US20150238403A1 - Low viscous cosmetic composition using a natural emulsifying agent - Google Patents

Low viscous cosmetic composition using a natural emulsifying agent Download PDF

Info

Publication number
US20150238403A1
US20150238403A1 US14/186,225 US201414186225A US2015238403A1 US 20150238403 A1 US20150238403 A1 US 20150238403A1 US 201414186225 A US201414186225 A US 201414186225A US 2015238403 A1 US2015238403 A1 US 2015238403A1
Authority
US
United States
Prior art keywords
cosmetic composition
composition
saccharide
oil
based surfactant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US14/186,225
Inventor
Byung Ryol PAIK
Hui Kyoung Chang
Myeong Ryeol LEE
Yong Joo NA
Lee Kyoung Kwon
Young So Kim
Sang Hoon Han
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Amorepacific Corp
Original Assignee
Amorepacific Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Amorepacific Corp filed Critical Amorepacific Corp
Priority to US14/186,225 priority Critical patent/US20150238403A1/en
Assigned to AMOREPACIFIC CORPORATION reassignment AMOREPACIFIC CORPORATION ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: CHANG, HUI KYOUNG, HAN, SANG HOON, KIM, YOUNG SO, KWON, LEE KYOUNG, LEE, MYEONG RYEOL, NA, YONG JOO, PAIK, Byung Ryol
Publication of US20150238403A1 publication Critical patent/US20150238403A1/en
Priority to US15/712,363 priority patent/US10555885B2/en
Abandoned legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60Sugars; Derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04Dispersions; Emulsions
    • A61K8/06Emulsions
    • A61K8/062Oil-in-water emulsions
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/42Amides
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60Sugars; Derivatives thereof
    • A61K8/604Alkylpolyglycosides; Derivatives thereof, e.g. esters
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73Polysaccharides
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/02Preparations for care of the skin for chemically bleaching or whitening the skin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59Mixtures
    • A61K2800/596Mixtures of surface active compounds

