USRE39218E1 - Anhydrous and water-resistant cosmetic compositions - Google Patents
Anhydrous and water-resistant cosmetic compositions Download PDFInfo
- Publication number
- USRE39218E1 USRE39218E1 US09/987,885 US98788501A USRE39218E US RE39218 E1 USRE39218 E1 US RE39218E1 US 98788501 A US98788501 A US 98788501A US RE39218 E USRE39218 E US RE39218E
- Authority
- US
- United States
- Prior art keywords
- composition according
- chosen
- cosmetic composition
- silicone
- carbon atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 101
- 239000002537 cosmetic Substances 0.000 title claims abstract description 41
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 21
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 56
- 239000000049 pigment Substances 0.000 claims abstract description 33
- 239000000945 filler Substances 0.000 claims abstract description 16
- 239000000463 material Substances 0.000 claims abstract description 3
- -1 alkyl radical Chemical class 0.000 claims description 49
- 125000004432 carbon atom Chemical group C* 0.000 claims description 21
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical group O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 18
- 229920002545 silicone oil Polymers 0.000 claims description 14
- 125000001424 substituent group Chemical group 0.000 claims description 14
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 12
- 239000000499 gel Substances 0.000 claims description 12
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 12
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 11
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 claims description 10
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 9
- 239000000843 powder Substances 0.000 claims description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 8
- 239000004408 titanium dioxide Substances 0.000 claims description 8
- 150000005840 aryl radicals Chemical class 0.000 claims description 7
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 7
- 239000003349 gelling agent Substances 0.000 claims description 7
- 239000010445 mica Substances 0.000 claims description 7
- 229910052618 mica group Inorganic materials 0.000 claims description 7
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 6
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 claims description 6
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 claims description 6
- 239000012860 organic pigment Substances 0.000 claims description 6
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 6
- 241001237961 Amanita rubescens Species 0.000 claims description 5
- 239000004698 Polyethylene Substances 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- 229940086555 cyclomethicone Drugs 0.000 claims description 4
- 239000004005 microsphere Substances 0.000 claims description 4
- 239000003921 oil Substances 0.000 claims description 4
- 229920000573 polyethylene Polymers 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- 239000010936 titanium Substances 0.000 claims description 4
- 229910052719 titanium Inorganic materials 0.000 claims description 4
- 239000005995 Aluminium silicate Substances 0.000 claims description 3
- 229910052582 BN Inorganic materials 0.000 claims description 3
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 claims description 3
- 239000004677 Nylon Substances 0.000 claims description 3
- 229920002472 Starch Polymers 0.000 claims description 3
- 239000004809 Teflon Substances 0.000 claims description 3
- 229920006362 Teflon® Polymers 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- 235000012211 aluminium silicate Nutrition 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 3
- 229920001778 nylon Polymers 0.000 claims description 3
- 239000008107 starch Substances 0.000 claims description 3
- 235000019698 starch Nutrition 0.000 claims description 3
- 239000000454 talc Substances 0.000 claims description 3
- 229910052623 talc Inorganic materials 0.000 claims description 3
- 150000003722 vitamin derivatives Chemical class 0.000 claims description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
- 239000004411 aluminium Substances 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- 229910052788 barium Inorganic materials 0.000 claims description 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical group [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000011575 calcium Substances 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- TUJKJAMUKRIRHC-UHFFFAOYSA-N hydroxyl Chemical compound [OH] TUJKJAMUKRIRHC-UHFFFAOYSA-N 0.000 claims description 2
