- acetyl-amino) propionic acid ethyl ester (also referred to as repellent 3535).

According to the invention advantageous is a content of repellents of 0.005 to 70.0 wt .-% used, in particular 0.01 to 50.0% by weight and very particularly preferably 3 to 15% by weight based on the total weight of the part preparation.

anhydrous polyols

sThere is preferred according to the invention, when the polyalcohols are chosen are from the group of substances with a molecular weight between 200 and 600 g / mol, for example polyethylene glycol (200) (= PEG-4), polyethylene glycol (300) (= PEG-6), polyethylene glycol (400) (= PEG-8), polyethylene glycol (1000) (= PEG-5) and polyethylene glycol (1200) (= PEG-6). The invention very particularly preferred polyhydric alcohols are the compounds polyethylene glycol (400) (= PEG-8), polyethylene glycol (1000) (= PEG-5) and polyethylene glycol (1200) (= PEG-6).

According to the invention preferred is a polyalcohol concentration of 40 to 90% by weight and especially preferably from 40 to 85% by weight, based on the total weight the partial preparation.

By "anhydrous" according to the invention polyols understood whose water concentration is less than 5% by weight and preferably less than 3% by weight, each based on the weight of the polyol.

Color and effect materials

As pigmentary dyes advantageous according to the invention it is possible to use all compounds listed from the corresponding positive list of the Cosmetics Ordinance or the EC list of cosmetic colorants. In most cases, they are identical to the food-approved dyes. In addition to colored pigments, the preparations according to the invention may also contain other dyes. Examples of advantageous color pigments are titanium dioxide, mica, iron oxides (eg Fe ₂ O ₃ , Fe ₃ O ₄ , FeO (OH)) and / or tin oxide. Advantageous dyes are, for example, carmine, Berlin blue, chrome oxide green, ultramarine blue and / or manganese violet. It is particularly advantageous to choose the dyes and / or color pigments from the following list. The Color Index Numbers (CIN) are taken from the Rowe Color Index, 3rd Edition, Society of Dyers and Colourists, Bradford, England, 1971.

It can also be cheap be, as a dye one or more substances from the following Group to choose: 2,4-Dihydroxyazobenzene, 1- (2'-chloro-4'-nitro-1'-phenylazo) -2-hydroxynaphthalene, Ceresrot, 2- (4-sulfo-1-naphthylazo) -1-naphthol-4-sulfonic acid, calcium salt of 2-hydroxy-1,2'-azonaphthalene-1'-sulfonic acid, calcium and barium salts 1- (2-sulfo-4-methyl-1-phenylazo) -2-naphthylcarboxylic acid, calcium salt of 1- (2-sulfo-1-naphthylazo) -2-hydroxynaphthalene-3-carboxylic acid, aluminum salt of 1- (4-sulfo-1-phenylazo) -2-naphthol-6-sulfonic acid, aluminum salt of 1- (4-sulfo-1-naphthylazo) -2-naphthol-3,6-disulfonic acid, 1- (4- Sulfo-1-naphthylazo) -2-naphthol-6,8-disulfonic acid, aluminum salt 8-amino-2-phenylazo-1-naphthol-3,6-disulfonic acid, aluminum salt 4- (4-sulfo-1-phenylazo) -1- (4-sulfophenyl) -5-hydroxy-pyrazolone-3-carboxylic acid, 4 '- [(4' '- sulfo-1' '- phenylazo) -T sulfo-1'-naphthylazo] -1-hydroxy-8-acetylaminonaphthalene-3,5-disulfonic acid, aluminum and zirconium salts of 4,5-dibromofluorescein, aluminum and zirconium salts of 2,4,5,7-tetrabromo-fluorescein, 3 ', 4', 5 ', 6'-tetrachloro-2,4,5,7-tetrabromo-fluorescein and its aluminum salt, aluminum salt of 2,4,5,7-tetraiodofluorescein, Aluminum salt of quinophthalone-disulfonic acid, aluminum salt of indigo-disulfonic acid, 4,4'-dimethyl-6,6'-dichlorothioindigo, complex salt (Na, Al, Ca) of carminic acid, red and black iron oxide (CIN: 77 491 (red) and 77 499 (black)), Iron oxide hydrate (CIN: 77 492), manganese ammonium diphosphate (CIN 77745), Ultramarine (CIN 77007) and titanium dioxide.

Titanium dioxides according to the invention, which may be present in both the rutile and anatase crystal modifications Advantageously treated superficially in the sense of the present invention ("Coated"), for example a hydrophilic, amphiphilic or hydrophobic character formed should be or should be preserved. This surface treatment can consist of that the pigments according to known methods with a thin hydrophilic and / or hydrophobic inorganic and / or organic layer be provided. The different surface coatings can be used in the According to the present invention also contain water.

Inorganic surface coatings for the purposes of the present invention may consist of aluminum oxide (Al ₂ O ₃ ), aluminum hydroxide Al (OH) ₃ or aluminum oxide hydrate (also: Alumina, CAS No .: 1333-84-2), sodium hexametaphosphate (NaPO ₃ ) ₆ , sodium metaphosphate (NaPO ₃ ) _n , silicon dioxide (SiO ₂ ) (also: silica, CAS No .: 7631-86-9), zirconium oxide (ZrO ₂ ) or iron oxide (Fe ₂ O ₃ ). These inorganic surface coatings may be present alone, in combination and / or in combination with organic coating materials.

For this become oxides, oxide hydrates or phosphates, for example of the elements Al, Si, Zr precipitated in dense layers on the pigment surface.