Definitions

  • the present invention relates to a low-viscosity cosmetic composition using a natural emulsifying agent and, more particularly to an oil-in-water type cosmetic composition that realizes a low-viscosity formulation using a naturally derived saccharide-based surfactant in place of a synthetic surfactant to offer safety to the skin, feel good on the skin with fast absorption, give stability to the formulation and add luster to the skin in an effective manner.
  • emulsion type cosmetics of various kinds, such as creams, lotions, etc., available to protect the skin and keep it in healthy condition.
  • Such emulsion type cosmetics are required to exert the sufficient effects of oil-soluble ingredients, feel good on the skin and secure stability of preservation while being used after opening.
  • low-viscosity oil-in-water type formulations is quite a thin consistency to feel good on the skin with fast absorption and advantageously enhances the luster of the skin in contrast to the solubilized low-viscosity formulations.
  • low-viscosity formulations have difficulty in achieving stability. Low-viscosity formulations are more difficult to make with a naturally derived surfactant which has a low emulsifying capacity. It is therefore one problem in the field of cosmetics to prepare a stable low-viscosity oil-in-water type cosmetic composition using a naturally derived surfactant.
  • One method to prepare a stable low-viscosity oil-in-water type cosmetic composition is preparing a nano-emulsion.
  • a nano-emulsion typically, by preparing a nano-emulsion, the particle size is minimized to allow the composition in Brownian motion not affected by the gravity, thereby securing the stability of the formulation.
  • the representative method of preparing a nano-emulsion is the high pressure emulsification method.
  • the high pressure emulsification method uses a strong physical force in preparing a nano-emulsion and thus requires the use of a microfluidizer, causing additional energy consumption.
  • the high pressure emulsification method is not suitable as a method for preparing a cosmetic composition for improving skin stability in the aspect of the safety to the human body.
  • the inventors of the present invention have revealed the interactions between naturally derived surfactants and natural oil-soluble ingredients and found out that the interactions can be used to lower the viscosity of the cosmetic composition, maintain the stability to the maximum and improve the skin safety.
  • a cosmetic composition that includes a mixture of a saccharide-based surfactant having a relatively large hydrophilic portion and a saccharide-based surfactant having a relatively small hydrophilic portion; and a natural oil-soluble ingredient.
  • the cosmetic composition of the present invention uses a naturally derived surfactant and a natural oil-soluble ingredient, so it is non-irritating, of low-viscosity, stable in formulation, with a light feeling, easily absorbed into the skin and more effective in enhancing the luster of the skin. Also, the cosmetic composition of the present invention uses a whitening component as well to provide more effective whitening and lustering effects for the skin.
  • the present invention provides a low-viscosity cosmetic composition containing a naturally derived surfactant and a natural oil-soluble ingredient, and more particularly an oil-in-water type cosmetic composition.
  • the cosmetic composition of the present invention is a low-viscosity oil-in-water type emulsion using a naturally derived saccharide-based surfactant instead of a synthetic surfactant and a natural oil-soluble ingredient to offer a great skin safety and secure improved formulation stability. Also, the cosmetic composition can enhance the luster of the skin and provide a great whitening effect.
  • the oil-in-water type cosmetic composition of the present invention has a low viscosity of 1,000 to 4,000 cps.
  • the viscosity of the cosmetic composition less than 1,000 cps provides poor stability, while the viscosity of the cosmetic composition greater than 4,000 cps undesirably leads to difficulty of securing a thin constancy of the cosmetic composition.
  • the present invention employs a mixture of a natural saccharide-based surfactant having a relatively large hydrophilic portion and a natural saccharide-based surfactant having a relatively small hydrophilic portion.
  • a combination of the saccharide-based surfactant having a relatively large hydrophilic portion and the saccharide-based surfactant having a relatively small hydrophilic portion at a predetermined ratio can make oil particles packed with the interfacial membrane in an effective manner to stabilize the oil-in-water formulation.
  • the formulation stability can be achieved because the saccharide-based surfactant having a relatively small hydrophilic portion compactly fills in the gap between the interfacial membranes consisting of the saccharide-based surfactant having a relatively high hydrophilic portion.
  • the surfactant having a relatively small hydrophilic portion may include at least one selected from the group consisting of sucrose fatty acid ester, cetearyl glucoside, arachidyl glucoside, C12-20 alkylglucoside, etc., of which the hydrophilic portion consists of a monosaccharide or a disaccharide such as sucrose, glucoside of the like and thus has a relatively small volume.
  • the surfactant having a relatively large hydrophilic portion may include at least one selected from the group consisting of polyglyceryl-3methylglucose distearate, inulin lauryl carbamate, etc., of which the hydrophilic portion consists of a polymer of monosaccharide or polysaccharide such as inulin or the like and thus has a relatively large volume.
  • the surfactant may be a mixture of C12-20 alkylglucoside and inulin lauryl carbamate.
  • the cosmetic composition of the present invention contains the mixture of naturally derived saccharide-based surfactants at an amount of 0.20 wt. % to 1.50 wt. % with respect to the total weight of the composition.
  • the content of the mixture of naturally derived saccharide-based surfactants less than 0.20 wt. % leads to low emulsion stability to induce the phase separation, while the content of the mixture of naturally derived saccharide-based surfactants greater than 1.50 wt. % undesirably causes the viscosity of the composition greater than 4,000 cps.
  • the weight ratio of the natural saccharide-based surfactant having a relatively small hydrophilic portion to the natural saccharide-based surfactant having a relatively large hydrophilic portion is preferably in the range of 0.4 to 2.5. If the mixing ratio is out of the above-defined range, the emulsion stability can be so low to cause the phase separation.
  • the naturally derived oil-soluble ingredient as used in the present invention may include at least one selected from solid ingredients, including a surfactant having a melting temperature of 30° C. or above and being in the solid state at the room temperature, fat, wax, higher alcohol, higher fatty acid, and hydrocarbon; or liquid ingredients, including oil, ester, hydrocarbon.
  • solid ingredients including a surfactant having a melting temperature of 30° C. or above and being in the solid state at the room temperature, fat, wax, higher alcohol, higher fatty acid, and hydrocarbon; or liquid ingredients, including oil, ester, hydrocarbon.
  • the solid ingredients may include, for example, surfactants, such as sucrose fatty acid ester, cetearyl glucoside, inulin lauryl carbamate, C12-20 alkylglucoside, ammonium lauryl sulfate, sodium lauryl glucose carboxylate, lauryl glucoside, hydrogenated lecithin, lecithin, caprylyl/capryl glucoside, etc.; fats, such as shea butter, mango seed butter, cacao seed butter, etc.; waxes, such as myristyl myristate, camellia sinensis leaf extract, jojoba, sunflower seed, carnauba wax, candelilla wax, bee wax, etc.; higher alcohols, such as cetyl alcohol, stearyl alcohol, behenyl alcohol, etc.; higher fatty acids, such as caprylic/capric triglyceride, lauric acid, myristic acid, palmitic acid, stearic acid, etc.; and
