EP0333143A2 - Medicinal soaps - Google Patents

Medicinal soaps Download PDF

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Publication number
EP0333143A2
EP0333143A2 EP89104542A EP89104542A EP0333143A2 EP 0333143 A2 EP0333143 A2 EP 0333143A2 EP 89104542 A EP89104542 A EP 89104542A EP 89104542 A EP89104542 A EP 89104542A EP 0333143 A2 EP0333143 A2 EP 0333143A2
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EP
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Prior art keywords
biocidal
liquid
cleaning agent
aminopropyl
bis
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP89104542A
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German (de)
French (fr)
Other versions
EP0333143A3 (en
EP0333143B1 (en
Inventor
Siegfried Dr. Ing.-Chem. Güller
Joachim Dipl.-Ing. Fritschi
Ernest Meier
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Lonza AG
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Lonza AG
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/40—Monoamines or polyamines; Salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/65—Mixtures of anionic with cationic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/30—Amines; Substituted amines ; Quaternized amines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof

Definitions

  • Liquid detergents with a biocidal action which contain a tertiary alkylamine as an active ingredient, have hitherto not been known.
  • a combination of the good cleaning action of anionic surfactants with the broad spectrum of microbicides and the high effectiveness of the aliphatic amines would be desirable.
  • the object of the invention is to provide liquid cleaning agents based on anionic surfactants with a biocidal effect.
  • a liquid biocidal cleaning agent which essentially consists of N, N-bis (3-aminopropyl) laurylamine and an anionic cleaning component or contains these components.
  • the active ingredient N, N-bis (3-aminopropyl) laurylamine is preferably used in pure form; however, it is also possible to use mixtures with other N, N-bis (3-aminopropyl) alkylamines if these contain sufficient amounts of N, N-bis (3-aminopropyl) laurylamine.
  • Such mixtures can be produced, for example, from corresponding technical fatty amine mixtures, such as, in particular, coconut amine, by known processes.
  • Soaps such as sodium stearate, potassium stearate or triethanolamine are preferably found as the anionic cleaning component of the liquid, biocidal cleaning agents according to the invention soaps, sulphonated aromatic hydrocarbons such as n-alkylbenzene sulfonates, sulfonated aliphatic hydrocarbons such as secondary alkane sulfonates, sulfonated ⁇ -olefins, sulphated fatty alcohols such as sodium lauryl sulphate, sulphated fatty alcohol ethers such as Natriumlaurylpolyglykolethersulfat, sulfonated fatty acid methyl ester, as Palmkernsulfofettklamethylester, sulfonated maleic acid esters, such as lauryl, or carboxymethylated Fatty alcohol polyglycol ethers, such as lauryl polyglycol ether acetate, both individually and in combination, use.
  • An additional solvent is preferably added to the liquid, biocidal cleaning agents according to the invention for easier handling and metering.
  • biocidal cleaning agents As an additional solvent of the liquid, biocidal cleaning agents according to the invention, water or an alcohol with up to 4 C atoms, such as e.g. Methanol, ethanol, n-propanol, iso-propanol, n-butanol, iso-butanol, tert-butanol or sec-butanol, or a mixture of these.
  • an alcohol with up to 4 C atoms such as e.g. Methanol, ethanol, n-propanol, iso-propanol, n-butanol, iso-butanol, tert-butanol or sec-butanol, or a mixture of these.
  • the N, N-bis (3-aminopropyl) laurylamine as a biocidal active ingredient is preferably used in the form of a 20 to 40% aqueous solution in the preparation of the liquid, biocidal cleaning agents according to the invention, and the anionic cleaning component is preferably in the form of a 20 to 80% aqueous solution, so that the water contained in these components is simultaneously the solvent of the finished formulation represents.
  • biocidal cleaning agents it is particularly advantageous to additionally use nonionic surfactants, such as fatty alcohol ethoxylates, alkylphenol ethoxylates, fatty acid ethoxylates, fatty acid alkylolamides, fatty acid alkylolamide ethoxylates, fatty amine ethoxylates or polyalkylene oxide block polymers or mixtures thereof.
  • nonionic surfactants such as fatty alcohol ethoxylates, alkylphenol ethoxylates, fatty acid ethoxylates, fatty acid alkylolamides, fatty acid alkylolamide ethoxylates, fatty amine ethoxylates or polyalkylene oxide block polymers or mixtures thereof.
  • the amount of solvent used in the production of the liquid, biocidal cleaning agent according to the invention is not critical.
  • biocidal cleaning agents which contain solvents such as water or alcohol, 10 to 90% by weight, based on the finished formulation, of solvents are advantageously used.
  • biocidal cleaning agents according to the invention, the addition of ethylenediaminetetraacetic acid, nitrilotriacetic acid, phosphonic acids or polycarboxylic acids or salts of the acids, silicates, phosphates, sodium cumene sulfonate or alkalis is also expedient.
  • the liquid, biocidal cleaning agents according to the invention can be used as disinfectant cleaners, for example in the food industry, in the kitchen area, or generally for hard surfaces.
  • N, N-bis (3-aminopropyl) laurylamine (30% aqueous solution) 50% by weight
  • Triethanolamine soap of unsaturated vegetable fatty acids (38% aqueous solution) 10% by weight
  • a straight-chain ethoxylate with a degree of ethoxylation of approx. 7, a molar mass of approx. 470 and a hydroxyl number of approx. 120 7% by weight demineralised water 33% by weight
  • the liquid, biocidal cleaning agent according to the invention was applied to its microbicidal formulation in the formulation according to the example given in accordance with the "Guidelines for the Testing and Assessment of Chemical Disinfection Methods" (status 1.1.1981) of the German Society for Hygiene and Microbiology, Gustav Fischer Verlag, Stuttgart, 1981 Properties as a surface disinfectant with cleaning properties have been investigated and are effective as surface disinfectants based on the "in vitro tests” and the “tests under practical conditions” in accordance with the "Requirements for inclusion in the VII. List of the German Society for Hygiene and Microbiology" to watch.

Abstract

Liquid cleaning agents with a biocidal action are prepared from N,N-bis(3-aminopropyl)laurylamine and an anionic surfactant as cleaning component.

Description

Flüssige Reinigungsmittel mit biozider Wirkung, die ein ter­tiäres Alkylamin als Wirkstoff enthalten, sind bisher nicht bekannt.Liquid detergents with a biocidal action, which contain a tertiary alkylamine as an active ingredient, have hitherto not been known.

Wünschenswert wäre eine Kombination der guten Reinigungs­wirkung anionischer Tenside mit dem breiten mikrobiziden Wirkungsspektrum und der hohen Wirksamkeit der aliphatischen Amine.A combination of the good cleaning action of anionic surfactants with the broad spectrum of microbicides and the high effectiveness of the aliphatic amines would be desirable.

Aufgabe der Erfindung ist es, flüssige Reinigungsmittel auf Basis anionischer Tenside mit biozider Wirkung zu schaffen.The object of the invention is to provide liquid cleaning agents based on anionic surfactants with a biocidal effect.

Erfindungsgemäss wird die Aufgabe durch ein flüssiges biozides Reinigungsmittel gelöst, das im wesentlichen aus N,N-Bis-(3-ami­nopropyl)-laurylamin und einer anionischen Reinigungskomponente besteht oder diese Bestandteile enthält. Der Wirkstoff N,N-Bis-­(3-aminopropyl)-laurylamin wird vorzugsweise in reiner Form ein­gesetzt; es ist jedoch auch möglich, Gemische mit anderen N,N-­Bis-(3-aminopropyl)-alkylaminen zu verwenden, wenn diese ausrei­chende Mengen N,N-Bis-(3-aminopropyl)-laurylamin enthalten. Sol­che Gemische können beispielsweise aus entsprechenden techni­schen Fettamingemischen, wie insbesondere Kokosamin, nach be­kannten Verfahren hergestellt werden.According to the invention the object is achieved by a liquid biocidal cleaning agent which essentially consists of N, N-bis (3-aminopropyl) laurylamine and an anionic cleaning component or contains these components. The active ingredient N, N-bis (3-aminopropyl) laurylamine is preferably used in pure form; however, it is also possible to use mixtures with other N, N-bis (3-aminopropyl) alkylamines if these contain sufficient amounts of N, N-bis (3-aminopropyl) laurylamine. Such mixtures can be produced, for example, from corresponding technical fatty amine mixtures, such as, in particular, coconut amine, by known processes.

Als anionische Reinigungskomponente der erfindungsgemässen flüssigen, bioziden Reinigungsmittel finden vorzugsweise Sei­fen, wie Natriumstearat, Kaliumstearat oder Triethanolamin­ seifen, sulfonierte aromatische Kohlenwasserstoffe, wie n-Alkylbenzolsulfonate, sulfonierte aliphatische Kohlenwasser­stoffe, wie sekundäre Alkansulfonate, sulfonierte α-Olefine, sulfatierte Fettalkohole, wie Natriumlaurylsulfat, sulfatierte Fettalkoholether, wie Natriumlaurylpolyglykolethersulfat, sul­fonierte Fettsäuremethylester, wie Palmkernsulfofettsäure­methylester, sulfonierte Maleinsäureester, wie Laurylsulfo­succinat, oder carboxymethylierte Fettalkoholpolyglykolether, wie Laurylpolyglykoletheracetat, sowohl einzeln als auch in Kombination, Verwendung.Soaps such as sodium stearate, potassium stearate or triethanolamine are preferably found as the anionic cleaning component of the liquid, biocidal cleaning agents according to the invention soaps, sulphonated aromatic hydrocarbons such as n-alkylbenzene sulfonates, sulfonated aliphatic hydrocarbons such as secondary alkane sulfonates, sulfonated α-olefins, sulphated fatty alcohols such as sodium lauryl sulphate, sulphated fatty alcohol ethers such as Natriumlaurylpolyglykolethersulfat, sulfonated fatty acid methyl ester, as Palmkernsulfofettsäuremethylester, sulfonated maleic acid esters, such as lauryl, or carboxymethylated Fatty alcohol polyglycol ethers, such as lauryl polyglycol ether acetate, both individually and in combination, use.

Vorzugsweise wird den erfindungsgemässen flüssigen, bioziden Reinigungsmitteln zur leichteren Handhabung und Dosierung ein zusätzliches Lösungsmittel zugefügt.An additional solvent is preferably added to the liquid, biocidal cleaning agents according to the invention for easier handling and metering.

Als zusätzliches Lösungsmittel der erfindungsgemässen flüssi­gen, bioziden Reinigungsmittel wird vorzugsweise Wasser oder ein Alkohol mit bis zu 4 C-Atomen, wie z.B. Methanol, Ethanol, n-Propanol, iso-Propanol, n-Butanol, iso-Butanol, tert-Butanol oder sec-Butanol, oder eine Mischung der genannten eingesetzt.As an additional solvent of the liquid, biocidal cleaning agents according to the invention, water or an alcohol with up to 4 C atoms, such as e.g. Methanol, ethanol, n-propanol, iso-propanol, n-butanol, iso-butanol, tert-butanol or sec-butanol, or a mixture of these.

Das N,N-Bis-(3-aminopropyl)-laurylamin als biozider Wirkstoff wird bei der Herstellung der erfindungsgemässen flüssigen, bioziden Reinigungsmittel vorzugsweise in Form einer 20 bis 40%igen wässrigen Lösung und die anionische Reinigungskompo­nente vorzugsweise in Form einer 20 bis 80%igen wässrigen Lö­sung eingesetzt, so dass das in diesen Komponenten enthaltene Wasser gleichzeitig das Lösungsmittel der fertigen Formulie­ rung darstellt.The N, N-bis (3-aminopropyl) laurylamine as a biocidal active ingredient is preferably used in the form of a 20 to 40% aqueous solution in the preparation of the liquid, biocidal cleaning agents according to the invention, and the anionic cleaning component is preferably in the form of a 20 to 80% aqueous solution, so that the water contained in these components is simultaneously the solvent of the finished formulation represents.

Zur Verbesserung der Reinigungswirkung der erfindungsgemässen flüssigen, bioziden Reinigungsmittel ist es besonders günstig, noch zusätzlich nichtionische Tenside, wie Fettalkoholethoxy­late, Alkylphenolethoxylate, Fettsäureethoxylate, Fettsäure­alkylolamide, Fettsäurealkylolamidethoxylate, Fettaminethoxy­late oder Polyalkylenoxid-Blockpolymerisate oder Mischungen derselben, zu verwenden.To improve the cleaning action of the liquid, biocidal cleaning agents according to the invention, it is particularly advantageous to additionally use nonionic surfactants, such as fatty alcohol ethoxylates, alkylphenol ethoxylates, fatty acid ethoxylates, fatty acid alkylolamides, fatty acid alkylolamide ethoxylates, fatty amine ethoxylates or polyalkylene oxide block polymers or mixtures thereof.

Die bei der Herstellung der erfindungsgemässen flüssigen, bio­ziden Reinigungsmittel verwendete Menge an Lösungsmittel ist nicht kritisch. Bei bioziden Reinigungsmitteln, die Lösungs­mittel wie Wasser oder Alkohol enthalten, werden vorteilhaf­terweise 10 bis 90 Gew.%, bezogen auf die fertige Formulie­rung, Lösungsmittel angewendet.The amount of solvent used in the production of the liquid, biocidal cleaning agent according to the invention is not critical. In the case of biocidal cleaning agents which contain solvents such as water or alcohol, 10 to 90% by weight, based on the finished formulation, of solvents are advantageously used.

Zur weiteren Erhöhung der Reinigungswirkung der erfindungsge­mässen flüssigen, bioziden Reinigungsmittel ist darüber hinaus der Zusatz von Ethylendiamintetraessigsäure, Nitrilotriessig­säure, Phosphonsäuren oder Polycarbonsäuren oder Salzen der genannten Säuren, Silikaten, Phosphaten, Natrium-cumolsulfonat oder Alkalien zweckmässig.To further increase the cleaning action of the liquid, biocidal cleaning agents according to the invention, the addition of ethylenediaminetetraacetic acid, nitrilotriacetic acid, phosphonic acids or polycarboxylic acids or salts of the acids, silicates, phosphates, sodium cumene sulfonate or alkalis is also expedient.

Die erfindungsgemässen flüssigen, bioziden Reinigungsmittel können als Desinfektionsreiniger, z.B. in der Lebensmittelin­dustrie, im Küchenbereich, oder allgemein für harte Oberflä­chen, eingesetzt werden.The liquid, biocidal cleaning agents according to the invention can be used as disinfectant cleaners, for example in the food industry, in the kitchen area, or generally for hard surfaces.

Beispielexample

Als Beispiel für ein flüssiges, biozides Reinigungsmittel, gemäss der Erfindung, ist folgende Formulierung stellvertre­tend: N,N-Bis-(3-aminopropyl)-laurylamin (30%ige wässrige Lösung) 50 Gew.% Triethanolaminseife ungesättigter pflanzlicher Fettsäuren (38%ige wässrige Lösung) 10 Gew.% Ethoxylat eines geradkettigen mit einem Ethoxylierungsgrad von ca. 7, einer molaren Masse von ca. 470 und einer Hydroxylzahl von ca. 120 7 Gew.% demineralisiertes Wasser 33 Gew.% The following formulation is representative of an example of a liquid, biocidal cleaning agent according to the invention: N, N-bis (3-aminopropyl) laurylamine (30% aqueous solution) 50% by weight Triethanolamine soap of unsaturated vegetable fatty acids (38% aqueous solution) 10% by weight A straight-chain ethoxylate with a degree of ethoxylation of approx. 7, a molar mass of approx. 470 and a hydroxyl number of approx. 120 7% by weight demineralised water 33% by weight

Herstellung:Manufacturing:

Unter starkem Rühren wurde das N,N-Bis-(3-aminopropyl)-­laurylamin dem vorgelegten Wasser bei Raumtemperatur zuge­setzt. Unter Rühren wurden die beiden anderen Komponenten zugesetzt, wobei das Rühren so lange fortgesetzt wurde, bis eine klare Lösung entstand.With vigorous stirring, the N, N-bis (3-aminopropyl) laurylamine was added to the water initially charged at room temperature. The other two components were added with stirring, the stirring being continued until a clear solution was obtained.

Physikalische Eigenschaften:Physical Properties:

Wirkstoffgehalt: 25,8% Wasser: 74,2% Aussehen: farblose bis gelbliche, klare bis leicht getrübte Flüssigkeit
Löslichkeit: leicht löslich in kaltem und warmem Wasser Dichte bei 20°C: 0,987 g/cm3 pH-Wert (Konzentrat): 11,0 pH-Wert (1%ige Gebrauchslösung): 10,5 Oberflächenspannung: (1%ige Gebrauchslösung) 33 nN/m Active substance content: 25.8% Water: 74.2% Appearance: colorless to yellowish, clear to slightly cloudy liquid
Solubility: easily soluble in cold and warm water Density at 20 ° C: 0.987 g / cm3 pH value (concentrate): 11.0 pH value (1% working solution): 10.5 Surface tension: (1% working solution) 33 nN / m

Mikrobiologische Wirksamkeit:Microbiological effectiveness:

Das erfindungsgemässe flüssige, biozide Reinigungsmittel wurde in der Formulierung nach dem angegebenen Beispiel gemäss den "Richtlinien für die Prüfung und Bewertung chemischer Desin­fektionsverfahren" (Stand 1.1.1981) der Deutschen Gesellschaft für Hygiene und Mikrobiologie, Gustav Fischer Verlag, Stutt­gart, 1981 auf seine mikrobiziden Eigenschaften als Flächen­desinfektionsmittel mit Reinigungswirkung untersucht und ist aufgrund der durchgeführten "In-vitro-Tests" und der "Versuche unter praxisnahen Bedingungen" entsprechend den "Anforderungen für die Aufnahme in die VII. Liste der Deutschen Gesellschaft für Hygiene und Mikrobiologie" als Flächendesinfektionsmittel als wirksam anzusehen.The liquid, biocidal cleaning agent according to the invention was applied to its microbicidal formulation in the formulation according to the example given in accordance with the "Guidelines for the Testing and Assessment of Chemical Disinfection Methods" (status 1.1.1981) of the German Society for Hygiene and Microbiology, Gustav Fischer Verlag, Stuttgart, 1981 Properties as a surface disinfectant with cleaning properties have been investigated and are effective as surface disinfectants based on the "in vitro tests" and the "tests under practical conditions" in accordance with the "Requirements for inclusion in the VII. List of the German Society for Hygiene and Microbiology" to watch.

Anwendungskonzentration:Application concentration:

0,75% / 4 Stunden Einwirkungszeit
1,00% / 1 Stunde Einwirkungszeit

Figure imgb0001
Figure imgb0002
Figure imgb0003
Figure imgb0004
Figure imgb0005
 0.75% / 4 hours exposure time
1.00% / 1 hour exposure time
Figure imgb0001
Figure imgb0002
Figure imgb0003
Figure imgb0004
Figure imgb0005

Claims (7)

1. Flüssige, biozide Reinigungsmittel, enthaltend N,N-Bis-­(3-aminopropyl)-laurylamin als biozider Wirkstoff und eine anionische Reinigungskomponente.1. Liquid, biocidal cleaning agent containing N, N-bis (3-aminopropyl) laurylamine as a biocidal active ingredient and an anionic cleaning component. 2. Flüssige, biozide Reinigungsmittel gemäss Patentanspruch 1, enthaltend N,N-Bis-(3-aminopropyl)-laurylamin als biozider Wirkstoff und zusätzlich ein Lösungsmittel.2. Liquid, biocidal cleaning agent according to claim 1, containing N, N-bis (3-aminopropyl) laurylamine as a biocidal active ingredient and additionally a solvent. 3. Flüssige, biozide Reinigungsmittel gemäss Patentanspruch 2, dadurch gekennzeichnet, dass als Lösungsmittel Wasser oder Alkohole mit bis zu 4 C-Atomen verwendet werden.3. Liquid, biocidal cleaning agent according to claim 2, characterized in that water or alcohols with up to 4 carbon atoms are used as solvents. 4. Flüssige, biozide Reinigungsmittel gemäss wenigstens einem der Pa­tentansprüche 1 bis 3, enthaltend N,N-Bis-(3-aminopropyl)-­laurylamin als biozider Wirkstoff in Mengen von 50 bis 99 Gew.% und 1 bis 50 Gew.% anionische Reinigungskomponente, jeweils bezogen auf die Summe der beiden Wirkstoffe.4. Liquid, biocidal cleaning agent according to at least one of claims 1 to 3, containing N, N-bis (3-aminopropyl) laurylamine as biocidal active ingredient in amounts of 50 to 99% by weight and 1 to 50% by weight of anionic cleaning component , each based on the sum of the two active ingredients. 5. Flüssige, biozide Reinigungsmittel gemäss wenigstens einem der Patentansprüche 1 bis 4, dadurch gekennzeichnet, dass das N,N-Bis-(3-aminopropyl)-laurylamin als 20 bis 40%ige wässrige Lösung und die anionische Reinigungskomponente als 20 bis 80%ige wässrige Lösung verwendet werden.5. Liquid, biocidal cleaning agent according to at least one of claims 1 to 4, characterized in that the N, N-bis (3-aminopropyl) laurylamine as a 20 to 40% aqueous solution and the anionic cleaning component as 20 to 80% aqueous solution can be used. 6. Flüssige, biozide Reinigungsmittel gemäss wenigstens einem der Patentansprüche 1 bis 5, dadurch gekennzeichnet, dass als zusätzliche Komponente nichtionische Tenside enthalten sind.6. Liquid, biocidal cleaning agent according to at least one of claims 1 to 5, characterized in that nonionic surfactants are contained as an additional component. 7. Verwendung der flüssigen, bioziden Reinigungsmittel gemäss wenigstens einem der Patentansprüche 1 bis 6 als Desinfek­tionsreiniger für harte Oberflächen.7. Use of the liquid, biocidal cleaning agent according to at least one of claims 1 to 6 as a disinfectant cleaner for hard surfaces.
EP89104542A 1988-03-18 1989-03-14 Medicinal soaps Expired - Lifetime EP0333143B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH1035/88 1988-03-18
CH1035/88A CH675429A5 (en) 1988-03-18 1988-03-18

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EP0333143A2 true EP0333143A2 (en) 1989-09-20
EP0333143A3 EP0333143A3 (en) 1990-03-28
EP0333143B1 EP0333143B1 (en) 1994-08-03

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AT (1) ATE109501T1 (en)
CH (1) CH675429A5 (en)
DE (1) DE58908124D1 (en)
ES (1) ES2056985T3 (en)

Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0385369A2 (en) * 1989-02-27 1990-09-05 Lonza Ag Method for the antimicrobiol preservation of surfactant
EP0551975A1 (en) * 1992-01-17 1993-07-21 SCHÜLKE & MAYR GMBH Disinfectant concentrate and disinfectant based on amines and alcohols and use thereof
DE4306344C1 (en) * 1993-02-25 1994-08-04 Schuelke & Mayr Gmbh Disinfectant concentrate and amine and alcohol based disinfectants
FR2701037A1 (en) * 1993-01-29 1994-08-05 Hakawerk H Kunz Gmbh Detergents for textile articles made of poly(vinyl chloride) fibres
EP0620013A2 (en) * 1993-04-15 1994-10-19 Bode Chemie GmbH & Co. Desinfectant for toilet systems with holding tanks and similar equipment
WO1995000613A1 (en) 1993-06-28 1995-01-05 Henkel-Ecolab Gmbh & Co. Ohg Cleaning and disinfecting agent
WO1997001621A1 (en) * 1995-06-27 1997-01-16 The Procter & Gamble Company Cleaning/sanitizing methods, compositions, and/or articles for non-food inanimate surfaces
WO1997043368A1 (en) * 1996-05-10 1997-11-20 Unilever N.V. Cleaning and/or disinfecting composition
EP0835064A1 (en) * 1995-06-27 1998-04-15 The Procter & Gamble Company Cleaning/sanitizing methods, compositions, and/or articles for produce
EP0848907A1 (en) * 1996-12-21 1998-06-24 B. Braun Medical AG Sprayable disinfecting preparation
DE19749964A1 (en) * 1997-11-04 1999-05-06 Ulrich Grajecki Gmbh & Co Dipl Alkaline solutions for washing polyester bottles
WO2002023990A1 (en) * 2000-09-20 2002-03-28 Lonza Ag Disinfectant
WO2004003126A1 (en) * 2002-06-27 2004-01-08 Ecolab Inc. Foam disinfectant
DE19722757B4 (en) * 1997-05-31 2005-12-01 Bode Chemie Gmbh & Co. Kg Aldehyde-free disinfectant for surfaces and instruments
WO2015026268A1 (en) 2013-08-20 2015-02-26 Limited Liability Company "Nearmedic Plus" Reagent allowing for microorganism inactivation, extraction and storage of bacterial dna in form suitable for highly effective molecular diagnostics
WO2018089761A1 (en) * 2016-11-11 2018-05-17 Lonza Inc. Disinfectant composition having residual biocidal properties
EP3542628A1 (en) * 2018-03-22 2019-09-25 Chemische Fabrik Dr. Weigert GmbH & Co. KG Disinfectant and use of n,n-bis(3-aminopropyl) alkylamine in disinfectant
WO2021195015A1 (en) * 2020-03-23 2021-09-30 Ecolab Usa Inc. Novel 2-in-1 sanitizing and rinse aid compositions employing amine based surfactants in machine warewashing
US11432545B2 (en) 2017-06-05 2022-09-06 Arxada, LLC Fast kill disinfectant wiping composition and premoistened wipes made from same

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EP0385369A2 (en) * 1989-02-27 1990-09-05 Lonza Ag Method for the antimicrobiol preservation of surfactant
EP0385369A3 (en) * 1989-02-27 1992-01-02 Lonza Ag Method for the antimicrobiol preservation of surfactant
EP0551975A1 (en) * 1992-01-17 1993-07-21 SCHÜLKE & MAYR GMBH Disinfectant concentrate and disinfectant based on amines and alcohols and use thereof
DE4201038A1 (en) * 1992-01-17 1993-07-22 Schuelke & Mayr Gmbh DISINFECTANT CONCENTRATE AND DISINFECTANT ON AMINE AND ALCOHOL BASE AND THEIR USE
US5393789A (en) * 1992-01-17 1995-02-28 Eastman Kodak Company Amine-and alcohol-based disinfectant concentrate and disinfectant and use thereof
FR2701037A1 (en) * 1993-01-29 1994-08-05 Hakawerk H Kunz Gmbh Detergents for textile articles made of poly(vinyl chloride) fibres
DE4306344C1 (en) * 1993-02-25 1994-08-04 Schuelke & Mayr Gmbh Disinfectant concentrate and amine and alcohol based disinfectants
US5554656A (en) * 1993-02-25 1996-09-10 Reckitt & Colman Inc. Disinfectant concentrates and disinfectants on amine and alcohol base and their use
EP0620013A3 (en) * 1993-04-15 1996-06-05 Bode Chemie Gmbh & Co Desinfectant for toilet systems with holding tanks and similar equipment.
DE4311840A1 (en) * 1993-04-15 1994-10-20 Bode Chemie Gmbh & Co Disinfectants for collective toilet systems and similar systems
DE4311840C2 (en) * 1993-04-15 1999-04-01 Bode Chemie Gmbh & Co Disinfectants for collective toilet systems and similar systems
EP0620013A2 (en) * 1993-04-15 1994-10-19 Bode Chemie GmbH & Co. Desinfectant for toilet systems with holding tanks and similar equipment
FR2708278A1 (en) * 1993-06-28 1995-02-03 Paragerm Snc Cleansing and disinfecting composition for hospital environment.
TR27796A (en) * 1993-06-28 1995-08-29 Henkel Ecolab Gmbh & Co Ohg Cleaning and disinfection agents.
WO1995000613A1 (en) 1993-06-28 1995-01-05 Henkel-Ecolab Gmbh & Co. Ohg Cleaning and disinfecting agent
WO1997001621A1 (en) * 1995-06-27 1997-01-16 The Procter & Gamble Company Cleaning/sanitizing methods, compositions, and/or articles for non-food inanimate surfaces
US6613731B1 (en) 1995-06-27 2003-09-02 The Procter & Gamble Company Cleaning/sanitizing methods, compositions, and/or articles for non-food inanimate surfaces
EP0835064A1 (en) * 1995-06-27 1998-04-15 The Procter & Gamble Company Cleaning/sanitizing methods, compositions, and/or articles for produce
EP1146109A3 (en) * 1995-06-27 2001-10-24 The Procter & Gamble Company Cleaning/Sanitizing methods, compositions, and/or articles for non-food inanimate surfaces
EP1146109A2 (en) * 1995-06-27 2001-10-17 The Procter & Gamble Company Cleaning/Sanitizing methods, compositions, and/or articles for non-food inanimate surfaces
US6054139A (en) * 1996-05-10 2000-04-25 Diversey Lever Inc. Cleaning and/or disinfecting composition
WO1997043368A1 (en) * 1996-05-10 1997-11-20 Unilever N.V. Cleaning and/or disinfecting composition
EP0848907A1 (en) * 1996-12-21 1998-06-24 B. Braun Medical AG Sprayable disinfecting preparation
DE19722757C5 (en) * 1997-05-31 2010-01-21 Bode Chemie Gmbh Aldehyde-free disinfectant for surfaces and instruments
DE19722757B4 (en) * 1997-05-31 2005-12-01 Bode Chemie Gmbh & Co. Kg Aldehyde-free disinfectant for surfaces and instruments
DE19749964B4 (en) * 1997-11-04 2004-05-13 Dipl.-Ing. Ulrich Grajecki (Gmbh & Co) Washing solution for the beverage and food industry
DE19749964A1 (en) * 1997-11-04 1999-05-06 Ulrich Grajecki Gmbh & Co Dipl Alkaline solutions for washing polyester bottles
JP2004509138A (en) * 2000-09-20 2004-03-25 ロンザ　ア−ゲ− disinfectant
EP1671541A1 (en) * 2000-09-20 2006-06-21 Lonza Ag Disinfectant
WO2002023990A1 (en) * 2000-09-20 2002-03-28 Lonza Ag Disinfectant
US6939840B2 (en) 2000-09-20 2005-09-06 Lonza Ag Disinfectant
WO2004003126A1 (en) * 2002-06-27 2004-01-08 Ecolab Inc. Foam disinfectant
US8097265B2 (en) 2002-06-27 2012-01-17 Ecolab Usa Inc. Foam disinfectant
EA032990B1 (en) * 2013-08-20 2019-08-30 Общество С Ограниченной Ответственностью "Ниармедик Плюс" Reagent for the treatment and storage of a biological sample
WO2015026268A1 (en) 2013-08-20 2015-02-26 Limited Liability Company "Nearmedic Plus" Reagent allowing for microorganism inactivation, extraction and storage of bacterial dna in form suitable for highly effective molecular diagnostics
WO2018089761A1 (en) * 2016-11-11 2018-05-17 Lonza Inc. Disinfectant composition having residual biocidal properties
US10149471B2 (en) 2016-11-11 2018-12-11 Lonza Inc. Disinfectant composition having residual biocidal properties
US10631537B2 (en) 2016-11-11 2020-04-28 Lonza Llc Disinfectant composition having residual biocidal properties
US11432545B2 (en) 2017-06-05 2022-09-06 Arxada, LLC Fast kill disinfectant wiping composition and premoistened wipes made from same
EP3542628A1 (en) * 2018-03-22 2019-09-25 Chemische Fabrik Dr. Weigert GmbH & Co. KG Disinfectant and use of n,n-bis(3-aminopropyl) alkylamine in disinfectant
WO2021195015A1 (en) * 2020-03-23 2021-09-30 Ecolab Usa Inc. Novel 2-in-1 sanitizing and rinse aid compositions employing amine based surfactants in machine warewashing
CN115038333A (en) * 2020-03-23 2022-09-09 埃科莱布美国股份有限公司 Novel 2 in 1 germicidal rinse aid compositions using amine based surfactants in warewashing
US11718813B2 (en) 2020-03-23 2023-08-08 Ecolab Usa Inc. 2-in-1 sanitizing and rinse aid compositions employing amine based surfactants in machine warewashing

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ATE109501T1 (en) 1994-08-15
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ES2056985T3 (en) 1994-10-16
EP0333143A3 (en) 1990-03-28
EP0333143B1 (en) 1994-08-03

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