- 229910052712 strontium Inorganic materials 0.000 claims description 2
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims description 2
- 230000000475 sunscreen effect Effects 0.000 claims description 2
- 239000000516 sunscreening agent Substances 0.000 claims description 2
- ORGHESHFQPYLAO-UHFFFAOYSA-N vinyl radical Chemical compound C=[CH] ORGHESHFQPYLAO-UHFFFAOYSA-N 0.000 claims description 2
- 229930003231 vitamin Natural products 0.000 claims description 2
- 239000011782 vitamin Substances 0.000 claims description 2
- 235000013343 vitamin Nutrition 0.000 claims description 2
- 229940088594 vitamin Drugs 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims 5
- 229940067573 brown iron oxide Drugs 0.000 claims 4
- 239000011787 zinc oxide Substances 0.000 claims 4
- WTFXARWRTYJXII-UHFFFAOYSA-N iron(2+);iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Fe+2].[Fe+3].[Fe+3] WTFXARWRTYJXII-UHFFFAOYSA-N 0.000 claims 3
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 claims 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims 3
- 229920002050 silicone resin Polymers 0.000 claims 3
- 239000004927 clay Substances 0.000 claims 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 11
- RXKJFZQQPQGTFL-UHFFFAOYSA-N dihydroxyacetone Chemical compound OCC(=O)CO RXKJFZQQPQGTFL-UHFFFAOYSA-N 0.000 description 10
- 0 *[Si]([1*])([2*])O[Si]([3*])([4*])O[Si]([5*])([6*])O[Si](*)([1*])[2*] Chemical compound *[Si]([1*])([2*])O[Si]([3*])([4*])O[Si]([5*])([6*])O[Si](*)([1*])[2*] 0.000 description 8
- 230000000694 effects Effects 0.000 description 6
- 235000013980 iron oxide Nutrition 0.000 description 6
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 6
- 229940120503 dihydroxyacetone Drugs 0.000 description 5
- 238000003892 spreading Methods 0.000 description 4
- YBGZDTIWKVFICR-JLHYYAGUSA-N Octyl 4-methoxycinnamic acid Chemical compound CCCCC(CC)COC(=O)\C=C\C1=CC=C(OC)C=C1 YBGZDTIWKVFICR-JLHYYAGUSA-N 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 230000000670 limiting effect Effects 0.000 description 3
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 229920004482 WACKER® Polymers 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- DLAHAXOYRFRPFQ-UHFFFAOYSA-N dodecyl benzoate Chemical compound CCCCCCCCCCCCOC(=O)C1=CC=CC=C1 DLAHAXOYRFRPFQ-UHFFFAOYSA-N 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 description 2
- 238000012216 screening Methods 0.000 description 2
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 1
- FPIPGXGPPPQFEQ-UHFFFAOYSA-N 13-cis retinol Natural products OCC=C(C)C=CC=C(C)C=CC1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-UHFFFAOYSA-N 0.000 description 1
- TYYHDKOVFSVWON-UHFFFAOYSA-N 2-butyl-2-methoxy-1,3-diphenylpropane-1,3-dione Chemical compound C=1C=CC=CC=1C(=O)C(OC)(CCCC)C(=O)C1=CC=CC=C1 TYYHDKOVFSVWON-UHFFFAOYSA-N 0.000 description 1
- ZAKOWWREFLAJOT-CEFNRUSXSA-N D-alpha-tocopherylacetate Chemical compound CC(=O)OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C ZAKOWWREFLAJOT-CEFNRUSXSA-N 0.000 description 1
- ZZZCUOFIHGPKAK-UHFFFAOYSA-N D-erythro-ascorbic acid Natural products OCC1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- FPIPGXGPPPQFEQ-BOOMUCAASA-N Vitamin A Natural products OC/C=C(/C)\C=C\C=C(\C)/C=C/C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-BOOMUCAASA-N 0.000 description 1
- 229930003268 Vitamin C Natural products 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 description 1
- XNEFYCZVKIDDMS-UHFFFAOYSA-N avobenzone Chemical compound C1=CC(OC)=CC=C1C(=O)CC(=O)C1=CC=C(C(C)(C)C)C=C1 XNEFYCZVKIDDMS-UHFFFAOYSA-N 0.000 description 1
- 229960005193 avobenzone Drugs 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- PZTQVMXMKVTIRC-UHFFFAOYSA-L chembl2028348 Chemical compound [Ca+2].[O-]S(=O)(=O)C1=CC(C)=CC=C1N=NC1=C(O)C(C([O-])=O)=CC2=CC=CC=C12 PZTQVMXMKVTIRC-UHFFFAOYSA-L 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229940057946 d&c red no. 7 Drugs 0.000 description 1
- ZAKOWWREFLAJOT-UHFFFAOYSA-N d-alpha-Tocopheryl acetate Natural products CC(=O)OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C ZAKOWWREFLAJOT-UHFFFAOYSA-N 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 150000002194 fatty esters Chemical class 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 230000003760 hair shine Effects 0.000 description 1
- 229940119170 jojoba wax Drugs 0.000 description 1
- 239000000787 lecithin Substances 0.000 description 1
- 229940067606 lecithin Drugs 0.000 description 1
- 235000010445 lecithin Nutrition 0.000 description 1
- 235000010187 litholrubine BK Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229960001679 octinoxate Drugs 0.000 description 1
- 235000019645 odor Nutrition 0.000 description 1
- 239000010773 plant oil Substances 0.000 description 1
- 229920000131 polyvinylidene Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 235000019615 sensations Nutrition 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 229930003799 tocopherol Natural products 0.000 description 1
- 239000011732 tocopherol Substances 0.000 description 1
- 235000019149 tocopherols Nutrition 0.000 description 1
- 235000019155 vitamin A Nutrition 0.000 description 1
- 239000011719 vitamin A Substances 0.000 description 1
- 235000019154 vitamin C Nutrition 0.000 description 1
- 239000011718 vitamin C Substances 0.000 description 1
- 229940045997 vitamin a Drugs 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- QUEDXNHFTDJVIY-UHFFFAOYSA-N γ-tocopherol Chemical class OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/04—Preparations for care of the skin for chemically tanning the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/29—Titanium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
- A61K8/585—Organosilicon compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
- A61Q1/06—Lipsticks
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
- A61K2800/31—Anhydrous
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
- A61K2800/43—Pigments; Dyes
Definitions
- the invention is directed to anhydrous and water-resistant make-up compositions comprising, inter alia, at least one silicone gum.
- Water-resistant compositions in water-in-oil or water-in-silicone emulsion form are known in the prior art.
- the use of such emulsions relies on the fact that after spreading, the water evaporates and the oil or the silicone remains in contact with the skin, giving a water-resistant make-up.
- the application of such compositions has the drawback of leaving the skin with an oily appearance and of giving a greasy feel. The result obtained after application is not really natural, and the make-up shines or becomes shiny.
- Another form of water-resistant cosmetic compositions is a composition in which fillers, including pigments, are introduced into a volatile or non-volatile silicone oil.
- the major drawback of this type of composition lies in the stretching effect on the skin, and in the unpleasant, dry sensation which appears after application.
- the effect sought in the use of such compositions containing pigments, namely a coloration of the skin is often not achieved.
- the very nature of the composition is such that the distribution of the pigments in the composition after spreading is not homogeneous; the pigments spread more or less uniformly and tend to agglomerate in the pores and the folds in the skin. This effect runs counter to the search for a coloration close to that obtained naturally.
- compositions obtained have faults both with regard to the stability and with regard to the homogeneity of the dispersion of the pigments. Solutions to these problems have been proposed, such as, for example, the use of water-soluble dyes or of dihydroxyacetone (DHA). In the case of water-soluble dyes, the make-ups obtained are not water-resistant and are not perfectly homogeneous.
- DHA dihydroxyacetone
- An object of the present invention is to provide solutions to the various problems encountered in the applications of the prior art and to propose a cosmetic composition possessing good water resistance and at the same time possessing good cosmetic properties.
- the Inventors have been able to show, surprisingly and unexpectedly, that it is possible to obtain anhydrous, water-resistant make-up compositions which are highly homogeneous in particular with regard to spreading, by mixing together pigments and at least a large proportion of silicone gum and a silicone oil.
- a subject of the present invention is an anhydrous, water-resistant cosmetic composition preferably comprising from 2 to 50% of at least one silicone gum, from 10 to 90% of at least one silicone oil, from 0.5 to 15% of at least one pigment and from 0 to 30% of at least one filler.
- compositions according to the invention have the advantage of being stable over time. They are water-resistant since they are anhydrous, and do not contain any water-soluble dyes or solvent. They also have good staying power and do not cause any pulling effect on the skin.
- the silicone gum is preferably present in a proportion ranging from 2% to 50%, more preferably ranging from 4 to 15% and still more preferably ranging from 6% to 9%.
- the silicone gum preferably has a molecular weight not greater than 1,500,000. More preferably, the silicone gum has a molecular weight ranging from 200,000 to 1,000,000.
- the silicon gum preferably corresponds to the formula: in which:
- n and p may have values preferably ranging from 0 to 5000, and more preferably ranging from 0 to 3000.
- silicone gum which may be used according to (the invention, there may preferably be mentioned those for which:
- composition according to the invention preferably also comprises at least one silicone oil, in a proportion preferably ranging from 10 to 90%.
- a volatile or non-volatile silicone oil may be used.
- the silicone oil and gum are used in the form of a homogeneous premix consisting of the silicone gum solubilized in the silicone oil.
- composition according to the invention preferably also comprises pigments, in a proportion ranging from 0.5 to 15%, and more preferably ranging from 2 to 8%.
- the pigments may be white or coloured and inorganic or organic.
- the pigments used in the composition according to the invention may or may not be coated.
- compositions according to the invention allow a homogeneous and stable dispersion to be obtained, even when pigments which have not been precoated are used.
- titanium dioxide TiO 2
- zinc oxide ZnO
- zirconium dioxide ZrO 2
- black, yellow, red and brown iron oxides cerium dioxide (CeO 2 ) or alternatively the organic pigments known as barium, strontium, calcium and aluminium lakes.
- composition according to the invention preferably contains 0 to 30% of fillers. These fillers may preferably be inorganic or synthetic and lamellar or non-lamellar.
- Talc mica, silica, kaolin, powders of nylon and of polyethylene, Telfon, starch, titanium mica, natural mother of pearl, boron nitride and hollow microspheres such as Expancel from Nobel Industrie may be mentioned.
- composition according to the invention may also comprise constituents usually used in cosmetic compositions of this type. These constituents are preferably chosen as a function of the desired cosmetic effect for the final composition, such as the covering power, the transparency, the matt quality and/or the satiny appearance.
- compositions according to the invention may be in the form of a product for making up the skin, such as a foundation, a blusher, an eyeshadow or a lipstick, or even in the form of a hair product such as a styling make-up gel.
- compositions according to the invention will now be given by way of example, without any limiting nature being implied.
- A) and B) were mixed together with a spatula and were passed 3 times through a cylinder mill.
- C), D) and E) were then added with moderate stirring.
- the pigments used were not precoated, the pigments were fully dispersed in the composition and the make-up obtained was homogeneous.
- compositions having the following compositions (in g) were prepared:
- Compos. D Compos. E
- Compos. F A) Polydimethylsiloxane 67.50 67.50 67.50 at a concentration of 12-14% in cyclopentasiloxane (Q2-1401)
- Thickened gelled creams were obtained, which were easy and pleasant to apply, and which gave a homogeneous and uniform coloration of natural appearance to the skin.
- Compos. G Compos. H
- Silcone oil AK 500,000 10.00 — from Wacker
- Polydimethylsiloxane at a 6.64 12.30 concentration of 12-14% is cyclomethicone (Q2-1401 from Dow)
- Polyphenylsiloxane at a — 40.00 concentration of 15% in cyclopentadimethylsiloxane (Silbione 71634 from Rhone- Poulenc)
- D) Gelling agent (Bentone gel — 18.00 VS38 from Rhéox)
- a lipstick having the following composition was prepared:
- a screening tanning fluid having the following composition was prepared:
- a shiny, smooth brown-coloured tanning fluid was obtained, which was easy to apply and gave a homogeneous and uniform coloration of natural appearance to the skin.
Abstract
Description
-
- R1, R2, R5, and R6 each independently represents an alkyl radical having from 1 to 6 carbon atoms;
- R3 and R4 each independently represents an alkyl radical having from 1 to 6 carbon atoms or an aryl radical;
- X represents an alkyl radical having from 1 to 6 carbon atoms, a hydroxyl radical or a vinyl radical;
- n and p are chosen so as to give the silicone gum a viscosity preferably of greater than 100,000 mPa s, and more preferably of greater than 500,000 mPa s.
-
- the substituents R1 to R6 and X represent a methyl group, p=0 and n=2700, such as that sold under the name SE30 by the company General Electric;
- the substituents R1 to R6 and X represent a methyl group, p=0 and n=2300, such as that sold under the name AK 500000 by the company Wacker;
- the substituents R1 to R6 represent a methyl group, the substituent X represents a hydroxyl group, p=0 and n=2700, in solution at a concentration of 13% in cyclopentasiloxane, such as that sold under the name Q2-1401 by the company Dow Corning;
- the substituents R1 to R6 represent a methyl group, the substituent X represents a hydroxyl group, p=0 and n=2700, in solution at a concentration of 13% in polydimethylsiloxane, such as that sold under the name Q2-1403 by the company Dow Corning;
- the substituents R1, R2, R5, R6 and X represent a methyl group and the substituents R3 and R4 represent an aryl group and p and n are such that the molecular weight of the compound is 600,000, such as that sold under the name 761 by the company Rhone-Poulenc.
- cyclomethicones D4, D5, D6;
- polydimethylsiloxanes (PDMS) of viscosity preferably less than 100 mPa s and more preferably less than 10 mPa s;
- alkyldimethicones such as X2-1731 from Dow corning corresponding to the formula:
in which R represents the radical CnH2n+1, with n having a value preferably ranging from 3 to 8. The silicone oil is Preferably present in the composition in a proportion ranging from 30 to 70%.
-
- gelling agents, such as the modified clays known under the name bentone, which are sold by the company NL Industrie and used as they are or prepackaged in a gel; hydrophobic silica; waxes, for example polyethylene; aluminum fatty salts. The percentage of gelling agent in the composition will be chosen depending on whether a supple or creamy formula is desired.
- vitamins such as tocopherols and derivatives thereof, vitamin A and derivatives thereof, vitamin C and derivatives thereof such as the fatty esters, including the palpitate ester.
- sunscreens such as octyl methoxycinnamate (Parsol MCX), 3-benzophenone (Uvinul M40), and butylmethoxydibenzoylmethane (Parsol 1789).
- oily materials such as plant oils, synthetic esters, lecithin, fragrances and essential oils.
Compos. A | Compos. B | Compos. C | ||
A) | Polydimethylsiloxane | 67.50 | 67.50 | 67.50 |
at a concentration | ||||
of 12-14% in | ||||
cyclopentasiloxane | ||||
(Q2-1401 from Dow) | ||||
B) | TiO2 + iron oxides* | 3.36 | 3.36 | 3.36 |
C) | cyclopentadimethyl- | 9.50 | 9.50 | — |
siloxane | ||||
D) | Gelling agent | |||
bentone gel IMP (NL | 18.64 | 19.14 | — | |
Industrie) | ||||
bentone gel VS-5 PC | — | 28.14 | 28.14 | |
(Stearinerie Dubois) | ||||
E) | Fillers | |||
Expancel | 1.00 | 1.00 | 1.00 | |
microspheres | ||||
Teflon Ceri-dust | — | 2.00 | — | |
*Non-coated pigments |
Compos. D | Compos. E | Compos. F | ||
A) | Polydimethylsiloxane | 67.50 | 67.50 | 67.50 |
at a concentration | ||||
of 12-14% in | ||||
cyclopentasiloxane | ||||
(Q2-1401) | ||||
B) | TiO2 + iron oxides* | 3.36 | 3.36 | 3.36 |
C) | Crosslinked silicone | 20.00 | 10.00 | 10.00 |
powder in a PDMS | ||||
(KSG 16 from Shin | ||||
Etsu) | ||||
bentone gel VS-5 PC | — | 10.00 | — | |
(Dubois) | ||||
Unitwix (United | — | — | — | |
Guardian) | ||||
D) | Polyvinylidene | 1.00 | 1.00 | 1.00 |
E) | Silicone oils | |||
Alkyldimethicone | — | — | 5.00 | |
X2-1731 (Dow) | ||||
Cyclopentadimethyl- | qs 100 | qs 100 | qs 100 | |
siloxane | ||||
*Non-coated pigments |
Compos. G | Compos. H | ||
A) | Silcone oil (AK 500,000 | 10.00 | — |
from Wacker) | |||
Polydimethylsiloxane at a | 6.64 | 12.30 | |
concentration of 12-14% is | |||
cyclomethicone (Q2-1401 from | |||
Dow) | |||
Polyphenylsiloxane at a | — | 40.00 | |
concentration of 15% in | |||
cyclopentadimethylsiloxane | |||
(Silbione 71634 from Rhone- | |||
Poulenc) | |||
B) | TiO2 + iron oxides* | 3.36 | 7.7 |
C) | Crosslinked silicone powder | 20.00 | 10.00 |
(KSG 16 from Shin Etsu) | |||
D) | Gelling agent (Bentone gel | — | 18.00 |
VS38 from Rhéox) | |||
E) | Silicone-containing resin | — | 5.00 |
beads (Tospearl 120 from | |||
Toshiba) | |||
F) | Cyclopentadimethylsiloxane | 60.00 | qs 100 |
*Non-coated pigments |
Polydimethylsiloxane at a concentration of | 70.00 | ||
12-14% in cyclomethicone (Q2-1401) | |||
Crosslinked silicone powder in PDMS (KSG 16 | 10.00 | ||
from Shin Etsu) | |||
Cyclopentadimethylsiloxane | 10.00 | ||
Silicone-coated titanium oxide | 2.83 | ||
Silicone-coated iron oxides | 4.70 | ||
D&C red No. 7 | 0.47 | ||
Titanium mica | 2.00 | ||
Polydimethylsiloxane at a concentration | 70.00 | ||
of 12-14% in cyclomethicone (Q2-1401) | |||
UV screening agents Parsol MCX from BASF | 7.00 | ||
Hydroxy-4-methoxybenzophenone | 2.00 | ||
FINSOLV TN (C12-C15 alkyl benzoate) from Finetax | 9.00 | ||
Jojoba oil | 1.00 | ||
α-tocopheryl acetate | 1.00 | ||
Ethanol | 4.70 | ||
Fragrance | 0.30 | ||
Crosslinked silicone powder in PDMS (KSG 16 | 10.00 | ||
from Shin Etsu) | |||
TiO2 + iron oxides (non-coated) | 1.70 | ||
Claims (41)
Priority Applications (1)
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US09/987,885 USRE39218E1 (en) | 1994-09-30 | 2001-11-16 | Anhydrous and water-resistant cosmetic compositions |
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9411743A FR2725129B1 (en) | 1994-09-30 | 1994-09-30 | WATER RESISTANT ANHYDROUS COSMETIC COMPOSITION |
US53804695A | 1995-10-02 | 1995-10-02 | |
US08/882,298 US5849316A (en) | 1994-09-30 | 1997-06-25 | Anhydrous and water resistant cosmetic compositions |
US09/138,379 US5985297A (en) | 1994-09-30 | 1998-08-24 | Anhydrous and water-resistant cosmetic compositions |
US09/987,885 USRE39218E1 (en) | 1994-09-30 | 2001-11-16 | Anhydrous and water-resistant cosmetic compositions |
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Cited By (4)
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US20100098765A1 (en) * | 2008-10-22 | 2010-04-22 | Mercado Clara G | Powder Makeup Compositions And Methods |
US7790202B1 (en) * | 2007-04-09 | 2010-09-07 | Martell Helen D | Multi-purpose skin composition |
US10888514B1 (en) | 2019-09-24 | 2021-01-12 | L'oreal | Cosmetic compositions |
US11141359B2 (en) | 2018-03-30 | 2021-10-12 | L'oreal | Anhydrous cosmetic composition |
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