  • the liquid ingredients may include, for example, oils, such as meadowfoam seed oil, sunflower seed oil, macadamia seed oil, green tea seed oil, coconut oil, olive oil, camellia oil, etc.; esters, such as phytosteryl/octyldodecyl lauroyl glutamate, isostearyl isostearate, methylheptyl isostearate, dicaprylyl carbonate, isopropyl palmitate, etc.; ethers, such as dicaprylyl ether, etc.; and hydrocarbons, such as squalane, etc.
  • oils such as meadowfoam seed oil, sunflower seed oil, macadamia seed oil, green tea seed oil, coconut oil, olive oil, camellia oil, etc.
  • esters such as phytosteryl/octyldodecyl lauroyl glutamate, isostearyl isostearate, methylheptyl isostearate, dicaprylyl carbonate,
  • the cosmetic composition of the present invention contains the oil-soluble ingredient in an amount of 5 wt. % to 15 wt. % with respect to the total weight of the composition.
  • the term “the content of the oil-soluble ingredient” as used herein means the total weight of the oil-soluble component excluding the surfactant which is an emulsifying agent.
  • the content of the oil-soluble ingredient less than 5 wt. % leads to failure to provide the effect as an emulsion type cosmetic, while the content of the oil-soluble ingredient greater than 15 wt. % undesirably ends up having difficulty of securing the formulation stability.
  • the present invention may further use an additional whitening ingredient in order to enhance the effect of lustering the skin and provide a whitening effect.
  • the whitening ingredient may further include at least one selected from the group consisting of, particularly, green tea polysaccharide, mushroom-derived yeast extract, and niacinamide. These whitening ingredients are effective to reduce melanin pigments and create a synergy in regards to the whitening efficacy, improving the whitening effect.
  • the green tea polysaccharide which is isolated from green tea powder through hot-water extraction, ultrafiltration, and ethanol precipitation inhibits the production of melanin and the expression of MMP-1 and increases the moisturizing ability of the skin to provide a good whitening effect.
  • the mushroom-derived yeast extract which is separated from truffles by enzyme hydrolysis and heat treatment intensifies the activities of LC3 protein and lysosome participating in the autophagy process in the epidermal keratinocytes to eliminate waste matters from the skin, thus making the skin light and clear.
  • niacinamide which is a vitamin B3 component inhibits the transfer of melanin from the cells that produce melanin to the surface of the skin to help reduce pigmentation and improve the skin tone.
  • these ingredients such as green tea polysaccharide, mushroom-derived yeast extract, and niacinamide, as used in the present invention function on the respective steps of the skin whitening process to provide a synergy, so they are all desirably used in combination.
  • the cosmetic composition of the present invention may contain green tea polysaccharide and mushroom-derived yeast extract in an amount of 0.01 wt. % to 5.0 wt. % with respect to the total weight of the composition.
  • the content of green tea polysaccharide and mushroom-derived yeast extract less than 0.01 wt. % is too insignificant to provide the skin whitening effect, while the content of green tea polysaccharide and mushroom-derived yeast extract greater than 5.0 wt. % undesirably causes skin irritation.
  • the content of niacinamide may be 2 wt. %, which is usually accepted as the effective amount.
  • the cosmetic composition of the present invention may further contain an appropriate amount of auxiliary ingredients typically used in the preparation of oil-in-water type cosmetics, such as colors, fragrances, preservatives, thickening agents, and so forth.
  • auxiliary ingredients typically used in the preparation of oil-in-water type cosmetics, such as colors, fragrances, preservatives, thickening agents, and so forth.
  • the content of the auxiliary ingredients may be 0 to 20 wt. % with respect to the total weight of the cosmetic composition.
  • the cosmetic composition of the present invention may be formulated into a wide variety of applications, including fundamental skin cosmetic compositions, such as skin toner, nutrient toner, gel, lotion, etc.; hair-care cosmetic compositions, such as hair tonic, hair essence, hair restorer such as hair treatment, etc.; and other drugs and quasi-drugs.
  • oil-in-water type emulsions of Examples 1 to 5 and Comparative Examples 1 to 6 are prepared in the manner as described in the following preparation method according to the composition as given in Tables 1 and 2.
  • step (3) The oil phase of the step (2) is added to the water phase of the step (1), and the mixture is blended with a homo-mixer under agitation.
  • Example 1 and Comparative Examples 1 to 6 Each oil-in-water type emulsion of Example 1 and Comparative Examples 1 to 6 was evaluated in regards to the change of viscosity and stability on the function of the change in the combination and content of surfactants (Comparative Examples 1 to 4) and the change in the content of the oil-soluble ingredient (Comparative Examples 5 and 6).
  • the viscosity was measured with Spindle No. 3 at 12 rpm using a Brookfield viscometer LVDV-II (manufactured by Brookfield engineering laboratories). The measurement results are presented in Table 3.
  • the oil-in-water type emulsion of Example 1 having the combination and content of naturally derived saccharide-based surfactants and the content of the oil-soluble ingredient according to the present invention can secure formulation stability and light feel with a thin constancy at the target viscosity of 4,000 cps or below.
  • the oil-in-water type emulsion which contains the naturally derived saccharide-based surfactants at an amount of less than 0.20 wt. % (Comparative Example 1) has an extremely low viscosity and undergoes phase separation at high temperature the next day without securing formulation stability.
  • the oil-in-water type emulsion which contains the naturally derived saccharide-based surfactants at an amount of greater than 1.50 wt. % (Comparative Example 4) secures formulation stability but has an extremely high viscosity to offer a thin consistency, leaving residues on the skin.
  • the oil-in-water type emulsion undergoes phase separation at high temperature and fails to secure formulation stability when it does not contain either one of the saccharide-based surfactant having a relatively large hydrophilic portion or the saccharide-based surfactant having a relatively small hydrophilic portion or has an inappropriate combination of the saccharide-based surfactant having a relatively large hydrophilic portion and the saccharide-based surfactant having a relatively small hydrophilic portion (Comparative Examples 2 and 3).
  • the oil-in-water type emulsion which contains the oil-soluble ingredient at an amount of less than 5 wt.
  • the cosmetic composition containing none of green tea polysaccharide, mushroom-derived yeast extract and niacinamide shows the melanin index improving effect after 8 weeks.
  • the cosmetic composition containing niacinamide (Example 2) has the melanin index improving effect.
  • the cosmetic composition containing either a combination of niacinamide and green tea polysaccharide or a combination of niacinamide and mushroom-derived yeast extract (Example 3 or 4) exerts the greater effect to improve the melanin index.
  • the cosmetic composition containing all the three ingredients of niacinamide, green tea polysaccharide and mushroom-derived yeast extract provides the synergy effect to remarkably reduce the melanin index.

Abstract

The present invention relates to a low-viscosity cosmetic composition using a natural emulsifying agent. More specifically, the present invention relates to a cosmetic composition using a naturally derived saccharide-based surfactant in place of a chemical surfactant and realizing a low-viscosity formulation to offer safety to the skin, feel good on the skin with fast absorption, give stability to the formulation and add luster to the skin in an effective manner.

Description

    BACKGROUND OF THE INVENTION
  • 1. Field of the Invention
  • The present invention relates to a low-viscosity cosmetic composition using a natural emulsifying agent and, more particularly to an oil-in-water type cosmetic composition that realizes a low-viscosity formulation using a naturally derived saccharide-based surfactant in place of a synthetic surfactant to offer safety to the skin, feel good on the skin with fast absorption, give stability to the formulation and add luster to the skin in an effective manner.
  • 2. Background Art
  • There are emulsion type cosmetics of various kinds, such as creams, lotions, etc., available to protect the skin and keep it in healthy condition. Such emulsion type cosmetics are required to exert the sufficient effects of oil-soluble ingredients, feel good on the skin and secure stability of preservation while being used after opening.
  • With an increase in the attention to the skin safety in recent years, many customers prefer cosmetics made of natural ingredients. But, natural surfactants are likely to be inferior in the emulsifying capacity to synthetic surfactants. On the other hand, low-viscosity oil-in-water type formulations is quite a thin consistency to feel good on the skin with fast absorption and advantageously enhances the luster of the skin in contrast to the solubilized low-viscosity formulations. However, low-viscosity formulations have difficulty in achieving stability. Low-viscosity formulations are more difficult to make with a naturally derived surfactant which has a low emulsifying capacity. It is therefore one problem in the field of cosmetics to prepare a stable low-viscosity oil-in-water type cosmetic composition using a naturally derived surfactant.
  • One method to prepare a stable low-viscosity oil-in-water type cosmetic composition is preparing a nano-emulsion. Typically, by preparing a nano-emulsion, the particle size is minimized to allow the composition in Brownian motion not affected by the gravity, thereby securing the stability of the formulation. The representative method of preparing a nano-emulsion is the high pressure emulsification method. But, the high pressure emulsification method uses a strong physical force in preparing a nano-emulsion and thus requires the use of a microfluidizer, causing additional energy consumption. With a succession of publications of studies on the toxic properties of nano-cosmetics, the high pressure emulsification method is not suitable as a method for preparing a cosmetic composition for improving skin stability in the aspect of the safety to the human body.
  • The selection of surfactants to secure long-term stability to the maximum is a problem to solve in order to prepare a stable oil-in-water type cosmetic composition with a combination of naturally derived surfactants having a low emulsifying capacity. Such an appropriate combination of natural surfactants is very difficult to find. Further, the proper content range of the oil-soluble ingredient used in combination with the natural surfactants is also of great importance.
  • PRIOR ART Patent Document
  • Korean Patent Laid-Open No. 2010-0059279 (filed on Jun. 4, 2010)
  • DISCLOSURE OF INVENTION Technical Problem
  • In an attempt to search for a combination of naturally derived surfactants suitable for implementation of a low-viscosity oil-in-water type cosmetic composition, the inventors of the present invention have revealed the interactions between naturally derived surfactants and natural oil-soluble ingredients and found out that the interactions can be used to lower the viscosity of the cosmetic composition, maintain the stability to the maximum and improve the skin safety.
  • It is therefore an object of the present invention to provide a cosmetic composition using a naturally derived surfactant to provide a low-viscosity oil-in-water type formulation with skin safety and fast absorption into the skin and thus enhance the luster of the skin.
  • Technical Solution
  • To achieve the object of the present invention, there is provided a cosmetic composition that includes a mixture of a saccharide-based surfactant having a relatively large hydrophilic portion and a saccharide-based surfactant having a relatively small hydrophilic portion; and a natural oil-soluble ingredient.
  • Advantageous Effects
  • The cosmetic composition of the present invention uses a naturally derived surfactant and a natural oil-soluble ingredient, so it is non-irritating, of low-viscosity, stable in formulation, with a light feeling, easily absorbed into the skin and more effective in enhancing the luster of the skin. Also, the cosmetic composition of the present invention uses a whitening component as well to provide more effective whitening and lustering effects for the skin.
  • BEST MODE FOR CARRYING OUT THE INVENTION
  • The present invention provides a low-viscosity cosmetic composition containing a naturally derived surfactant and a natural oil-soluble ingredient, and more particularly an oil-in-water type cosmetic composition.
  • The cosmetic composition of the present invention is a low-viscosity oil-in-water type emulsion using a naturally derived saccharide-based surfactant instead of a synthetic surfactant and a natural oil-soluble ingredient to offer a great skin safety and secure improved formulation stability. Also, the cosmetic composition can enhance the luster of the skin and provide a great whitening effect.
  • The oil-in-water type cosmetic composition of the present invention has a low viscosity of 1,000 to 4,000 cps. The viscosity of the cosmetic composition less than 1,000 cps provides poor stability, while the viscosity of the cosmetic composition greater than 4,000 cps undesirably leads to difficulty of securing a thin constancy of the cosmetic composition.
  • In order to use a naturally derived surfactant with enhanced emulsifying capacity, the present invention employs a mixture of a natural saccharide-based surfactant having a relatively large hydrophilic portion and a natural saccharide-based surfactant having a relatively small hydrophilic portion. A combination of the saccharide-based surfactant having a relatively large hydrophilic portion and the saccharide-based surfactant having a relatively small hydrophilic portion at a predetermined ratio can make oil particles packed with the interfacial membrane in an effective manner to stabilize the oil-in-water formulation. In this regard, the formulation stability can be achieved because the saccharide-based surfactant having a relatively small hydrophilic portion compactly fills in the gap between the interfacial membranes consisting of the saccharide-based surfactant having a relatively high hydrophilic portion.
  • In the present invention, among the naturally derived saccharide-based surfactants, the surfactant having a relatively small hydrophilic portion may include at least one selected from the group consisting of sucrose fatty acid ester, cetearyl glucoside, arachidyl glucoside, C12-20 alkylglucoside, etc., of which the hydrophilic portion consists of a monosaccharide or a disaccharide such as sucrose, glucoside of the like and thus has a relatively small volume. Further, the surfactant having a relatively large hydrophilic portion may include at least one selected from the group consisting of polyglyceryl-3methylglucose distearate, inulin lauryl carbamate, etc., of which the hydrophilic portion consists of a polymer of monosaccharide or polysaccharide such as inulin or the like and thus has a relatively large volume. Most preferably, the surfactant may be a mixture of C12-20 alkylglucoside and inulin lauryl carbamate.
