DE10247696A1 - Cosmetic or dermatological emulsions useful e.g. as hair shampoos, shower gels or shaving foams contain a combination of a saccharide-N-alkylurethane and a surfactant - Google Patents

Abstract

Cosmetic or dermatological emulsions contain a combination of (a) a saccharide-N-alkylurethane; and (b) one or more surfactants, optionally together with (c) further cosmetic and/or dermatological agents or auxiliaries.

Description

The present invention relates to a cosmetic and / or dermatological preparation containing one Combination of saccharide-N-alkyl urethanes and surfactants.

The desire for a clean and well-groomed exterior probably as old as mankind. Impure skin and an unkempt hair Costume provide ideal breeding ground and home for Pathogens and parasites of all kinds. The pleasure in personal hygiene has been steadily reinforced than in the 1960s, in addition to the "classic" soap, liquid cleaning agents could be formulated with newly developed synthetic surfactants. Bathing and showering have become an integral part of our daily lives and consumers have a variety of products these days for the Cleaning the different parts of the body to disposal.

Cosmetic and / or dermatological cleaning preparations are usually in the form of a foam with water towards the cleansing parts of the body applied. Basis of almost all cosmetic or dermatological cleaning preparations are detergent surfactants. Surfactants are amphiphilic substances that contain organic, Dissolve non-polar substances in water can. They are characterized by an ambivalent behavior towards water and lipids from: The surfactant molecule contains at least one hydrophilic and one lipophilic group, which the Accumulation at the interface enable between these two classes of substances. Worry this way Surfactants for a reduction in surface tension of water, wetting the skin, facilitating dirt removal and solution, a gentle rinse and ever on request - also for foam regulation. This is the basis for given the removal of dirt containing lipid.

• – anionische Tenside,
• – kationische Tenside,
• – amphotere Tenside und
• – nichtionische Tenside.

The hydrophilic parts of a surfactant molecule are mostly polar functional groups, for example -COO ^- , -OS0 ₃ ^2– , -SO ₃ ^- , while the hydrophobic parts generally represent non-polar hydrocarbon radicals. Surfactants are generally classified according to the type and charge of the hydrophilic part of the molecule. There are four groups:

• - anionic surfactants,
• - cationic surfactants,
• - amphoteric surfactants and
• - nonionic surfactants.

Most cosmetic and dermatological Cleaning preparations are in the form of more or less viscous liquids (Cleaning water, gels and milks) or as a solid (e.g. soap, detergent) in front. They are usually applied to the skin with your hands or fingers or the skin appendages (e.g. hair, nails) are applied.

For the wet shave of the whisker requires shaving foams and gels that soften the whiskers and so the hair necessary to cut them Effort - and to minimize the unpleasant pulling on the hair shaft. The softening The whiskers is achieved through water absorption by the increase of the pH of the hair becomes. Wet shaving agents therefore usually contain soaps or Fatty acid salts, whose pH is in the range of 8-10. These soap-containing formulations are fundamental also suitable for cleaning the skin.

Soap-containing cleaning agents and especially products for according to the prior art, wet shaving has a number of Disadvantages on. The skin feels usually dry and rough after use. This in the cosmetic experts also call it "squeaky-feeling" extremely unpopular with consumers.

Soaps containing detergents are about that usually not particularly temperature stable. That's why when warming again and again to separate individual components of the preparation, especially when using different fatty acid cuts, due to the different melting and crystallization properties of the different fatty acids and their mixtures.

However, because soaps themselves are inexpensive and environmentally friendly surface active Represent substances, it was the object of the present invention To remedy the disadvantages of the prior art Cleaning agents and / or shaving agents (e.g. shampoos, shower gels, shaving foams etc.) a variety of requirements are imposed on these preparations meet at the same time Should: These preparations are expected to be skin-friendly and a pleasant feeling on the skin leave on skin after application. Furthermore should froth up easily and form a creamy, fine-bubble foam. Such preparations However, the prior art have the disadvantage that they meet these requirements insufficiently fair become. Good foaming Products are usually not skin-friendly and leave behind a dry feeling on the skin. Particularly mild, skin-friendly products in turn foam in usually bad.

Another disadvantage of the prior art Technology consists in the fact that, especially in the industrialized countries, in the population increasingly intolerance and allergic reactions to a variety of chemicals and ingredients comes from Kosmtika or Dermatika. Of this development are in increasingly also cosmetic and dermatological preparations containing surfactants affected as it is the protective Partially detach the lipid layer on the skin and deep into it on the one hand draw in the skin, on the other hand stick to the skin for a long time can. Therefore, the concentration of surfactants in cosmetic and / or dermatological preparations if possible be kept low. There is also a need for surfactants Preparations with different surfactant compositions because of intolerance and allergic reactions are substance-specific and affected People were given the opportunity is, cosmetic and / or dermatological preparations with a tailored to your intolerance profile Use composition.

The object of the present invention it was the shortcomings the prior art of cosmetic and / or surfactant-containing dermatological preparations, in particular hair shampoos, shower gels and shaving foams, to eliminate or at least significantly reduce. It should Preparations are developed that are skin-friendly and based on the skin feels pleasant (soft, neat, smooth, clean). At the same time lather these preparations well and form a creamy, fine-bubble, dense, stable foam.

Surprised solved are the tasks through a cosmetic and / or dermatological Preparation containing a combination of one or more Saccharide-N-alkyl urethanes and one or more surfactants, in addition to any other cosmetic and / or dermatological active ingredients, auxiliaries and additives.

The describes EP 0 964 054 A1 the use of fructan N-alkylurethanes as surface-active compounds in various preparations, but this document could not point the way to the present invention.

It is advantageous according to the invention if one or more oligo- or polysaccharides (e.g. Fructans such as Levan and inulin; Glucans such as starch, amylose, amylopectin, Chitin, glycogen and callose) can be used. They are preferred one or more polyfructosans (fructans) are used. According to the invention particularly it is preferred to use inulin as the polysaccharide.

According to the invention, the degree of polymerization is advantageous of the oligosaccharide or polysaccharide at least 3, preferably 3 to 100, particularly preferably 5 to 75, very particularly preferably 6 to 40 and most preferably between 10 and 35. The degree of polymerization gives the number of monosaccharide building blocks of a polysaccharide on.

According to the invention, the degree of substitution is advantageous of the saccharide on N-alkyl urethanes 0.1 to 2.0, preferably 0.15 to 1.5, particularly preferably 0.20 to 1.2, most preferably 0.4 to 0.8, and most preferred 0.5 to 0.6. The degree of substitution gives the average Number of alkyl urethane substituents on a monosaccharide unit of the saccharide.

In terms of the ending, it is advantageous if the alkyl radical of the N-alkylurethane groups with which the saccharides according to the invention is / are, is formed from linear or branched, saturated or unsaturated Alkyl groups with a carbon number of 3 to 22 carbon atoms, where all N-alkyl urethane groups of a saccharide or polysaccharide consist of the same or different N-alkylurethane groups can. Preferred according to the invention are alkyl radicals with a carbon number of 3 to 18 carbon atoms and particularly preferably from 3 to 16 carbon atoms. Most according to the invention N-n-octyl carbamate groups are preferred.

According to the invention, all polysaccharide-N-alkyl urethanes can be used particularly advantageously in the EP 964 054 A1 as well as in the journal Biomacromolecules (2001, Volume 2, pages 1256-1259) disclosed polysaccharide-N-alkylurethanes. Polysaccharide-N-alkyl urethanes, for example, which are offered by ORAFTI under the product group Inutec ^® Surfactans, in particular INUTEC ^® LIC 0.1, are very particularly preferred according to the invention.

Advantageously according to the invention cosmetic according to the invention and / or dermatological emulsion the total amount of saccharide-N-alkyl urethanes from 0.05 to 10% by weight, preferably from 0.1 to 5% by weight and very particularly preferably from 0.2 to 2% by weight, based in each case on the total weight of the surfactant-containing preparations.

The minimum amount is advantageous according to the invention of saccharide-N-alkyl urethanes 0.05% by weight, preferably 0.1% by weight and very particularly preferably 0.2% by weight, in each case based on the total weight of the surfactant-containing preparations.

The maximum amount is advantageous according to the invention of saccharide-N-alkyl urethanes 10% by weight, preferably 5% by weight and very particularly preferably 2% by weight, based in each case on the Total weight of preparations containing surfactants.

The cosmetic preparations according to the invention contain surfactants. It is advantageous according to the invention if as surfactants anionic, cationic, nonionic and / or amphoteric surfactants be used.

Ionic surfactants, ie anionic, cationic and / or ampho, are preferred according to the invention tere surfactants used.

• – Acylglutamate, insbesondere Natriumacylglutamat
• – Sarcosinate, beispielsweise Myristoyl Sarcosin, TEA-lauroyl Sarcosinat, Natriumlauroylsarcosinat und Natriumcocoylsarkosinat,

Advantageous wash-active anionic surfactants for the purposes of the present invention are acylamino acids and their salts, such as

• - Acylglutamate, especially sodium acylglutamate
• Sarcosinates, for example myristoyl sarcosin, TEA lauroyl sarcosinate, sodium lauroyl sarcosinate and sodium cocoyl sarcosinate,

• – Acylisethionate, z.B. Natrium-/ Ammoniumcocoylisethionat,
• – Sulfosuccinate, beispielsweise Dioctylnatriumsulfosuccinat, Dinatriumlaurethsulfosuccinat, Dinatriumlaurylsulfosuccinat und Dinatriumundecylenamido MEA-Sulfosuccinat, Dinatrium PEG-5 Laurylcitratsulfosuccinat und Derivate,

sowie Schwefelsäureester, wie

• – Alkylethersulfat, beispielsweise Natrium-, Ammonium-, Magnesium-, MIPA-, TIPA- Laurethsulfat, Natriummyrethsulfat und Natrium C_12–13 Parethsulfat,
• – Alkylsulfate, beispielsweise Natrium-, Ammonium- und TEA- Laurylsulfat.

Sulfonic acids and their salts, such as

• Acyl isethionates, for example sodium / ammonium cocoyl isethionate,
• Sulfosuccinates, for example dioctyl sodium sulfosuccinate, disodium laureth sulfosuccinate, disodium lauryl sulfosuccinate and disodium undecylenamido MEA sulfosuccinate, disodium PEG-5 lauryl citrate sulfosuccinate and derivatives,

as well as sulfuric acid esters, such as

• Alkyl ether sulfate, for example sodium, ammonium, magnesium, MIPA, TIPA laureth sulfate, sodium myreth sulfate and sodium C _12-13 pareth sulfate,
• - Alkyl sulfates, for example sodium, ammonium and TEA lauryl sulfate.

• – Taurate, beispielsweise Natriumlauroyltaurat und Natriummethylcocoyltaurat,
• – Ether-Carbonsäuren, beispielsweise Natriumlaureth-13 Carboxylat und Natrium PEG-6 Cocamide Carboxylat, Natrium PEG-7-Olivenöl-Carboxylat
• – Phosphorsäureester und Salze, wie beispielsweise DEA-OIeth-10 Phosphat und Dilaureth-4 Phosphat,
• – Alkylsulfonate, beispielsweise Natriumcocosmonoglyceridsulfat, Natrium C_12–14 Olefinsulfonat, Natriumlaurylsulfoacetat und Magnesium PEG-3 Cocamidsulfat,
• – Acylglutamate wie Di-TEA-palmitoylaspartat und Natrium Caprylic/ Capric Glutamat,
• – Acylpeptide, beispielsweise Palmitoyl hydrolysiertes Milchprotein, Natrium Cocoyl hydrolysiertes Soja Protein und Natrium-/ Kalium Cocoyl hydrolysiertes Kollagen

sowie Carbonsäuren und Derivate, wie

• – beispielsweise Laurinsäure, Aluminiumstearat, Magnesiumalkanolat und Zinkundecylenat,
• – Ester-Carbonsäuren, beispielsweise Calciumstearoyllactylat, Laureth-6 Citrat und Natrium PEG-4 Lauramidcarboxylat,
• – Alkylarylsulfonate.

Other advantageous anionic surfactants are

• Taurates, for example sodium lauroyl taurate and sodium methyl cocoyl taurate,
• - Ether carboxylic acids, for example sodium laureth-13 carboxylate and sodium PEG-6 cocamide carboxylate, sodium PEG-7 olive oil carboxylate
• Phosphoric acid esters and salts, such as DEA-OIeth-10 phosphate and dilaureth-4 phosphate,
• Alkyl sulfonates, for example sodium coconut monoglyceride sulfate, sodium C _12-14 olefin sulfonate, sodium lauryl sulfoacetate and magnesium PEG-3 cocamide sulfate,
• Acylglutamates such as di-TEA-palmitoylaspartate and sodium caprylic / capric glutamate,
• Acyl peptides, for example palmitoyl hydrolyzed milk protein, sodium cocoyl hydrolyzed soy protein and sodium / potassium cocoyl hydrolyzed collagen

as well as carboxylic acids and derivatives, such as

• For example lauric acid, aluminum stearate, magnesium alkanolate and zinc undecylenate,
• Ester carboxylic acids, for example calcium stearoyl lactylate, laureth-6 citrate and sodium PEG-4 lauramide carboxylate,
• - alkylarylsulfonates.

Favorable washing active cationic For the purposes of the present invention, surfactants are quaternary surfactants. quaternary Surfactants contain at least one N atom with 4 alkyl or aryl groups is covalently linked. Alkyl betaine, for example, are advantageous, Alkylamidopropylbetaine and alkylamidopropylhydroxysultain.

• – Alkylamine,
• – Alkylimidazole und
• – thoxylierte Amine

und insbesondere deren Salze.Further advantageous cationic surfactants for the purposes of the present invention are also

• - alkylamines,
• - alkylimidazoles and
• - thoxylated amines

and especially their salts.

Favorable washing active amphoteric For the purposes of the present invention, surfactants are acyl- / dialkylethylenediamines, for example sodium acylamphoacetate, disodium acylamphodipropionate, Disodium alkyl amphodiacetate, sodium acyl amphohydroxypropyl sulfonate, Disodium acylamphodiacetate, sodium acylamphopropionate, and N-coconut fatty acid amidoethyl-nhydroxyethylglycinate Sodium salts.

Other advantageous amphoteric surfactants are N-alkylamino acids, for example aminopropylalkylglutamide, alkylaminopropionic acid, sodium alkylimidodipropionate and lauroamphocarboxyglycinate.

• – Alkanolamide, wie Cocamide MEA/ DEA/ MIPA,
• – Ester, die durch Veresterung von Carbonsäuren mit Ethylenoxid, Glycerin, Sorbitan oder anderen Alkoholen entstehen,
• – Ether, beispielsweise ethoxylierte Alkohole, ethoxyliertes Lanolin, ethoxylierte Polysiloxane, propoxylierte POE Ether und Alkylpolyglycoside wie Laurylglucosid, Decylglycosid und Cocoglycosid.

Advantageous wash-active non-ionic surfactants for the purposes of the present invention are

• Alkanolamides, such as Cocamide MEA / DEA / MIPA,
• Esters formed by esterification of carboxylic acids with ethylene oxide, glycerol, sorbitan or other alcohols,
• - Ethers, for example ethoxylated alcohols, ethoxylated lanolin, ethoxylated polysiloxanes, propoxylated POE ethers and alkyl polyglycosides such as lauryl glucoside, decyl glycoside and cocoglycoside.

Another advantageous non-ionic Surfactants are alcohols and amine oxides, such as cocoamidopropylamine oxide.

It is advantageous that the active detergent according to the invention Select surfactants from the group of surfactants that have an HLB value of more than 25, those which are particularly advantageous have an HLB value of more than 35.

It is special according to the invention preferred if anionic surfactants are used as surfactants it being preferred to use sodium laureth sulfate alone or as a surfactant use in combination with other surfactants. Particularly preferred are these combinations if the preparation according to the invention is used as a shampoo, Shower gel, foam or tub bath and used as a hand wash lotion becomes.

According to the invention, however, it is also preferred if one or more fatty acids and / or their salts as surfactants, alone or in combination with others Surfactants is used. This is particularly advantageous if the preparation is used as shaving cream.

According to the invention, it is advantageous if one or more surfactants in a concentration of 1 to 50 % By weight, preferably in a concentration 5 of 30 to% by weight and most preferably in a concentration of 10 to 20 % By weight, in each case based on the total weight of the preparation is used.

Anionic surfactants, preferably alkyl sulfates, particularly preferably ethoxylated alkyl sulfates (lauryl ether sulfates; Myristyl ether sulfates) are advantageous according to the invention in a concentration of 1-20% by weight and preferably in a concentration of 5-12 % By weight, based on the total weight of the preparation used.

These concentration ranges apply also preferred if soaps of fatty acids (carboxylic acids and Derivatives) are used, as is the case with shaving foams and gels, for example the case is.

Amphoteric surfactants, preferably quaternary surfactants, alkylamidopropylbetaine are particularly preferred and are advantageous according to the invention in a concentration of 1-20% by weight and preferably in one Concentration of 2-10% by weight, based on the total weight the preparation used.

According to the invention, these surfactants are preferred used in combination with LES.

According to the invention can advantageously as Amphoteric surfactants also acyl / dialkyl ethylenediamines, in particular Disodium alkyl amphodiacetate can be used. For these amphoteric surfactants the preferred concentration ranges from 1-10% by weight and particularly preferably from 1-5% by weight, in each case based on the total weight of the preparation.

Furthermore, polysorbates can be used as a detergent Agents advantageous according to the invention be incorporated into the preparation.

• – Polyoxyethylen(20)sorbitanmonolaurat (Tween 20, CAS-Nr.9005-64-5)
• – Polyoxyethylen(4)sorbitanmonolaurat (Tween 21, CAS-Nr.9005-64-5)
• – Polyoxyethylen(4)sorbitanmonostearat (Tween 61, CAS-Nr. 9005-67-8)
• – Polyoxyethylen(20)sorbitantristearat (Tween 65, CAS-Nr. 9005-71-4)
• – Polyoxyethylen(20)sorbitanmonooleat (Tween 80, CAS-Nr. 9005-65-6)
• – Polyoxyethylen(5)sorbitanmonooleat (Tween 81, CAS-Nr. 9005-65-5)
• – Polyoxyethylen(20)sorbitantrioleat (Tween 85, CAS-Nr. 9005-70-3).

Polysorbates which are advantageous in the sense of the invention are

• - Polyoxyethylene (20) sorbitan monolaurate (Tween 20, CAS No. 9005-64-5)
• - Polyoxyethylene (4) sorbitan monolaurate (Tween 21, CAS No. 9005-64-5)
• - Polyoxyethylene (4) sorbitan monostearate (Tween 61, CAS No. 9005-67-8)
• - Polyoxyethylene (20) sorbitan tristearate (Tween 65, CAS No. 9005-71-4)
• - Polyoxyethylene (20) sorbitan monooleate (Tween 80, CAS No. 9005-65-6)
• - Polyoxyethylene (5) sorbitan monooleate (Tween 81, CAS No. 9005-65-5)
• - Polyoxyethylene (20) sorbitan trioleate (Tween 85, CAS No. 9005-70-3).

• – Polyoxyethylen(20)sorbitanmonopalmitat (Tween 40, CAS-Nr. 9005-66-7)
• – Polyoxyethylen(20)sorbitanmonostearat (Tween 60, CAS-Nr. 9005-67-8).

Are particularly particularly advantageous

• - Polyoxyethylene (20) sorbitan monopalmitate (Tween 40, CAS No. 9005-66-7)
• - Polyoxyethylene (20) sorbitan monostearate (Tween 60, CAS No. 9005-67-8).

These are advantageous according to the invention in a concentration of 0.1 to 5% by weight and in particular in a concentration of 1.5 to 2.5% by weight, based on the Increase the total weight of the formulation individually or as a mixture Polysorbates.

The cosmetic and / or dermatological invention Preparations containing surfactants are also characterized in that The relationship the total amount of saccharides to the total amount of surfactants of 1: 1000 to 10: 1, preferably from 1: 300 to 1: 1 and very particularly preferably from 1: 100 to 1: 5.

The cosmetic and / or dermatological preparation according to the invention can in addition to one or more water phases additionally contain one or more oil phases and for example in the form of W / O- (water in oil-), W / S- (water in silicone oil) O / W - (Oil in water) or B / W (silicone oil in water) emulsion. Furthermore, according to the invention, they can advantageously also be present in so-called multiple emulsions, for example W / O / W, O / W / O, W / S / W or SAN / S emulsions. Such formulations may preferably also be a microemulsion (e.g. a PIT emulsion), a solid emulsions (ie an emulsion which is stabilized by solids, e.g. a Pickering emulsion), a sprayable emulsion or be a hydrodispersion. Furthermore, the preparations in the sense of the present invention can also be virtually water-free (water content below 5% by weight based on the total weight of the preparation.

The preparation according to the invention can be in the form of an aqueous phase in addition to water according to the invention also others Contain ingredients, for example alcohols, diols or polyols low C number, and their ethers, preferably ethanol, isopropanol, propylene glycol, Ethylene glycol, ethylene glycol monoethyl or monobutyl ether, propylene glycol monomethyl, monoethyl or monobutyl ether, Diethylene glycol monomethyl or monoethyl ether and analog products.

The oil phase of the preparation according to the invention, i.e. the lipophilic organic components become advantageous chosen from the group of polar oils, for example from the group of lecithins and fatty acid triglycerides, namely the triglycerol esters of saturated and / or unsaturated, branched and / or unbranched alkane carboxylic acids with a chain length of 8 to 24, especially 12 to 18 carbon atoms. The fatty acid triglycerides can for example, advantageously chosen are from the group of synthetic, semi-synthetic and natural oils, such as z. B. cocoglyceride, olive oil, Sunflower oil, Soybean oil, Peanut oil, rapeseed oil, almond oil, palm oil, coconut oil, castor oil, wheat germ oil, grape seed oil, safflower oil, evening primrose oil, macadamia nut oil and the like more.

According to the invention, z. B. natural Waxes of animal and vegetable origin, such as Beeswax and other insect waxes as well as berry wax, shea butter and / or Lanolin (wool wax).

Other advantageous polar oil components can in the sense of the present invention can also be selected from the group of Esters from saturated and / or unsaturated, branched and / or unbranched alkane carboxylic acids with a chain length of 3 to 30 carbon atoms and saturated and / or unsaturated, branched and / or unbranched alcohols with a chain length of 3 to 30 carbon atoms and from the group of esters from aromatic carboxylic acids and saturated and / or unsaturated, branched and / or unbranched alcohols with a chain length of 3 to 30 carbon atoms. Such ester oils can then advantageously chosen are selected from the group octyl palmitate, octyl cocoate, octyl isostearate, Octyldodeceyl myristate, octyl dodecanol, cetearyl isononanoate, isopropyl myristate, Isopropyl palmitate, isopropyl stearate, isopropyl oleate, n-butyl stearate, n-hexyl laurate, n-decyl oleate, isooctyl stearate, isononyl stearate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl laurate, 2-hexyldecyl stearate, 2-octyldodecyl palmitate, Stearyl heptanoate, oleyl oleate, olerlerucate, erucyl oleate, erucylerucate, Tridecyl stearate, tridecyl trimellitate, as well as synthetic, semi-synthetic and natural Mixtures of such esters, such as. B. Jojoba oil.

Furthermore, the oil phase can advantageously be chosen from the group of dialkyl ethers and dialkyl carbonates, advantageous are z. B. dicaprylyl ether (Cetiol OE) and / or dicaprylyl carbonate, for example that under the trade name Cetiol CC at Cognis available.

It is further preferred that the oil component from the group consisting of isoeicosane, neopentyl glycol, propylene glycol dicaprylate / dicaprate, caprylic / capric / diglyceryl succinate, butylene glycol dicaprylate / dicaprate, cocoglycerides (z. B. Myritol ^® 331 from Henkel), C _12-13 alkyl lactate , Di-C _12-13 alkyl tartrate, trüsostearin, dipentaerythrityl hexacaprylate / hexacaprate, propylene glycol monoisostearate, tricaprylin, dimethyl isosorbide. It is particularly advantageous if the oil phase of the formulations according to the invention has a content of C _12-15 alkyl benzoate or consists entirely of this.

Advantageous oil components are also e.g. B. butyloctyl salicylate (for example that available under the trade designation Hallbrite BHB Fa. CP Hall), hexadecyl and butyloctyl benzoate and mixtures thereof (Hall AB) and / or diethylhexyl (Corapan ^® TQ by Haarmann & Reimer).

Any mix of such oil and wax components are to be used advantageously for the purposes of the present invention.

The lipid phase can contain the polar oil components according to the invention in a Concentration of up to 40% by weight based on the total weight the lipid phase.

Furthermore, the oil phase can also be advantageous also non-polar oils contain, for example those which are selected from the group of branched and unbranched hydrocarbons and waxes, in particular Mineral oil, Vaseline (petrolatum), paraffin oil, Squalane and squalene, polyolefins, hydrogenated polyisobutenes and Isohexadecane. Among the polyolefins are polydecenes and hydrogenated ones Polyisobutenes are the preferred substances.

The oil phase can also be advantageous have a content of cyclic or linear silicone oils or completely such oils exist, although it is preferred, except the silicone oil or silicone oils one additional Content of other oil phase components to use.

werden auch als Polydimethylsiloxan bzw. Dimethicon (INCI) bezeichnet. Dimethicone gibt es in verschiedenen Kettenlängen bzw. mit verschiedenen Molekulargewichten.Silicone oils are high-molecular synthetic polymeric compounds in which silicon atoms are linked in a chain and / or network-like manner via oxygen atoms and the remaining valences of silicon by hydrocarbon residues (mostly methyl, more rarely ethyl, propyl, phenyl groups, etc.) are saturated. The silicone oils are systematically referred to as polyorganosiloxanes. The methyl-substituted polyorganosiloxanes, which are the most important compounds of this group in terms of quantity and are characterized by the following structural formula

are also known as polydimethylsiloxane or dimethicone (INCI). Dimethicone is available in different chain lengths or with different molecular weights.

Advantageous polyorganosiloxanes in For the purposes of the present invention, dimethylpolysiloxanes are examples [Poly (dimethylsiloxane)], which, for example, under the trade names Abil 10 to 10,000 are available from Th. Goldschmidt. Also advantageous are phenylmethylpolysiloxanes (INCI: Phenyl Dimethicone, Phenyl Trimethicones), cyclic silicones (octamethylcyclotetrasiloxane or Decamethylcyclopentasiloxane), which according to INCI also as Cyclomethicone amino modified silicones (INCI: Amodimethicone) and silicone waxes, e.g. B. Polysiloxane-Polyalkylene Copolymers (INCI: Stearyl Dimethicone and Cetyl Dimethicone) and Dialkoxydimethylpolysiloxane (Stearoxy Dimethicone and Behenoxy Stearyl Dimethicone) which are available from Th. Goldschmidt as different Abil-Wax types. But other silicone oils are also to be used advantageously for the purposes of the present invention, for example Cetyldimethicone, hexamethylcyclotrisiloxane, polydimethylsiloxane, Poly (methylphenylsiloxane).

It is advantageous according to the invention to use the lipophilic components of a preparation according to the invention as refatting substances. As moisturizing substances are used advantageously to choose, for example, such as PurCellin, Eucerit ^® and Neocerit® ^®.

It is also advantageous according to the invention if in the preparations according to the invention Thickeners can be used. These can be advantageous, for example can be selected from further compounds of the group of gums.

Gums include plant or tree sap that harden in the air and form resins or extracts from aquatic plants. From this group can can advantageously be chosen for the purposes of the present invention e.g. gum arabic, carob flour, tragacanth, karaya, Guar gum, pectin, gellan gum, carrageenan, agar, algine, chondrus, Xanthan gum.

The use of derivatized gums such as hydroxypropyl guar ( ^Jaguar® HP 8) is also advantageous.

The cosmetic advantageous according to the invention Preparations are characterized in that the guar or hydroxypropyltrimethylammonium chlorides a charge density of 0.4 to 1.0 meq / g and a molecular weight from 100,000 to 1,800,000. Preferred guar-hydroxypropyltrimethyl-ammonium chloride according to the invention come from the Jaguar series, the product is particularly preferred according to the invention Jaguar Excel from Rhodia.

It is advantageous according to the invention one or more guar hydroxypropyltrimethylammonium chlorides in a concentration of 0.01 to 10% by weight, preferably in a concentration of 0.01 to 2% by weight and very particularly preferably in a concentration of 0.01 to 0.5% by weight, in each case based on the total weight of the preparation.

Also advantageous according to the invention is the use of polysaccharides and derivatives.

Among the polysaccharides and derivatives are e.g. hyaluronic acid, Chitin and chitosan, chondroitin sulfates, starch and starch derivatives are advantageous according to the invention Thickener.

Also advantageous according to the invention is the use of cellulose derivatives.

Located among the cellulose derivatives e.g. Methyl cellulose, carboxymethyl cellulose, hydroxyethyl cellulose, Hydroxypropylmethylcellulose as an advantageous thickener according to the invention.

Also advantageous according to the invention is the use of layered silicates.

Layered silicates include naturally occurring and synthetic clays such as montmorillonite, bentonite, hectorite, laponite, magnesium aluminum silicates such as Veegum ^® . These can be used as such or in modified form as thickeners, such as stearylalkonium hectorites.

Silica gels can also be used advantageously be used.

Also advantageous according to the invention is the use of polyacrylates.

Located under the polyacrylates e.g. Carbopol types from Noveon (Carbopol 980, 981, 1382, 5984, 2984, ETD 2001, ETD 2020, ETD 2050 or Pemulen TR1 & TR2).

Also advantageous according to the invention is the use of polymers.

Among the polymers are e.g. Polyacrylamides (Seppigel 305), polyvinyl alcohols, PVP, PVP / VA copolymers, polyglycols.

It is advantageous according to the invention one or more thickening in a concentration of 0.1 to 5% by weight, based on the total weight of the preparation.

Furthermore, it can be advantageous according to the invention if salts are used in the preparations according to the invention to thicken the preparation, so that preparations with viscosities of 2000 mPas up to 6000 mPas can be produced. Salts are to be understood as meaning mono- or polyvalent alkali metal compounds or alkaline earth metal compounds with halogen anions. Sodium chloride is particularly preferably used.

It is advantageous according to the invention one or more alkyl salts or earth alkyl salts in a concentration from 0.1 to 3% by weight, based on the total weight of the preparation use.

The preparation according to the invention can advantageously contain one or more preservatives according to the invention. Advantageous preservatives for the purposes of the present invention are, for example, formaldehyde releasers (such as, for example, DMDM hydantoin, which is available, for example, from Lonza under the trade name Glydant ™), iodopropyl butyl carbamates (for example those under the trade names Glycacil-L, Glycacil -S available from Lonza and / or Dekaben LMB from Jan Dekker), parabens (ie alkyl p-hydroxybenzoate, such as methyl, ethyl, propyl and / or butyl paraben), phenoxyethanol, ethanol, benzoic acid and the like. According to the invention, the preservation system usually also advantageously includes preservation aids, such as, for example, octoxyglycerol, glycine soya, etc. The table below gives an overview of some preservatives which are advantageous according to the invention:

Are also advantageous in cosmetics common Preservatives or preservatives, such as dibromodicyanobutane (2-bromo-2-bromomethylglutarodinitrile), phenoxyethanol, 3-1od-2-propynyl butyl carbamate, 2-bromo-2-nitro-propane-1,3-diol, imidazolidinyl urea, 5-chloro-2-methyl-4-isothiazolin-3-one, 2-chloroacetamide, Benzalkonium chloride, benzyl alcohol, salicylic acid and salicylates.

It is special according to the invention preferred if iodopropyl butyl carbamates are used as preservatives, Parabens (methyl, ethyl, propyl and / or butyl paraben) and / or Phenoxyethanol can be used.

According to the invention, one or several preservatives in a concentration of 2% by weight or less than 2% by weight, preferably 1.5% by weight or less 1.5% by weight and particularly preferably 1% by weight or less 1% by weight, based in each case on the total weight of the preparation contain.

The preparation according to the invention advantageously contains one or more conditioners. Conditioning preferred according to the invention includes, for example, all compounds which are described in Section 4 below in the International Cosmetic Ingredient Dictionary and Handbook (Volume 4, publisher: RC Pepe, JA Wenninger, GN McEwen, The Cosmetic, Toiletry, and Fragrance Association, 9th edition, 2002) the keywords Hair Conditioning Agents, Humectants, Skin-Conditioning Agents, Skin-Conditioning Agents-Emollient, Skin-Conditioning Agents-Humactant, Skin-Conditioning Agents-Miscellaneous, Skin-Conditioning Agents-Occlusive and Skin Protectans are all listed in the EP 0934956 (P.11-13) under waten soluble conditioning agent and oil soluble conditioning agent. Some of these compounds are listed under the components of the aqueous phase and the oil phase. Further conditioners which are advantageous according to the invention are, for example, those based on the international nomenclature for cosmetic ingredients (INCI) compounds designated as polyquaternium (in particular polyquaternium-1 to polyquaternium-56).

Conditioners advantageous according to the invention from the group of polyquaternium compounds, for example the connections listed in the table.

Furthermore, it is in the sense of the present Invention, the preparation according to the invention Pearlescent pigments, mica and / or effect pigments to add to make the preparation more visually attractive.

The preparations according to the invention can be advantageous according to the invention contain one or more UV light protection filters.

Particularly advantageous at room temperature liquid UV filter substances in the sense of the present invention are homomenthyl salicylate (INCI: Homosalate), 2-ethylhexyl-2-cyano-3,3-diphenylacrylate (INCI: Octocrylene), 2-ethylhexyl-2-hydroxybenzoate (2-ethylhexyl salicylate, octyl salicylate, INCI: ethylhexyl salicylate) and esters of cinnamic acid, preferably 4-methoxycinnamic acid (2-ethylhexyl) ester (2-ethylhexyl-4-methoxycinnamate, INCI: ethylhexyl methoxycinnamate) and isopentyl 4-methoxycinnamate (Isopentyl-4-methoxycinnamate, INCI: Isoamyl p-methoxycinnamate) and polymeric UV filters such as the (3- (4- (2,2-bis-ethoxycarbonylvinyl) phenoxy) propenyl) methylsiloxane / dimethylsiloxane Copolymer, which, for example, at Hoffmann-La Roche under the Trade name Parsol SLX is available.

Preferred inorganic pigments are metal oxides and / or other metal compounds which are sparingly soluble or insoluble in water, in particular oxides of titanium (TiO ₂ ), zinc (ZnO), iron (e.g. Fe ₂ O ₃ ), zirconium (ZrOz), silicon (SiO ₂ ), manganese (e.g. MnO), aluminum (Al ₂ O ₃ ), cerium (e.g. Ce ₂ 0 ₃ ), mixed oxides of the corresponding metals as well as mixtures of such oxides and the sulfate of barium (BaSO ₄ ) ,

The pigments can be advantageous in the sense of present invention also in the form of commercially available oily or aqueous predispersions come into use. Dispersions can advantageously be used before these dispersions and / or solubilizing agents may be added.

The pigments can be advantageous according to the invention superficial treated ("coated"), for example a hydrophilic, amphiphilic or hydrophobic character is formed will or should be preserved. This surface treatment can consist of that the Pigments according to known methods with a thin hydrophilic and / or hydrophobic inorganic and / or organic layer be provided. The various surface coatings can be in According to the present invention also contain water.

Inorganic surface coatings in the sense of the present invention can consist of aluminum oxide (Al ₂ O ₃ ), aluminum hydroxide Al (OH) ₃ , or aluminum oxide hydrate (also: alumina, CAS no .: 1333-84-2), sodium hexametaphosphate (NaPO ₃ ) ₆ , sodium metaphosphate (NaPO ₃ ) _n , silicon dioxide (SiO ₂ ) (also: silica, CAS No .: 7631-86-9), barium sulfate (BaSO ₄ ) or iron oxide (Fe ₂ O ₃ ). These inorganic surface coatings can occur alone, in combination and / or in combination with organic coating materials.

Organic surface coatings in the sense of the present invention consist of vegetable or animal aluminum stearate, vegetable or animal stearic acid, Lauric acid, Dimethylpolysiloxane (also: Dimethicone), methylpolysiloxane (Methicone), Simethicone (a mixture of dimethylpolysiloxane with an average chain length from 200 to 350 dimethylsiloxane units and silica gel) or alginic acid. This organic surface coatings can alone, in combination and / or in combination with inorganic Coating materials occur.

Zinc oxide particles and predispersions of zinc oxide particles suitable according to the invention are available under the following trade names from the listed companies:

Suitable titanium dioxide particles and predispersions of titanium dioxide particles are available under the following trade names from the companies listed:

Advantageous UV-A filter substances for the purposes of the present invention are dibenzoylmethane derivatives, in particular 4- (tert-butyl) -4'-methoxydibenzoylmethane (CAS-Nr. 70356-09-1), marketed by Givaudan under the trade name Parsol ^® 1789 and is sold by Merck under the trade name Eusolex ^® 9020.

• – Phenylen-1,4-bis-(2-benzimidazyl)-3,3'-5,5'-tetrasulfonsäure und ihre Salze, besonders die entsprechenden Natrium-, Kalium- oder Triethanolammonium-Salze, insbesondere das Phenylen-1,4-bis-(2-benzimidazyl)-3,3'-5,5'-tetrasulfonsäure-bis-natriumsalz mit der INCI-Bezeichnung Disodium Phenyl Dibenzimidazole Tetrasulfonate (CAS-Nr.: 180898-37-7), welches beispielsweise unter der Handelsbezeichnung Neo Heliopan AP bei Haarmann & Reimer erhältlich ist;
• – Salze der 2-Phenylbenzimidazol-5-sulfonsäure, wie ihr Natrium-, Kalium- oder ihr Triethanolammonium-Salz sowie die Sulfonsäure selbst mit der INCI Bezeichnung Phenylbenzimidazole Sulfonsäure (CAS.-Nr. 27503-81-7), welches beispielsweise unter der Handelsbezeichnung Eusolex 232 bei Merck oder unter Neo Heliopan Hydro bei Haarmann & Reimer erhältlich ist;
• – 1,4-di(2-oxo-10-Sulfo-3-bornylidenmethyl)-Benzol (auch: 3,3'-(1,4-Phenylendimethylene)-bis-(7,7-dimethyl-2-oxo-bicyclo-[2.2.1]hept-1-ylmethan Sulfonsäure) und dessen Salze (besonders die entprechenden 10-Sulfato-verbindungen, insbesondere das entsprechende Natrium-, Kalium- oder Triethanolammonium-Salz), das auch als Benzol-1,4-di(2-oxo-3-bor nylidenmethyl-10-sulfonsäure) bezeichnet wird. Benzol-1,4-di(2-oxo-3-bornylidenmethyl-10-sulfonsäure) hat die INCI-Bezeichnung Terephtalidene Dicampher Sulfonsäure (CAS.-Nr.: 90457-82-2) und ist beispielsweise unter dem Handelsnamen Mexoryl SX von der Fa. Chimex erhältlich;
• – Sulfonsäure-Derivate des 3-Benzylidencamphers, wie z. B. 4-(2-Oxo-3-bornylidenmethyl)benzolsulfonsäure, 2-Methyl-5-(2-oxo-3-bornylidenmethyl)sulfonsäure und deren Salze.
• – Hydroxybenzophenon-Derivate, wie z.B. 2-(4-Diethylamino-2-hydroxybenzoyl)-benzoic acid hexylester, welches beispielsweise von der Firma BASF unter dem Handelsnamen Uvinul^® A Plus erhältlich ist.
• – Benzoxazol-Derivate, wie z.B. das 2,4-bis-[5-1(dimethylpropyl)benzossazol-2-y1-(4-phenyl)iminoJ-6-(2-ethylhexyl)-imino-1,3,5-triazine (CAS-Nr.: 288254-16-0), welches beispielsweise unter dem Handelsnamen UVASorb^® K2A von der Firma 3V Sigma erhältlich ist.

Advantageous further UV filter substances in the sense of the present invention are sulfonated, water-soluble UV filters, such as. B .:

• - Phenylene-1,4-bis (2-benzimidazyl) -3,3'-5,5'-tetrasulfonic acid and its salts, especially the corresponding sodium, potassium or triethanolammonium salts, especially the phenylene-1,4 -bis- (2-benzimidazyl) -3,3'-5,5'-tetrasulfonic acid bis-sodium salt with the INCI name Disodium Phenyl Dibenzimidazole Tetrasulfonate (CAS No .: 180898-37-7), which, for example, under the Trade name Neo Heliopan AP is available from Haarmann &Reimer;
• - Salts of 2-phenylbenzimidazole-5-sulfonic acid, such as its sodium, potassium or triethanolammonium salt and the sulfonic acid itself with the INCI name phenylbenzimidazole sulfonic acid (CAS No. 27503-81-7), which, for example, under the Trade name Eusolex 232 is available from Merck or under Neo Heliopan Hydro from Haarmann &Reimer;
• - 1,4-di (2-oxo-10-sulfo-3-bornylidenemethyl) benzene (also: 3,3 '- (1,4-phenylenedimethylene) -bis- (7,7-dimethyl-2-oxo bicyclo- [2.2.1] hept-1-ylmethane sulfonic acid) and its salts (especially the corresponding 10-sulfato compounds, especially the corresponding sodium, potassium or triethanolammonium salt), which is also called benzene-1,4- di (2-oxo-3-boronylmethyl-10-sulfonic acid) Benzene-1,4-di (2-oxo-3-bornylidenemethyl-10-sulfonic acid) has the INCI name Terephtalidene Dicampher Sulfonic Acid (CAS.- No .: 90457-82-2) and is available, for example, under the trade name Mexoryl SX from Chimex;
• - Sulfonic acid derivatives of 3-benzylidene camphor, such as. B. 4- (2-oxo-3-bornylidene methyl) benzenesulfonic acid, 2-methyl-5- (2-oxo-3-bornylidene methyl) sulfonic acid and salts thereof.
• - hydroxybenzophenone derivatives such as 2- (4-diethylamino-2-hydroxybenzoyl) -benzoic acid hexyl ester, which is obtainable for example by the company BASF under the trade name Uvinul A Plus ^® like.
• - Benzoxazole derivatives, such as, for example, 2,4-bis- [5-1 (dimethylpropyl) benzossazol-2-y1- (4-phenyl) iminoJ-6- (2-ethylhexyl) imino-1,3,5- , which is available for example under the trade name Uvasorb K2A ^® by the company 3V Sigma triazine (CAS-No .: 288254-16-0).

Advantageous UV filter substances in the sense of the present invention are also so-called broads band filter, ie filter substances that absorb both UV-A and UV-B radiation.

• – 2,4-Bis-{[4-(2-Ethyl-hexyloxy)-2-hydroxyJ-phenyl}-6-(4-methoxyphenyl)-1,3,5-triazin (INCI: Aniso Triazin), welches unter der Handelsbezeichnung Tinosorb^® S bei der CIBA-Chemikalien GmbH erhältlich ist;
• – Diethylhexylbutylamidotriazon (INCI: Diethylhexylbutamidotriazone), welches unter der Handelsbezeichnung UVASORB HEB bei Sigma 3V erhältlich ist;
• – 4,4',4''-(1,3,5-Triazin-2,4,6-triyltrümino)-tris-benzoesäure-tris(2-ethylhexylester), auch: 2,4,6-Tris-[anilino-(p-carbo-2'-ethyl-1'-hexyloxy)]-1,3,5-triazin (INCI: Ethylhexyl Triazone), welches von der BASF Aktiengesellschaft unter der Warenbezeichnung UVINUL^® T 150 vertrieben wird.

Advantageous broadband filters or UV-B filter substances are, for example, triazine derivatives, such as, for. B.

• - 2,4-bis - {[4- (2-ethyl-hexyloxy) -2-hydroxyJ-phenyl} -6- (4-methoxyphenyl) -1,3,5-triazine (INCI: Aniso triazine), which is listed under the trade name Tinosorb ^® S is available from CIBA-Chemicals GmbH;
• - Diethylhexylbutylamidotriazon (INCI: Diethylhexylbutamidotriazone), which is available under the trade name UVASORB HEB from Sigma 3V;
• - 4,4 ', 4''- (1,3,5-triazine-2,4,6-triyltrümino) -tris-benzoic acid-tris (2-ethylhexyl ester), also: 2,4,6-tris- [ anilino- (p-carbo-2'-ethyl-1'-hexyloxy)] - 1,3,5-triazine (INCI: ethylhexyl triazone), which is sold by BASF Aktiengesellschaft under the trade name UVINUL ^® T 150.

An advantageous broadband filter in the sense of the present invention is also the 2,2'-methylenebis (6- (2N-benzotriazol-2-yl) -4- (1,1,3,3-tetramethylbutyl) phenol), which is under the trade name Tinosorb ^® M is available from CIBA-Chemicals GmbH.

Another advantageous broadband filter for the purposes of the present invention is 2- (2H-benzotriazol-2-yl) -4-methyl-6- [2-methyl-3- [1,3,3,3-tetramethyl-1 - [( trimethylsilyl) oxy] disiloxanyl] propyl] - phenol (CAS no .: 155633-54-8) with the INCI name Drometrizole Trisiloxane, which is available under the trade name Mexoryl ^® XL from Chimex.

The other UV filter substances can be oil soluble or water soluble his.

• – 3-Benzylidencampher-Derivate, vorzugsweise 3-(4-Methylbenzyliden)campher, 3-Benzylidencampher;
• – 4-Aminobenzoesäure-Derivate, vorzugsweise 4-(Dimethylamino)-benzoesäure(2-ethylhexyl)ester, 4-(Dimethylamino)benzoesäureamylester;
• – Derivate des Benzophenons, vorzugsweise 2-Hydroxy-4-methoxybenzophenon, 2-Hydroxy-4-methoxy-4'-methylbenzophenon, 2,2'-Dihydroxy-4-methoxybenzophenon
• – sowie an Polymere gebundene UV-Filter.
• – 3-(4-(2,2-bis Ethoxycarbonylvinyl)-phenoxy)propenyl)-methoxysiloxan/Dimethylsiloxan – Copolymer welches beispielsweise unter der Handelsbezeichnung Parsol^® SLX bei Hoffmann La Roche erhältlich ist.

Advantageous oil-soluble UV-B and / or broadband filter substances in the sense of the present invention are e.g. B .:

• - 3-benzylidene camphor derivatives, preferably 3- (4-methylbenzylidene) camphor, 3-benzylidene camphor;
• - 4-aminobenzoic acid derivatives, preferably 4- (dimethylamino) benzoic acid (2-ethylhexyl) ester, 4- (dimethylamino) benzoic acid amyl ester;
• - Derivatives of benzophenone, preferably 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-methoxy-4'-methylbenzophenone, 2,2'-dihydroxy-4-methoxybenzophenone
• - As well as UV filters bound to polymers.
• - 3- (4- (2,2-bis ethoxycarbonylvinyl) phenoxy) propenyl) -methoxysiloxan / dimethylsiloxane - copolymer which is obtainable for example from Hoffmann La Roche under the trade name Parsol ^® SLX.

The list of UV filters mentioned, which can be used within the meaning of the present invention Of course not be limiting.

The UV light protection filter advantageous according to the invention are preferred in a concentration of 0.1 to 30% by weight, especially in a concentration of 0.5 to 15% by weight on the total weight of the formulation.

The preparation according to the invention can be advantageous according to the invention Contain glitter fabrics and / or other effect substances.

Advantageous embodiments of the cosmetic according to the invention Preparation are also characterized as being additional Ingredients opacifiers and / or pearlescent agents. According to the invention, substances are used as opacifiers and substance mixtures understood, which the preparation has a cloudy emulsion-like Give appearance.

As a pearlescent agent substances according to the invention and mixtures of substances understood that the preparation has an opalescent Give appearance. Mixtures are also advantageous according to the invention from turbidity and pearlescent agents.

• – PEG-3 Distearat (z.B. CUTINA TS der Firma Cognis),
• – eine Kombination aus Glycoldistearat, Glycerin, Laureth-4 und Cocamidopropylbetain (z.B. Euperlan PK 3000 und Euperlan PK 4000 der Firma Cogrtis),
• – eine Kombination aus Glycoldistearat, Cocosglucosiden, Glyceryloleat und Glycerylstearat (z.B. Lamesoft TM Benz der Firma Cognis).
• – Styrol/Acrylat Copolymere (z.B. Acusol OP 301 von Rohm & Haas)

Opacifiers / pearlescent agents or mixtures which are advantageous according to the invention include:

• - PEG-3 distearate (e.g. CUTINA TS from Cognis),
• A combination of glycol distearate, glycerol, laureth-4 and cocamidopropyl betaine (e.g. Euperlan PK 3000 and Euperlan PK 4000 from Cogrtis),
• - A combination of glycol distearate, cocosglucosides, glyceryl oleate and glyceryl stearate (eg Lamesoft TM Benz from Cognis).
• - styrene / acrylate copolymers (e.g. Acusol OP 301 from Rohm & Haas)

The preparation according to the invention can advantageously contain one or more antioxidants. The antioxidants are advantageously selected from the group consisting of amino acids (eg glycine, histidine, tyrosine, tryptophan) and their derivatives, imidazoles (eg urocanic acid) and their derivatives, peptides such as D, L-carnosine, D-carnosine, L-carnosine and their derivatives (e.g. anserine), carotenoids, carotenes (e.g. α-carotene, β-carotene, lycopene) and their derivatives, aurothioglucose, propylthiouracil and other thiols (e.g. thioredoxin, glutathione, cysteine, cystine, cystamine and their glycosyl, N- Acetyl, methyl, ethyl, propyl, amyl, butyl and lauryl, palmitoyl, oleyl, γ-linoleyl, cholesteryl and glyceryl esters) and their salts, dilaurylthiodipropionate, distearylthiodipropionate, thiodipropionic acid and their derivatives ( Esters, ethers, peptides, lipids, nucleotides, nucleosides and salts) and (metal) chelators (e.g. α-hydroxy fatty acids, palmitic acid, Phytic acid, lactoferrin), α-hydroxy acids (e.g. citric acid, lactic acid, malic acid), humic acid, bile acid, bile extracts, bilirubin, biliverdin, EDTA, EGTA and their derivatives, unsaturated fatty acids and their derivatives (e.g. γ-linolenic acid, linoleic acid, oleic acid), Folic acid and its derivatives, alanine diacetic acid, flavonoids, polyphenols, catechins, vitamin C and derivatives (e.g. ascorbyl palmitate, Mg ascorbyl phosphate, ascorbyl acetate), tocopherols and derivatives (e.g. vitamin E acetate), as well as coniferyl benzoate of the benzoin resin, rutinic acid and its acid Ferulic acid and its derivatives, butylated hydroxytoluene, butylated hydroxyanisole, nordihydroguajak resin acid, nordihydroguajaretic acid, trihydroxybutyrophenone, uric acid and its derivatives, mannose and its derivatives, zinc and its derivatives (e.g. ZnO, ZnSO ₄ ) selenium and its derivatives (e.g. stilbene methionine) eg stilbene oxide, trans-stilbene oxide) and the derivatives suitable according to the invention (salts, esters, Et forth, sugar, nucleotides, nucleosides, peptides and lipids) of these active ingredients.

The amount of antioxidants (a or more compounds) in the preparations is preferably 0.001 to 10 wt .-%, particularly preferably 0.025 - 2.0 wt .-%, in particular 0.05 - 1.0 % By weight, based on the total weight of the preparation.

The compositions contain according to the invention except the above-mentioned substances, if appropriate, those customary in cosmetics Additives, for example perfume, dyes, antimicrobial Lipid-replenishing substances Agents, complexing and sequestering agents, pearlescent agents, Antidandruff agents (e.g. selenium disulfide, zinc pyrithione, piroctone, Olamin, climbazole, octopirox, polydocanol and their combinations), Antiperspirant salts (e.g. acidic aluminum and / or aluminum / zirconium salts such as aluminum chlorohydrate and / or aluminum / zirconium chlorohydrate), Plant extracts, vitamins, active ingredients, peeling substances (abrasives, e.g. polymer beads or powder made of polyethylene, polypropylene etc. inorganic oxides, Silicates etc.). Can also in the hair straightening preparation (e.g. thioglycolates).

In particular, it is advantageous according to the invention the preparation according to the invention Add vitamins, plant extracts and UV light protection filters. For example, the addition of calcium-vitamin complexes (e.g. from γ-oryzanol and calcium salts such as calcium panthotenate, calcium chloride, calcium acetate) according to the invention particularly advantageous.

In addition, the active compounds according to the invention (one or more compounds) can also be selected very advantageously from the group of hydrophilic active compounds, in particular from the following group:
α-Hydroxy acids such as lactic acid or salicylic acid or their salts such as Na lactate, Ca lactate, TEA lactate, urea, allantoin, serine, sorbitol, glycerol, milk proteins, panthenol, chitosan, polydocanol.

The list of active ingredients mentioned or combinations of active ingredients in the preparations according to the invention can be used should go without saying not be limiting. The active ingredients can be individual or in any Combinations with each other can be used.

The amount of such active substances (a or more compounds) in the preparations according to the invention is preferably 0.001 to 30% by weight, particularly preferably 0.05-20% by weight, especially 1-10 % By weight, based on the total weight of the preparation.

The in the preparations according to the invention incorporated active ingredients serve among other things for prophylaxis and / or Treatment of inflammatory skin conditions and / or for skin protection in sensitive and dry skin Skin (such as atopic eczema, seborrheic eczema, polymorphic Light dermatosis, psoriasis, vitiligo, wound healing disorders, Itching, sensitive or irritated skin, light-related skin damage and UV-induced immunosuppression, changes in desquamation, changes normal fibroblast and keratinocyte proliferation, changes normal fibroblast and keratinocyte differentiation deficit sensitive or hypoactive skin conditions or loss-making sensitive or hypoactive conditions of skin appendages and to reduce skin thickness).

The preparations according to the invention provide in extremely in every respect satisfactory preparations, which is not limited to the raw material selection mentioned in this document are.

According to the invention, it is advantageous if the cosmetic according to the invention Preparation kept in a bottle or squeeze bottle and be applied out of this. Bottles are corresponding or squeeze bottles containing a preparation according to the invention, according to the invention.

The preparation according to the invention can be advantageous according to the invention as a watering be applied to a substrate. The substrates according to the invention can smooth or surface structured his. Preferred according to the invention are surface structured Substrates.

The combination is also in accordance with the invention from the cosmetic according to the invention and / or dermatological preparation and an insoluble one Substrate.

In the substrates according to the invention can the fabric formation by warp and weft, by stitch formation or by intertwining, and / or cohesive and / or adhesive connection of textile fibers. It is preferred according to the invention if the substrate is a composite.

Substrates are preferred according to the invention in the form of towels used, which consist of fleece, in particular from hydroentangled and / or water jet embossed Fleece. The substrates can advantageously also be designed as a bulk, perforated fleece or net.

Such substrates can be used for macro embossing desired Have patterns. The selection to be made is based on the one hand after the impregnation to be applied and on the other hand according to the field of application on which the subsequent cloth Should be used.

It has proven to be advantageous for the cloth if it has a weight of 20 to 120 g / m ² , preferably 30 to 80 g / m ^2, particularly preferably 40 to 60 g / m ² (measured at 20 ° C. ± 2 ° C and with a humidity of 65% ± 5% for 24 hours).

The thickness of the substrate is preferably 0.2 mm to 2 mm, in particular 0.4 mm to 1.5 mm, very particularly preferably 0.6 mm to 0.9 mm.

As raw materials for the nonwoven of the cloth generally all organic and inorganic fibers on natural and synthetic base can be used. Examples include viscose, cotton, Cellulose, jute, hemp, sisal, silk, wool, polypropylene, polyester, Polyethylene terephthalate (PET), aramid, nylon, polyvinyl derivatives, Polyurethanes, polylactide, polyhydroxyalkanoate, cellulose esters and / or Polyethylene as well as mineral fibers such as glass fibers or carbon fibers cited. However, the present invention is not based on the materials mentioned limited, but can a large number of other fibers can be used to form the fleece. It is particularly advantageous for the purposes of the present invention if the fibers used are not water-soluble.

In an advantageous embodiment of the fleece, the fibers consist of a mixture of 60% to 80% viscose with 40% to 20% PET, especially 70% viscose and 30 % PET. A mixture of 70% viscose and is particularly advantageous 30% PET.

A fleece according to the invention can be advantageous according to the invention have a mixture of three different fiber materials. In In such a case, a mixture of 40% to 80% viscose is included 50% to 20% PET and 1 to 30% cotton preferred. According to the invention particularly a mixture of 40% viscose and 50% PET and 10 is preferred % Cotton.

Fibers are also particularly advantageous made of high-strength polymers such as polyamide, polyester and / or highly stretched Polyethylene.

In addition, the Fibers also dyed to emphasize the visual attractiveness of the fleece and / or increase to be able to. The fibers can additionally Contain UV stabilizers and / or preservatives.

The ones used to form the cloth Fibers preferably have a water absorption rate greater than 60 mm / [10 min] (measured with the EDANA test 10.1-72), in particular more than 80 mm / [10 min].

Furthermore, the formation of the Fibers used preferably have a water absorption capacity of more than 5 g / g (measured with the EDANA test 10.1-72), in particular more than 8 g / g.

Advantageous wipes in the sense of the present invention have a tear strength of in particular

The stretchability of advantageous cloth is preferably

In a special according to the invention Dosage form of such substrates according to the invention, the substrate after impregnation be dried with the preparation and then the Presented to users in the form of a dry cleaning cloth become.

The preparation according to the invention can be advantageous stored in a foam dispenser and applied out of it becomes. The foam dispenser can be advantageous according to the invention a mechanical pump dispenser (Pumpfoamer) or an aerosol can. act.

The preparations according to the invention can be advantageous according to the invention foamed with a propellant become. This is according to the invention in an amount of 0.5 to 20% by weight, especially advantageous in an amount of 5 to 15 and very particularly advantageous in an amount of 8 to 11% by weight, based in each case on the Total weight of the formulation used. According to the invention particularly advantageous propellants are propane, isobutane and n-butane and their Mixtures.

Of course, the specialist knows that it is there are non-toxic propellants that are essential for the realization of the present Invention in the form of aerosol preparations would be suitable to which, however, because of harmful effects on the environment or other circumstances should be avoided, especially fluorocarbons and Chlorofluorocarbons (CFCs).

The use of the cosmetic according to the invention is according to the invention and / or dermatological preparation for cleaning and / or care the skin and skin appendages.

The use of the cosmetic according to the invention is according to the invention and / or dermatological preparation as shower, foam and / or Bath.

The use of the cosmetic according to the invention is according to the invention and / or dermatological preparation as a hair shampoo.

The use of the cosmetic according to the invention is according to the invention and / or dermatological preparation as shaving cream.

The use of the cosmetic according to the invention is according to the invention and / or dermatological preparation as a facial cleansing preparation for removing decorative cosmetics.

The use of the cosmetic according to the invention is according to the invention and / or dermatological preparation for cleaning and washing garments and textiles ("detergents").

The use of the cosmetic according to the invention is according to the invention and / or dermatological preparation for cleaning objects of the daily Life (e.g. dishes, table and cabinet surfaces, cars).

The use of the cosmetic according to the invention is according to the invention and / or dermatological preparation for cleaning and care of Mammals' skins and coats of hair, especially of domestic and farm animals (e.g. dogs; cats, rodents, Horses, cows, Etc.).

The use of the cosmetic according to the invention is according to the invention and / or dermatological preparation for controlling aphids and scale insects, in particular if this is on the leaves of ornamental and useful plants.

Last but not least is the use cosmetic or dermatological preparations for prophylaxis and / or treatment of inflammatory skin conditions and / or for skin protection in sensitive and dry skin Skin according to the invention.

The following examples are intended illustrate the present invention without restricting it. All Unless otherwise stated, quantities, proportions and percentages are the same specified, on the weight and the total amount or on the total weight of the preparations related.

Formulation examples: formulations for shower gels

Recipes for shower emulsions

Recipes for Pumpoamer:

Recipes for post-foaming gel

Formulations for soaps 1) Basic soap

2) Color slurry

The basic soap noodles are made with the color slurry and the rest Components in a standard soap mixer (Screw mixer with perforated sieve) dosed by repeated mixing homogenized, over a Extruded press discharged, cut and processed into pieces in the usual way.

Recipes for Syndets 1) Basic soap:

The basic soap noodles are made with the rest Components in a usual Soap mixer (screw mixer with perforated sieve) dosed by repeated Mix homogenized, over extruded, cut and in the usual way Way to pieces processed

Recipes for shampoos

Recipes for gel shower preparations

Recipes for shower oils

Recipes for 2-phase baths

Formulations for shaving foams

Recipes for shaving gels

Sample formulations for impregnation media for substrates

Claims (20)

Cosmetic and / or dermatological preparation containing a combination of one or more saccharide-N-alkylurethanes and one or more surfactants, in addition to any other cosmetic and / or dermatological active ingredients, auxiliaries and additives. Cosmetic and / or dermatological preparation according to claim 1, characterized in that as one or more Saccharide oligo- and / or polysaccharides can be used. Cosmetic and / or dermatological preparation according to one of the claims 1 or 2, characterized in that one or more as saccharide Polyfructosane (fructans) can be used. Cosmetic and / or dermatological preparation according to one of the claims 1 to 3, characterized in that inulin is used as saccharide becomes. Cosmetic and / or dermatological preparation according to one of claims 1 to 4, characterized in that the degree of polymerization of the polysaccharide is at least 3 and the substitution degree of N-alkyl urethanes is selected from the range 0.1 to 2.0. Cosmetic and / or dermatological preparation according to one of the claims 1 to 5, characterized in that the alkyl radical of the N-alkylurethane groups is formed from linear or branched, saturated or unsaturated Alkyl groups with a carbon number of 3 to 22 carbon atoms, where all N-alkyl urethane groups a saccharide consist of the same or different N-alkyl urethane groups can. Cosmetic and / or dermatological preparation according to one of the claims 1 to 6, characterized in that the total amount of saccharide-N-alkylurethanes from 0.05 to 10% by weight, based on the total weight of the preparation is. Cosmetic and / or dermatological preparation according to one of the claims 1 to 7, characterized in that the surfactants are anionic, cationic and / or amphoteric surfactants are used. Cosmetic and / or dermatological preparation according to one of the claims 1 to 8, characterized in that the. Total amount of surfactants from 1 to 50% by weight, based on the total weight of the preparation is. Cosmetic and / or dermatological preparation according to one of the claims 1 to 9, characterized in that the ratio of the total amount of saccharides to the total amount of surfactants from 1: 1000 to 10: 1, preferably from 1: 300 to 1: 1 and very particularly preferably from 1: 100 to 1: 5. Cosmetic and / or dermatological preparation according to one of the claims 1 to 10, characterized in that sodium laureth sulfate as Surfactant used alone or in combination with other surfactants becomes. Cosmetic and / or dermatological preparation according to one of the claims 1 to 10, characterized in that one or more fatty acids and / or their salts as a surfactant alone or in combination with other surfactants is used. Cosmetic and / or dermatological preparation according to one of the claims 1 to 12, characterized in that they are in a foam dispenser stored and used from there. Cosmetic and / or dermatological preparation according to one of the claims 1 to 12, characterized in that they are used as an impregnation for an insoluble Substrate is used. Combination of a cosmetic and / or dermatological Preparation according to one of the claims 1 to 12 and an insoluble one Substrate. Use of a cosmetic and / or dermatological Preparation according to one of the preceding claims for cleaning and / or Care of the skin and skin appendages. Use of a cosmetic and / or dermatological Preparation according to one of the preceding claims as a shower, foam and / or Bath. Use of a cosmetic and / or dermatological Preparation according to one of the preceding claims as a hair shampoo. Use of a cosmetic and / or dermatological Preparation according to one of the preceding claims as a shaving cream. Use of a cosmetic and / or dermatological Preparation according to one of the preceding claims as a facial cleansing preparation for removing decorative cosmetics.