The Inorganic aftertreatment is generally carried out in an aqueous Suspension of the pigment by adding soluble aftertreatment chemicals, such as. Aluminum sulfate, and subsequent precipitation of the in the neutral range slightly soluble Hydroxides by specific adjustment of the pH with caustic soda.

To Inorganic aftertreatment are the coated pigments separated from the suspension by filtration and washed thoroughly, around the solved Remove salts, then The isolated pigments are dried.

Titanium dioxides to which aluminum hydroxide has been applied to the surface, such as titanium dioxide grades C47-051 and C47-5175 available from Sun Chemical, are particularly preferred for the purposes of this invention. Further preferred pigments are titanium dioxides, which are coated with aluminum and / or silicon oxides, such as, for example, from Krosnos Titan: Kronos 1071 and 1075 or from Kingfisher: A310.03 Tudor Aspen.

organic surface coatings For the purposes of the present invention may consist of vegetable or animal aluminum stearate, vegetable or animal stearic acid, lauric acid, dimethylpolysiloxane (also: dimethicone), methylpolysiloxane (methicone), simethicone (a mixture of dimethylpolysiloxane with an average chain length from 200 to 350 dimethylsiloxane units and silica gel) or alginic acid. These organic surface coatings can alone, in combination and / or in combination with inorganic Coating materials occur.

Further it may be advantageous according to the invention to use its pearlescent pigments.

• • „Fischsilber" (Guanin/Hypoxanthin-Mischkristalle aus Fischschuppen) und
• • „Perlmutt" (vermahlene Muschelschalen),

monokristalline Perlglanzpigmente wie z. B. Bismuthoxychlorid (BiOCl), Schicht-Substrat Pigmente: z. B. Glimmer/MetalloxidThese include natural pearlescent pigments, such as r. B.

• • "fish-silver" (guanine / hypoxanthine mixed crystals from fish scales) and
• • "mother-of-pearl" (ground mussel shells),

monocrystalline pearlescent pigments such. B. Bismuthoxychlorid (BiOCl), layer substrate pigments: z. Mica / metal oxide

Base for pearlescent pigments are for example powdered Pigments or castor oil dispersions of Bismuth oxychloride and / or titanium dioxide and bismuth oxychloride and / or Titanium dioxide on mica. In particular vorteihaft z. B. the under the CIN 77163 listed luster pigment.

Also advantageous, for example, are the following pearlescent pigment types based on mica / metal oxide:

Especially preferred are those from Merck under the trade name Timiron, Colorona or Dichrona available Pearlescent pigments.

Of course, the list of pearlescent pigments mentioned should not be limiting. Pearlescent pigments which are advantageous in the context of the present invention are obtainable in numerous ways known per se. For example, other substrates except mica can be coated with other metal oxides such. As silica and the like. Advantageous r. B. coated with TiO ₂ and Fe ₂ O ₃ SiO ₂ particles ("Ronaspheren"), which are sold by Merck.

It may also be advantageous to completely dispense with a substrate such as mica. Particularly preferred are pearlescent pigments which are prepared using SiO ₂ . Such Pigments which may also have additional gonichromatic effects are e.g. B. available under the trade name Sicopearl Fantastico at the Finna BASF.

Farther can be advantageous Pigments of Engelhard / Mearl based on calcium sodium Borosilicate, which are coated with titanium dioxide, can be used. These are available under the name Reflecks. They point through their Particle size of 40-180 μm in addition to the color of a glittering effect.

The Dyes and pigments can both individually and in mixture and with each other be coated, with different coating thicknesses In general, different color effects are caused.

The particularly according to the invention preferred pigments Dyes are listed blue pigments such as e.g. INCI: CI 77007, Outremer Supercosmetique W 6803 of Les Colorants Wackherr, INCI: CI 77891 + Mica + Silica, Timiron Splendid Blue from Merck.

According to the invention preferred are also mica coated with titania and silica, e.g. INCI: Mica + CI 77891 + Silica, Timiron Arctic Silver from Merck, INCI: Mica + CI 77891, Timiron Gleamer Flake MP-45 from Merck; With Titanium dioxide and tin oxide coated alumina or silica, e.g. INCI: Silica + CI 77891 + Tin Oxide, Xirona Magic Mauve from Merck; e.g. INCI: Alumina + CI 77891 + Tin Oxide, Xirona Silver, mica coated with titanium dioxide and Berlin blue, e.g. INCI: Mica + CI 77891 + CI 77510, Colorona Light Blue and Colorona Dark Blue from Merck.

Pearl Luster:

Prefers is also the use of pearlescing agents based on dialkyl ethers, at 30 ° C are fixed and, for example, have the following formula: R-O-R '. Here, R and R 'may be the same or different be; straight-chain or branched, saturated or unsaturated alkyl radicals be. these can consist of 12 to 30 carbon atoms, preferably from 14 to 24 Carbon atoms. Most preferably, R and R 'are a stearyl radical (e.g. INCI: distearyl ether, Cutina STE from Cognis).

The used dialkyl ethers are at a concentration of over 0.1% at 25 ° C not soluble in water.

Preferably could also acylated radicals consisting of a fatty acid chain with 8 to 30 carbon atoms exist, be used.

Per acylated derivative contains at least one RC (= O) group, where R is a fatty acid chain with with 8 to 30 carbon atoms.

Insbesondre Ethylene glycol monostearates and ethylene glycol distearates, e.g. INCI: Glycol Distearate, Cutina AGS of Cognis, INCI: Aqua + Glycol Distearate + Glycerol + laureth-4 + cocamidopropyl betaine, Euperlan PK 3000 OK from Cognis, INCI: PEG-3 Distearate, Cutina TS from Cognis.

These become advantageous according to the invention used in a concentration between 0.5% and 2%.

Opacifiers:

According to the invention advantageous possible is also the use of opacifiers. Preference is given to the sodium salts of a polymer of styrene a monomer consisting of acrylic acid, methacrylic acid or a another olefin and one of its esters, e.g. INCI: Sodium Styrene / Acrylates Copolymer, Acusol OP 301 from Rohm & Haas.

These become advantageous according to the invention used in a concentration between 0.5% and 2%.

Also Glitter and glitter particles can According to the invention advantageous be included in at least one of the part preparations.

Cosmetics advantageous according to the invention or the foam dispenser advantageously used according to the invention are characterized in that a surfactant-containing preparation is present in the first chamber and a shampoo, a shower gel, a hair cure, an anhydrous polyol-containing admixture in the second chamber preparation, which releases heat on contact with water, containing an emulsion. It is advantageous according to the invention if the surfactant-containing preparation is a shampoo or a shower gel.

According to the invention advantageous can both anionic, cationic, nonionic and zwitterionic Surfactants are used.

• • Acylglutamate, insbesondere Natriumacylglutamat
• • Sarcosinate, beispielsweise Myristoyl Sarcosin, TEA-lauroyl Sarcosinat, Natriumlauroylsarcosinat und Natriumcocoylsarkosinat,

Sulfonsäuren und deren Salze, wie

• • Acylisethionate, z.B. Natrium-/Ammoniumcocoylisethionat,
• • Sulfosuccinate, beispielsweise Dioctylnatriumsulfosuccinat, Dinatriumlaurethsulfosuccinat, Dinatriumlaurylsulfosuccinat und Dinatriumundecylenamido MEA-Sulfosuccinat, Dinatrium PEG-5 Laurylcitratsulfosuccinat und Derivate,

sowie Schwefelsäureester, wie

• • Alkylethersulfat, beispielsweise Natrium-, Ammonium-, Magnesium-, MIPA-, TIPA-Laurethsulfat, Natriummyrethsulfat und Natrium C_12-13 Parethsulfat,
• • Alkylsulfate, beispielsweise Natrium-, Ammonium- und TEA-Laurylsulfat.

Advantageous washing-active anionic surfactants in the context of the present invention are
Acylamino acids and their salts, such as

• Acylglutamates, especially sodium acylglutamate
• Sarcosinates, for example myristoyl sarcosine, TEA lauroyl sarcosinate, sodium lauroyl sarcosinate and sodium cocoyl sarcosinate,

Sulfonic acids and their salts, such as

• Acyl isethionates, eg sodium / ammonium cocoyl isethionate,
• Sulfosuccinates, for example dioctyl sodium sulphosuccinate, disodium laureth sulphosuccinate, disodium lauryl sulphosuccinate and disodium undecylenamido MEA sulphosuccinate, disodium PEG-5 lauryl citrate sulphosuccinate and derivatives,

and sulfuric acid esters, such as

• Alkyl ether sulfate, for example, sodium, ammonium, magnesium, MIPA, TIPA laureth sulfate, sodium myreth sulfate and sodium C _12-13 pareth sulfate,
• Alkyl sulfates, for example, sodium, ammonium and TEA lauryl sulfate.

advantageous Washing-active cationic surfactants in the context of the present invention are quaternary surfactants. quaternary Surfactants contain at least one N atom containing 4 alkyl or aryl groups covalently linked. For example, alkylbetaine, Alkylamidopropylbetaine and Alkylamidopropylhydroxysultaine.

• • Acyl-/dialkylethylendiamine, beispielsweise Natriumacylamphoacetat, Dinatriumacylamphodipropionat, Dinatriumalkylamphodiacetat, Natriumacylamphohydroxypropylsulfonat, Dinatriumacylamphodiacetat und Natriumacylamphopropionat,

Advantageous washing-active amphoteric surfactants in the context of the present invention are

• Acyl / dialkylethylenediamines, for example sodium acylamphoacetate, disodium acylamphodipropionate, disodium alkylamphodiacetate, sodium acylamphohydroxypropylsulfonate, disodium acylamphodiacetate and sodium acylamphopropionate,

• • Alkanolamide, wie Cocamide MEA/DEA/MIPA,
• • Ester, die durch Veresterung von Carbonsäuren mit Ethylenoxid, Glycerin, Sorbitan oder anderen Alkoholen entstehen,
• • Ether, beispielsweise ethoxylierte Alkohole, ethoxyliertes Lanolin, ethoxylierte Polysiloxane, propoxylierte POE Ether und Alkylpolyglycoside wie Laurylglucosid, Decylglycosid und Cocoglycosid.

Advantageous washing-active nonionic surfactants in the context of the present invention are

• Alkanolamides, such as cocamide MEA / DEA / MIPA,
• Esters formed by the esterification of carboxylic acids with ethylene oxide, glycerol, sorbitan or other alcohols,
• Ethers, for example ethoxylated alcohols, ethoxylated lanolin, ethoxylated polysiloxanes, propoxylated POE ethers and alkyl polyglycosides such as lauryl glucoside, decyl glycoside and cocoglycoside.

• • Taurate, beispielsweise Natriumlauroyltaurat und Natriummethylcocoyltaurat,
• • Ether-Carbonsäuren, beispielsweise Natriumlaureth-13 Carboxylat und Natrium PEG-6 Cocamide Carboxylat, Natrium PEG-7-Olivenöl-Carboxylat
• • Phosphorsäureester und Salze, wie beispielsweise DEA-Oleth-10 Phosphat und Dilaureth-4 Phosphat,
• • Alkylsulfonate, beispielsweise Natriumcocosmonoglyceridsulfat, Natrium C_12-14 Olefinsulfonat, Natriumlaurylsulfoacetat und Magnesium PEG-3 Cocamidsulfat.

Further advantageous anionic surfactants are

• Taurates, for example sodium lauroyl taurate and sodium methyl cocoyl taurate,
• Ether carboxylic acids, for example sodium laureth-13 carboxylate and sodium PEG-6 cocamide carboxylate, sodium PEG-7 olive oil carboxylate
• Phosphoric acid esters and salts, such as DEA-oleth-10 phosphate and dilaureth-4 phosphate,
• Alkyl sulfonates, for example, sodium coconut monoglyceride sulfate, sodium C _12-14 olefin sulfonate, sodium lauryl sulfoacetate and magnesium PEG-3 cocamide sulfate.

• • N-Alkylaminosäuren, beispielsweise Aminopropylalkylglutamid, Alkylaminopropionsäure, Natriumalkylimidodipropionat und Lauroamphocarboxyglycinat und N-Kokosfettsäureamidoethyl-N-hydroxyethylglycinat Natriumsalze und deren Derivate.

Further advantageous amphoteric surfactants are

• N-alkylamino acids, for example aminopropylalkylglutamide, alkylaminopropionic acid, sodium alkylimidodipropionate and lauroamphocarboxyglycinate and N-coconut fatty acid amidoethyl-N-hydroxyethylglycinate sodium salts and derivatives thereof.

Further advantageous nonionic surfactants are alcohols.

• • Acylglutamate wie Di-TEA-palmitoylaspartat und Natrium Caprylic/Capric Glutamat,
• • Acylpeptide, beispielsweise Palmitoyl hydrolysiertes Milchprotein, Natrium Cocoyl hydrolysiertes Soja Protein und Natrium-/Kalium Cocoyl hydrolysiertes Kollagen

sowie Carbonsäuren und Derivate, wie

• • beispielsweise Laurinsäure, Aluminiumstearat, Magnesiumalkanolat und Zinkundecylenat,
• • Ester-Carbonsäuren, beispielsweise Calciumstearoyllactylat, Laureth-6 Citrat und Natrium PEG-4 Lauramidcarboxylat,
• • Alkylarylsulfonate.

Further suitable anionic surfactants for the purposes of the present invention are further

• Acylglutamates such as di-TEA-palmitoylaspartate and sodium caprylic / capric glutamate,
• Acyl peptides, for example palmitoyl hydrolyzed milk protein, sodium cocoyl hydrolyzed soy Protein and sodium / potassium cocoyl hydrolyzed collagen

as well as carboxylic acids and derivatives, such as

• For example, lauric acid, aluminum stearate, magnesium alkoxide and zinc undecylenate,
• Ester carboxylic acids, for example calcium stearoyl lactylate, laureth-6 citrate and sodium PEG-4 lauramide carboxylate,
• • alkylarylsulfonates.

• • Alkylamine,
• • Alkylimidazole,
• • ethoxylierte Amine

insbesondere deren Salze.Further suitable cationic surfactants for the purposes of the present invention are further

• • alkylamines,
• • alkylimidazoles,
• • ethoxylated amines

in particular their salts.

Further suitable nonionic surfactants in the context of the present invention are also amine oxides, such as cocoamidopropylamine oxide.

It Advantageously, the detergent surfactant (s) of the invention is advantageous to choose the group of surfactants which have an HLB value of more than 25, particularly advantageous are those which have an HLB value of more than 35.

According to the invention preferred anionic surfactants are N-acyl amino acids, alkyl sulfates or alkyl ether sulfates or a surfactant combinations of alkyl ether sulfates with amphoteric or nonionic surfactants, wherein a surfactant combination of Alkyl ether sulfates with Alkylamidopropylbetainen or Alkylamphoacetaten or alkylpoyglucosides is particularly preferred. Especially preferred are also combinations of acylglutamates and alkylpolyglucosides.

It is advantageous in the context of the present invention, when the content on one or more detergent surfactants in the corresponding Partial preparation from the range of 0.1 to 30% by weight, preferably from 0.1 to 25% by weight, most preferably from 0.1 to 10 % By weight selected is, in each case based on the total weight of the part preparation.

R₁, R₂, R₃ = H, Fettsäurerest
darstellen.According to the invention, the preparations according to the invention may advantageously contain polysorbates. Polysorbates represent a class of compounds derived from sorbitan, a furan derivative derived from sorbitol by cleavage of two equivalents of water. The hydroxyl groups of sorbitan are etherified with polyethylene glycols, the ends of which may be esterified with fatty acids. They can be generalized by the formula

R ₁ , R ₂ , R ₃ = H, fatty acid residue
represent.

• – Polyoxyethylen(20)sorbitanmonolaurat (Tween 20, CAS-Nr.9005-64-5)
• – Polyoxyethylen(4)sorbitanmonolaurat (Tween 21, CAS-Nr.9005-64-5)
• – Polyoxyethylen(4)sorbitanmonostearat (Tween 61, CAS-Nr. 9005-67-8)
• – Polyoxyethylen(20)sorbitantristearat (Tween 65, CAS-Nr. 9005-71-4)
• – Polyoxyethylen(20)sorbitanmonooleat (Tween 80, CAS-Nr. 9005-65-6)
• – Polyoxyethylen(5)sorbitanmonooleat (Tween 81, CAS-Nr. 9005-65-5)
• – Polyoxyethylen(20)sorbitantrioleat (Tween 85, CAS-Nr. 9005-70-3).

For the purposes of the invention, advantageous polysorbates are for example the

• Polyoxyethylene (20) sorbitan monolaurate (Tween 20, CAS No 9005-64-5)
• Polyoxyethylene (4) sorbitan monolaurate (Tween 21, CAS No. 9005-64-5)
• Polyoxyethylene (4) sorbitan monostearate (Tween 61, CAS No. 9005-67-8)
• Polyoxyethylene (20) sorbitan tristearate (Tween 65, CAS No. 9005-71-4)
• Polyoxyethylene (20) sorbitan monooleate (Tween 80, CAS No. 9005-65-6)
• Polyoxyethylene (5) sorbitan monooleate (Tween 81, CAS No. 9005-65-5)
• Polyoxyethylene (20) sorbitan trioleate (Tween 85, CAS No. 9005-70-3).

These are inventively advantageous in a concentration of 0.1 to 5% by weight and ins particular in a concentration of 1.5 to 2.5% by weight, based on the total weight of the partial preparation, individually or as a mixture of several polysorbates used.

hydrocolloids

The partial preparations according to the invention advantageously contain one or more hydrocolloids according to the invention. "Hydrocolloid" is the technological abbreviation for the more correct term "hydrophilic colloid". Hydrocolloids, also called thickeners or gelling agents, are macromolecules that have a largely linear shape and intermolecular interaction forces that allow side and Hauptvalenzbindungen between the individual molecules and thus the formation of a net-like structure. They are partially water-soluble natural or synthetic polymers which form gels or viscous solutions in aqueous systems. They increase the viscosity of the water either by binding water molecules (hydration) or by absorbing and enveloping the water in their intertwined macromolecules, while at the same time restricting the mobility of the water. Such water-soluble polymers represent a large group of chemically very different natural and synthetic polymers whose common feature is their solubility in water or aqueous media. The prerequisite for this is that these polymers have a sufficient number of hydrophilic groups for water solubility and are not too strongly crosslinked. The hydrophilic groups may be nonionic, anionic or cationic in nature, for example as follows:

The group of cosmetically and dermatologically relevant hydrocolloids can be classified as follows:
organic, natural compounds, such as agar-agar, carrageenan, tragacanth, gum arabic, alginates, pectins, polyoses, guar flour, locust bean gum, starch, dextrins, gelatin, casein, organic, modified natural products such. As carboxymethyl cellulose and other cellulose ethers, hydroxyethyl and propyl cellulose and the like, organic, fully synthetic compounds such. As polyacrylic and polymethacrylic compounds, vinyl polymers, polycarboxylic acids, polyethers, polyimines, polyamides, inorganic compounds such. As polysilicic acids, clay minerals such as montmorillonites, zeolites, silicic acids.

When advantageous according to the invention Hydrocolloids are agar-agar, carrageenan, tragacanth, gum arabic, Alginates, pectins, polyoses, guar flour, locust bean gum, Strength, Dextrins, gelatin, casein, cellulose ethers, hydroxyethyl and propyl cellulose derivatives, Polyacrylic and polymethacrylic compounds, vinyl polymers, polycarboxylic acids, polyethers, Polyimines, polyamides, polysilicic acids, clay minerals, zeolites, silicas used.

in der R ein Wasserstoff oder eine Methylgruppe darstellen kann.Hydrocolloids which are preferred according to the invention are, for example, methylcelluloses, which are referred to as the methyl ethers of cellulose. They are characterized by the following structural formula

in which R can represent a hydrogen or a methyl group.

Especially advantageous in the context of the present invention are in general also referred to as methylcelluloses cellulose mixed ethers, which in addition to a dominating content of methyl additionally 2-hydroxyethyl, 2-hydroxypropyl or 2-hydroxybutyl groups. Particularly preferred are (hydroxypropyl) methylcelluloses, for example, under the trade name Methocel E4M the Dow Chemical Comp. available.

Further according to the invention Advantageous is sodium carboxymethyl cellulose, the sodium salt of glycolic acid ether cellulose, for which R in structural formula I is a hydrogen and / or CH 2 -COONa can represent. Particularly preferred is that under the trade name Natrosol Plus 330 CS available from Aqualon, also available as cellulose Gum refers to sodium carboxymethylcellulose.

Prefers For the purposes of the present invention, xanthan (CAS no. 11138-66-2), too Called xanthan gum, which is an anionic heteropolysaccharide which is usually formed by fermentation from corn sugar and isolated as the potassium salt. It is owned by Xanthomonas campestris and some other species under aerobic conditions Molecular weight of 2 × 10 6 up to 24 × 106 produced. Xanthan is from a chain with (3-1,4-bound glucose (Cellulose) formed with side chains. The structure of the subgroups consists of glucose, mannose, glucuronic acid, acetate and pyruvate. xanthan is the name for the first microbial anionic heteropolysaccharide. It is from Xanthomonas campestris and some other species under aerobic Conditions with a molecular weight of 2-15 106 produced. xanthan is made from a chain with (3-1,4-bonded Glucose (cellulose) with side chains formed. The structure of the subgroups consists of glucose, mannose, glucuronic acid, acetate and pyruvate. The Number of pyruvate units determines the viscosity of xanthan. Xanthan becomes in two days Batch cultures with a yield of 70-90%, based on used Carbohydrate, produced. In this case, yields of 25-30 g / l reached. The workup is carried out after killing the culture by precipitation with r. B. 2-propanol. Xanthan is subsequently added dried and ground.

Favorable Gelling agent in the context of the present invention is also carrageenan, a gel-forming and similar like agar based extract from north Atlantic, counting to the Florideen Red algae (Chondrus crispus and Gigartina stellata).

Frequently, the term carrageenan is used for the dried algae product and carrageenan for the extract thereof. The carrageenan precipitated from the hot-water extract of the algae is a colorless to sand-colored powder with a molecular weight range of 100,000-800,000 and a sulphate content of about 25%. Carrageenan, which is very slightly soluble in warm water; Upon cooling, a thixotropic gel forms, even if the water content is 95-98%. The strength of the gel is effected by the double helix structure of the carrageenan. Carrageenan has three main components: The gel-forming κ fraction consists of D-galactose-4-sulfate and 3,6-anhydro-α-D-galactose, which are alternately glycosidically linked in the 1,3- and 1,4-positions (Agar, in contrast, contains 3,6-anhydro-α-L-galactose). The non-gelling λ-fraction is composed of 1,3-glycosidically linked D-galactose-2-sulfate and 1,4-linked D-galactose-2,6-disulfate residues u. easily soluble in cold water. The ι-carrageenan composed of D-galactose-4-sulfate in 1,3-bond and 3,6-anhydro-D-galactose-2-sulfate in 1,4-bond is both water-soluble and gel-forming. Other carrageenan types are also denoted by Greek letters: α, β, γ, μ, ν, ξ, π, ω, χ. The type of cations present (K ⁺ , NH ₄ ⁺ , Na ⁺ , Mg ²⁺ , Ca ²⁺ ) also influences the solubility of the carrageenans.

Polyacrylates are also advantageously gelators to be used in the context of the present invention. According to the invention advantageous polyacrylates are acrylate-alkyl acrylate copolymers, in particular those from the group of so-called carbomers or carbopols (Carbopol ^® is actually a registered trademark of NOVEON Inc.) are selected. In particular, the acrylate-alkyl acrylate copolymers which are advantageous according to the invention have the following structure:

In this put R 'one long-chain alkyl radical and x and y are numbers which the respective stoichiometric Symbolize the proportion of the respective comonomers.

Preferred are acrylate copolymers and / or acrylate-alkyl acrylate copolymers sold under the trade names Carbopol ^® 1382, Carbopol ^® 981 and Carbopol ^® 5984, Aqua SF-1 from NOVEON Inc. or as Aculyn ^® 33 from International Specialty Products Corp. are available.

Further advantageous are copolymers of C10-30-alkyl acrylates and a or more monomers of acrylic acid, methacrylic acid or their esters cross-linked with an allyl ether of sucrose or an allyl ether of pentaerythritol.

Advantageous are compounds which have the INCI name "Acrylates / C 10-30 Alkyl Acrylates Crosspolymer "wear. Particularly advantageous are those under the trade names Pemulen TR1 and Pemulen TR2 available from NOVEON Inc.

Also advantageous are compounds having the INCI name "acrylates / C12-24 pareth-25 acrylate copolymer" (under the trade names Synthalen ^® W2000 in 3V Inc.), the methacrylate, the INCI name "acrylates / steareth-20 copolymer "(under the trade names Aculyn ^® 22 available from International Specialty Products Corp.), which the INCI name" acrylates / steareth-20 itaconate copolymer "(available under the trade names Structure 2001 ^® available from National Starch), the INCI the name "acrylates / aminoacrylates / C10-30 alkyl PEG-20 itaconate copolymer" (available under the trade name Structure Plus ^® from National Starch) and similar polymers.

The particularly according to the invention preferred hydrocolloids are: acrylates copolymer (AQUA SF-1), acrylates / C 10-30 Alkyl Acrylate Crosspolyme (Carbopol ETD 2020), Xanthan gum (Wine).

The Part preparations according to the invention advantageously contain one or more hydrocolloids / gelling agents in a concentration of 0.1 to 8% by weight, preferably 0.2 to 6% by weight and most preferably from 0.3 to 4% by weight, in each case based on the total weight of the part preparation.

film formers

Erfindungsgemäß vorteilhafte Filmbildner According to the invention, at least one of the two part preparations may advantageously contain one or more film formers. Film formers which are advantageous according to the invention can be selected from the compounds listed in the table.

According to the invention, advantageous film formers

Further inventively advantageous film formers are cellulose derivatives and quaternized guar gum derivatives, in particular guar hydroxypropylammonium represents (eg Jaguar Excel ^®, Jaguar C 162 ^® from Rhodia, CAS 65497-29-2, CAS 39421-75-5).

And nonionic poly-N-vinylpyrrolidone / polyvinyl acetate copolymers (such as Luviskol VA 64W ^®, BASF), anionic acrylate copolymers (eg Luviflex Soft ^®, BASF), and / or amphoteric amide / acrylate / methacrylate copolymers (for example, Amphomer ^®, National Starch) can be advantageously used according to the invention as a film former.

complexing

It is also advantageous, the preparations according to the invention complexing agents add. Advantageously, the complexing agents are selected from the group consisting of ethylenediaminetetraacetic acid (EDTA) and their anions, nitrilotriacetic acid (NTA) and their anions, hydroxyethylenediaminotriacetic acid (HOEDTA) and their anions, diethyleneaminopentaacetic acid (DPTA) and their anions, trans-1,2-diaminocyclohexanetetraacetic acid (CDTA) and its anions, Tetrasodium Iminodisuccinate, Trisodium Etylenediamine Disuccinate.

Oil components / lipids

A optionally desired oil component the cosmetic or dermatological part preparations in the sense The present invention is advantageously selected from the group of esters from saturated and / or unsaturated, branched and / or unbranched alkanecarboxylic acids of a chain length of 3 to 30 carbon atoms and saturated and / or unsaturated, branched and / or unbranched alcohols of a chain length of 3 to 30 carbon atoms, from the group of esters of aromatic carboxylic acids and saturated and / or unsaturated, branched and / or unbranched alcohols of a chain length of 3 to 30 carbon atoms. Such ester oils can then chosen advantageous are from the group isopropyl myristate, isopropyl palmitate, isopropyl stearate, Isopropyl oleate, n-butyl stearate, n-hexyl laurate, n-decyl oleate, isooctyl stearate, isononyl stearate, Isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl laurate, 2-hexyldecyl stearate, 2-octyl dodecyl palmitate, oleyl oleate, Oleyl erucate, erucyl oleate, erucyl erucate and synthetic, semisynthetic and natural Mixtures of such esters, e.g. B. jojoba oil.

Further can the oil component chosen favorably are from the group of branched and unbranched hydrocarbons and waxes, the silicone oils, the dialkyl ether, the group of saturated or unsaturated, branched or unbranched alcohols, as well as the fatty acid triglycerides, namely the triglycerol esters of saturated and / or unsaturated branched and / or unbranched alkanecarboxylic acids of a chain length of 8 to 24, in particular 12 to 18 carbon atoms. The fatty acid triglycerides can for example, advantageously chosen are selected from the group of synthetic, semi-synthetic and natural oils, e.g. B. Olive oil, Sunflower oil, Soybean oil, Peanut oil, rapeseed oil, almond oil, palm oil, coconut oil, palm kernel oil, and the like.

Also any mixtures of such oil and wax components are advantageous in the sense of the present Use invention.

Advantageous becomes the oil component chosen from the group 2-ethylhexyl isostearate, octyldodecanol, isotridecyl isononanoate, Isoeicosane, 2-ethylhexyl cocoate, C12-15 alkyl benzoate, caprylic capric triglyceride, dicaprylyl ether.

Especially advantageous are mixtures of C12-15-alkyl benzoate and 2-ethylhexyl isostearate, Mixtures of C12-15-Alkylbenzoat and Isotridecylisononanoat as well Mixtures of C12-15 alkyl benzoate, 2-ethylhexyl isostearate and isotridecyl isononanoate.

From The hydrocarbons are paraffin oil, squalane and squalene advantageous to be used in the sense of the present invention.

Advantageous can the oil component furthermore have a content of cyclic or linear silicone oils or completely from such oils but it is preferred, except the silicone oil or the silicone oils An additional Content of other oil phase components to use.

Advantageous Cyclomethicone (Octamethylcyclotetrasiloxan) is used as a silicone oil to be used according to the invention. But also other silicone oils are advantageous for the purposes of the present invention to use for example, hexamethylcyclotrisiloxane, polydimethylsiloxane, poly (methylphenylsiloxane).

Especially also advantageous are mixtures of cyclomethicone and isotridecyl isononanoate, from cyclomethicone and 2-ethylhexyl isostearate.

auszeichnen, wobei R' und R'' typischerweise unverzweigte aliphatische Reste mit 15 oder 17 Kohlenstoffatomen und bis zu 4 cis-Doppelbindungen darstellen.The oil component is also advantageously selected from the group of phospholipids. The phospholipids are phosphoric acid esters of acylated glycerols. Of the utmost importance among the phosphatidylcholines are, for example, the lecithins, which are distinguished by the general structure

characterized in that R 'and R''typically represent unbranched aliphatic radicals having 15 or 17 carbon atoms and up to 4 cis double bonds.

Aqueous phase

Next Water can / can the aqueous according to the invention Phases also water-soluble Ingredients include, for example, alcohols, diols or polyols low C number, and their ethers, preferably ethanol, isopropanol, Propylene glycol, glycerol, ethylene glycol, ethylene glycol monoethyl or -monobutyl ether, propylene glycol monomethyl, -monoethyl- or monobutyl ether, diethylene glycol monomethyl or monoethyl ether and analogous products, furthermore lower C number alcohols, e.g. ethanol, Isopropanol, 1,2-propanediol and glycerol.

According to the invention advantageous At least one of the preparations 1 and 2 according to the invention may be used in addition to one or more water phases one or more oil phases and for example in the form of W / O, O / W, W / O / W or O / W / O emulsions available. Such formulations may preferably also have a Microemulsion (eg a PIT emulsion), a solid emulsions (i.e., an emulsion stabilized by solids, z. B. a Pickering emulsion), with transparent or translucent Microemulsions according to the invention particularly are preferred.

According to the invention advantageous can at least one of the two part preparations 1 and 2 in the form an emulsion or dispersion, with both macro- and also microemulsions, O / W emulsions, W / O emulsions, B / W emulsions, W / S emulsions as also multiple emulsions advantageous in the sense of the present invention can be used.

The Compositions according to the invention except the aforementioned substances optionally further customary in cosmetics Additives, for example perfume, dyes, antimicrobials, moisturizing Agents, complexing and sequestering agents, pearlescent agents, Plant extracts, self-tanner (e.g., DNA), depigmenting agents, anti-dandruff agents, vitamins, other active substances, complexes of gamma-oryzanol and calcium salts, Niacinamide and its derivatives, panthenol and its derivatives, subtilisin, Minerals, preservatives, bactericides, pigments containing a coloring Have effect, thickener, softening, moisturizing and / or moisturizing substances, or other common ingredients of a cosmetic or dermatological formulation such as alcohols, polyols, polymers, foam stabilizers, Electrolytes, organic solvents or silicone derivatives. The pH of the partial preparations according to the invention is doing in the for the usual Way with the appropriate acids (lactic acid, citric acid, phosphoric acid etc.) and bases (e.g., NaOH).

It is advantageous according to the invention if the two part preparations 1 and 2 differently colored and / or loaded with different effect substances.

It is advantageous according to the invention if the viscosity of the part preparations 1 and 2 in both chambers is 1-2000 mPaS, preferably 1-1500 mPaS and particularly preferably 1-1200 mPas. The viscosity according to the invention is measured as follows:
The viscosity is measured at 25 ° C in a DIN cylinder system at a shear rate of 100 1 / s.

The mixing ratio of the two partial preparations available in the pantries 1 and 2 is in the removal from the foam dispenser according to the invention advantageous 1: 9 to 9: 1. According to the invention preferred is a mixture ratio from about 1: 1.

According to the invention advantageous can the foam dispenser according to the invention also have more than 2 pantries which with the corresponding Number of cosmetic (or dermatological) part preparations befalls are mixed and foamed together during the removal.

According to the invention Use of the cosmetic according to the invention and / or dermatics for cleansing and care of the skin and / or Skin appendages.

Especially is the use of the cosmetic and / or dermatological agent according to the invention as a shower gel, bath or shampoo (hair shampoo) according to the invention.

But is also the use of the cosmetic according to the invention and / or dermatics as a skin cream, lotion or gel for the care of the skin according to the invention advantageous.

Further the products according to the invention are suitable Excellent for cleaning and care of items of the daily Life (e.g., dishes, table and cupboards, cars).

The The following examples are intended to illustrate the present invention, without restricting it. All Quantities, percentages and percentages are, unless otherwise stated indicated on the weight and the total amount or on the total weight the preparations.

example 1

Chamber 1 (shower formulation) Examples 1-5:

Of the pH is at 4.8-5.4 set.

Chamber 2 (surfactant-free drug solution) Examples 1-5:

Example 2:

Chamber 1 (shower formulation) Examples 1-5: chamber 1: shower formulation; Chamber 2: shampoo

The pH is adjusted to 4.8-5.4. Chamber 2 (shampoo) Examples 1-5:

Example 3. Heating Effect

Compartment 1 (surfactant formulation) compartment 1: surfactant formulation; Chamber 2: surfactant-free phase

Chamber 2 surfactant free phase

Example 4: Microemulsion In conjunction with surfactant formulation

Compartment 1 (surfactant formulation) (examples 1-5) compartment 1: surfactant phase; Chamber 2: microemulsion

Chamber 2 (microemulsion) Examples 1-6:

Claims (9)

Cosmetic which is formed from a) a foam dispenser with two separate storage chambers, the contents of which can be taken simultaneously by means of two coupled feed pumps via a common outlet opening and which foams the preparations by means of air, and b) two cosmetic preparations 1 and 2, which are each located in one of the two storage chambers of the foam dispenser and are characterized in that i) at least one of the two preparations contains one or more cosmetic and / or dermatological active ingredients and ii) at least one of the two preparations contains one or more surfactants. Using a foam dispenser with two of each other separate pantries whose contents are coupled by means of two feed pumps simultaneously over a common outlet can be removed and which the preparations by means of air foams, for mixing and foaming active ingredient-containing cosmetic and / or dermatological preparations, wherein both phases are preferably mixed and foamed together, that a complete Mixing takes place and the two preparations with the naked eye no more than separate domains be perceived. Cosmetic according to claim 1 or use according to claim 2, characterized in that the preparation in the first chamber one or more ingredients selected from the group anionic Surfactants, nonionic surfactants, amphoteric surfactants, polymers, perfume oils, emulsifiers, Enzyme substrates, contains. Cosmetic according to claim 1 or use according to claim 2, characterized in that the preparation in the second chamber one or more ingredients selected from the group water, cationic surfactants, polymers, emulsifiers, dyes, cosmetic and / or dermatological agents. Cosmetic or use according to one of the preceding Claims, characterized in that one or more active substances are selected from the group of UV protection filters, vitamins, vitamin derivatives, Antioxidants, anti-wrinkle agents, self-tanning, depigmenting agents, repellents, Plant extracts, enzymes, anhydrous polyols, dyes, effect substances. Cosmetic or use according to one of the preceding Claims, characterized in that in the first chamber a surfactant-containing Preparation and in the second chamber a shampoo, a shower gel, a hair conditioner, an anhydrous polyol-containing preparation, the Contact with water heat releases, an emulsion are included. Cosmetic or use according to claim 8, characterized in that the surfactant-containing preparation is a shampoo or represents a shower gel. Cosmetic or use according to one of the preceding Claims, characterized in that the surfactant-containing preparation in the first chamber one or more anionic surfactants in a concentration from 1 to 30% by weight based on the total weight of the preparation in the first chamber, contains. Cosmetic or use according to one of the preceding Claims, characterized in that the viscosity of the solutions in both chambers 1-2000 mPas is.