  • The cosmetic composition of the present invention contains the mixture of naturally derived saccharide-based surfactants at an amount of 0.20 wt. % to 1.50 wt. % with respect to the total weight of the composition. The content of the mixture of naturally derived saccharide-based surfactants less than 0.20 wt. % leads to low emulsion stability to induce the phase separation, while the content of the mixture of naturally derived saccharide-based surfactants greater than 1.50 wt. % undesirably causes the viscosity of the composition greater than 4,000 cps. Supposing that the content of the natural saccharide-based surfactant having a relatively large hydrophilic portion is 1, the weight ratio of the natural saccharide-based surfactant having a relatively small hydrophilic portion to the natural saccharide-based surfactant having a relatively large hydrophilic portion is preferably in the range of 0.4 to 2.5. If the mixing ratio is out of the above-defined range, the emulsion stability can be so low to cause the phase separation.
  • The naturally derived oil-soluble ingredient as used in the present invention may include at least one selected from solid ingredients, including a surfactant having a melting temperature of 30° C. or above and being in the solid state at the room temperature, fat, wax, higher alcohol, higher fatty acid, and hydrocarbon; or liquid ingredients, including oil, ester, hydrocarbon.
  • More specifically, the solid ingredients may include, for example, surfactants, such as sucrose fatty acid ester, cetearyl glucoside, inulin lauryl carbamate, C12-20 alkylglucoside, ammonium lauryl sulfate, sodium lauryl glucose carboxylate, lauryl glucoside, hydrogenated lecithin, lecithin, caprylyl/capryl glucoside, etc.; fats, such as shea butter, mango seed butter, cacao seed butter, etc.; waxes, such as myristyl myristate, camellia sinensis leaf extract, jojoba, sunflower seed, carnauba wax, candelilla wax, bee wax, etc.; higher alcohols, such as cetyl alcohol, stearyl alcohol, behenyl alcohol, etc.; higher fatty acids, such as caprylic/capric triglyceride, lauric acid, myristic acid, palmitic acid, stearic acid, etc.; and hydrocarbons, such as ceresin, etc. The liquid ingredients may include, for example, oils, such as meadowfoam seed oil, sunflower seed oil, macadamia seed oil, green tea seed oil, coconut oil, olive oil, camellia oil, etc.; esters, such as phytosteryl/octyldodecyl lauroyl glutamate, isostearyl isostearate, methylheptyl isostearate, dicaprylyl carbonate, isopropyl palmitate, etc.; ethers, such as dicaprylyl ether, etc.; and hydrocarbons, such as squalane, etc.
  • The cosmetic composition of the present invention contains the oil-soluble ingredient in an amount of 5 wt. % to 15 wt. % with respect to the total weight of the composition. The term “the content of the oil-soluble ingredient” as used herein means the total weight of the oil-soluble component excluding the surfactant which is an emulsifying agent. The content of the oil-soluble ingredient less than 5 wt. % leads to failure to provide the effect as an emulsion type cosmetic, while the content of the oil-soluble ingredient greater than 15 wt. % undesirably ends up having difficulty of securing the formulation stability.
  • The present invention may further use an additional whitening ingredient in order to enhance the effect of lustering the skin and provide a whitening effect. In the present invention, the whitening ingredient may further include at least one selected from the group consisting of, particularly, green tea polysaccharide, mushroom-derived yeast extract, and niacinamide. These whitening ingredients are effective to reduce melanin pigments and create a synergy in regards to the whitening efficacy, improving the whitening effect.
  • Among the whitening ingredients used in the present invention, the green tea polysaccharide which is isolated from green tea powder through hot-water extraction, ultrafiltration, and ethanol precipitation inhibits the production of melanin and the expression of MMP-1 and increases the moisturizing ability of the skin to provide a good whitening effect. Also, the mushroom-derived yeast extract which is separated from truffles by enzyme hydrolysis and heat treatment intensifies the activities of LC3 protein and lysosome participating in the autophagy process in the epidermal keratinocytes to eliminate waste matters from the skin, thus making the skin light and clear. Finally, niacinamide which is a vitamin B3 component inhibits the transfer of melanin from the cells that produce melanin to the surface of the skin to help reduce pigmentation and improve the skin tone. In particular, these ingredients, such as green tea polysaccharide, mushroom-derived yeast extract, and niacinamide, as used in the present invention function on the respective steps of the skin whitening process to provide a synergy, so they are all desirably used in combination.
  • Among the skin whitening ingredients, the cosmetic composition of the present invention may contain green tea polysaccharide and mushroom-derived yeast extract in an amount of 0.01 wt. % to 5.0 wt. % with respect to the total weight of the composition. The content of green tea polysaccharide and mushroom-derived yeast extract less than 0.01 wt. % is too insignificant to provide the skin whitening effect, while the content of green tea polysaccharide and mushroom-derived yeast extract greater than 5.0 wt. % undesirably causes skin irritation. On the other hand, the content of niacinamide may be 2 wt. %, which is usually accepted as the effective amount.
  • The cosmetic composition of the present invention may further contain an appropriate amount of auxiliary ingredients typically used in the preparation of oil-in-water type cosmetics, such as colors, fragrances, preservatives, thickening agents, and so forth. Preferably, the content of the auxiliary ingredients may be 0 to 20 wt. % with respect to the total weight of the cosmetic composition.
  • In consideration of the low-viscosity characteristic, if not specifically limited in the formulation, the cosmetic composition of the present invention may be formulated into a wide variety of applications, including fundamental skin cosmetic compositions, such as skin toner, nutrient toner, gel, lotion, etc.; hair-care cosmetic compositions, such as hair tonic, hair essence, hair restorer such as hair treatment, etc.; and other drugs and quasi-drugs.
  • Hereinafter, the present invention will be described in further detail with reference to the examples and experimental examples, which are given only for better understanding of the present invention. So it should be understood that modifications, substitutions, or additions as known in the related art could be made thereto without departing from the spirit and scope of the invention.
  • [REFERENCE EXAMPLE] PREPARATION OF EXAMPLES AND COMPARATIVE EXAMPLES
  • The oil-in-water type emulsions of Examples 1 to 5 and Comparative Examples 1 to 6 are prepared in the manner as described in the following preparation method according to the composition as given in Tables 1 and 2.
  • TABLE 1
    Example
    No Ingredient 1 2 3 4 5
    1 C14-22 alcohol * C12-20 0.50 0.50 0.50 0.50 0.50
    alkylglucoside
    2 Vegetable squalane 3.00 3.00 3.00 3.00 3.00
    3 Dicaprylyl carbonate 4.00 4.00 4.00 4.00 4.00
    4 Dicaprylyl ether 2.00 2.00 2.00 2.00 2.00
    5 Caprylic/capric 2.00 2.00 2.00 2.00 2.00
    triglyceride
    6 Cetearyl alcohol * 0.50 0.50 0.50 0.50 0.50
    glyceryl stearate *
    stearic acid *
    hydrogenated lecithin*
    polyglyceryl-3-methyl
    glucose distearate
    7 Butyrospermum parkii 0.50 0.50 0.50 0.50 0.50
    (shea butter) extract
    (shea butter (organic))
    8 Stearyl glycyrrhetinate 0.01 0.01 0.01 0.01 0.01
    9 Purified water To To To To To
    100 100 100 100 100
    10 Disodium EDTA 0.02 0.02 0.02 0.02 0.02
    11 Niacinamide, nicotiamide 0.00 2.00 2.00 2.00 2.00
    (BP)
    12 Inulin lauryl carbamate 0.40 0.40 0.40 0.40 0.40
    13 Xanthan gum 0.15 0.15 0.15 0.15 0.15
    14 Dipropylene glycol 2.00 2.00 2.00 2.00 2.00
    15 Tromethamine 0.05 0.05 0.05 0.05 0.05
    16 Phenoxyethanol 0.30 0.30 0.30 0.30 0.30
    17 Ethylhexyl glycerin 0.05 0.05 0.05 0.05 0.05
    18 Butylene glycol 5.00 5.00 5.00 5.00 5.00
    19 Hydroxyethyl 0.30 0.30 0.30 0.30 0.30
    acrylate/sodium acryloyl
    dimethyl taurate
    copolymer
    20 Purified water 8.00 8.00 8.00 8.00 8.00
    21 Carbomer 0.08 0.08 0.08 0.08 0.08
    22 Broussonetia kazinoki 1.00 1.00 1.00 1.00 1.00
    root extract *
    propanediol * ginko
    biloba leaf extract *
    butylene glycol *
    glycyrrhiza glabra
    (licorice) root extract
    23 Purified water * butylene 0.00 0.00 1.00 0.00 0.50
    glycol * camellia
    sinensis leaf extract *
    caprylyl glycol *
    1,2-hexanediol
    24 Butylene glycol * silybum 0.10 0.10 0.10 0.10 0.10
    marianum fruit extract
    25 Mushroom-derived yeast 0.00 0.00 0.00 1.00 0.50
    extract
    26 Butylene glycol 3.00 3.00 3.00 3.00 3.00
    27 Resveratrol (10%) 0.01 0.01 0.01 0.01 0.01
    (methylmethacrylate/
    acrylonitrile
    copolymer/resveratrol)
    28 Compound fragrance 0.15 0.15 0.15 0.15 0.15
  • TABLE 2
    Comparative Example
    No Ingredient 1 2 3 4 5 6
    1 C14-22 alcohol * C12-20 0.10 0.50 0.15 1.15 0.50 0.50
    alkyl glycoside
    2 Vegetable squalane 3.00 3.00 3.00 3.00 1.00 4.00
    3 Dicapryryl carbonate 4.00 4.00 4.00 4.00 1.00 5.00
    4 Dicaprylyl ether 2.00 2.00 2.00 2.00 1.00 3.00
    5 Caprylic/capric 2.00 2.00 2.00 2.00 0.50 3.00
    triglyceride
    6 Cetearyl alcohol * 0.50 0.50 0.50 0.50 0.50 1.00
    glyceryl stearate *
    stearic acid *
    hydrogenated lecithin*
    polyglyceryl-3-methyl
    glucose distearate
    7 Butyrospermum parkii 0.50 0.50 0.50 0.50 0.50 1.00
    (shea butter) extract
    (shea butter (organic))
    8 Stearyl glycyrrhetinate 0.01 0.01 0.01 0.01 0.01 0.01
    9 Purified water To To To To To To
    100 100 100 100 100 100
    10 Disodium EDTA 0.02 0.02 0.02 0.02 0.02 0.02
    11 Niacinamide, 0.00 0.00 0.00 0.00 0.00 0.00
    nicotiamide (BP)
    12 Inulin lauryl carbamate 0.08 0.00 0.40 0.40 0.40 0.40
    13 Xanthan gum 0.15 0.15 0.15 0.15 0.15 0.15
    14 Dipropylene glycol 2.00 2.00 2.00 2.00 2.00 2.00
    15 Tromethamine 0.05 0.05 0.05 0.05 0.05 0.05
    16 Phenoxyethanol 0.30 0.30 0.30 0.30 0.30 0.30
    17 Ethylhexyl glycerin 0.05 0.05 0.05 0.05 0.05 0.05
    18 Butylene glycol 5.00 5.00 5.00 5.00 5.00 5.00
    19 Hydroxyethyl 0.30 0.30 0.30 0.30 0.30 0.30
    acrylate/sodium
    acryloyl dimethyl
    taurate copolymer
    20 Purified water 8.00 8.00 8.00 8.00 8.00 8.00
    21 Carbomer 0.08 0.08 0.08 0.08 0.08 0.08
    22 Broussonetia kazinoki 1.00 1.00 1.00 1.00 1.00 1.00
    root extract *
    propanediol * ginko
    biloba leaf extract *
    butylene glycol *
    glycyrrhiza glabra
    (licorice) root extract
    23 Purified water * 0.00 0.00 0.00 0.00 0.00 0.00
    butylene glycol *
    camellia sinensis leaf
    extract * caprylyl
    glycol * 1,2-hexanediol
    24 Butylene glycol * 0.10 0.10 0.10 0.10 0.10 0.10
    silybum marianum fruit
    extract
    25 Mushroom-derived yeast 0.00 0.00 0.00 0.00 0.00 0.00
    extract
    26 Butylene glycol 3.00 3.00 3.00 3.00 3.00 3.00
    27 Resveratrol (10%) 0.01 0.01 0.01 0.01 0.01 0.01
    (methylmethacrylate/
    acrylonitrile
    copolymer/resveratrol)
    28 Compound fragrance 0.15 0.15 0.15 0.15 0.15 0.15
  • <Preparation Method>
  • (1) The ingredients 9 to 17 of Table 1 are mixed together and dissolved at 70° C. to prepare a water phase.
  • (2) In a separate container, the ingredients 1 to 8 of Table 1 are dissolved at 70° C. to prepare an oil phase.
  • (3) The oil phase of the step (2) is added to the water phase of the step (1), and the mixture is blended with a homo-mixer under agitation.
  • (4) The ingredients 18 and 19 and the ingredients 20 and 21 are added to the mixture of the step (3), and the resultant mixture is stirred with a homo-mixture and then cooled down to 50° C.
  • (5) The ingredients 22 to 28 are added to the mixture of the step (4), and the resultant mixture is stirred with a homo-mixer and, after degasification, cooled down to 30° C. to prepare a cosmetic composition.
  • [Experimental Example 1] Change of viscosity and stability on the function of the combination and content of naturally derived saccharide-based surfactants and the content of oil-soluble ingredient
  • Each oil-in-water type emulsion of Example 1 and Comparative Examples 1 to 6 was evaluated in regards to the change of viscosity and stability on the function of the change in the combination and content of surfactants (Comparative Examples 1 to 4) and the change in the content of the oil-soluble ingredient (Comparative Examples 5 and 6). In this regard, the viscosity was measured with Spindle No. 3 at 12 rpm using a Brookfield viscometer LVDV-II (manufactured by Brookfield engineering laboratories). The measurement results are presented in Table 3.
  • TABLE 3
    Test Viscosity
    substance (cps) Stability In-use feel
    Example 1 1,630 Good Quite a thin
    constancy
    Comparative 240 Separation at 60° C. Feels light
    Example 1 next day
    Comparative 870 Separation at 60° C. Feels light
    Example 2 in 7 days
    Comparative 865 Separation at 60° C. Feels light
    Example 3 next day
    Comparative 2,350 Good Feels heavy and
    Example 4 leaves residue
    Comparative 1,100 Good Lacks in
    Example 5 softness
    Comparative 2,120 Separation at 30° C. Too oily
    Example 6 immediately after
    preparation
    Good: Typically, considered to secure 4-week stability in a cycle pyrostat at −10° C., 5° C., 30° C., 37° C., 45° C. or 60° C.
  • As can be seen from the results of Table 3, the oil-in-water type emulsion of Example 1 having the combination and content of naturally derived saccharide-based surfactants and the content of the oil-soluble ingredient according to the present invention can secure formulation stability and light feel with a thin constancy at the target viscosity of 4,000 cps or below. Contrarily, the oil-in-water type emulsion which contains the naturally derived saccharide-based surfactants at an amount of less than 0.20 wt. % (Comparative Example 1) has an extremely low viscosity and undergoes phase separation at high temperature the next day without securing formulation stability. The oil-in-water type emulsion which contains the naturally derived saccharide-based surfactants at an amount of greater than 1.50 wt. % (Comparative Example 4) secures formulation stability but has an extremely high viscosity to offer a thin consistency, leaving residues on the skin. Further, the oil-in-water type emulsion undergoes phase separation at high temperature and fails to secure formulation stability when it does not contain either one of the saccharide-based surfactant having a relatively large hydrophilic portion or the saccharide-based surfactant having a relatively small hydrophilic portion or has an inappropriate combination of the saccharide-based surfactant having a relatively large hydrophilic portion and the saccharide-based surfactant having a relatively small hydrophilic portion (Comparative Examples 2 and 3). Finally, the oil-in-water type emulsion which contains the oil-soluble ingredient at an amount of less than 5 wt. % (Comparative Example 5) lacks in softness, and the oil-in-water type emulsion which contains the oil-soluble ingredient at an amount of greater than 15 wt. % (Comparative Example 6) fails to emulsify and undergoes phase separation at the room temperature.
  • [Experimental Example 2] Measurement of skin melanin index according to the content of whitening ingredient
  • To evaluate the whitening effect of the cosmetic compositions of Examples 1 to 5, thirty-one healthy women who are 25 to 35 years old with at least third-degree hyperpigmentation on the face according to SOP are told to use each emulsion for 8 weeks to measure the skin lightness and the melanin index after the applications. More specifically, thirty-one women are divided into two groups: the one consists of 15 women, the other 16 women. Each group uses two compositions. The melanin index is measured with a Mexameter three times on the hyperpigmented region and the non-pigmented region before the application of each emulsion and after 8 weeks of application. The melanin index is used to calculate the improvement rate of melanin index according to the following equation 1 and then averaged. The results are presented in Table 4.
  • Improvement rate ( % ) of melanin index = Melanin index after 8 weeks - Melanin index before use Melanin index before use × 100 [ Equation 1 ]
  • TABLE 4
    Measurement results
    Measured Example
    Index region 1 2 3 4 5
    Improvement Hyperpigmented −0.07 −3.21 −4.68 −4.13 −7.34
    rate (%) of region
    melanin Non-pigmented −0.03 −3.01 −3.45 −3.14 −5.84
    index region
  • As can be seen from Table 4, the cosmetic composition containing none of green tea polysaccharide, mushroom-derived yeast extract and niacinamide (Example 1) shows the melanin index improving effect after 8 weeks. The cosmetic composition containing niacinamide (Example 2) has the melanin index improving effect. The cosmetic composition containing either a combination of niacinamide and green tea polysaccharide or a combination of niacinamide and mushroom-derived yeast extract (Example 3 or 4) exerts the greater effect to improve the melanin index. Also, the cosmetic composition containing all the three ingredients of niacinamide, green tea polysaccharide and mushroom-derived yeast extract (Example 5) provides the synergy effect to remarkably reduce the melanin index.

Claims (14)

1. A cosmetic composition comprising a mixture of a first saccharide-based surfactant having a first hydrophilic portion and a second saccharide-based surfactant having a second hydrophilic portion, the first hydrophilic portion of the first saccharide-based surfactant being more hydrophilic than the second hydrophilic portion of the second saccharide-based surfactant; and a natural oil-soluble ingredient, wherein
the composition contains the mixture of the first saccharide-based surfactant and the second saccharide-based surfactant in an amount of 0.20 wt. % to 1.50 wt. % with respect to the total weght or the composition.
2. The cosmetic composition as claimed in claim 1, wherein the composition is an oil-in-water type composition.
3. The cosmetic composition as claimed in claim 1, wherein the composition has a viscosity of 1,000 to 4,000 cps.
4. The cosmetic composition as claimed in claim 1, wherein the first saccharide-based surfactant includes at least one selected from the group consisting of polyglyceryl-3-methyl glucose distearate and inulin lauryl carbamate.
5. The cosmetic composition as claimed in claim 1, wherein the second saccharide-based surfactant includes at least one selected from the group consisting of sucrose fatty acid ester, cetearyl glucoside, arachidyl glucoside, and C12-20 alkylglucoside.
6. The cosmetic composition as claimed in claim 1, wherein the second saccharide-based surfactant and the first saccharide-based surfactant are used at a weight ratio of 0.4 to 2.5
7. (canceled)
8. The cosmetic composition as claimed in claim 1, wherein the natural oil-soluble ingredient comprises:
a solid oil-soluble ingredient including a surfactant having a melting temperature of 30° C. or above and being in the solid state at the room temperature, said solid oil-soluble ingredient comprising a fat, a wax, a higher alcohol, a higher fatty acid, or a hydrocarbon; or
a liquid oil-soluble ingredient including an oil, an ester, or a hydrocarbon.
9. The cosmetic composition as claimed in claim 1, wherein the cosmetic composition contains the natural oil-soluble ingredient in an amount of 5 wt. % to 15 wt. % with respect to the total weight of the composition.
10. The cosmetic composition as claimed in claim 1, wherein the composition further comprises at least one ingredient selected from green tea polysaccharide, mushroom-derived yeast extract, and niacinamide.
11. The cosmetic composition as claimed in claim 10, wherein the composition contains the green tea polysaccharide and the mushroom-derived yeast extract each at an amount of 0.01 wt. % to 5.0 wt. % with respect to the total weight of the composition.
12. The cosmetic composition as claimed in claim 10, wherein the composition contains the niacinamide at an amount of 2 wt. % with respect to the total weight of the composition.
13. The cosmetic composition as claimed in claim 1, wherein the composition is for improving skin luster.
14. The cosmetic composition as claimed in claim 10, wherein the composition is for whitening the skin.
US14/186,225 2014-02-21 2014-02-21 Low viscous cosmetic composition using a natural emulsifying agent Abandoned US20150238403A1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US14/186,225 US20150238403A1 (en) 2014-02-21 2014-02-21 Low viscous cosmetic composition using a natural emulsifying agent
US15/712,363 US10555885B2 (en) 2014-02-21 2017-09-22 Low viscous cosmetic composition using a natural emulsifying agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US14/186,225 US20150238403A1 (en) 2014-02-21 2014-02-21 Low viscous cosmetic composition using a natural emulsifying agent

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US15/712,363 Continuation US10555885B2 (en) 2014-02-21 2017-09-22 Low viscous cosmetic composition using a natural emulsifying agent

Publications (1)

Publication Number Publication Date
US20150238403A1 true US20150238403A1 (en) 2015-08-27

Family

ID=53881163

Family Applications (2)

Application Number Title Priority Date Filing Date
US14/186,225 Abandoned US20150238403A1 (en) 2014-02-21 2014-02-21 Low viscous cosmetic composition using a natural emulsifying agent
US15/712,363 Active US10555885B2 (en) 2014-02-21 2017-09-22 Low viscous cosmetic composition using a natural emulsifying agent

Family Applications After (1)

Application Number Title Priority Date Filing Date
US15/712,363 Active US10555885B2 (en) 2014-02-21 2017-09-22 Low viscous cosmetic composition using a natural emulsifying agent

Country Status (1)

Country Link
US (2) US20150238403A1 (en)

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6218345B1 (en) * 1996-07-03 2001-04-17 The Procter & Gamble Company Cleansing compositions
US20020045554A1 (en) * 2000-08-31 2002-04-18 Unilever Home And Personal Care Usa Foaming antibacterial cleansing skin product
US20040151793A1 (en) * 2001-07-03 2004-08-05 Valentina Paspaleeva-Kuhn Agent containing fat (oil), which contains onion extract, the production and use thereof for caring, preventing or treating damaged skin tissue, especially scarred tissue
US20060110415A1 (en) * 2004-11-22 2006-05-25 Bioderm Research Topical Delivery System for Cosmetic and Pharmaceutical Agents
WO2006121610A2 (en) * 2005-05-05 2006-11-16 Genencor International, Inc. Personal care compositions and methods for their use
US7157413B2 (en) * 2002-07-08 2007-01-02 L'oreal Detergent cosmetic compositions comprising an anionic surfactant, an amphoteric, cationic, and/or nonionic surfactant, and a polysacchardie, and use thereof
US20080220031A1 (en) * 2005-07-25 2008-09-11 Basf Aktiengesellschaft Dermocosmetic Preparations
US20100247458A1 (en) * 2005-07-26 2010-09-30 Shiseido Co., Ltd. Emulsified External Skin Preparations
US20120021960A1 (en) * 2009-03-27 2012-01-26 Evonik Goldschmidt Gmbh Aqueous hair and skin cleansing compositions
US8283304B2 (en) * 2009-10-14 2012-10-09 S.C. Johnson & Son, Inc. Green compositions containing synergistic blends of surfactants and linkers
US8636982B2 (en) * 2007-08-07 2014-01-28 Foamix Ltd. Wax foamable vehicle and pharmaceutical compositions thereof

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101113374B1 (en) 2008-11-26 2012-02-21 (주)아모레퍼시픽 Cosmetic composition for improving the skin elasticity

Patent Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6218345B1 (en) * 1996-07-03 2001-04-17 The Procter & Gamble Company Cleansing compositions
US20020045554A1 (en) * 2000-08-31 2002-04-18 Unilever Home And Personal Care Usa Foaming antibacterial cleansing skin product
US20040151793A1 (en) * 2001-07-03 2004-08-05 Valentina Paspaleeva-Kuhn Agent containing fat (oil), which contains onion extract, the production and use thereof for caring, preventing or treating damaged skin tissue, especially scarred tissue
US20100247689A1 (en) * 2001-07-03 2010-09-30 Merz Pharma Gmbh & Co. Kgaa Agent containing fat (oil), which contains onion extract, the production and use thereof for caring, preventing or treating damaged skin tissue, especially scarred tissue
US7157413B2 (en) * 2002-07-08 2007-01-02 L'oreal Detergent cosmetic compositions comprising an anionic surfactant, an amphoteric, cationic, and/or nonionic surfactant, and a polysacchardie, and use thereof
US20060110415A1 (en) * 2004-11-22 2006-05-25 Bioderm Research Topical Delivery System for Cosmetic and Pharmaceutical Agents
WO2006121610A2 (en) * 2005-05-05 2006-11-16 Genencor International, Inc. Personal care compositions and methods for their use
US20080220031A1 (en) * 2005-07-25 2008-09-11 Basf Aktiengesellschaft Dermocosmetic Preparations
US20100247458A1 (en) * 2005-07-26 2010-09-30 Shiseido Co., Ltd. Emulsified External Skin Preparations
US8636982B2 (en) * 2007-08-07 2014-01-28 Foamix Ltd. Wax foamable vehicle and pharmaceutical compositions thereof
US20120021960A1 (en) * 2009-03-27 2012-01-26 Evonik Goldschmidt Gmbh Aqueous hair and skin cleansing compositions
US8283304B2 (en) * 2009-10-14 2012-10-09 S.C. Johnson & Son, Inc. Green compositions containing synergistic blends of surfactants and linkers

Non-Patent Citations (6)

* Cited by examiner, † Cited by third party
Title
Agubata et al. Effect of Oil, Surfactant and Co-Surfactant Concentrations on the Phase Behavior, Physicochemical Properties and Drug Release from Self-Emulsifying Drug Delivery Systems. Drug Discov Develop and Deliv. 2014; 1(1):1-7. *
Gullapalli et al. In¯uence of an optimized non-ionic emulsi®er blend on properties of oil-in-water emulsions. European Journal of Pharmaceutics and Biopharmaceutics 48 (1999):233-238. *
Howe et al. Rheology and stability of oil-in-water nanoemulsions stabilised by anionic surfactant and gelatin 2) addition of homologous series of sugar-based co-surfactants. Advances in Colloid and Interface Science 144 (2008) 30–37. *
Li et al. Molecular behavior and synergistic effects between sodium dodecylbenzene sulfonate and Triton X-100 at oil/water interface. Journal of Colloid and Interface Science 307 (2007) 215–220. *
Narayanan. Interfacial Processes and Molecular Aggregation of Surfactants, Page 85, 2008 *
Peng et al. Optimization of water-in-oil nanoemulsions by mixed surfactants. Colloids and Surfaces A: Physicochem. Eng. Aspects 370 (2010) 136–142, *

Also Published As

Publication number Publication date
US10555885B2 (en) 2020-02-11
US20180008521A1 (en) 2018-01-11

Similar Documents

Publication Publication Date Title
KR102014998B1 (en) Low viscous cosmetic composition using a natural emulsifying agent
US20090175808A1 (en) Composition and uses thereof
KR101490713B1 (en) Low viscous O/W cosmetic composition having improved cosmetics formulation stability and safety
CN110022850B (en) Composition comprising truffle extract and neohesperidin dihydrochalcone
US10342755B2 (en) Cosmetic composition comprising specific combination of surfactants
JP2014520804A (en) Methods and compositions useful for treating Fitzpatrick type IV, V or VI skin
CN115006285A (en) Smoothie-like makeup remover composition and preparation method thereof
EP2253305A2 (en) Skin treatment for pore refinement
JP2016523279A (en) Two-phase composition containing magnesium acetate
CN104644532B (en) Use the low viscosity cosmetic composition of naturally occurring emulsifying agent
WO2015107709A1 (en) Emulsion composition for skin
KR101532938B1 (en) Water-in-Oil Type Emulsified Cosmetic Composition Containing High Content Butter
US10555885B2 (en) Low viscous cosmetic composition using a natural emulsifying agent
KR102563508B1 (en) Oil in water type cosmetic composition containing stabilized high oil content
KR20200115565A (en) Method for inhibiting discoloration of external composition containing adenosine phosphate and tranexamic acid
CN111773151B (en) Whitening and freckle-removing antioxidant emulsion and preparation method thereof
WO2022224380A1 (en) Cosmetic
EP4031096A1 (en) Gel composition with high oil content, the preparation method and the use of the same
JP5641665B2 (en) External preparation for skin and method for producing the same
JP7343885B2 (en) skin cosmetics
TWI610687B (en) Low viscous cosmetic composition using a natural emulsifying agent
KR102513929B1 (en) Functional comsmetics materials having composition and composition ratio for skin elasticity, Manufacturing method thereof and Comsmetics for skin care
JP4077382B2 (en) Skin preparation
EP1543812A1 (en) Cleansing composition
CN112826762B (en) Bicontinuous microemulsion composition and application thereof

Legal Events

Date Code Title Description
AS Assignment

Owner name: AMOREPACIFIC CORPORATION, KOREA, REPUBLIC OF

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:PAIK, BYUNG RYOL;CHANG, HUI KYOUNG;LEE, MYEONG RYEOL;AND OTHERS;REEL/FRAME:032319/0052

Effective date: 20140221

STCB Information on status: application discontinuation

Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION