DE2005076A1 - Thick, dough-like product intended for direct coloring of keratin fibers and especially hair - Google Patents

Thick, dough-like product intended for direct coloring of keratin fibers and especially hair

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Publication number
DE2005076A1
DE2005076A1 DE19702005076 DE2005076A DE2005076A1 DE 2005076 A1 DE2005076 A1 DE 2005076A1 DE 19702005076 DE19702005076 DE 19702005076 DE 2005076 A DE2005076 A DE 2005076A DE 2005076 A1 DE2005076 A1 DE 2005076A1
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DE
Germany
Prior art keywords
microcapsules
dough
product according
cosmetic product
keratin fibers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DE19702005076
Other languages
German (de)
Inventor
Roger Soisy; Kalopissis Gregoire Paris; Zviak Charles Franeonville; Charle (Frankreich)
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Individual
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Individual
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Publication date
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Publication of DE2005076A1 publication Critical patent/DE2005076A1/en
Pending legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/11—Encapsulated compositions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/35—Ketones, e.g. benzophenone
    • A61K8/355—Quinones
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A61K8/411—Aromatic amines, i.e. where the amino group is directly linked to the aromatic nucleus
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A61K8/415—Aminophenols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/10—Preparations for permanently dyeing the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/41—Particular ingredients further characterized by their size
    • A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns

Description

PATENTANWÄLTEPATENT LAWYERS PROF. DR. DR. J. REITSTÖTTER 0 Π Π C Π 7 CPROF. DR. DR. J. REITSTÖTTER 0 Π Π C Π 7 C DR.-ING. WOLFRAM BUNTE /UUOU/ODR.-ING. WOLFRAM BUNTE / UUOU / O DR. KARL GEORG LÖSCHDR. KARL GEORG LÖSCH

D - 8OOO MÜNCHEN 13, BAUERSTRASSE 22. FERNRUF (ΟΘ11) 37 65 83D - 8OOO MUNICH 13, BAUERSTRASSE 22. FERNRUF (ΟΘ11) 37 65 83

München, den M/11007Munich, M / 11007

L·OREAL
14, rue Royale, Paris 8e, PrankreichL · OREAL
14, rue Royale, Paris 8e, France

Dickflüssiges teigartiges Produkt, das für die direkte Färbung von Keratinfasern und insbesondere von Haaren bestimmt istThick, dough-like product that is used for direct coloring of keratin fibers and especially of Hair is intended

Es kann bekanntlich ein Interesse daran bestehen, die Färbung von Haaren, Wimpern, Augenbrauen und allgemein von Keratinfasern direkt und lokalisiert bewirken zu können.As is well known, there can be interest in the coloring of hair, eyelashes, eyebrows and, in general, of keratin fibers to be able to bring about a direct and localized effect.

Erfindungsgemäß wird ein dickflüssiges teigartiges Produkt beschrieben, das beispielsweise als Stab, Stift oder auch als mit einer feuchten Bürste verwendbare kleine Platte konditioniert ist, das die direkte lokalisierte Färbung von Keratinfasern erlaubt.According to the invention, a viscous dough-like product is described, for example as a stick, stick or as A small plate that can be used with a damp brush is conditioned, which directs localized staining of keratin fibers permitted.

Die vorliegende Erfindung betrifft somit ein neues dickflüssiges, teigartiges kosmetisches Produkt, das für die direkte Färbung von Keratinfasern verwendbar ist, welches im wesentlichen dadurch gekennzeichnet ist, daS es in einem teigartigenThe present invention thus relates to a new viscous, dough-like cosmetic product that is used for direct Coloring of keratin fibers can be used, which is essentially characterized in that it is in a dough-like manner

— 1 —- 1 -

D 0 9 8 3 2 / 1 0 j 5D 0 9 8 3 2/1 0 j 5

Μ/11ΌΟ7Μ / 11ΌΟ7

Träger vom klassischen Typ Mikrokapseln mit Dimensionen zwischen 50 und 800/u enthält, die mindestens einen Farbstoff mit einer für die Keratinfasern geeigneten Affinität enthalten, bei dem die gleichzeitige Verwendung eines Oxydationsmittels nicht erforderlich ist, damit die gewünschte Farbe in Erscheinung tritt.Carrier of the classic type microcapsules with dimensions between 50 and 800 / u containing at least one dye with an affinity suitable for the keratin fibers, in which the simultaneous use of an oxidizing agent is not necessary for the desired color to appear.

Das erfindungsgemäße Produkt erlaubt somit die direkte lokalisierte Anwendung von Direktfarbstoffen oder von Schnelloxydationsfarbstoffen, bei denen die Färbung durch Umsetzung mit Sauerstoff aus der Luft auftritt. Bei einer vorteilhaften Ausführungsform enthält jede Mikrokapsel des erfindungsgemäßen Produkts eine einzige chemische Verbindung, wobei die erhaltene Gesamtzusammensetzung in dem erfindungsgemäßen Produkt aus einer Mischung von Mikrokapseln entsprechend jedem der gewünschten Produkte besteht. Eine der charakteristischen Eigeeschaften des erfindungsgemäßen Produkts besteht darin, daß es im Verlauf der Zeit vollständig unverändert bleibt, da die in dem Produkt enthaltenen Farbstoffe in Mikrokapseln konditioniert sind, was diese gegenüber dem Außenmedium und den Bestandteilen des Trägers isoliert, so daß die Farbstoffe keinerlei Verschlechterung im Verlauf der Zeit vor ihrer Anwendung auf die Keratinfasern, die man zu färben wünscht, unterliegen.The product according to the invention thus allows direct localized Use of direct dyes or rapid oxidation dyes, in which the color occurs through reaction with oxygen from the air. In an advantageous embodiment each microcapsule of the product according to the invention contains a single chemical compound, the obtained Overall composition in the product according to the invention from a mixture of microcapsules corresponding to each of the desired ones Products. One of the characteristic proprietary businesses of the product according to the invention is that it remains completely unchanged over time, since the The dyes contained in the product are conditioned in microcapsules, what these are compared to the external medium and the constituents of the support so that the dyes do not deteriorate with the lapse of time prior to their use on the keratin fibers that one wishes to dye, are subject to.

Die Präsentation des erfindungsgemäßen Produkts kann in Form eines Stabes oder Stiftes erfolgen, die eine direkte lokalisierte Anwendung erlauben, oder in Form einer kleinen Platte, die mittels einer feuchten Bürste verwendet werden kann, oder in Form einer Papierserviette, die mit erfindungsgemäßen Produkt bedeckt ist. Die Applikation der Farbstoffe, die Keratinfasern, wie Haaren, Wimpern oder Augenbrauen, Farbe verleihen sollen, erfolgt durch Zerplatzen der Mikrokapseln in dem Moment, in dem der Benutzer das erfindungsgemäße kosmetische Produkt auf die zu färbenden Keratinfasern drückt.The presentation of the product according to the invention can take place in the form of a stick or pencil, which localizes a direct Allow application, or in the form of a small plate that can be used with a damp brush, or in the form of a paper napkin covered with the product according to the invention. The application of the dyes, the keratin fibers, how hair, eyelashes or eyebrows are supposed to give color, is done by bursting the microcapsules at the moment in which the user presses the cosmetic product according to the invention onto the keratin fibers to be colored.

009832/1935009832/1935

M/11007 J M / 11007 J.

Die Konditionierung in Mikrokapseln kann mittels jeder geeigneten bekannten Arbeitsweise und insbesondere durch Zentrifugieren des Farbstoffanteiles in Mikrοtröpfchen durch einen flüssigen Film erfolgen, der dazu bestimmt ist, nach der Verfestigung die Wand der Mikrokapseln zu bilden. Wenn der zu mikroverkapselnde Färbstoffanteil aus einer Mischung von Pulvern gebildet wird, kann man auch ein Vakuum-Umhüllungsverfahren verwenden, durch Verflüchtigung des Produkts, das die Wand bilden soll, im Vakuum und Ablagerung dieses Produkts auf den Mikroteilchen der Farbstofffraktion. Für die Bildung der Wände der Mikrokapseln können alle geeigneten Materialien verwendet werden, die nicht mit dem dickflüssigen teigartigen Träger des erfindungsgemäflen kosmetischen Produkts reagieren, insbesondere Polyäthylen mit niedrigem Schmelzpunkt und Celluloseacetophthalat. Das Gewicht der Materialien, die die Wand der Mikrokapseln bilden, liegt im allgemeinen unter IC Gew.-^ der mikroverkapselten Farbstofffraktion.Conditioning in microcapsules can be carried out using any suitable known method and in particular by centrifugation of the dye content in micro-droplets through a liquid film, which is intended to form the wall of the microcapsules after solidification. If the to microencapsulating dye component from a mixture of powders A vacuum encapsulation process can also be used by volatilizing the product that forms the wall is supposed to form, in vacuum and deposition of this product on the microparticles of the dye fraction. For the formation of the walls of the microcapsules, any suitable materials can be used that are not compatible with the viscous dough-like carrier of the cosmetic product according to the invention react, in particular Low melting point polyethylene and cellulose acetophthalate. The weight of the materials that make up the wall of the Forming microcapsules is generally below IC wt .- ^ the microencapsulated dye fraction.

Zur weiteren Veranschaulichuni" der Erfindung werden nachfolgend als Beispiele drei Mißführnngsfnrmon beschriften, die die vorliegende Erfindung jedoch in !'.einer Veino 1 eschranken sollen.In order to further illustrate the invention, three examples of misappropriation are given below, which, however, are intended to limit the present invention in one category.

Beispiel 1example 1

Haarfärbemittel in Form oiue» :>1 j*le£ Hair dye in the form o iue » : > 1 j * le £

Der teigartige-Träpfr der er1 iri ι ρ ••«irußon kopmelifchoti Pro dukts hat folgerte ZuFamriniBi-i yr.v:The dough-like-Träpfr der er 1 iri ι ρ •• «irußon kopmelifchoti product has concluded ZuFamriniBi-i yr.v:

Natriumstearat β r Sodium stearate β r

Sorbitsirup 5,5 fSorbitol syrup 5.5 f

Wasser J, 7Water J, 7

Alkohol "75,?;-.Alcohol "75,?; -.

Parfüm 2,3 fPerfume 2,3 f

'■> 0 9 8 3 2 / 1 9 3 5'■> 0 9 8 3 2/1 9 3 5

BAD ORlQlNAI.BAD ORlQlNAI.

Es werden Mikrokapseln mit mittleren Dimensionen von etwa 300 /u hergestellt. Die Wand dieser Mikrokapseln besteht aus Celluloseacetophthalat. In diesen Mikrokapseln werden isoliert die folgenden Produkte konditioniert: Aminohydrochinonhydrochlorid, 3-Methylaπ]ino-l,4-dihydroxybenzolhydrobromid, 2-Methyl-4T6-diaminophenolsulfat, 4-Methoxy-2-aminophenolhydrochlorid, 2,5-Diamino-4-methylphenoldihydrochlOΓidf 4-N1N-Diäthylamino-2,6-diaminophenoltrihydrochlorid, reines, trockenes Natriumcarbonat. Die so erhaltenen Mikrokapseln werden dann in den der folgenden Formulierung entsprechenden Verhältnissen gemischt:Microcapsules with average dimensions of about 300 / u are produced. The wall of these microcapsules is made of cellulose acetophthalate. The following products are isolated in these microcapsules conditioned: Aminohydroquinone hydrochloride, 3-Methylaπ] ino-1,4-dihydroxybenzene hydrobromide, 2-methyl-4 T 6-diaminophenol sulfate, 4-methoxy-2-aminophenol hydrochloride, 2,5-diamino-4- methylphenoldihydrochlOΓid f 4-N 1 N-diethylamino-2,6-diaminophenol trihydrochloride, pure, dry sodium carbonate. The microcapsules thus obtained are then mixed in the proportions corresponding to the following formulation:

Aminohydrochinonhydrochlorid, mikroverkapselt 0,28 gAminohydroquinone hydrochloride, microencapsulated 0.28 g

3-Methylamino-l,4-dihydroxybenzolhydrobromid, mikroverkapselt 0,34 g3-methylamino-1,4-dihydroxybenzene hydrobromide, microencapsulated 0.34 g

2-Methyl-4,6-diaminophenolsulfat, mikroverkapselt 0,96 g 4-Methoxy-2-amlnophenolhydrochlorid, mikroverkapselt 1,08 g 2,5-Diamino-4-methylphenoldihydΓOchlorid, mikrover-2-methyl-4,6-diaminophenol sulfate, microencapsulated 0.96 g 4-methoxy-2-aminophenol hydrochloride, microencapsulated 1.08 g 2,5-diamino-4-methylphenol dihydric chloride, micro-

kapselt 0,32 gencapsulates 0.32 g

4-N,N-Diäthylamino-2,6-diaminophenoltrihydrochlorid, mikroverkapselt 0,40 g4-N, N-diethylamino-2,6-diaminophenol trihydrochloride, microencapsulated 0.40 g

Natriumcarbonat, rein, trocken, mikroverkapselt 0,28 gSodium carbonate, pure, dry, microencapsulated 0.28 g

Diese Mischung von Mikrokapseln wird zu dem Träger gegeben und es wird berste Homogenität des Ganzen sichergestellt. Das erhaltene Produkt wird in Form eines Stabes konditioniert.This mixture of microcapsules is added to the carrier and complete homogeneity is ensured. That product obtained is conditioned in the form of a stick.

Wenn man den so hergestellten Stab auf Haaren reibt, die etwa 50 % weiße Haare enthalten, so erzielt man durch Reibung das Zerplatzen der an der Oberfläche dec Stabes in dem Bereich, in dem die Reibung stattfindet, engeordneten Mikrokapseln. Die Mischung von Farbptoffen kommt dann mit den Haaren in Berührung, gegenüber denen diese eine gute Affinität besitzen, und die Mischung der Farbstoffe kommt gleichzeitig mit Luft in Berührung. Auf den Haaren tritt an der Stelle, an der der Stab gerieben worden ist, eine dunkelblonde Färbung in Erscheinung.If the rod produced in this way is rubbed on hair which contains about 50 % white hair, the microcapsules arranged on the surface of the rod in the area in which the friction takes place bursts through friction. The mixture of dyes then comes into contact with the hair, towards which the hair has a good affinity, and the mixture of dyes comes into contact with air at the same time. A dark blonde color appears on the hair where the stick has been rubbed.

009832/1935009832/1935

Beispiel 2Example 2

Stab für die Färbung der AugenbrauenRod for coloring the eyebrows

Der teigartige Träger des erfindungsgemäßen kosmetischen Produkts hat folgende Zusammensetzung:The dough-like carrier of the cosmetic product according to the invention has the following composition:

weißes Ceresin (Schmelzpunkt 670C) 25 g hydriertes Baumwollsamenöl 5 gwhite ceresin (melting point 67 ° C.) 25 g hydrogenated cottonseed oil 5 g

Rizinusöl 43 g Camauba-Wachs 4,5 gCastor oil 43 g Camauba wax 4.5 g

Mineralöl (75/85) 6g |Mineral oil (75/85) 6g |

Es werden Mikrokapseln mit mittleren Dimensionen von etwa 100/U hergestellt. Die Wand dieser Mikrokapseln besteht aus Celluloseacetophthalat. In diesen Mikrokapseln werden isoliert folgende Produkte konditioniert: Aminohydrochinonhydrochlorid, 3-Methylamino-1,4-dihydroxybenzolhydrobromid, 2-Methyl-4r6-diaminophenolsulfat, 4-Methoxy-2-aminophenolhydrochlorid, 4-N,N-Biäthylamino-2,6-diaminophenoltrihydrochlorid, 2-Amlno-4-N-methylaminophenölsulfat, Natriumcarbonat.Microcapsules with average dimensions of about 100 / U are produced. The wall of these microcapsules is made of Cellulose acetophthalate. The following products are isolated in these microcapsules: Aminohydroquinone hydrochloride, 3-methylamino-1,4-dihydroxybenzene hydrobromide, 2-methyl-4r6-diaminophenol sulfate, 4-methoxy-2-aminophenol hydrochloride, 4-N, N-bioethylamino-2,6-diaminophenol trihydrochloride, 2-Amino-4-N-methylaminophenöl sulfate, Sodium.

Die so erhaltenen Mikrokapseln werden derart gemischt, daß sich folgende Formulierung ergibt:The microcapsules obtained in this way are mixed in such a way that the following formulation results:

Aminohydrochinonhydrochlorid, mikroverkapselt 0,5 gAminohydroquinone hydrochloride, microencapsulated 0.5 g

3-Methylamino-1,4-dihydroxybenzolhydrobromid, mikro verkapselt 0,8 g3-methylamino-1,4-dihydroxybenzene hydrobromide, micro encapsulated 0.8 g

2-Methyl-4,6-diaminophenolsulfat, mikroverkapselt 1,2 g 4-Methoxy-2-aminophenDihydrochiorid, mikroverkapselt 1,5 g 4-N,N-Diäthylamino-2,6-dlaminophenoltrihydrochlorid, mikroverkapselt 1 g2-methyl-4,6-diaminophenol sulfate, microencapsulated 1.2 g 4-methoxy-2-aminophendihydrochloride, microencapsulated 1.5 g 4-N, N-diethylamino-2,6-dlaminophenol trihydrochloride, microencapsulated 1 g

2-Amino-4-N-methylaminophenolsulfat, mikroverkapselt 2,5 g Natriumcarbonat, mikroverkapselt 5 g2-Amino-4-N-methylaminophenol sulfate, microencapsulated 2.5 g Sodium carbonate, microencapsulated 5 g

Diese Mischung von Mikrokapseln wird zu dem hergestellten Träger hinzugefügt und es wird beste Homogenität des GanzenThis mixture of microcapsules is added to the prepared carrier and there will be the best homogeneity of the whole

009832/1 935009832/1 935

realisiert. Das erhaltene Produkt wird in Form eines Stabes konditioniert.realized. The product obtained is conditioned in the form of a stick.

Wenn »mn den so hergestellten Stab auf blonden oder teilweise weißen Augenbrauen reibt, so erzielt man durch die Heibung das Zerplatzen von Mikrokapseln, die sich auf der Oberfläche des Stabes in der Zone befinden, wo die Reibung stattfindet. Die Farbstoffmischung kommt dann mit den Augenbrauen in Berührung, gegenüber denen sie eine gute Affinität besitzt, und kommt gleichzeitig mit der Luft in Berührung. Auf diese Weise tritt bei den Augenbrauen an der Stelle, an der mit den Stab gerieben worden ist, eine dunkelbraune Fätobung auf.If you rub the stick made in this way on blond or partially white eyebrows, you achieve that by heating Rupture of microcapsules located on the surface of the rod in the zone where the friction takes place. The dye mixture then comes into contact with the eyebrows, towards which it has a good affinity, and comes into contact with the air at the same time. In this way, the eyebrow occurs at the point where the rod has been rubbed, a dark brown discoloration.

Beispiel 5Example 5

Für die Färbung der Wimpern und der Augenbrauen bestimmte klei ne Platte A small plate designed for coloring the eyelashes and eyebrows

In einer ersten Stufe wird die Mischung der folgenden Produkte hergestellt:In a first stage, the mixture of the following products is made:

Stearinsäure (U.S.P. Dreifachdruck) 9fl gStearic acid (USP triple printing) 9 f lg Vaseline (Schmelzpunkt 430C) 5,5 gVaseline (melting point 43 ° C.) 5.5 g Mineralöl (65/75) 9,1 gMineral oil (65/75) 9.1 g

In einer zweiten Stufe werden Mikrokapseln mit mittleren Dimensionen von etwa 200/u hergestellt, wobei die Wände dieser Mikrokapseln aus Celluloseacetophthalat bestehen.In a second stage, microcapsules with mean dimensions of about 200 / u are produced, the walls of which Microcapsules are made from cellulose acetophthalate.

In diesen Mikrokapseln werden isoliert folgende Produkte kon- / ditioniert: quaternäres Ammoniumdisulfat von 2-Aminobenzthiazol-N-äthyl-N-piperidinoäthylanilin, Natriumcarbonat. Die so erhaltenen Mikrokapseln werden derart gemischt, daß sich folgende Formulierung ergibt:The following products are isolated in these microcapsules ditioned: quaternary ammonium disulfate of 2-aminobenzothiazole-N-ethyl-N-piperidinoethylaniline, sodium carbonate. The so The microcapsules obtained are mixed in such a way that the following formulation results:

009832/1935009832/1935

M/11007 *M / 11007 *

quaternäres Ammoniumdisulfat von 2-Aminobenzthiazol-N-äthyl-N-piperidlnoäthylanilin, inikroverkapselt 3 gquaternary ammonium disulfate of 2-aminobenzothiazole-N-ethyl-N-piperidlnoethylaniline, microencapsulated 3 g

Natriumcarbonat, mikroverkapselt 1 gSodium carbonate, microencapsulated 1 g

In einer dritten Stufe wird diese Mischung von Mikrokapseln zu einer flüssigen Zusammensetzung gegeben, die enthält:In a third stage, this mixture of microcapsules is added to a liquid composition that contains:

Triäthanolamin 2,75 gTriethanolamine 2.75 g

Wasser 64,45 gWater 64.45 g

Die die Mikrokapseln enthaltende Flüssigkeit wird so bewegt,The liquid containing the microcapsules is moved in such a way that

daß vollständige Homogenität erhalten wird, und auf 6O0C er-that complete homogeneity is obtained, and to 6O 0 C

wärmt. Dann wird sie unter Rühren mit der während der ersten ™ Stufe hergestellten Zusammensetzung, die ebenfalls auf 6O0C erwärmt ist, gemischt. Dann läßt man die Mischung unter Rühren abkühlen.warms. Then, it is mixed with stirring with the sheet produced during the first stage ™ composition which is also heated to 6O 0 C. The mixture is then allowed to cool while stirring.

Das Produkt wird in Form einer kleinen Platte konditioniert, die mittels einer feuchten Bürste angewendet wird. Im Zeitpunkt der Reibung der Bürste auf dem Produkt oder im Zeitpunkt der Reibung der Bürste auf den Augenbrauen oder den Wimpern, die man färben will, zerplatzen die Mikrokapseln, die der Einwirkung der Borsten der Purste unterliegen, und p.eben die Farbstoffmischung, dip eic- enthalten, frei. Auf diese Wrise kann man die Wimpern und die Augenbrauen in dauerhafter g Weise schwarz-blau färben.The product is conditioned in the form of a small plate that is applied with a damp brush. When the brush rubs against the product or when the brush rubs against the eyebrows or eyelashes that are to be tinted, the microcapsules, which are subject to the action of the bristles of the purste, burst and release the dye mixture, dip eic - included, free. In this Wrise can be dyed black and blue eyelashes and eyebrows in a permanent manner g.

Die vorstehend beschriebenen Ausfiibrungsformen soll' τι die vorliegende Erfindung in keiner Weise beschränken und en können Modifikationen durchgeführt werden, ohne den Rahmeti der Erfindung zu verlassen.The embodiments described above should 'τι the The present invention in no way limit or can Modifications can be made without the framework of the Invention to leave.

Insbesondere kennen die verwendeten Mikrokapseln nicht nur aus einer einzigen Hmhüllung, sondern aus mehreren übereinanderIn particular, they are not only familiar with the microcapsules used a single envelope, but of several on top of each other

0 0 8832/19350 0 8832/1935

M/11007M / 11007

angeordneten Umhüllungen bestehen, wobei die innere Hülle gegenüber tiikroverkapselten Produkten inert ist und wobei die äußere Hülle gegenüber dem Medium inert ist, worin die Mikrokapseln angeordnet sind.arranged casings exist, wherein the inner shell is inert to Tiikroenkapselten products and wherein the outer shell is inert to the medium in which the microcapsules are arranged.

009832/1935009832/1935

Claims (5)

M/11007 3 PATENTANSPRÜCHEM / 11007 3 PATENT CLAIMS 1. Dickflüssiges, teigartiges kosmetisches Produkt, das für die direkte Färbung von Keratinfasern verwendbar ist, dadurch gekennzeichnet, daß es in einem teigartigen Träger vom klassischen Typ Mikrokapseln mit Dimensionen zwischen 50 und 800/u enthält, die mindestens einen Farbstoff mit einer geeigneten Affinität für Keratinfasern, bei dem keine gleichzeitige Anwendung eines Oxydationsmittels für das Auftreten der gewünschten Farbe erforderlich ist, enthalten.1. Thick, dough-like cosmetic product which can be used for direct coloring of keratin fibers, thereby characterized in that it is in a dough-like carrier of the classic type microcapsules with dimensions between 50 and 800 / u contains at least one dye with a suitable affinity for keratinous fibers, which does not have any simultaneous Application of an oxidizing agent is required for the appearance of the desired color. 2. Kosmetisches Produkt nach Anspruch 1, dadurch gekennzeichnet, daß die Mikrokapseln mindestens einen Direktfarbstoff enthalten.2. Cosmetic product according to claim 1, characterized in that the microcapsules have at least one direct dye contain. 3. Kosmetisches Produkt nach Anspruch 1, dadurch gekennzeichnet, daß die Mikrokapseln mindestens einen Schnelloxydationsfarbstoff enthalten, bei dem die Färbung durch Umsetzung mit Sauerstoff aus der Luft auftritt.3. Cosmetic product according to claim 1, characterized in that the microcapsules have at least one rapid oxidation dye in which the color occurs through reaction with oxygen from the air. 4. Kosmetisches Produkt nach Anspruch 1 bis 3, dadurch gekennzeichnet, daß die Gesamtheit der Mikrokapseln eine Mischung von Direktfarbstoffen und Schnelloxydationsfarbstoffen enthält.4. Cosmetic product according to claim 1 to 3, characterized in that that the entirety of the microcapsules is a mixture of direct dyes and rapid oxidation dyes contains. 5. Kosmetisches Produkt nach Anspruch 1 bis 4, dadurch gekennzeichnet, daß es in Form eines Stabes oder Stiftes oder in Form einer kleinen Platte, die man mit Hilfe einer feuchten Bürste verwendet, oder in Form des Überzuges einer Papierserviette konditioniert ist.5. Cosmetic product according to claim 1 to 4, characterized in that that it is in the form of a stick or pencil or in the form of a small plate that you can use with a damp Brush used, or conditioned in the form of the coating of a paper napkin. 009832/1935 ORrQINAt INSPECTED009832/1935 ORrQINAt INSPECTED
DE19702005076 1969-02-04 1970-02-04 Thick, dough-like product intended for direct coloring of keratin fibers and especially hair Pending DE2005076A1 (en)

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LU57894 1969-02-04

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DE2005076A1 true DE2005076A1 (en) 1970-08-06

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DE19702005076 Pending DE2005076A1 (en) 1969-02-04 1970-02-04 Thick, dough-like product intended for direct coloring of keratin fibers and especially hair

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BE (1) BE744921A (en)
CH (1) CH507713A (en)
DE (1) DE2005076A1 (en)
FR (1) FR2030282B1 (en)
GB (1) GB1288128A (en)
IT (1) IT954111B (en)
LU (1) LU57894A1 (en)

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EP0782435B2 (en) † 1994-09-19 2003-11-19 Colour Direct Hair dye composition
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US7637962B2 (en) 2004-07-30 2009-12-29 Wella Ag Multicomponent kit and method for dyeing keratin fibers
FR2944440A1 (en) * 2008-12-19 2010-10-22 Oreal Composition, useful for dyeing human keratin fibers, comprises fatty substance, and auto-oxidizable dyes in a medium
US7879113B2 (en) 2008-12-19 2011-02-01 L'oreal S.A. Composition comprising at least one fatty substance and at least one silicate, dyeing or lightening process using it and devices or kits therefor
US7901464B2 (en) 2007-12-21 2011-03-08 L'oreal S.A. Process for lightening direct dyeing or oxidation dyeing in the presence of at least one organic amine, device therefor and anhydrous composition
US7909887B2 (en) 2007-12-21 2011-03-22 L'oreal S.A. Method for dyeing in the presence of at least one oxidizing agent and at least one organic amine, device for use thereof and ready-to-use composition
US7909888B2 (en) 2008-12-19 2011-03-22 L'oreal Process for dyeing or lightening human keratin fibers using an anhydrous composition and a monoethanolamine/basic amino acid mixture, and suitable device therefor
US7914591B2 (en) 2008-12-19 2011-03-29 L'oreal S.A. Process for the lightening dyeing of keratin materials using at least one anhydrous dyeing composition comprising at least one alkaline agent and at least one oxidizing composition
US7918902B2 (en) 2008-12-19 2011-04-05 L'oreal S.A. Process for lightening or process for direct dyeing or oxidation dyeing of keratin fibers in the presence of at least one ammonium salt and device therefor
US7918903B2 (en) 2008-12-19 2011-04-05 L'oreal, S.A. Composition for the oxidation dyeing of keratin fibers comprising at least one fatty substance and at least one N,N bis(beta-hydroxyethyl)-para-phenylenediamine
US7922777B2 (en) 2008-12-19 2011-04-12 L'ORéAL S.A. Lightening and dyeing of human keratin fibers using an anhydrous composition comprising a monoethyanolamine/basic amino acid mixture, and device therefor
US7927383B2 (en) 2008-12-19 2011-04-19 L'oreal S.A. Composition comprising at least one fatty substance and at least one surfactant comprising ethylene oxide, dyeing or lightening process using it and devices therefor
US7927381B2 (en) 2008-12-19 2011-04-19 L'oreal S.A. Process for lightening or lightening direct dyeing or oxidation dyeing in the presence of an aqueous composition comprising at least one fatty substance, and device
US7927382B2 (en) 2008-12-19 2011-04-19 L'oreal S.A. Ready-to-use composition for the oxidation dyeing of keratin fibers comprising at least one fatty substance, at least one oxidation chosen from 4,5-diaminopyrazoles and acid addition salts thereof, at least one additional dye precursor other than the at least one oxidation base, at least one oxidizing agent, and optionally at least one alkaline agent, and processes and kits therewith
US7927380B2 (en) 2008-12-19 2011-04-19 L'oreal S.A. Composition for oxidation dyeing of keratin fibers comprising at least one fatty substance, at least one oxidation base, at least one dye precursor, at least one oxidizing agent, and optionally at least one alkaline agent, and processes and kits therewith
US7931698B2 (en) 2008-12-19 2011-04-26 L'oreal S.A. Ready-to-use composition for oxidation dyeing of keratin fibers comprising at least one fatty substance, at least one thickener, at least one dye precursor, at least one oxidizing agent, and at least one alkaline agent, and process and kits therewith
US7935154B2 (en) 2008-12-19 2011-05-03 L'oreal S.A. Process for lightening or lightening direct dyeing or oxidation dyeing in the presence of at least one organic amine and at least one inorganic base, and device therefor
US7947089B2 (en) 2008-12-19 2011-05-24 L'oreal S.A. Method of coloring or lightening in the presence of an inorganic base and kit
US7981165B2 (en) 2008-12-19 2011-07-19 L'oreal S.A. Process for lightening keratin materials using an anhydrous composition comprising at least one fatty substance and at least one alkaline agent, and at least one oxidizing composition
US7988737B2 (en) 2008-12-19 2011-08-02 L'oreal S.A. Ready-to-use composition for oxidation dyeing of keratin fibers comprising at least one fatty substance chosen from fatty amides and fatty acid esters, at least one dye precursor, at least one oxidizing agent and optionally at least one alkaline agent, and methods and kits therewith
US7988738B2 (en) 2008-12-19 2011-08-02 L'oreal S.A. Process for the lightening dyeing of keratin materials using an emulsion comprising a dye and an alkaline agent and an oxidizing composition
US8066781B2 (en) 2008-12-19 2011-11-29 L'oreal S.A. Composition comprising at least one fatty substance and at least one cationic polymer, dyeing or lightening process using it and devices therefor
US8070831B2 (en) 2008-12-19 2011-12-06 L'oreal S.A. Composition comprising at least one solid fatty alcohol, dyeing or lightening process using same and devices
US8092553B2 (en) 2008-12-19 2012-01-10 L'oreal S.A. Composition for the oxidation dyeing of keratin fibers comprising para-aminophenol, dipropylene glycol and at least one additional dye precursor
US8114170B2 (en) 2009-12-22 2012-02-14 L'oreal S.A. Agent for coloring and/or bleaching keratin fibers comprising composition (A), composition (B), at least one fat and at least one reductone
US8118884B2 (en) 2009-12-22 2012-02-21 L'oreal S.A. Dyeing or lightening compositions comprising at least one fatty substance and at least one amphoteric polymer
US8142518B2 (en) 2009-12-22 2012-03-27 L'oreal Agent for dyeing and/or bleaching keratin fibers in two parts, comprising at least one fatty substance and at least one sequestrant
US8147564B2 (en) 2009-12-22 2012-04-03 L'oreal Agent for dyeing and/or bleaching keratin fibers, comprising composition (A), anhydrous composition (B), and at least one fatty substance
US8262739B2 (en) 2008-12-19 2012-09-11 L'oreal S.A. Hair treatment process using a direct emulsion comprising an oxidizing agent and a composition containing an alkaline agent
US8889110B2 (en) 2008-12-19 2014-11-18 L'oreal Oxidizing composition for the treatment of keratin fibers comprising at least one oil, at least one fatty alcohol and at least one oxyalkylenated fatty alcohol
US9005594B2 (en) 2007-12-21 2015-04-14 L'oreal Method for lightening human keratin fibers using at least one anhydrous composition, at least one organic amine, and at least one oxidizing agent, and device for use thereof
US9017424B2 (en) 2008-12-19 2015-04-28 L'oreal Process for lightening keratin materials using an emulsion comprising an alkaline agent and an oxidizing composition
US11691035B2 (en) 2008-12-19 2023-07-04 L'oreal Oxidizing composition for the treatment of keratin fibers comprising at least one cationic polymer, at least one fatty amide and at least one anti-oxygen agent

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DE102004042097A1 (en) * 2004-08-30 2006-03-09 Henkel Kgaa Agent for dyeing keratinous fibers
FR2882517B1 (en) * 2005-02-28 2007-05-25 Oreal COSMETIC COMPOSITION CONTAINING TRIBOCHROME COMPOUND, PROCESS USING THE SAME AND USES THEREOF
FR2940082B1 (en) * 2008-12-19 2013-10-11 Oreal METHOD FOR DIRECT LIGHTENING COLORING OR OXIDATION IN THE PRESENCE OF AN INORGANIC BASE AND DEVICE
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GB749045A (en) * 1954-03-12 1956-05-16 Indola N V Improvements in and relating to the dyeing of hair
FR1526397A (en) * 1966-05-12 1968-05-24 Hans Schwarzkopf Substance and method for coloring and blonding living hair

Cited By (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3801606A1 (en) * 1988-01-21 1989-07-27 Goldwell Gmbh AGENTS AND METHODS OF OXIDATIVE FAIRING, IN PARTICULAR FOR THE POST-RIGHT ACQUISITION OF LIVING HAIR
EP0782435B2 (en) † 1994-09-19 2003-11-19 Colour Direct Hair dye composition
WO2005094760A1 (en) * 2004-03-31 2005-10-13 Schwan-Stabilo Cosmetics Gmbh & Co. Kg. Cosmetic preparation
US7637962B2 (en) 2004-07-30 2009-12-29 Wella Ag Multicomponent kit and method for dyeing keratin fibers
US7909887B2 (en) 2007-12-21 2011-03-22 L'oreal S.A. Method for dyeing in the presence of at least one oxidizing agent and at least one organic amine, device for use thereof and ready-to-use composition
US9005594B2 (en) 2007-12-21 2015-04-14 L'oreal Method for lightening human keratin fibers using at least one anhydrous composition, at least one organic amine, and at least one oxidizing agent, and device for use thereof
US7901464B2 (en) 2007-12-21 2011-03-08 L'oreal S.A. Process for lightening direct dyeing or oxidation dyeing in the presence of at least one organic amine, device therefor and anhydrous composition
US7927380B2 (en) 2008-12-19 2011-04-19 L'oreal S.A. Composition for oxidation dyeing of keratin fibers comprising at least one fatty substance, at least one oxidation base, at least one dye precursor, at least one oxidizing agent, and optionally at least one alkaline agent, and processes and kits therewith
US7981165B2 (en) 2008-12-19 2011-07-19 L'oreal S.A. Process for lightening keratin materials using an anhydrous composition comprising at least one fatty substance and at least one alkaline agent, and at least one oxidizing composition
US7914591B2 (en) 2008-12-19 2011-03-29 L'oreal S.A. Process for the lightening dyeing of keratin materials using at least one anhydrous dyeing composition comprising at least one alkaline agent and at least one oxidizing composition
US7918902B2 (en) 2008-12-19 2011-04-05 L'oreal S.A. Process for lightening or process for direct dyeing or oxidation dyeing of keratin fibers in the presence of at least one ammonium salt and device therefor
US7918903B2 (en) 2008-12-19 2011-04-05 L'oreal, S.A. Composition for the oxidation dyeing of keratin fibers comprising at least one fatty substance and at least one N,N bis(beta-hydroxyethyl)-para-phenylenediamine
US7922777B2 (en) 2008-12-19 2011-04-12 L'ORéAL S.A. Lightening and dyeing of human keratin fibers using an anhydrous composition comprising a monoethyanolamine/basic amino acid mixture, and device therefor
US7927383B2 (en) 2008-12-19 2011-04-19 L'oreal S.A. Composition comprising at least one fatty substance and at least one surfactant comprising ethylene oxide, dyeing or lightening process using it and devices therefor
US7927381B2 (en) 2008-12-19 2011-04-19 L'oreal S.A. Process for lightening or lightening direct dyeing or oxidation dyeing in the presence of an aqueous composition comprising at least one fatty substance, and device
US7927382B2 (en) 2008-12-19 2011-04-19 L'oreal S.A. Ready-to-use composition for the oxidation dyeing of keratin fibers comprising at least one fatty substance, at least one oxidation chosen from 4,5-diaminopyrazoles and acid addition salts thereof, at least one additional dye precursor other than the at least one oxidation base, at least one oxidizing agent, and optionally at least one alkaline agent, and processes and kits therewith
US7879113B2 (en) 2008-12-19 2011-02-01 L'oreal S.A. Composition comprising at least one fatty substance and at least one silicate, dyeing or lightening process using it and devices or kits therefor
US7931698B2 (en) 2008-12-19 2011-04-26 L'oreal S.A. Ready-to-use composition for oxidation dyeing of keratin fibers comprising at least one fatty substance, at least one thickener, at least one dye precursor, at least one oxidizing agent, and at least one alkaline agent, and process and kits therewith
US7935154B2 (en) 2008-12-19 2011-05-03 L'oreal S.A. Process for lightening or lightening direct dyeing or oxidation dyeing in the presence of at least one organic amine and at least one inorganic base, and device therefor
US7947089B2 (en) 2008-12-19 2011-05-24 L'oreal S.A. Method of coloring or lightening in the presence of an inorganic base and kit
US7909888B2 (en) 2008-12-19 2011-03-22 L'oreal Process for dyeing or lightening human keratin fibers using an anhydrous composition and a monoethanolamine/basic amino acid mixture, and suitable device therefor
US7988737B2 (en) 2008-12-19 2011-08-02 L'oreal S.A. Ready-to-use composition for oxidation dyeing of keratin fibers comprising at least one fatty substance chosen from fatty amides and fatty acid esters, at least one dye precursor, at least one oxidizing agent and optionally at least one alkaline agent, and methods and kits therewith
US7988738B2 (en) 2008-12-19 2011-08-02 L'oreal S.A. Process for the lightening dyeing of keratin materials using an emulsion comprising a dye and an alkaline agent and an oxidizing composition
US8066781B2 (en) 2008-12-19 2011-11-29 L'oreal S.A. Composition comprising at least one fatty substance and at least one cationic polymer, dyeing or lightening process using it and devices therefor
US8070831B2 (en) 2008-12-19 2011-12-06 L'oreal S.A. Composition comprising at least one solid fatty alcohol, dyeing or lightening process using same and devices
US8092553B2 (en) 2008-12-19 2012-01-10 L'oreal S.A. Composition for the oxidation dyeing of keratin fibers comprising para-aminophenol, dipropylene glycol and at least one additional dye precursor
US11691035B2 (en) 2008-12-19 2023-07-04 L'oreal Oxidizing composition for the treatment of keratin fibers comprising at least one cationic polymer, at least one fatty amide and at least one anti-oxygen agent
US9017424B2 (en) 2008-12-19 2015-04-28 L'oreal Process for lightening keratin materials using an emulsion comprising an alkaline agent and an oxidizing composition
FR2944440A1 (en) * 2008-12-19 2010-10-22 Oreal Composition, useful for dyeing human keratin fibers, comprises fatty substance, and auto-oxidizable dyes in a medium
US8889110B2 (en) 2008-12-19 2014-11-18 L'oreal Oxidizing composition for the treatment of keratin fibers comprising at least one oil, at least one fatty alcohol and at least one oxyalkylenated fatty alcohol
US8262739B2 (en) 2008-12-19 2012-09-11 L'oreal S.A. Hair treatment process using a direct emulsion comprising an oxidizing agent and a composition containing an alkaline agent
US8147564B2 (en) 2009-12-22 2012-04-03 L'oreal Agent for dyeing and/or bleaching keratin fibers, comprising composition (A), anhydrous composition (B), and at least one fatty substance
US8142518B2 (en) 2009-12-22 2012-03-27 L'oreal Agent for dyeing and/or bleaching keratin fibers in two parts, comprising at least one fatty substance and at least one sequestrant
US8118884B2 (en) 2009-12-22 2012-02-21 L'oreal S.A. Dyeing or lightening compositions comprising at least one fatty substance and at least one amphoteric polymer
US8114170B2 (en) 2009-12-22 2012-02-14 L'oreal S.A. Agent for coloring and/or bleaching keratin fibers comprising composition (A), composition (B), at least one fat and at least one reductone

Also Published As

Publication number Publication date
GB1288128A (en) 1972-09-06
CH507713A (en) 1971-05-31
BE744921A (en) 1970-07-27
IT954111B (en) 1973-08-30
FR2030282A1 (en) 1970-11-13
FR2030282B1 (en) 1973-03-16
LU57894A1 (en) 1970-08-04

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