US20070163990A1 - Container comprising an in-mold label positioned proximate to a surface topography - Google Patents

Container comprising an in-mold label positioned proximate to a surface topography Download PDF

Info

Publication number
US20070163990A1
US20070163990A1 US11/635,977 US63597706A US2007163990A1 US 20070163990 A1 US20070163990 A1 US 20070163990A1 US 63597706 A US63597706 A US 63597706A US 2007163990 A1 US2007163990 A1 US 2007163990A1
Authority
US
United States
Prior art keywords
container
mold label
polyethylene
copolymers
surface topography
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US11/635,977
Inventor
Roberto Escobosa
Paul Nutley
Michael McCutchan
dean zimmerman
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Priority to US11/635,977 priority Critical patent/US20070163990A1/en
Assigned to PROCTER & GAMBLE COMPANY, THE reassignment PROCTER & GAMBLE COMPANY, THE ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: NUTLEY, PAUL OWEN, ZIMMERMAN, DEAN ARTHUR, ESCOBOSA, ROBERTO, MCCUTCHAN, MICHAEL DEAN
Publication of US20070163990A1 publication Critical patent/US20070163990A1/en
Abandoned legal-status Critical Current

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D23/00Details of bottles or jars not otherwise provided for
    • B65D23/08Coverings or external coatings
    • B65D23/0842Sheets or tubes applied around the bottle with or without subsequent folding operations
    • B65D23/0864Applied in mould
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D23/00Details of bottles or jars not otherwise provided for
    • B65D23/10Handles
    • B65D23/102Gripping means formed in the walls, e.g. roughening, cavities, projections
    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/04Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps to be fastened or secured by the material of the label itself, e.g. by thermo-adhesion
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C49/00Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
    • B29C49/24Lining or labelling
    • B29C2049/2412Lining or labelling outside the article
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C49/00Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
    • B29C49/24Lining or labelling
    • B29C2049/2464Means for verifying or keeping the position of the lining or label, e.g. sensors, or attachment on mould wall
    • B29C2049/2466Means for verifying or keeping the position of the lining or label, e.g. sensors, or attachment on mould wall using electrostatic force
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C49/00Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
    • B29C49/24Lining or labelling
    • B29C2049/2464Means for verifying or keeping the position of the lining or label, e.g. sensors, or attachment on mould wall
    • B29C2049/2472Means for verifying or keeping the position of the lining or label, e.g. sensors, or attachment on mould wall using vacuum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C49/00Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
    • B29C49/24Lining or labelling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/04Polymers of ethylene
    • B29K2023/06PE, i.e. polyethylene
    • B29K2023/0608PE, i.e. polyethylene characterised by its density
    • B29K2023/0625LLDPE, i.e. linear low density polyethylene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/04Polymers of ethylene
    • B29K2023/06PE, i.e. polyethylene
    • B29K2023/0608PE, i.e. polyethylene characterised by its density
    • B29K2023/0633LDPE, i.e. low density polyethylene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/04Polymers of ethylene
    • B29K2023/06PE, i.e. polyethylene
    • B29K2023/0608PE, i.e. polyethylene characterised by its density
    • B29K2023/0641MDPE, i.e. medium density polyethylene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/04Polymers of ethylene
    • B29K2023/06PE, i.e. polyethylene
    • B29K2023/0608PE, i.e. polyethylene characterised by its density
    • B29K2023/065HDPE, i.e. high density polyethylene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/04Polymers of ethylene
    • B29K2023/08Copolymers of ethylene
    • B29K2023/083EVA, i.e. ethylene vinyl acetate copolymer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/10Polymers of propylene
    • B29K2023/12PP, i.e. polypropylene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2027/00Use of polyvinylhalogenides or derivatives thereof as moulding material
    • B29K2027/06PVC, i.e. polyvinylchloride
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2067/00Use of polyesters or derivatives thereof, as moulding material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2067/00Use of polyesters or derivatives thereof, as moulding material
    • B29K2067/04Polyesters derived from hydroxycarboxylic acids
    • B29K2067/046PLA, i.e. polylactic acid or polylactide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2077/00Use of PA, i.e. polyamides, e.g. polyesteramides or derivatives thereof, as moulding material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D2203/00Decoration means, markings, information elements, contents indicators
    • B65D2203/02Labels
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W90/00Enabling technologies or technologies with a potential or indirect contribution to greenhouse gas [GHG] emissions mitigation
    • Y02W90/10Bio-packaging, e.g. packing containers made from renewable resources or bio-plastics

Definitions

  • the present invention relates to a container for liquid compositions comprising a surface topography, a reservoir comprising a liquid composition and an in-mold label positioned proximate to the surface topography thereby increasing the resilience of the container.
  • Liquid composition such as shampoos, conditioners, bodywash, in-shower moisturizers, lotions, detergents, toothpaste, ketchup and the like are commonly packaged in blow molded containers.
  • Consumers desire a container from which it is easy to dispense the contents.
  • dispensing is effected by the geometry of the container, orientation (e.g., inverted containers also known as “tottles”), material, orifice design and thickness of the container.
  • orientation e.g., inverted containers also known as “tottles”
  • material e.g., inverted containers also known as “tottles”
  • thickness of the container e.g., a high degree of resilience is desirable as consumers often need to squeeze the container several times to dispense enough product.
  • An increase in thickness of the squeezable wall may result in an increase of the resilience, and said wall may reform its shape quicker.
  • Labels are commonly comprised on these containers for decoration purposes and to provide information to the user, such as the composition's formula, or the method of use. Labels also may improve the intrinsic properties of containers, such as the deformation characteristics and restorative capability after squeezing.
  • in-mold label One type of label that is used is an in-mold label.
  • the most common process for in-mold labeling is blow molding.
  • In-mold labeling during production of containers by blow molding is known in the prior art.
  • a label is laid in the opened blow mold, usually by a robot, in such a way that the printed outside of the label is in contact with the mold wall, and the unprinted inside faces the blow molding to be shaped.
  • the still- molten surface of the polymer composition comes into close contact with the label and bonds thereto to give a label ed container.
  • the label is either, particularly in the case of simple in-label shapes, supplied in roll form and cut to size at the blow-molding machine (“cut in place”) or, in the case of more complex label shapes, cut to size in advance and away from the blow-molding machine, stacked and later segregated from the stack at the blow-molding machine (cut & stack process) and introduced individually into the respective blow mold.
  • Films made from thermoplastics have recently increasingly been used for the in-mold labeling of containers.
  • the films which are suitable for a use of this type have to have a selected property profile in order to ensure that the in-mold label 6 and mold nestle against one another in a flat and bubble-free manner and for the label to properly bond to the container.
  • Known labels result in bubbles and wrinkles if there is surface texture present such as a ridge on the face of the container. Bubbles and other optical defects occur more often in containers that have surface topographies with high degree of curvature and when the labels are thinner than 4.5 mils.
  • the object of the present invention was to provide an inexpensive method of decorating highly curved or texturized surfaces through an in-mold label that also helps to improve the resilience of a container comprising a liquid composition.
  • the object on which the invention is achieved is by the use of a film comprising at least one layer selected from the group consisting of polyethylene, copolymers of polyethylene, polypropylene, copolymers of polypropylene, nylon, polyester, copolymers of polyester, polylactic acid, cellophane, polyvinyl chloride, ionomers, ethylene-acrylic acid copolymers, metallocene polyethylene, metallocene polypropylene, and mixtures thereof having a thickness of at least 4.5 mils.
  • the present invention is directed to a container for liquid compositions comprising a reservoir comprising a liquid composition, a surface topography, and an in-mold label positioned proximate to the surface topography.
  • the surface topography selected from the group consisting of ridges, valleys, a grooves, dimples, depressions, bumps, convexity, concavity, ribs, protrusions, curves, raised surfaces or other surface topography.
  • the in-mold label has a thickness of at least 4.5 mils.
  • the in-mold label is comprised of a material selected from the group consisting of polyethylene, copolymers of polyethylene, polypropylene, copolymers of polypropylene, nylon, polyester, copolymers of polyester, polylactic acid, cellophane, polyvinyl chloride, ionomers, ethylene-acrylic acid copolymers, metallocene polyethylene, metallocene polypropylene, and mixtures thereof.
  • the present invention also includes a method of increasing resiliency in containers for liquid compositions.
  • FIG. 1 illustrates a perspective view of the container of the present invention is a bottle.
  • FIG. 2 illustrates a perspective view of the container of the present invention is a tottle.
  • ambient conditions refers to surrounding conditions at one (1) atmosphere of pressure, 50% relative humidity, and 25° C.
  • bottle is a hollow rigid or semi-rigid container having a comparatively narrow dispensing end (neck or mouth).
  • the dispensing end is typically the end where the bottle's contents is filled into and dispensed from.
  • liquid composition refers to the compositions of the present invention, wherein the compositions are intended to include, but are not limited to, compositions for topical application to the skin, hair, teeth, body, surfaces, and fabric fibers.
  • Such compositions can include, but are not limited to, shampoos, conditioners, tooth cleansers, hair styling products, cleaners, soaps, cosmetics, foundations, antiperspirants, deodorants, lotions, creams, ointments, kitchen and bathroom cleansers, floor cleansers, dishwashing liquid, fabric softener, laundry detergent, fabric freshener, snacks, beverages, combinations thereof, and the like.
  • splitting refers to a striped design with a veined and/or mottled appearance similar to marble.
  • phase refers to a homogeneous, physically distinct, and mechanically separable portion of matter present in a non-homogeneous physical-chemical system.
  • the phases herein are compositions with different colors.
  • the phases comprise the same chemical compositions but with different colorants.
  • compositions of the present invention refers to the compositions of the present invention, wherein the compositions are intended to include compositions for topical application to the skin or hair.
  • Such personal care compositions can include, but are not limited to, shampoos, conditioners, hair styling products, cleansers, soaps, cosmetics, foundations, antiperspirants, deodorants, lotions, creams, ointments, combinations thereof, and the like.
  • a personal care composition comprises at least two phases that are present within the container as distinct layers or “stripes.”
  • the stripes may be relatively uniform and even across the dimension of the package.
  • the layers may be uneven, i.e. wavy, or may be non-uniform in dimension.
  • the stripes do not necessarily extend across the entire dimension of the package.
  • the “stripe” can comprise various geometric patterns, various colors and, or glitter or pearlescence, providing that the concentration of said alternative forms visually distinct bands or regions.
  • surface topography selected from the group consisting of ridges, valleys, a grooves, dimples, depressions, bumps, convexity, concavity, ribs, protrusions, curves, raised surfaces or other surface topography.
  • tottle refers to a bottle which rests on neck or mouth which its contents are filled in and dispensed from, but it is also the end upon which the bottle is intended to rest or sit upon (e.g., the bottle's base) for storage by the consumer and/or for display on the store shelf (this bottle is referred to herein as a “tottle”).
  • the closure on a tottle is flat or concave, such that the tottle, when stored, rests on the closure.
  • the closure can be, for example, a cap, flip-top, screw-on, screw-on flip-top cap, etc.
  • compositions in the package or upon being dispensed that display visually different phases. These different phases are either distinctively separate or partially mixed as long as the multiple phase composition remains visible to the naked eye.
  • the present invention is directed towards a container 2 for compositions as shown in FIG. I and FIG. 2 .
  • the container has a dispensing end 10 and a non-dispensing end 12 .
  • the dispensing end has a closure 14 .
  • the container 2 is a bottle 16 with a flat closure 14 .
  • the container 2 is a tottle 18 .
  • a clear or opaque container 2 is used.
  • the container 2 is made from a polyolefin, such as polypropylene, polyethylene (e.g., linear low density, low density, medium density, high density, copolymers such as ethylene, vinyl, and acetate), polyethylene terephthalate and co-polymers, and nylon.
  • the container 2 is a bottle 16 that is filled from the dispensing end 10 .
  • the closure 14 on a tottle 18 is flat or concave, such that the tottle, when stored, rests on the closure.
  • the closure 14 can be, for example, a cap, flip-top, screw-on, screw-on flip-top cap, etc.
  • a tottle 18 can be a preferred container 2 . If a tottle 18 is used, the personal care composition can be stored with the end from which it was filled facing downward. This avoids the need to tip the container 2 over to dispense product upon each usage by the consumer, thus eliminating the movement of air bubble(s) through the length of the product in the package upon each usage occasion by the consumer. Movement of air bubble(s) through the length of the product is undesirable from an aesthetic standpoint, as this can disrupt the attractive appearance of a product having visually distinct phases. This loss of product attractiveness undesirably detracts from the consumer's enjoyment of the product.
  • the container 2 is a bottle 16 that can stand on either end in an upright position.
  • the container 2 comprises a reservoir 4 containing a liquid composition and an in-mold label 6 .
  • the in-mold label 6 has a thickness of at least 4.5 mils; the in-mold label 6 comprising a film selected from the group of polyethylene, copolymers of polyethylene, polypropylene, copolymers of polypropylene, nylon, polyester, copolymers of polyester, polylactic acid, cellophane, polyvinyl chloride, ionomers, ethylene-acrylic acid copolymers, metallocene polyethylene, metallocene polypropylene, and mixtures thereof.
  • Types of polyethylenes include high density polyethylene (HDPE), medium density polyethylene (MDPE), low density polyethylene (LDPE), linear low density polyethylene (LLDPE).
  • Copolymers of polyethylene include polyethylene copolymers such as ethylene vinyl acetate (EVA) or ethylene.
  • the in-mold labeling process consists of placing an in-mold label 6 in an open mold in which the in-mold label 6 is held in place by vacuum, electrostatic or other means. The mold is closed and the molten plastic is forced into the mold. In-mold labeling can be done using injection or blow molding, however blow molding is the preferred process. In blow molding, air is introduced into the mold cavity which forces the molten resin in contact with the in-mold label 6 which fuses to the container 2 .
  • In-mold labeling produces excellent aesthetics as the in-mold label 6 fuses with the container 2 during the molding process. With a clear in-mold label 6 , the appearance can often be similar to printing on the container 2 . Printing onto a curved surface can be very difficult and requires an additional step. Printing onto a plastic surface can result in scuffing or smearing which is undesirable. With in-mold labeling, no additional printing or labeling step is required thus making it a very efficient process.
  • Blow molded containers 2 can be made from polyethylene and polyethylene copolymers including high density polyethylene (HDPE), medium density polyethylene (MDPE), low density polyethylene (LDPE), linear low density polyethylene (LLDPE), polyamide resins, ionomer resins, polyvinylchloride, ethylene vinyl acetate (EVA), polyester (PET) and polyester copolymers, polypropylene (PP and mixtures thereof.
  • HDPE high density polyethylene
  • MDPE medium density polyethylene
  • LDPE low density polyethylene
  • LLDPE linear low density polyethylene
  • polyamide resins polyamide resins
  • ionomer resins polyvinylchloride
  • EVA ethylene vinyl acetate
  • PET polyester copolymers
  • PP polypropylene
  • in-mold labeling is that it can be difficult for an in-mold label 6 to be placed over a surface topography with high curvature such as a ridge or valley as air can become trapped underneath the in-mold label 6 which is not desirable for consumers especially when a “no-label” look is desired. Also, the surface topography can make the label material fold on itself upon blowing of the container thereby creating an undesirable wrinkle or crease.
  • the present invention overcomes these limitations by using a thick in-mold label 6 that is capable of being applied in-mold without entrapment of air and which is not as susceptible to wrinkling or creasing.
  • in-mold labels 6 are placed on containers 2 with smooth surfaces. It was previously difficult to use in-mold labels 6 in on a surface topography 20 or especially if that surface topography comprises a transition from a concavity to a convexity 22 or a transition from a convexity to a concavity 22 on the container 2 .
  • the present invention is directed towards an in-mold label 6 of sufficient thickness that is placed over a surface topography.
  • the containers 2 of the present invention may be any shape known in the art. Most preferred are generally oval containers.
  • the containers 2 used in one of the embodiments of the present invention have at least one surface topography 20 selected from the group consisting of ridges, valleys, grooves, dimples, depressions, bumps, convexity, concavity, ribs, protrusions, curves, raised surfaces or other surface topography.
  • the surface topography 20 on the container 2 is typically positioned proximate to or on or covered by the in-mold label 6 .
  • the in-mold label 6 is at least 4.5 mils in thickness.
  • the in-mold label 6 has a thickness ranging from about 4.5 mils to about 40 mils, preferably from about 6 mils to 12 mils, even more preferably from about 8 mils to 12 mils, even more preferably from about 10 mils to about 12 mils, even more preferably from about 8 mils to 20 mils; with a maximum of 40 mils.
  • a thick in-mold label 6 provides additional benefits in terms of resistance to squeezing, as the fused material becomes a structural part of the container thus improving its resilience and allowing for easier dispensing of fluids.
  • the in-mold label 6 may be made by techniques known in the art.
  • the primary process is film extrusion.
  • the in-mold label 6 may consist of one layer or multiple layers.
  • a common process for producing in-mold label 6 s is co extrusion whereby the heat seal layer consists of a resin with a lower melting point than the printing surface in order to avoid any distortion.
  • Another common process for producing in-mold labels 6 is by laminating two or more separate films with an adhesive or tie layer between each film.
  • the in-mold label 6 may contain additional layers of paper or foil.
  • the in-mold label 6 is pre-printed/decorated before being placed in the mold using processes known in the art. Decoration may include foil, inks, paper, holograms or other techniques. Secondary labels such as coupons or instructions could also be attached.
  • the in-mold label 6 of the present invention may be multilayered having an inner layer and at least one outer layer. In some embodiments, the inner layer and the outer layer may have different melting points. In some embodiments, the inner layer may have a lower melting point that the outer layer.
  • the inner layer of the in-mold label is preferably heat sealable.
  • the film according to the invention can have three layers and can comprise co extruded layers including the base layer and at least one top layer on both sides. If desired, two-layered, four-layered, five-layered or more layered embodiments are also possible.
  • the film is preferably comprised of a polyolefin, preferably a propylene polymer, and optionally fillers and further additives in effective amounts in each case.
  • the film material is a polypropylene/polyethylene co-extruded film with an EVA adhesive layer.
  • propylene polymers comprise about 70% by weight of the material and 30% by weight of the material is polyethylene.
  • Preferred polyolefins are propylene polymers. These propylene polymers comprise from 90 to 100% by weight, preferably from 95 to 100% by weight, in particular from 98 to 100% by weight, of propylene units, and have a melting point of 120° C.
  • propylene polymers for the base layer, with isotactic propylene homopolymer being particularly preferred.
  • the stated percentages by weight are based on the respective polymer.
  • propylene polymer Also suitable is a mixture of said propylene homopolymers and/or copolymers and/or terpolymers with other polyolefins, in particular made from monomers having from 2 to 6 carbon atoms, where the mixture comprises at least 50% by weight, in particular at least 75% by weight, of propylene polymer.
  • Suitable other polyolefins in the polymer mixture are polyethylenes, in particular HDPE, MDPE, LDPE, VLDPE and LLDPE, where the proportion of these polyolefins is in each case not in excess of 15% by weight, based on the polymer mixture.
  • the inner surface, inner layer that comes into contact with the molten resin must be capable of forming a seal with the container 2 such that it does not easily come off.
  • the inner layer should be capable of melting at the temperature of the molten resin that is used to form the container 2 .
  • the inner layer should be a heat seal layer.
  • the inner layer can be an adhesive layer.
  • the inner layer is preferably comprised of EVA or LDPE.
  • the in-mold label 6 is pre-printed/decorated before being placed in the mold using processes known in the art.
  • Decoration may include foil, inks, paper, holograms or other techniques. Secondary labels such as coupons or instructions could also be attached.
  • the outer layer of the multilayered film generally comprises at least 70% by weight, preferably from 75 to less than 100% by weight, in particular from 90 to 98% by weight, of a propylene polymer and in general antiblocking agents and stabilizers and, if desired, further conventional additives, such as lubricants, for example fatty acid amides or siloxanes, in effective amounts in each case. Preference is given to embodiments of the outer layer which comprise fatty acid amides. The above data in % by weight are based on the weight of the top layer.
  • the propylene polymer of the outer layer is preferably a copolymer of propylene and ethylene or propylene and butylene or propylene and another olefin having from 5 to 10 carbon atoms. Also suitable for the purposes of the invention are terpolymers of ethylene and propylene and butylene or ethylene and propylene and another olefin having from 5 to 10 carbon atoms. It is also possible to employ mixtures or blends of two or more of said copolymers and terpolymers.
  • ethylene-propylene copolymers and ethylene-propylenebutylene terpolymers preference is given to ethylene-propylene copolymers and ethylene-propylenebutylene terpolymers, in particular random ethylene-propylene copolymers having an ethylene content of from 2 to 10% by weight, preferably from 5 to 8% by weight, or random ethylene-propylene-1-butylene terpolymers having an ethylene content of from 1 to 10% by weight, preferably from 2 to 6% by weight, and a 1-butylene content of from 3 to 20% by weight, preferably from 8 to 10% by weight, in each case based on the weight of the copolymer or terpolymer.
  • PP, OPP or BOPP films are corona- or flame-treated on one side, preferably on the outer layer, in order to anchor printing inks, metal layers or adhesives to be applied.
  • the opposite, inner layer usually remains untreated.
  • the in-mold label 6 film according to the invention proved to be particularly simple and reliable to segregate in an embodiment with corona- or flame-pretreatment on both sides.
  • the in-mold label thickness is at least 4.5 mils. In a preferred embodiment the in-mold label thickness is 7.75 mils. In a preferred embodiment the film used to make the label is FasClear® 8SFC in-mold film from Avery Dennison.
  • the in-mold labeling process consists of placing an in-mold label 6 in an open mold in which the in-mold label 6 is held in place by vacuum, electrostatic or other means. The mold is closed and the molten plastic is forced into the mold. In-mold labeling can be done using injection or blow molding, however blow molding is the preferred process. In blow molding, air is introduced into the mold cavity which forces the molten resin in contact with the in-mold label 6 which fuses to the container 2 .
  • the container 2 of the present invention is typically formed by blow-molding.
  • the present invention also comprises a method of increasing resiliency of a container for liquid compositions.
  • the method comprises manufacturing a container for a liquid composition comprising a reservoir comprising a liquid composition, a surface topography selected from the group consisting of ridges, valleys, a grooves, dimples, depressions, bumps, convexity, concavity, ribs, protrusions, curves, raised surfaces or other surface topography.
  • the method comprises positioning an in-mold label proximate to said surface topography.
  • the in-mold label has a thickness of at least 4.5 mils.
  • the in-mold label is comprised of a material selected from the group consisting of polyethylene, copolymers of polyethylene, polypropylene, copolymers of polypropylene, nylon, polyester, copolymers of polyester, polylactic acid, cellophane, polyvinyl chloride, ionomers, ethylene-acrylic acid copolymers, metallocene polyethylene, metallocene polypropylene, and mixtures thereof.
  • the liquid composition of the present invention can be selected from the group consisting of personal care composition, cosmetic compositions, detergent compositions, medicaments, and foodstuffs.
  • suitable liquid compositions can include shampoos, conditioners, foundations, washes, soaps, and the like.
  • the liquid compositions used to in making the personal care compositions herein have substantially the same density and/or rheology.
  • suitable examples of compositions that can be used herein include, but are not limited to, U.S. Pat. No. 4,159,028, issued Jun. 26, 1979, in the name of Barker et al.: U.S. Pat. No. 4,335,103, issued Jun. 15, 1982, in the name of Barker et al.; U.S. Pat. No. 6,245,344, issued Jun.
  • At least two liquid compositions are used that are physically distinct, preferably visually distinct.
  • the visually distinct phases are of a different color.
  • one or more phases can comprise a dye, pigment, pearlescent agent, lake, coloring, or mixtures thereof.
  • Colorants useful in the present invention can be, for example, selected from the group consisting of Red 30 Low Iron, FD&C Red 40 AL Lake, D&C Red Lake Blend of Lake 27 & Lake 30, FD&C Yellow 5 Al Lake, FD&C Yellow 6 Al Lake, FD&C Yellow 5 Lake, FD&C Blue #1 AL Lake, Kowet Titanium Dioxide, D&C Red 30 Talc Lake, D&C Red 6 Barium Lake, D&C Red 7 Calcium Lake, D&C Red 34 Calcium Lake, D&C Red 30 AL lake, D&C Red 27 AL lake, D&C Yellow 10 AL lake, D&C Red 21 AL Lake, Yellow Iron Oxide, D&C Red 30 Lake, Octocir Yellow 6 AL Lake, Octocir Yellow 5 AL Lake, D&C Red 28 Lake, D&C Orange 5 Zirc Al Lake, Cos Red Oxide BC, Cos Iron Oxide Red BC, Cos Iron oxide Black BC, Cos Iron Oxide Yellow, Cos Iron Oxide Brown, Cos Iron Oxide Yellow BC, Euroxide Red Unsteril
  • the personal care composition comprises at least two physically distinct phases.

Abstract

A container for liquid compositions including a reservoir including a liquid composition a surface topography and an in-mold label positioned proximate to the surface topography to improve the resilience of the container. The surface topography is selected from the group consisting of ridges, valleys, grooves, dimples, depressions, bumps, convexity, concavity, ribs, protrusions, curves, raised surfaces or other surface topography. The in-mold label has a thickness of at least 4.5 mils; wherein the in-mold label is made from a material selected selected from the group consisting of polyethylene, copolymers of polyethylene, polypropylene, copolymers of polypropylene, nylon, polyester, copolymers of polyester, polylactic acid, cellophane, polyvinyl chloride, ionomers, ethylene-acrylic acid copolymers, metallocene polyethylene, metallocene polypropylene, and mixtures thereof.

Description

    CROSS REFERENCE TO RELATED APPLICATION
  • This application claims the benefit of U.S. Provisional Application No. 60/748,733, filed Dec. 8, 2005.
  • FIELD OF THE INVENTION
  • The present invention relates to a container for liquid compositions comprising a surface topography, a reservoir comprising a liquid composition and an in-mold label positioned proximate to the surface topography thereby increasing the resilience of the container.
  • BACKGROUND OF THE INVENTION
  • Liquid composition, such as shampoos, conditioners, bodywash, in-shower moisturizers, lotions, detergents, toothpaste, ketchup and the like are commonly packaged in blow molded containers. Consumers desire a container from which it is easy to dispense the contents. For squeezable containers, dispensing is effected by the geometry of the container, orientation (e.g., inverted containers also known as “tottles”), material, orifice design and thickness of the container. In the case of squeezable containers, a high degree of resilience is desirable as consumers often need to squeeze the container several times to dispense enough product. An increase in thickness of the squeezable wall may result in an increase of the resilience, and said wall may reform its shape quicker. However users typically do not like containers with thick plastic walls, as the containers can be harder to squeeze. These containers may also be more expensive to manufacture as more material is required to form the wall. Labels are commonly comprised on these containers for decoration purposes and to provide information to the user, such as the composition's formula, or the method of use. Labels also may improve the intrinsic properties of containers, such as the deformation characteristics and restorative capability after squeezing.
  • One type of label that is used is an in-mold label. The most common process for in-mold labeling is blow molding. In-mold labeling during production of containers by blow molding is known in the prior art. In this process, a label is laid in the opened blow mold, usually by a robot, in such a way that the printed outside of the label is in contact with the mold wall, and the unprinted inside faces the blow molding to be shaped. During introduction of the tubular melt and shaping of the parison by the air pressure, the still- molten surface of the polymer composition comes into close contact with the label and bonds thereto to give a label ed container.
  • In this labeling process, it must be ensured that the label lies against the mold wall in a flat and fold-free manner. This is achieved either by means of vacuum applied to fine air-removal perforations in such a way that the perforations are substantially sealed by the label, or by means of electrostatic forces between the electrostatically charged label and the earthed mold.
  • In this production process, the label is either, particularly in the case of simple in-label shapes, supplied in roll form and cut to size at the blow-molding machine (“cut in place”) or, in the case of more complex label shapes, cut to size in advance and away from the blow-molding machine, stacked and later segregated from the stack at the blow-molding machine (cut & stack process) and introduced individually into the respective blow mold.
  • Films made from thermoplastics have recently increasingly been used for the in-mold labeling of containers. The films which are suitable for a use of this type have to have a selected property profile in order to ensure that the in-mold label 6 and mold nestle against one another in a flat and bubble-free manner and for the label to properly bond to the container. Known labels result in bubbles and wrinkles if there is surface texture present such as a ridge on the face of the container. Bubbles and other optical defects occur more often in containers that have surface topographies with high degree of curvature and when the labels are thinner than 4.5 mils. However, it is often desired to decorate such texturized or highly curved surfaces to enhance the container's appeal to consumers and to direct attention to a particular feature such as a logo, version name, and the like. This is usually achieved through a post-molding secondary decoration step such as silk screening, applying a sticker, pad printing, etc., which results in increased cost. It has now been found that the use of a thick film allows the labeling of surface textures such as a ridge and of highly curved areas without resulting in bubbles, wrinkles or any other optical defects as occurs with known labels. It also has been found that a thick label helps to increase the resilience of the container allowing the wall of the container to reform its shape quicker and allowing its contents to be more easily dispensed. It also helps to reduce material fatigue caused by repeated squeezing of the container wall and which can lead to permanent deformation of said wall making the container harder to squeeze. The object of the present invention was to provide an inexpensive method of decorating highly curved or texturized surfaces through an in-mold label that also helps to improve the resilience of a container comprising a liquid composition. In particular, it should be possible to apply the film as a bubble-free in-mold label to curved bodies, including those having certain surface topographies and without creating wrinkles or any other optical defects.
  • The object on which the invention is achieved is by the use of a film comprising at least one layer selected from the group consisting of polyethylene, copolymers of polyethylene, polypropylene, copolymers of polypropylene, nylon, polyester, copolymers of polyester, polylactic acid, cellophane, polyvinyl chloride, ionomers, ethylene-acrylic acid copolymers, metallocene polyethylene, metallocene polypropylene, and mixtures thereof having a thickness of at least 4.5 mils.
  • SUMMARY OF THE INVENTION
  • The present invention is directed to a container for liquid compositions comprising a reservoir comprising a liquid composition, a surface topography, and an in-mold label positioned proximate to the surface topography. The surface topography selected from the group consisting of ridges, valleys, a grooves, dimples, depressions, bumps, convexity, concavity, ribs, protrusions, curves, raised surfaces or other surface topography. The in-mold label has a thickness of at least 4.5 mils. The in-mold label is comprised of a material selected from the group consisting of polyethylene, copolymers of polyethylene, polypropylene, copolymers of polypropylene, nylon, polyester, copolymers of polyester, polylactic acid, cellophane, polyvinyl chloride, ionomers, ethylene-acrylic acid copolymers, metallocene polyethylene, metallocene polypropylene, and mixtures thereof. The present invention also includes a method of increasing resiliency in containers for liquid compositions.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • FIG. 1 illustrates a perspective view of the container of the present invention is a bottle.
  • FIG. 2 illustrates a perspective view of the container of the present invention is a tottle.
  • DETAILED DESCRIPTION OF THE INVENTION
  • The term “ambient conditions” as used herein, unless otherwise specified, refers to surrounding conditions at one (1) atmosphere of pressure, 50% relative humidity, and 25° C.
  • The term “bottle” as used herein, is a hollow rigid or semi-rigid container having a comparatively narrow dispensing end (neck or mouth). The dispensing end (neck or mouth) is typically the end where the bottle's contents is filled into and dispensed from.
  • The term “liquid composition” as used herein, unless otherwise specified, refers to the compositions of the present invention, wherein the compositions are intended to include, but are not limited to, compositions for topical application to the skin, hair, teeth, body, surfaces, and fabric fibers. Such compositions can include, but are not limited to, shampoos, conditioners, tooth cleansers, hair styling products, cleaners, soaps, cosmetics, foundations, antiperspirants, deodorants, lotions, creams, ointments, kitchen and bathroom cleansers, floor cleansers, dishwashing liquid, fabric softener, laundry detergent, fabric freshener, snacks, beverages, combinations thereof, and the like.
  • The term “marbling” as used herein refers to a striped design with a veined and/or mottled appearance similar to marble.
  • The term “phase” as used herein refers to a homogeneous, physically distinct, and mechanically separable portion of matter present in a non-homogeneous physical-chemical system. In some embodiments, the phases herein are compositions with different colors. In some embodiments, the phases comprise the same chemical compositions but with different colorants.
  • The term “personal care composition” as used herein, unless otherwise specified, refers to the compositions of the present invention, wherein the compositions are intended to include compositions for topical application to the skin or hair. Such personal care compositions can include, but are not limited to, shampoos, conditioners, hair styling products, cleansers, soaps, cosmetics, foundations, antiperspirants, deodorants, lotions, creams, ointments, combinations thereof, and the like.
  • The term “stripe” as used herein means that each phase present in the composition occupies separate but distinct physical spaces inside the package in which it is stored, but are in direct contact with one another. In one preferred embodiment of the present invention, a personal care composition comprises at least two phases that are present within the container as distinct layers or “stripes.” The stripes may be relatively uniform and even across the dimension of the package. Alternatively the layers may be uneven, i.e. wavy, or may be non-uniform in dimension. The stripes do not necessarily extend across the entire dimension of the package. The “stripe” can comprise various geometric patterns, various colors and, or glitter or pearlescence, providing that the concentration of said alternative forms visually distinct bands or regions.
  • The term “surface topography”, as used herein, selected from the group consisting of ridges, valleys, a grooves, dimples, depressions, bumps, convexity, concavity, ribs, protrusions, curves, raised surfaces or other surface topography.
  • As used herein “tottle” refers to a bottle which rests on neck or mouth which its contents are filled in and dispensed from, but it is also the end upon which the bottle is intended to rest or sit upon (e.g., the bottle's base) for storage by the consumer and/or for display on the store shelf (this bottle is referred to herein as a “tottle”). Typically, the closure on a tottle is flat or concave, such that the tottle, when stored, rests on the closure. In particular embodiments, the closure can be, for example, a cap, flip-top, screw-on, screw-on flip-top cap, etc.
  • The term “visually distinctive” or “visually distinct” as used herein describes compositions in the package or upon being dispensed that display visually different phases. These different phases are either distinctively separate or partially mixed as long as the multiple phase composition remains visible to the naked eye.
  • I. Container
  • The present invention is directed towards a container 2 for compositions as shown in FIG. I and FIG. 2.
  • Any suitable container 2 can be used herein. The container has a dispensing end 10 and a non-dispensing end 12. The dispensing end has a closure 14. In one embodiment, shown in FIG. 1, the container 2 is a bottle 16 with a flat closure 14. In another embodiment, shown in FIG. 2 the container 2 is a tottle 18.
  • In a specific embodiment, a clear or opaque container 2 is used. For instance, in a particular embodiment, the container 2 is made from a polyolefin, such as polypropylene, polyethylene (e.g., linear low density, low density, medium density, high density, copolymers such as ethylene, vinyl, and acetate), polyethylene terephthalate and co-polymers, and nylon.
  • In one embodiment, the container 2 is a bottle 16 that is filled from the dispensing end 10. Typically, the closure 14 on a tottle 18 is flat or concave, such that the tottle, when stored, rests on the closure. In particular embodiments, the closure 14 can be, for example, a cap, flip-top, screw-on, screw-on flip-top cap, etc.
  • In particular embodiments, a tottle 18 can be a preferred container 2. If a tottle 18 is used, the personal care composition can be stored with the end from which it was filled facing downward. This avoids the need to tip the container 2 over to dispense product upon each usage by the consumer, thus eliminating the movement of air bubble(s) through the length of the product in the package upon each usage occasion by the consumer. Movement of air bubble(s) through the length of the product is undesirable from an aesthetic standpoint, as this can disrupt the attractive appearance of a product having visually distinct phases. This loss of product attractiveness undesirably detracts from the consumer's enjoyment of the product.
  • In yet another embodiment, the container 2 is a bottle 16 that can stand on either end in an upright position.
  • In either configuration shown FIG. 1 and FIG. 2, the container 2 comprises a reservoir 4 containing a liquid composition and an in-mold label 6. The in-mold label 6 has a thickness of at least 4.5 mils; the in-mold label 6 comprising a film selected from the group of polyethylene, copolymers of polyethylene, polypropylene, copolymers of polypropylene, nylon, polyester, copolymers of polyester, polylactic acid, cellophane, polyvinyl chloride, ionomers, ethylene-acrylic acid copolymers, metallocene polyethylene, metallocene polypropylene, and mixtures thereof. Types of polyethylenes include high density polyethylene (HDPE), medium density polyethylene (MDPE), low density polyethylene (LDPE), linear low density polyethylene (LLDPE). Copolymers of polyethylene include polyethylene copolymers such as ethylene vinyl acetate (EVA) or ethylene.
  • The in-mold labeling process consists of placing an in-mold label 6 in an open mold in which the in-mold label 6 is held in place by vacuum, electrostatic or other means. The mold is closed and the molten plastic is forced into the mold. In-mold labeling can be done using injection or blow molding, however blow molding is the preferred process. In blow molding, air is introduced into the mold cavity which forces the molten resin in contact with the in-mold label 6 which fuses to the container 2.
  • There are several advantages to in-mold labeling. In-mold labeling produces excellent aesthetics as the in-mold label 6 fuses with the container 2 during the molding process. With a clear in-mold label 6, the appearance can often be similar to printing on the container 2. Printing onto a curved surface can be very difficult and requires an additional step. Printing onto a plastic surface can result in scuffing or smearing which is undesirable. With in-mold labeling, no additional printing or labeling step is required thus making it a very efficient process.
  • Blow molded containers 2 can be made from polyethylene and polyethylene copolymers including high density polyethylene (HDPE), medium density polyethylene (MDPE), low density polyethylene (LDPE), linear low density polyethylene (LLDPE), polyamide resins, ionomer resins, polyvinylchloride, ethylene vinyl acetate (EVA), polyester (PET) and polyester copolymers, polypropylene (PP and mixtures thereof. A greater improvement in resilience is observed with materials that are relatively less stiff such as polyethylene and polyethylene copolymers.
  • One limitation however with in-mold labeling is that it can be difficult for an in-mold label 6 to be placed over a surface topography with high curvature such as a ridge or valley as air can become trapped underneath the in-mold label 6 which is not desirable for consumers especially when a “no-label” look is desired. Also, the surface topography can make the label material fold on itself upon blowing of the container thereby creating an undesirable wrinkle or crease. The present invention overcomes these limitations by using a thick in-mold label 6 that is capable of being applied in-mold without entrapment of air and which is not as susceptible to wrinkling or creasing.
  • Typically in-mold labels 6 are placed on containers 2 with smooth surfaces. It was previously difficult to use in-mold labels 6 in on a surface topography 20 or especially if that surface topography comprises a transition from a concavity to a convexity 22 or a transition from a convexity to a concavity 22 on the container 2. The present invention is directed towards an in-mold label 6 of sufficient thickness that is placed over a surface topography.
  • The containers 2 of the present invention may be any shape known in the art. Most preferred are generally oval containers. The containers 2 used in one of the embodiments of the present invention have at least one surface topography 20 selected from the group consisting of ridges, valleys, grooves, dimples, depressions, bumps, convexity, concavity, ribs, protrusions, curves, raised surfaces or other surface topography. The surface topography 20 on the container 2 is typically positioned proximate to or on or covered by the in-mold label 6.
  • The in-mold label 6 is at least 4.5 mils in thickness. The in-mold label 6 has a thickness ranging from about 4.5 mils to about 40 mils, preferably from about 6 mils to 12 mils, even more preferably from about 8 mils to 12 mils, even more preferably from about 10 mils to about 12 mils, even more preferably from about 8 mils to 20 mils; with a maximum of 40 mils. Furthermore a thick in-mold label 6 provides additional benefits in terms of resistance to squeezing, as the fused material becomes a structural part of the container thus improving its resilience and allowing for easier dispensing of fluids. Furthermore a thick in-mold label 6 is better able to provide insulation between the molten resin and the mold surface, thus allowing for temperature sensitive inks and decoration to be used that could not otherwise be used. A thin in-mold label 6 may result in wrinkling or creasing which is undesirable. The in-mold label 6 may be made by techniques known in the art. The primary process is film extrusion. The in-mold label 6 may consist of one layer or multiple layers. A common process for producing in-mold label 6 s is co extrusion whereby the heat seal layer consists of a resin with a lower melting point than the printing surface in order to avoid any distortion. Another common process for producing in-mold labels 6 is by laminating two or more separate films with an adhesive or tie layer between each film. The in-mold label 6 may contain additional layers of paper or foil.
  • The in-mold label 6 is pre-printed/decorated before being placed in the mold using processes known in the art. Decoration may include foil, inks, paper, holograms or other techniques. Secondary labels such as coupons or instructions could also be attached. The in-mold label 6 of the present invention may be multilayered having an inner layer and at least one outer layer. In some embodiments, the inner layer and the outer layer may have different melting points. In some embodiments, the inner layer may have a lower melting point that the outer layer. The inner layer of the in-mold label is preferably heat sealable.
  • The film according to the invention can have three layers and can comprise co extruded layers including the base layer and at least one top layer on both sides. If desired, two-layered, four-layered, five-layered or more layered embodiments are also possible. The film is preferably comprised of a polyolefin, preferably a propylene polymer, and optionally fillers and further additives in effective amounts in each case.
  • In some preferred embodiments, the film material is a polypropylene/polyethylene co-extruded film with an EVA adhesive layer. In these embodiments, propylene polymers comprise about 70% by weight of the material and 30% by weight of the material is polyethylene.
  • Preferred polyolefins are propylene polymers. These propylene polymers comprise from 90 to 100% by weight, preferably from 95 to 100% by weight, in particular from 98 to 100% by weight, of propylene units, and have a melting point of 120° C. or above, preferably from 150 to 170° C., Isotactic propylene homopolymer having an atactic content of 15% by weight or less, copolymers of ethylene and propylene having an ethylene content of 5% by weight or less, copolymers of propylene with C4-C8-olefins having an olefin content of 5% by weight or less, terpolymers of propylene, ethylene and butylene having an ethylene content of 10% by weight or less and having a butylene content of 15% by weight or less are preferred propylene polymers for the base layer, with isotactic propylene homopolymer being particularly preferred. The stated percentages by weight are based on the respective polymer.
  • Also suitable is a mixture of said propylene homopolymers and/or copolymers and/or terpolymers with other polyolefins, in particular made from monomers having from 2 to 6 carbon atoms, where the mixture comprises at least 50% by weight, in particular at least 75% by weight, of propylene polymer.
  • Suitable other polyolefins in the polymer mixture are polyethylenes, in particular HDPE, MDPE, LDPE, VLDPE and LLDPE, where the proportion of these polyolefins is in each case not in excess of 15% by weight, based on the polymer mixture.
  • The inner surface, inner layer that comes into contact with the molten resin must be capable of forming a seal with the container 2 such that it does not easily come off. The inner layer should be capable of melting at the temperature of the molten resin that is used to form the container 2. Preferably, the inner layer should be a heat seal layer. The inner layer can be an adhesive layer. The inner layer is preferably comprised of EVA or LDPE.
  • The in-mold label 6 is pre-printed/decorated before being placed in the mold using processes known in the art. Decoration may include foil, inks, paper, holograms or other techniques. Secondary labels such as coupons or instructions could also be attached.
  • The outer layer of the multilayered film generally comprises at least 70% by weight, preferably from 75 to less than 100% by weight, in particular from 90 to 98% by weight, of a propylene polymer and in general antiblocking agents and stabilizers and, if desired, further conventional additives, such as lubricants, for example fatty acid amides or siloxanes, in effective amounts in each case. Preference is given to embodiments of the outer layer which comprise fatty acid amides. The above data in % by weight are based on the weight of the top layer.
  • The propylene polymer of the outer layer is preferably a copolymer of propylene and ethylene or propylene and butylene or propylene and another olefin having from 5 to 10 carbon atoms. Also suitable for the purposes of the invention are terpolymers of ethylene and propylene and butylene or ethylene and propylene and another olefin having from 5 to 10 carbon atoms. It is also possible to employ mixtures or blends of two or more of said copolymers and terpolymers.
  • For the outer layer, preference is given to ethylene-propylene copolymers and ethylene-propylenebutylene terpolymers, in particular random ethylene-propylene copolymers having an ethylene content of from 2 to 10% by weight, preferably from 5 to 8% by weight, or random ethylene-propylene-1-butylene terpolymers having an ethylene content of from 1 to 10% by weight, preferably from 2 to 6% by weight, and a 1-butylene content of from 3 to 20% by weight, preferably from 8 to 10% by weight, in each case based on the weight of the copolymer or terpolymer.
  • Frequently encountered embodiments of PP, OPP or BOPP films are corona- or flame-treated on one side, preferably on the outer layer, in order to anchor printing inks, metal layers or adhesives to be applied.
  • The opposite, inner layer usually remains untreated. On laying in the blow-molding machine in accordance with the cut & stack process, the in-mold label 6 film according to the invention proved to be particularly simple and reliable to segregate in an embodiment with corona- or flame-pretreatment on both sides.
  • The in-mold label thickness is at least 4.5 mils. In a preferred embodiment the in-mold label thickness is 7.75 mils. In a preferred embodiment the film used to make the label is FasClear® 8SFC in-mold film from Avery Dennison.
  • II. Method
  • The in-mold labeling process consists of placing an in-mold label 6 in an open mold in which the in-mold label 6 is held in place by vacuum, electrostatic or other means. The mold is closed and the molten plastic is forced into the mold. In-mold labeling can be done using injection or blow molding, however blow molding is the preferred process. In blow molding, air is introduced into the mold cavity which forces the molten resin in contact with the in-mold label 6 which fuses to the container 2. Preferably, the container 2 of the present invention is typically formed by blow-molding.
  • The present invention also comprises a method of increasing resiliency of a container for liquid compositions. The method comprises manufacturing a container for a liquid composition comprising a reservoir comprising a liquid composition, a surface topography selected from the group consisting of ridges, valleys, a grooves, dimples, depressions, bumps, convexity, concavity, ribs, protrusions, curves, raised surfaces or other surface topography. The method comprises positioning an in-mold label proximate to said surface topography. The in-mold label has a thickness of at least 4.5 mils. The in-mold label is comprised of a material selected from the group consisting of polyethylene, copolymers of polyethylene, polypropylene, copolymers of polypropylene, nylon, polyester, copolymers of polyester, polylactic acid, cellophane, polyvinyl chloride, ionomers, ethylene-acrylic acid copolymers, metallocene polyethylene, metallocene polypropylene, and mixtures thereof.
  • III. Liquid Composition
  • The liquid composition of the present invention can be selected from the group consisting of personal care composition, cosmetic compositions, detergent compositions, medicaments, and foodstuffs.
  • Any suitable liquid compositions can be used in the practice of the invention herein. For instance, suitable liquid compositions can include shampoos, conditioners, foundations, washes, soaps, and the like. Preferably, the liquid compositions used to in making the personal care compositions herein have substantially the same density and/or rheology. Suitable examples of compositions that can be used herein include, but are not limited to, U.S. Pat. No. 4,159,028, issued Jun. 26, 1979, in the name of Barker et al.: U.S. Pat. No. 4,335,103, issued Jun. 15, 1982, in the name of Barker et al.; U.S. Pat. No. 6,245,344, issued Jun. 12, 2001 in the name of Thibiant et al.; U.S. Pat. No. 6,367,519, issued Apr. 9, 2002, in the name of Thibiant et al.; U.S. Pat. No. 6,516,838, issued Feb. 11, 2003, in the name of Thibiant et al.
  • In a preferred embodiment, at least two liquid compositions are used that are physically distinct, preferably visually distinct. In a particular embodiment, the visually distinct phases are of a different color. For instance, one or more phases can comprise a dye, pigment, pearlescent agent, lake, coloring, or mixtures thereof. Colorants useful in the present invention can be, for example, selected from the group consisting of Red 30 Low Iron, FD&C Red 40 AL Lake, D&C Red Lake Blend of Lake 27 & Lake 30, FD&C Yellow 5 Al Lake, FD&C Yellow 6 Al Lake, FD&C Yellow 5 Lake, FD&C Blue #1 AL Lake, Kowet Titanium Dioxide, D&C Red 30 Talc Lake, D&C Red 6 Barium Lake, D&C Red 7 Calcium Lake, D&C Red 34 Calcium Lake, D&C Red 30 AL lake, D&C Red 27 AL lake, D&C Yellow 10 AL lake, D&C Red 21 AL Lake, Yellow Iron Oxide, D&C Red 30 Lake, Octocir Yellow 6 AL Lake, Octocir Yellow 5 AL Lake, D&C Red 28 Lake, D&C Orange 5 Zirc Al Lake, Cos Red Oxide BC, Cos Iron Oxide Red BC, Cos Iron oxide Black BC, Cos Iron Oxide Yellow, Cos Iron Oxide Brown, Cos Iron Oxide Yellow BC, Euroxide Red Unsteril, Euroxide Black Unsteril, Euroxide Yellow Steril, Euroxide Black Steril, Euroxide Red, Euroxide Black, Hydrophobic Euroxide Black, Hydrophobic Euroxide Yellow, Hydrophobic Euroxide Red, D&C Yellow 6 Lake, D&C Yellow 5 Zr Lake, and mixtures thereof.
  • In one embodiment, the personal care composition comprises at least two physically distinct phases.
  • The dimensions and values disclosed herein are not to be understood as being strictly limited to the exact numerical values recited. Instead, unless otherwise specified, each such dimension is intended to mean both the recited value and a functionally equivalent range surrounding that value. For example, a dimension disclosed as “40 mm” is intended to mean “about 40 mm”.
  • All documents cited in the Detailed Description of the Invention are, in relevant part, incorporated herein by reference; the citation of any document is not to be construed as an admission that it is prior art with respect to the present invention. To the extent that any meaning or definition of a term in this document conflicts with any meaning or definition of the same term in a document incorporated by reference, the meaning or definition assigned to that term in this document shall govern.
  • While particular embodiments of the present invention have been illustrated and described, it would be obvious to those skilled in the art that various other changes and modifications can be made without departing from the spirit and scope of the invention. It is therefore intended to cover in the appended claims all such changes and modifications that are within the scope of this invention.

Claims (13)

1. An container for liquid compositions comprising
a reservoir comprising said liquid composition;
a surface topography selected from the group consisting of ridges, valleys, a grooves, dimples, depressions, bumps, convexity, concavity, ribs, protrusions, curves, raised surfaces or other surface topography; and
an in-mold label positioned proximate to said surface topography;
wherein said in-mold label having a thickness of at least 4.5 mils;
wherein said in-mold label is comprised of a material selected from the group consisting of polyethylene, copolymers of polyethylene, polypropylene, copolymers of polypropylene, nylon, polyester, copolymers of polyester, polylactic acid, cellophane, polyvinyl chloride, ionomers, ethylene-acrylic acid copolymers, metallocene polyethylene, metallocene polypropylene, and mixtures thereof.
2. The container of claim 1, wherein said surface topography comprises a transition from a concavity to convexity.
3. The container of claim 1, wherein said in-mold label has a thickness of from about 4.5 mils to about 40 mils.
4. The container of claim 1, wherein said in-mold label has a thickness of from about 8 to about 12 mils.
5. The container of claim 1, wherein the in-mold label comprised of mixtures of polypropylene, polyethylene and copolymers of polyethylene wherein said copolymer of polyethylene is ethylene vinyl acetate.
6. The container of claim 1, wherein said in-mold label comprises an outer layer and an inner layer.
7. The container of claim 5, wherein the inner layer has a lower melting point that the outer layer.
8. The container of claim 5, wherein said inner layer is heat sealable.
9. The container of claim 5, wherein said inner layer is adhesive.
10. The container of claim 1, wherein said liquid composition is a personal care composition.
11. The container of claim 1 wherein the container is a tottle.
12. The container of claim 1, wherein the container is comprised of polyethylene.
13. The container of claim 1, further comprising a closure.
US11/635,977 2005-12-08 2006-12-08 Container comprising an in-mold label positioned proximate to a surface topography Abandoned US20070163990A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US11/635,977 US20070163990A1 (en) 2005-12-08 2006-12-08 Container comprising an in-mold label positioned proximate to a surface topography

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US74873305P 2005-12-08 2005-12-08
US11/635,977 US20070163990A1 (en) 2005-12-08 2006-12-08 Container comprising an in-mold label positioned proximate to a surface topography

Publications (1)

Publication Number Publication Date
US20070163990A1 true US20070163990A1 (en) 2007-07-19

Family

ID=38007270

Family Applications (1)

Application Number Title Priority Date Filing Date
US11/635,977 Abandoned US20070163990A1 (en) 2005-12-08 2006-12-08 Container comprising an in-mold label positioned proximate to a surface topography

Country Status (4)

Country Link
US (1) US20070163990A1 (en)
EP (1) EP1957374A2 (en)
CN (1) CN101326106A (en)
WO (1) WO2007066310A2 (en)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070155637A1 (en) * 2005-04-13 2007-07-05 Smith Edward D Iii Structured multi-phased personal cleansing composition comprising branched anionic surfactants
US20070167338A1 (en) * 2006-01-09 2007-07-19 Mchugh Colin M Multiphase personal care compositions comprising beads
US20090028808A1 (en) * 2007-07-27 2009-01-29 The Procter & Gamble Company Personal care article for sequentially dispensing compositions with variable concentrations of partitioned benefit or suspended benefit agents
US20090028809A1 (en) * 2007-07-27 2009-01-29 Jonathan Robert Cetti Personal care article for sequentially dispensing compositions with variable concentrations of hydrophobic benefit materials
US20100237068A1 (en) * 2009-03-17 2010-09-23 Rubbermaid Incorporated Container With In-Molded Exposed Panel
US7820609B2 (en) 2005-04-13 2010-10-26 The Procter & Gamble Company Mild, structured, multi-phase personal cleansing compositions comprising density modifiers
US20110159409A1 (en) * 2009-12-30 2011-06-30 Sipix Chemical Inc. Decorated device and method of fabricating the same
US8104616B2 (en) 2006-02-11 2012-01-31 The Procter & Gamble Company Clamshell package for holding and displaying consumer products
US8153144B2 (en) 2006-02-28 2012-04-10 The Proctor & Gamble Company Stable multiphase composition comprising alkylamphoacetate
USD667729S1 (en) 2011-03-07 2012-09-25 The Procter & Gamble Company Bottle
US20130256178A1 (en) * 2010-12-23 2013-10-03 Kao Germany Gmbh Container having a labeled textured surface
WO2016032460A1 (en) * 2014-08-27 2016-03-03 Colgate-Palmolive Company Bottle with finger recess
WO2019118865A1 (en) * 2017-12-14 2019-06-20 Csp Technologies, Inc. Container with lid having fluorinated polymer internal surface and methods for making the same

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5784648B2 (en) * 2013-01-31 2015-09-24 花王株式会社 Bottle container
SG11201509363XA (en) * 2013-05-17 2015-12-30 Nestec Sa Packages for consumable products and methods for using same
WO2016162003A1 (en) * 2015-04-06 2016-10-13 Kiefel Gmbh Method for combined in-mould labelling and embossing of a packaging product and system for combined in-mould labelling and embossing of a packaging product
CN109501419A (en) * 2018-10-30 2019-03-22 上海海顺新型药用包装材料股份有限公司 In-mold labels composite membrane

Citations (95)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2438091A (en) * 1943-09-06 1948-03-16 American Cyanamid Co Aspartic acid esters and their preparation
US2798053A (en) * 1952-09-03 1957-07-02 Goodrich Co B F Carboxylic polymers
US3937811A (en) * 1973-06-08 1976-02-10 Societe Anonyme Dite: L'oreal Fatty compositions for use in cosmetic makeup compositions and said cosmetic makeup compositions
US4159028A (en) * 1977-03-28 1979-06-26 Almay, Inc. Method of forming and containerizing a multiphase cosmetic composition
US4263363A (en) * 1979-12-20 1981-04-21 Colgate-Palmolive Company Emulsion-containing absorbent article having improved water holding capacity
US4335103A (en) * 1977-03-28 1982-06-15 Almay, Inc. Multiphase cosmetic composition
US4387090A (en) * 1980-12-22 1983-06-07 The Procter & Gamble Company Hair conditioning compositions
US4425322A (en) * 1981-06-11 1984-01-10 Colgate-Palmolive Company Dual-action dentifrice
US4509949A (en) * 1983-06-13 1985-04-09 The B. F. Goodrich Company Water thickening agents consisting of copolymers of crosslinked acrylic acids and esters
US4518578A (en) * 1983-05-16 1985-05-21 Colgate-Palmolive Company Dentifrice composition containing visually clear pigment-colored stripe
US4899877A (en) * 1989-02-13 1990-02-13 Bares Group Packaging of tools
US5011690A (en) * 1987-06-05 1991-04-30 Unilever Patent Holdings B.V. Spheroidal silica
US5087445A (en) * 1989-09-08 1992-02-11 Richardson-Vicks, Inc. Photoprotection compositions having reduced dermal irritation
US5223315A (en) * 1988-04-06 1993-06-29 Toyo Seikan Kaisha Ltd. Container equipped with label and production method thereof
US5228912A (en) * 1991-05-28 1993-07-20 Merck Patent Gesellschaft Mit Beschrankter Haftung Surface-modified, platelet-shaped pigments having improved dispersibility
US5248495A (en) * 1992-04-16 1993-09-28 The Procter & Gamble Company Post foaming shaving gel composition
USRE34584E (en) * 1984-11-09 1994-04-12 The Procter & Gamble Company Shampoo compositions
US5393450A (en) * 1992-11-09 1995-02-28 Lever Brothers Company, Division Of Conopco, Inc. Washing composition containing fatty acid esters
US5451396A (en) * 1993-11-17 1995-09-19 S. C. Johnson & Son, Inc. Shaving compositions
US5487168A (en) * 1992-06-15 1996-01-23 International Business Machines Corporation Method and system for global optimization of device allocation
US5487884A (en) * 1987-10-22 1996-01-30 The Procter & Gamble Company Photoprotection compositions comprising chelating agents
US5530054A (en) * 1989-09-13 1996-06-25 Exxon Chemical Patents Inc. Elastomeric ethylene copolymers for hot melt adhesives
US5556628A (en) * 1992-08-05 1996-09-17 Rhone-Poulenc Chimie Free-flowing pseudoplastic cosmetic compositions/suspensions
US5612307A (en) * 1994-07-19 1997-03-18 Lever Brothers Company, Division Of Conopco, Inc. Detergent compositions containing separate stripes of surface active agents and benefit agent
US5635171A (en) * 1990-12-21 1997-06-03 L'oreal Cosmetic or pharmaceutical composition in the form of a rigid gel, particularly for containing inclusions therein
US5652228A (en) * 1993-11-12 1997-07-29 The Procter & Gamble Company Topical desquamation compositions
US5661189A (en) * 1994-07-19 1997-08-26 Lever Brothers Company, Division Of Conopco, Inc. Detergent composition
US5885948A (en) * 1995-02-15 1999-03-23 The Procter & Gamble Company Crystalline hydroxy waxes as oil in water stabilizers for skin cleansing liquid composition
US5929019A (en) * 1997-01-30 1999-07-27 Lever Brothers Company, Division Of Conopco, Inc. Cleansing composition with separately dispensed cleansing base and benefit base wherein benefit base also comprises surfactant
US5932203A (en) * 1996-03-27 1999-08-03 Proctor & Gamble Company Conditioning shampoo compositions containing select hair conditioning esters
US5935561A (en) * 1996-03-27 1999-08-10 Procter & Gamble Company Conditioning shampoo compositions containing select hair conditioning agents
US5947335A (en) * 1996-10-15 1999-09-07 Lever Brothers Company Dual compartment package
US5952286A (en) * 1995-08-07 1999-09-14 Lever Brothers Company Liquid cleansing composition comprising soluble, lamellar phase inducing structurant and method thereof
US6051541A (en) * 1998-12-16 2000-04-18 Unilever Home & Personal Care, Division Of Conopco, Inc. Process for preparing pourable, transparent/translucent liquid detergent with continuous suspending system
US6080707A (en) * 1995-02-15 2000-06-27 The Procter & Gamble Company Crystalline hydroxy waxes as oil in water stabilizers for skin cleansing liquid composition
US6114290A (en) * 1997-11-07 2000-09-05 Lever Brothers Company, Division Of Conopco, Inc. Detergent composition
US6174845B1 (en) * 1997-03-28 2001-01-16 Lever Brothers Company, Division Of Conopco, Inc. Personal washing bar compositions comprising emollient rich phase/stripe
US6176391B1 (en) * 1999-06-21 2001-01-23 Oddzon, Inc. Message providing candy dispenser
US6176395B1 (en) * 1999-04-21 2001-01-23 Pechiney Plastic Packaging, Inc. Dual dispense container
US6190648B1 (en) * 1997-06-25 2001-02-20 Kao Corporation Hair cosmetics
US6194364B1 (en) * 1996-09-23 2001-02-27 The Procter & Gamble Company Liquid personal cleansing compositions which contain soluble oils and soluble synthetic surfactants
US6213166B1 (en) * 2000-01-12 2001-04-10 Patrick Thibiant Apparatus and process for forming novel spiral compositions
US6245323B1 (en) * 2000-05-26 2001-06-12 Engelhard Corporation Bonded metal hydroxide-organic composite polymer films on particulate substrates
US6245344B1 (en) * 1999-07-28 2001-06-12 Patrick Thibiant Enhanced spiral compositions
US6255264B1 (en) * 1998-12-15 2001-07-03 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Detergent composition containing a benefit agent made up of aggregated particles
US6267978B1 (en) * 1996-06-27 2001-07-31 The Procter & Gamble Company Water-in-oil emulsions containing amino acid salts of salicylic acid
US6268322B1 (en) * 1999-10-22 2001-07-31 Unilever Home & Personal Care Usa, A Division Of Conopco, Inc. Dual chamber cleansing system, comprising multiple emulsion
US6294179B1 (en) * 1992-05-21 2001-09-25 Lever Brothers Company, Division Of Conopco, Inc. Method of exfoliating skin
US6335312B1 (en) * 1997-10-14 2002-01-01 The Procter & Gamble Company Personal cleansing compositions comprising mid-chain branched surfactants
US20020004468A1 (en) * 1999-12-01 2002-01-10 Ecolab Inc. Hand soap concentrate, use solution and method for modifying a hand soap concentrate
US6340723B1 (en) * 1999-10-05 2002-01-22 Merck Patent Gesellschaft Mit Beschraenkter Haftung Highly orientated flaky pigment and a process for producing the same
US20020010110A1 (en) * 2000-03-20 2002-01-24 Christine Hayward Extrudable multiphase composition comprising a lamellar phase and an isotropic phase
US6362156B1 (en) * 1998-12-16 2002-03-26 Unilever Home & Personal Care, Usa, Division Of Conopco, Inc. Pourable transparent/translucent liquid detergent composition with suspended particles
US6383999B1 (en) * 2000-02-10 2002-05-07 Unilever Home & Personal Care Usa. Division Of Conopco, Inc. Personal washing bar having adjacent emollient rich and emollient poor phases
US6395691B1 (en) * 2001-02-28 2002-05-28 Unilever Home & Personal Care Usa Division Of Conopco, Inc. Personal wash compositions containing particle-in-oil dispersion
US6429177B1 (en) * 2000-08-22 2002-08-06 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Separating multi-phase personal wash composition in a transparent or translucent package
US6506391B1 (en) * 1998-07-03 2003-01-14 L'oreal Cosmetic or dermatological composition in the form of a dispersion of an oily phase and an aqueous phase, stabilized with cubic gel particles
US6516838B2 (en) * 1999-07-28 2003-02-11 Patrick Thibiant Apparatus and process for forming novel spiral compositions
US20030049282A1 (en) * 2001-05-17 2003-03-13 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Method of enhanced moisture or reduced drying using wet-skin treatment compositions
US6533873B1 (en) * 1999-09-10 2003-03-18 Unilever Home & Personal Care Usa Division Of Conopco, Inc. Suspending clear cleansing formulation
US6534457B2 (en) * 2000-03-20 2003-03-18 Unilever Home And Personal Care Usa, Division Of Conopco, Inc. Extrudable multiphase composition comprising lamellar phase inducing structurant in each phase
US20030054019A1 (en) * 2001-05-17 2003-03-20 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Wet-skin treatment compositions
US20030068287A1 (en) * 2001-08-14 2003-04-10 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Dual compartment packaged cosmetic composition
US20030152540A1 (en) * 2002-02-08 2003-08-14 Putman Christopher Dean Rinse-off skin conditioning compositions
US20030161852A1 (en) * 2002-01-11 2003-08-28 Clariant Gmbh Cosmetic three-phase systems
US6673371B2 (en) * 2000-10-30 2004-01-06 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Shear gel compositions
US6673755B2 (en) * 2002-01-16 2004-01-06 The Procter & Gamble Company Personal cleansing compositions containing cleansing and skin active phases separated by one or more packaging barriers
US6682726B2 (en) * 2001-04-30 2004-01-27 The Gillette Company Self-foaming shaving lotion
US20040028932A1 (en) * 2000-12-06 2004-02-12 Susanne Holzer Label film with improved adhesion
US20040033914A1 (en) * 2002-08-14 2004-02-19 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Biphasic composition induced by polydextrose
US6699488B2 (en) * 2002-05-09 2004-03-02 The Procter & Gamble Company Rinsable skin conditioning compositions
US20040048758A1 (en) * 2002-09-11 2004-03-11 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Oil-containing personal wash compositions or emulsions comprising particles of high refractive index and defined thickness, geometry and size
US20040048757A1 (en) * 2002-09-11 2004-03-11 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Oil-containing personal wash liquid compositions or emulsions comprising particles of high refractive index and defined thickness, geometry and size
US20040057920A1 (en) * 2002-09-20 2004-03-25 The Procter & Gamble Company Striped liquid personal cleansing compositions containing a cleansing phase and a seperate benefit phase
US20040058920A1 (en) * 2002-04-09 2004-03-25 Jover Antoni Torrens Benzoxazinone-derived compounds, their preparation and use as medicaments
US20040092415A1 (en) * 2002-11-04 2004-05-13 The Procter & Gamble Company Striped liquid personal cleansing compositions containing a cleansing phase and a separate benefit phase with improved stability
US20040105827A1 (en) * 2000-10-03 2004-06-03 Sabine Grimm Use for make-up in particular of a cosmetic composition having a continuous hydrophilic comprising a multilayer goniochromatic pigment
US6764991B2 (en) * 2002-07-18 2004-07-20 Unilever Home & Personal Care Usa, Divsion Of Conopco, Inc. Exfoliating and moisturizing toilet bar
US6773811B2 (en) * 2001-08-01 2004-08-10 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Treatment for substrates
US20040158940A1 (en) * 2000-04-17 2004-08-19 The Procter & Gamble Company Phase-separated rinse-off hair coloring/cleansing products
US20050020468A1 (en) * 2003-07-22 2005-01-27 Seren Frantz New branched sulfates for use in personal care formulations
US20050100570A1 (en) * 2003-05-08 2005-05-12 The Procter & Gamble Company Multi-phase personal care composition
US6903057B1 (en) * 2004-05-19 2005-06-07 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Personal product liquid cleansers stabilized with starch structuring system
US20050139574A1 (en) * 2003-12-30 2005-06-30 Unilever Home & Personal Care Usa Bottle with soft feel handle
US20050143269A1 (en) * 2003-12-24 2005-06-30 Wei Karl S. Multi-phase personal cleansing compositions comprising a lathering cleansing phase and a non-lathering structured aqueous phase
US6929678B2 (en) * 2003-05-19 2005-08-16 Teledyne Tekmar Company Purge and trap concentrator with improved drying
US20060002880A1 (en) * 2004-07-02 2006-01-05 Peffly Marjorie M Personal care compositions containing cationically modified starch and an anionic surfactant system
US20060102654A1 (en) * 2004-07-23 2006-05-18 Seys Andrew C Multiple dispenser container
US20060118139A1 (en) * 2004-11-01 2006-06-08 Fausnight Ronald L System and method for cleaning and/or treating surfaces of objects
US20060182699A1 (en) * 2005-02-15 2006-08-17 Taylor Rebecca A Personal care compositions containing hydrophobically modified non-platelet particles
US20060191589A1 (en) * 2005-02-25 2006-08-31 Mccall Patrick C Multi-phase personal care compositions, processes for making and providing, and articles of commerce
US20070072781A1 (en) * 2005-04-13 2007-03-29 Soffin Daniel J Mild, structured, multi-phase personal cleansing compositions comprising density modifiers
US20070155637A1 (en) * 2005-04-13 2007-07-05 Smith Edward D Iii Structured multi-phased personal cleansing composition comprising branched anionic surfactants
US20070167338A1 (en) * 2006-01-09 2007-07-19 Mchugh Colin M Multiphase personal care compositions comprising beads
US20070187274A1 (en) * 2006-02-11 2007-08-16 The Procter & Gamble Company Clamshell package for holding and displaying consumer products

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0670736B2 (en) * 1989-01-11 1994-09-07 東洋製罐株式会社 In-mold label sticker label and labeled plastic container
JP2710258B2 (en) * 1991-10-09 1998-02-10 東洋製罐株式会社 Blow molded bottle with in-mold label
JPH09230791A (en) * 1996-02-22 1997-09-05 Kao Corp Thermally active label and production of molding with label
US7514131B2 (en) * 2002-11-22 2009-04-07 Yupo Corporation In-mold label with separable part

Patent Citations (99)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2438091A (en) * 1943-09-06 1948-03-16 American Cyanamid Co Aspartic acid esters and their preparation
US2798053A (en) * 1952-09-03 1957-07-02 Goodrich Co B F Carboxylic polymers
US3937811A (en) * 1973-06-08 1976-02-10 Societe Anonyme Dite: L'oreal Fatty compositions for use in cosmetic makeup compositions and said cosmetic makeup compositions
US4159028A (en) * 1977-03-28 1979-06-26 Almay, Inc. Method of forming and containerizing a multiphase cosmetic composition
US4335103A (en) * 1977-03-28 1982-06-15 Almay, Inc. Multiphase cosmetic composition
US4263363A (en) * 1979-12-20 1981-04-21 Colgate-Palmolive Company Emulsion-containing absorbent article having improved water holding capacity
US4387090A (en) * 1980-12-22 1983-06-07 The Procter & Gamble Company Hair conditioning compositions
US4425322A (en) * 1981-06-11 1984-01-10 Colgate-Palmolive Company Dual-action dentifrice
US4518578A (en) * 1983-05-16 1985-05-21 Colgate-Palmolive Company Dentifrice composition containing visually clear pigment-colored stripe
US4509949A (en) * 1983-06-13 1985-04-09 The B. F. Goodrich Company Water thickening agents consisting of copolymers of crosslinked acrylic acids and esters
USRE34584E (en) * 1984-11-09 1994-04-12 The Procter & Gamble Company Shampoo compositions
US5011690A (en) * 1987-06-05 1991-04-30 Unilever Patent Holdings B.V. Spheroidal silica
US5487884A (en) * 1987-10-22 1996-01-30 The Procter & Gamble Company Photoprotection compositions comprising chelating agents
US5223315A (en) * 1988-04-06 1993-06-29 Toyo Seikan Kaisha Ltd. Container equipped with label and production method thereof
US4899877A (en) * 1989-02-13 1990-02-13 Bares Group Packaging of tools
US5087445A (en) * 1989-09-08 1992-02-11 Richardson-Vicks, Inc. Photoprotection compositions having reduced dermal irritation
US5530054A (en) * 1989-09-13 1996-06-25 Exxon Chemical Patents Inc. Elastomeric ethylene copolymers for hot melt adhesives
US5635171A (en) * 1990-12-21 1997-06-03 L'oreal Cosmetic or pharmaceutical composition in the form of a rigid gel, particularly for containing inclusions therein
US5228912A (en) * 1991-05-28 1993-07-20 Merck Patent Gesellschaft Mit Beschrankter Haftung Surface-modified, platelet-shaped pigments having improved dispersibility
US5248495A (en) * 1992-04-16 1993-09-28 The Procter & Gamble Company Post foaming shaving gel composition
US6294179B1 (en) * 1992-05-21 2001-09-25 Lever Brothers Company, Division Of Conopco, Inc. Method of exfoliating skin
US5487168A (en) * 1992-06-15 1996-01-23 International Business Machines Corporation Method and system for global optimization of device allocation
US5556628A (en) * 1992-08-05 1996-09-17 Rhone-Poulenc Chimie Free-flowing pseudoplastic cosmetic compositions/suspensions
US5393450A (en) * 1992-11-09 1995-02-28 Lever Brothers Company, Division Of Conopco, Inc. Washing composition containing fatty acid esters
US5652228A (en) * 1993-11-12 1997-07-29 The Procter & Gamble Company Topical desquamation compositions
US5451396A (en) * 1993-11-17 1995-09-19 S. C. Johnson & Son, Inc. Shaving compositions
US5661189A (en) * 1994-07-19 1997-08-26 Lever Brothers Company, Division Of Conopco, Inc. Detergent composition
US5612307A (en) * 1994-07-19 1997-03-18 Lever Brothers Company, Division Of Conopco, Inc. Detergent compositions containing separate stripes of surface active agents and benefit agent
US5885948A (en) * 1995-02-15 1999-03-23 The Procter & Gamble Company Crystalline hydroxy waxes as oil in water stabilizers for skin cleansing liquid composition
US6080707A (en) * 1995-02-15 2000-06-27 The Procter & Gamble Company Crystalline hydroxy waxes as oil in water stabilizers for skin cleansing liquid composition
US5952286A (en) * 1995-08-07 1999-09-14 Lever Brothers Company Liquid cleansing composition comprising soluble, lamellar phase inducing structurant and method thereof
US5932203A (en) * 1996-03-27 1999-08-03 Proctor & Gamble Company Conditioning shampoo compositions containing select hair conditioning esters
US5935561A (en) * 1996-03-27 1999-08-10 Procter & Gamble Company Conditioning shampoo compositions containing select hair conditioning agents
US6267978B1 (en) * 1996-06-27 2001-07-31 The Procter & Gamble Company Water-in-oil emulsions containing amino acid salts of salicylic acid
US6194364B1 (en) * 1996-09-23 2001-02-27 The Procter & Gamble Company Liquid personal cleansing compositions which contain soluble oils and soluble synthetic surfactants
US5947335A (en) * 1996-10-15 1999-09-07 Lever Brothers Company Dual compartment package
US5929019A (en) * 1997-01-30 1999-07-27 Lever Brothers Company, Division Of Conopco, Inc. Cleansing composition with separately dispensed cleansing base and benefit base wherein benefit base also comprises surfactant
US6174845B1 (en) * 1997-03-28 2001-01-16 Lever Brothers Company, Division Of Conopco, Inc. Personal washing bar compositions comprising emollient rich phase/stripe
US6190648B1 (en) * 1997-06-25 2001-02-20 Kao Corporation Hair cosmetics
US6335312B1 (en) * 1997-10-14 2002-01-01 The Procter & Gamble Company Personal cleansing compositions comprising mid-chain branched surfactants
US6114290A (en) * 1997-11-07 2000-09-05 Lever Brothers Company, Division Of Conopco, Inc. Detergent composition
US6506391B1 (en) * 1998-07-03 2003-01-14 L'oreal Cosmetic or dermatological composition in the form of a dispersion of an oily phase and an aqueous phase, stabilized with cubic gel particles
US6255264B1 (en) * 1998-12-15 2001-07-03 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Detergent composition containing a benefit agent made up of aggregated particles
US6362156B1 (en) * 1998-12-16 2002-03-26 Unilever Home & Personal Care, Usa, Division Of Conopco, Inc. Pourable transparent/translucent liquid detergent composition with suspended particles
US6051541A (en) * 1998-12-16 2000-04-18 Unilever Home & Personal Care, Division Of Conopco, Inc. Process for preparing pourable, transparent/translucent liquid detergent with continuous suspending system
US6176395B1 (en) * 1999-04-21 2001-01-23 Pechiney Plastic Packaging, Inc. Dual dispense container
US6176391B1 (en) * 1999-06-21 2001-01-23 Oddzon, Inc. Message providing candy dispenser
US6516838B2 (en) * 1999-07-28 2003-02-11 Patrick Thibiant Apparatus and process for forming novel spiral compositions
US6245344B1 (en) * 1999-07-28 2001-06-12 Patrick Thibiant Enhanced spiral compositions
US6533873B1 (en) * 1999-09-10 2003-03-18 Unilever Home & Personal Care Usa Division Of Conopco, Inc. Suspending clear cleansing formulation
US6340723B1 (en) * 1999-10-05 2002-01-22 Merck Patent Gesellschaft Mit Beschraenkter Haftung Highly orientated flaky pigment and a process for producing the same
US6268322B1 (en) * 1999-10-22 2001-07-31 Unilever Home & Personal Care Usa, A Division Of Conopco, Inc. Dual chamber cleansing system, comprising multiple emulsion
US20020004468A1 (en) * 1999-12-01 2002-01-10 Ecolab Inc. Hand soap concentrate, use solution and method for modifying a hand soap concentrate
US6213166B1 (en) * 2000-01-12 2001-04-10 Patrick Thibiant Apparatus and process for forming novel spiral compositions
US6367519B2 (en) * 2000-01-12 2002-04-09 Patrick Thibiant Process for forming novel spiral compositions
US6383999B1 (en) * 2000-02-10 2002-05-07 Unilever Home & Personal Care Usa. Division Of Conopco, Inc. Personal washing bar having adjacent emollient rich and emollient poor phases
US6534456B2 (en) * 2000-03-20 2003-03-18 Unilever Home And Personal Care Usa, Division Of Conopco, Inc. Extrudable multiphase composition comprising a lamellar phase and an isotropic phase
US6534457B2 (en) * 2000-03-20 2003-03-18 Unilever Home And Personal Care Usa, Division Of Conopco, Inc. Extrudable multiphase composition comprising lamellar phase inducing structurant in each phase
US20020010110A1 (en) * 2000-03-20 2002-01-24 Christine Hayward Extrudable multiphase composition comprising a lamellar phase and an isotropic phase
US20040158940A1 (en) * 2000-04-17 2004-08-19 The Procter & Gamble Company Phase-separated rinse-off hair coloring/cleansing products
US6245323B1 (en) * 2000-05-26 2001-06-12 Engelhard Corporation Bonded metal hydroxide-organic composite polymer films on particulate substrates
US6429177B1 (en) * 2000-08-22 2002-08-06 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Separating multi-phase personal wash composition in a transparent or translucent package
US20040105827A1 (en) * 2000-10-03 2004-06-03 Sabine Grimm Use for make-up in particular of a cosmetic composition having a continuous hydrophilic comprising a multilayer goniochromatic pigment
US6673371B2 (en) * 2000-10-30 2004-01-06 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Shear gel compositions
US20040028932A1 (en) * 2000-12-06 2004-02-12 Susanne Holzer Label film with improved adhesion
US6395691B1 (en) * 2001-02-28 2002-05-28 Unilever Home & Personal Care Usa Division Of Conopco, Inc. Personal wash compositions containing particle-in-oil dispersion
US6682726B2 (en) * 2001-04-30 2004-01-27 The Gillette Company Self-foaming shaving lotion
US20030054019A1 (en) * 2001-05-17 2003-03-20 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Wet-skin treatment compositions
US20030049282A1 (en) * 2001-05-17 2003-03-13 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Method of enhanced moisture or reduced drying using wet-skin treatment compositions
US6773811B2 (en) * 2001-08-01 2004-08-10 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Treatment for substrates
US20030068287A1 (en) * 2001-08-14 2003-04-10 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Dual compartment packaged cosmetic composition
US20030161852A1 (en) * 2002-01-11 2003-08-28 Clariant Gmbh Cosmetic three-phase systems
US6673755B2 (en) * 2002-01-16 2004-01-06 The Procter & Gamble Company Personal cleansing compositions containing cleansing and skin active phases separated by one or more packaging barriers
US20030152540A1 (en) * 2002-02-08 2003-08-14 Putman Christopher Dean Rinse-off skin conditioning compositions
US20040058920A1 (en) * 2002-04-09 2004-03-25 Jover Antoni Torrens Benzoxazinone-derived compounds, their preparation and use as medicaments
US6699488B2 (en) * 2002-05-09 2004-03-02 The Procter & Gamble Company Rinsable skin conditioning compositions
US6764991B2 (en) * 2002-07-18 2004-07-20 Unilever Home & Personal Care Usa, Divsion Of Conopco, Inc. Exfoliating and moisturizing toilet bar
US20040033914A1 (en) * 2002-08-14 2004-02-19 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Biphasic composition induced by polydextrose
US20040048757A1 (en) * 2002-09-11 2004-03-11 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Oil-containing personal wash liquid compositions or emulsions comprising particles of high refractive index and defined thickness, geometry and size
US20040048758A1 (en) * 2002-09-11 2004-03-11 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Oil-containing personal wash compositions or emulsions comprising particles of high refractive index and defined thickness, geometry and size
US6780826B2 (en) * 2002-09-11 2004-08-24 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Oil-containing personal wash compositions or emulsions comprising particles of high refractive index and defined thickness, geometry and size
US6759376B2 (en) * 2002-09-11 2004-07-06 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Oil-containing personal wash liquid compositions or emulsions comprising particles of high refractive index and defined thickness, geometry and size
US20040057920A1 (en) * 2002-09-20 2004-03-25 The Procter & Gamble Company Striped liquid personal cleansing compositions containing a cleansing phase and a seperate benefit phase
US20040092415A1 (en) * 2002-11-04 2004-05-13 The Procter & Gamble Company Striped liquid personal cleansing compositions containing a cleansing phase and a separate benefit phase with improved stability
US20050100570A1 (en) * 2003-05-08 2005-05-12 The Procter & Gamble Company Multi-phase personal care composition
US6929678B2 (en) * 2003-05-19 2005-08-16 Teledyne Tekmar Company Purge and trap concentrator with improved drying
US20050020468A1 (en) * 2003-07-22 2005-01-27 Seren Frantz New branched sulfates for use in personal care formulations
US20050143269A1 (en) * 2003-12-24 2005-06-30 Wei Karl S. Multi-phase personal cleansing compositions comprising a lathering cleansing phase and a non-lathering structured aqueous phase
US20050139574A1 (en) * 2003-12-30 2005-06-30 Unilever Home & Personal Care Usa Bottle with soft feel handle
US6903057B1 (en) * 2004-05-19 2005-06-07 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Personal product liquid cleansers stabilized with starch structuring system
US20060002880A1 (en) * 2004-07-02 2006-01-05 Peffly Marjorie M Personal care compositions containing cationically modified starch and an anionic surfactant system
US20060102654A1 (en) * 2004-07-23 2006-05-18 Seys Andrew C Multiple dispenser container
US20060118139A1 (en) * 2004-11-01 2006-06-08 Fausnight Ronald L System and method for cleaning and/or treating surfaces of objects
US20060182699A1 (en) * 2005-02-15 2006-08-17 Taylor Rebecca A Personal care compositions containing hydrophobically modified non-platelet particles
US20060191589A1 (en) * 2005-02-25 2006-08-31 Mccall Patrick C Multi-phase personal care compositions, processes for making and providing, and articles of commerce
US20070072781A1 (en) * 2005-04-13 2007-03-29 Soffin Daniel J Mild, structured, multi-phase personal cleansing compositions comprising density modifiers
US20070155637A1 (en) * 2005-04-13 2007-07-05 Smith Edward D Iii Structured multi-phased personal cleansing composition comprising branched anionic surfactants
US20070167338A1 (en) * 2006-01-09 2007-07-19 Mchugh Colin M Multiphase personal care compositions comprising beads
US20070187274A1 (en) * 2006-02-11 2007-08-16 The Procter & Gamble Company Clamshell package for holding and displaying consumer products

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070155637A1 (en) * 2005-04-13 2007-07-05 Smith Edward D Iii Structured multi-phased personal cleansing composition comprising branched anionic surfactants
US7820609B2 (en) 2005-04-13 2010-10-26 The Procter & Gamble Company Mild, structured, multi-phase personal cleansing compositions comprising density modifiers
US20070167338A1 (en) * 2006-01-09 2007-07-19 Mchugh Colin M Multiphase personal care compositions comprising beads
US8104616B2 (en) 2006-02-11 2012-01-31 The Procter & Gamble Company Clamshell package for holding and displaying consumer products
US8153144B2 (en) 2006-02-28 2012-04-10 The Proctor & Gamble Company Stable multiphase composition comprising alkylamphoacetate
US20090028808A1 (en) * 2007-07-27 2009-01-29 The Procter & Gamble Company Personal care article for sequentially dispensing compositions with variable concentrations of partitioned benefit or suspended benefit agents
US20090028809A1 (en) * 2007-07-27 2009-01-29 Jonathan Robert Cetti Personal care article for sequentially dispensing compositions with variable concentrations of hydrophobic benefit materials
US20100237068A1 (en) * 2009-03-17 2010-09-23 Rubbermaid Incorporated Container With In-Molded Exposed Panel
US20110159409A1 (en) * 2009-12-30 2011-06-30 Sipix Chemical Inc. Decorated device and method of fabricating the same
US20130256178A1 (en) * 2010-12-23 2013-10-03 Kao Germany Gmbh Container having a labeled textured surface
US9114905B2 (en) * 2010-12-23 2015-08-25 Kao Germany Gmbh Container having a labeled textured surface
USD667729S1 (en) 2011-03-07 2012-09-25 The Procter & Gamble Company Bottle
WO2016032460A1 (en) * 2014-08-27 2016-03-03 Colgate-Palmolive Company Bottle with finger recess
US10589900B2 (en) 2014-08-27 2020-03-17 Colgate-Palmolive Company Bottle
WO2019118865A1 (en) * 2017-12-14 2019-06-20 Csp Technologies, Inc. Container with lid having fluorinated polymer internal surface and methods for making the same
CN111801210A (en) * 2017-12-14 2020-10-20 Csp技术公司 Lidded container with fluorinated polymeric inner surface and method of making same

Also Published As

Publication number Publication date
WO2007066310A2 (en) 2007-06-14
EP1957374A2 (en) 2008-08-20
CN101326106A (en) 2008-12-17
WO2007066310A3 (en) 2007-08-16

Similar Documents

Publication Publication Date Title
US20070163990A1 (en) Container comprising an in-mold label positioned proximate to a surface topography
AU2010224411B2 (en) Container with enhanced display
JP7442649B2 (en) Blow molded multilayer article with color gradation
US11814208B2 (en) Blow molded article with visual effects
JP4562739B2 (en) Preform made of two or more materials and method of obtaining the same
CA2568588C (en) Package for personal care products comprising a shrink label
US20130292287A1 (en) Flexible Containers Having a Decoration Panel
US10987848B2 (en) Article with different textured surfaces
US20050139574A1 (en) Bottle with soft feel handle
US20210130571A1 (en) Molded Article With Metallic Appearance
WO2002072441A1 (en) Process for shrink sleeved a bottle with a handle
US9114905B2 (en) Container having a labeled textured surface
JP2985677B2 (en) Colored liquid packaging
WO2014104239A1 (en) Labeled tube container
MX2008007331A (en) A container comprising an in-mold label positioned proximate to a surface topography
JP5002879B2 (en) Multilayer blow molded bottle
CN106687382A (en) Plastic container having excellent scratch resistance and antifouling properties
US20230294887A1 (en) Cap of a package suitable for storing personal health care products
US20230294886A1 (en) Cap of a package suitable for storing personal health care products
US20220348749A1 (en) Molded article with metallic appearance
JP3676519B2 (en) Container with light-shielding label
MXPA06008667A (en) Preforms made of two or more materials and processes for obtaining them

Legal Events

Date Code Title Description
AS Assignment

Owner name: PROCTER & GAMBLE COMPANY, THE, OHIO

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:ESCOBOSA, ROBERTO;NUTLEY, PAUL OWEN;MCCUTCHAN, MICHAEL DEAN;AND OTHERS;REEL/FRAME:019066/0234;SIGNING DATES FROM 20070205 TO 20070222

STCB Information on status: application discontinuation

Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION