WO1992019215A1 - Cosmetic waterproofing composition - Google Patents

Cosmetic waterproofing composition Download PDF

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Publication number
WO1992019215A1
WO1992019215A1 PCT/US1992/002964 US9202964W WO9219215A1 WO 1992019215 A1 WO1992019215 A1 WO 1992019215A1 US 9202964 W US9202964 W US 9202964W WO 9219215 A1 WO9219215 A1 WO 9219215A1
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WO
WIPO (PCT)
Prior art keywords
composition
gellant
mixtures
film former
mascara
Prior art date
Application number
PCT/US1992/002964
Other languages
French (fr)
Inventor
Hovig Ohannes Ounanian
Harvey Gedeon
Joseph Anthony Disomma
Natividad Jose
Original Assignee
The Procter & Gamble Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The Procter & Gamble Company filed Critical The Procter & Gamble Company
Publication of WO1992019215A1 publication Critical patent/WO1992019215A1/en

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25—Silicon; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/342—Alcohols having more than seven atoms in an unbroken chain
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8105—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • A61K8/8111—Homopolymers or copolymers of aliphatic olefines, e.g. polyethylene, polyisobutene; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof

Definitions

  • the invention is in the field of cosmetic compositions used to waterproof hair, skin, or eyelashes. Background of the Invention
  • Mascara is one of the oldest cosmetics known to man, having been used since Biblical times. Mascara accentuates the eyelashes, thereby making the eyes more pronounced.
  • Early mascaras were pressed cakes comprised of soap and pigments.
  • Cream mascara evolved next, which is a softer, creamier version which allows for the composition to be filled into tubes. Cream mascara is most popular today in its various forms.
  • mascara is desired.
  • a mascara user is thus free to continue * ⁇ using her favorite mascara, and may waterproof it when desired.
  • Even more desirable is a composition which not only waterproofs mascara, but assists in improving the wear of normal mascara by making it smudgeproof, smearproof, and flakeproof.
  • the invention is directed to a cosmetic waterproofing composition
  • a cosmetic waterproofing composition comprising: a) about 5 - 85% of a volatile mineral spirit, b) about 0.7 - 2.1% gellant, c) about 1 - 50% of a primary film former, and d) about 5 - 25% of a solvent oil.
  • the invention is also directed to a method for waterproofing skin, hair or eyelashes using the composition of the invention.
  • composition of the invention provides a waterproof coating to skin, hair or eyelashes when worn over the normal make-up. For example, if the composition is used to waterproof eyelashes it is worn over normal mascara.
  • the composition also enhances wear by making the underlying mascara more smudgeproof, flakeproof, and smearproof.
  • the first essential constituent of the waterproofing composition of the invention is a volatile mineral spirit.
  • This term means, in accordance with the instant invention, a volatile substance which provides thinning properties such as Cg_i2 isoparaffin, isododecane, or cyclomethicones.
  • Cg_i2 isoparaffin, isododecane, or cyclomethicones When referring to C9-12 isoparaffin, the C9-12 designation means that the carbon chains in the isoparaffin molecule range from nine to twelve carbon atoms.
  • the isoparaffins, isododecane, or cyclomethicones are available from a number of commercial sources.
  • the next essential constituent is a gellant or viscosity enhancer or thickener.
  • Suitable gellants include quaternium 18 hectorite (bentone), stearalkoniu hectorite, Ci8-36 acids, c 18-36 acic - lycol esters, triglycerides, glyceryl tribehenate, glyceryl tribehenate/calciu behenate, aluminum stearate, trihydroxystearin, aluminum magnesium hydroxy stearate, or aluminum distearate.
  • Preferred as the gellant is mixture of approximately 1 - 2% bentone.
  • the next essential constituent of the composition is a primary film former.
  • primary film former when used in accordance with this invention, means ingredients such as ethylene vinyl acetate (EVA), various polyethylenes with film- forming properties, synthetic or natural waxes, and so on.
  • EVA ethylene vinyl acetate
  • various polyethylenes with film- forming properties synthetic or natural waxes, and so on.
  • the final essential constituent of the composition is one or more solvent oils including but not limited to mineral oils, isostearyl alcohol cetyl octanoate, tricetyl citrate, squalane, natural or synthetic oils or esters, or any other oils usually used in cosmetic compositions.
  • solvent oils including but not limited to mineral oils, isostearyl alcohol cetyl octanoate, tricetyl citrate, squalane, natural or synthetic oils or esters, or any other oils usually used in cosmetic compositions.
  • composition may additionally contain preservatives such as propylparaben, methylparaben, diazolidinyl urea, trisodiu EDTA, etc.
  • preservatives such as propylparaben, methylparaben, diazolidinyl urea, trisodiu EDTA, etc.
  • additional nonessential constituents include small amounts of pigment to provide a more pleasant color or finish.
  • composition of the invention contains one or more colorants and a preservative.
  • the invention is also directed to a method for waterproofing skin, hair or eyelashes.
  • the composition of the invention makes ascaraed eyelashes waterproof, smudgeproof, flakeproof, and smearproof comprising applying the composition of the invention to the eyelashes over the coat of mascara.
  • the composition of the invention is applied to the eyelashes after the mascara is thoroughly dry.
  • the brush containing the composition of the invention is stroked over the upper and lower lashes.
  • the composition of the invention may also be used to waterproof the face and eyes if desired. A small quantity of the composition is lightly applied onto the face or eyes over make-up and allowed to dry. The result is a waterproof finish on skin.
  • composition of the invention may be stored in a variety of vehicles, but in the case of eyelash waterproofing compositions the most preferred container is a mascara-type tube with a cover containing a brush so that when the cover is removed the brush is extracted from the composition.
  • Example 1 Lash coating compositions were formulated as follows: weight %
  • the isoparaffin was combined with the isostearyl alcohol and heated to 85° - 87 ⁇ C. When this temperature was reached the A-C polyethylene 400 and A-C polyethylene 430 were added and mixed at moderate speed. The mixing was continued until all the polyethylenes were melted and the batch was clear and uniform. The preservatives were added and mixing continued. Color may be added here if desired. The batch was then cooled to 30 ⁇ C, and the mixing adjusted to minimize air entrapment. The batch was then poured into individual suitable storage containers.
  • composition of the invention was tested as an eyelash waterproofer on 100% human hair fashion lashes as follows:
  • Sample 1 Max Factor "For Your Eyes" non-waterproof mascara was applied in a standard manner to the lashes.
  • Sample 2 The eyelashes of Sample 1 were additionally coated with the waterproofing composition of the invention.
  • Sample 3 Max Factor's "Splish Splash” waterproof mascara was applied to lashes as a control.
  • the lash samples were placed over clean sheets of white paper and sprayed with a fine mist of tap water until saturated. The lashes were swirled in the pool of water while gently touching the paper to show mascara removal.
  • Sample 1 After visual assessment, Sample 1 showed a large removal of mascara with the water treatment. Sample 2 showed minimal removal. Sample 3, the control waterproof mascara showed minimal mascara removal.
  • the waterproofing composition of the invention was tested for its ability to waterproof a non-waterproof make-up composition.
  • the waterproof make-up patch retained its color and size and left only a trace of residue on the paper towel.
  • the Whipped Cream Fluid Make-up patch covered by the waterproofing composition of the invention did not show any change in color or size of the patch and left only a trace of material on a paper towel.
  • the waterproofing composition of the invention makes a non-waterproof make-up composition waterproof.

Abstract

The invention is directed to a cosmetic waterproofing composition comprising about 5 - 85 % of a volatile mineral spirit, about 0.7 - 2.1 % gellant, about 1 - 50 % of primary film former, and about 5 - 25 % of a solvent oil. The invention is also directed to a method for waterproofing skin, hair or eyelashes using the composition of the invention.

Description

COSMETIC WATERPROOFING COMPOSITION
Technical Field
The invention is in the field of cosmetic compositions used to waterproof hair, skin, or eyelashes. Background of the Invention
Mascara is one of the oldest cosmetics known to man, having been used since Biblical times. Mascara accentuates the eyelashes, thereby making the eyes more pronounced. Early mascaras were pressed cakes comprised of soap and pigments. Cream mascara evolved next, which is a softer, creamier version which allows for the composition to be filled into tubes. Cream mascara is most popular today in its various forms.
Most women form an affinity for a particular brand of mascara, and continue to use it due to personal preference. Since most of today's women are more active than their counterparts fifty years ago, women of today often desire mascaras with waterproofing capabilities, particularly during rainy weather, exercise sessions, etc. However, waterproof mascaras are generally not as popular because they color rather than thicken the lashes and are difficult to remove. Rather than owning two separate mascaras, one waterproof, one not waterproof, it is much more convenient to have a specific mascara waterproofing composition which can be applied over a woman's normal mascara during the times when waterproofing of
. mascara is desired. A mascara user is thus free to continue *■ using her favorite mascara, and may waterproof it when desired. Even more desirable is a composition which not only waterproofs mascara, but assists in improving the wear of normal mascara by making it smudgeproof, smearproof, and flakeproof.
In addition, women often wear face make-up which is susceptible to streaking or washing off in rainy weather. A waterproofing composition which could counteract the effects of weather and rain would be very desirable to keep make-up in place.
Summary of the Invention
The invention is directed to a cosmetic waterproofing composition comprising: a) about 5 - 85% of a volatile mineral spirit, b) about 0.7 - 2.1% gellant, c) about 1 - 50% of a primary film former, and d) about 5 - 25% of a solvent oil.
The invention is also directed to a method for waterproofing skin, hair or eyelashes using the composition of the invention.
Detailed Description
The composition of the invention provides a waterproof coating to skin, hair or eyelashes when worn over the normal make-up. For example, if the composition is used to waterproof eyelashes it is worn over normal mascara. The composition also enhances wear by making the underlying mascara more smudgeproof, flakeproof, and smearproof.
The first essential constituent of the waterproofing composition of the invention is a volatile mineral spirit. This term means, in accordance with the instant invention, a volatile substance which provides thinning properties such as Cg_i2 isoparaffin, isododecane, or cyclomethicones. When referring to C9-12 isoparaffin, the C9-12 designation means that the carbon chains in the isoparaffin molecule range from nine to twelve carbon atoms. The isoparaffins, isododecane, or cyclomethicones are available from a number of commercial sources. The next essential constituent is a gellant or viscosity enhancer or thickener. Suitable gellants include quaternium 18 hectorite (bentone), stearalkoniu hectorite, Ci8-36 acids, c18-36 acic- lycol esters, triglycerides, glyceryl tribehenate, glyceryl tribehenate/calciu behenate, aluminum stearate, trihydroxystearin, aluminum magnesium hydroxy stearate, or aluminum distearate. Preferred as the gellant is mixture of approximately 1 - 2% bentone.
The next essential constituent of the composition is a primary film former. The term primary film former, when used in accordance with this invention, means ingredients such as ethylene vinyl acetate (EVA), various polyethylenes with film- forming properties, synthetic or natural waxes, and so on.
The final essential constituent of the composition is one or more solvent oils including but not limited to mineral oils, isostearyl alcohol cetyl octanoate, tricetyl citrate, squalane, natural or synthetic oils or esters, or any other oils usually used in cosmetic compositions.
The composition may additionally contain preservatives such as propylparaben, methylparaben, diazolidinyl urea, trisodiu EDTA, etc. Other additional nonessential constituents include small amounts of pigment to provide a more pleasant color or finish.
More preferably the composition of the invention contains one or more colorants and a preservative.
The invention is also directed to a method for waterproofing skin, hair or eyelashes. In the case of waterproofing eyelashes, the composition of the invention makes ascaraed eyelashes waterproof, smudgeproof, flakeproof, and smearproof comprising applying the composition of the invention to the eyelashes over the coat of mascara. The composition of the invention is applied to the eyelashes after the mascara is thoroughly dry. The brush containing the composition of the invention is stroked over the upper and lower lashes. The composition of the invention may also be used to waterproof the face and eyes if desired. A small quantity of the composition is lightly applied onto the face or eyes over make-up and allowed to dry. The result is a waterproof finish on skin.
The composition of the invention may be stored in a variety of vehicles, but in the case of eyelash waterproofing compositions the most preferred container is a mascara-type tube with a cover containing a brush so that when the cover is removed the brush is extracted from the composition.
The invention will be further described in connection with the following Examples which are set forth for the purposes of illustration only.
Example 1 Lash coating compositions were formulated as follows: weight %
6.70 2.10 25.00 41.00 9.00 0.20 0.10 0.05 0.15 15.00
Figure imgf000006_0001
0.70 *Allied Chemical Corporation
The isoparaffin was combined with the isostearyl alcohol and heated to 85° - 87βC. When this temperature was reached the A-C polyethylene 400 and A-C polyethylene 430 were added and mixed at moderate speed. The mixing was continued until all the polyethylenes were melted and the batch was clear and uniform. The preservatives were added and mixing continued. Color may be added here if desired. The batch was then cooled to 30βC, and the mixing adjusted to minimize air entrapment. The batch was then poured into individual suitable storage containers.
Example 2
The composition of the invention was tested as an eyelash waterproofer on 100% human hair fashion lashes as follows:
Sample 1: Max Factor "For Your Eyes" non-waterproof mascara was applied in a standard manner to the lashes.
Sample 2: The eyelashes of Sample 1 were additionally coated with the waterproofing composition of the invention.
Sample 3: Max Factor's "Splish Splash" waterproof mascara was applied to lashes as a control.
The lash samples were placed over clean sheets of white paper and sprayed with a fine mist of tap water until saturated. The lashes were swirled in the pool of water while gently touching the paper to show mascara removal.
After visual assessment, Sample 1 showed a large removal of mascara with the water treatment. Sample 2 showed minimal removal. Sample 3, the control waterproof mascara showed minimal mascara removal.
Example 3
The waterproofing composition of the invention was tested for its ability to waterproof a non-waterproof make-up composition.
One patch of Max Factor Waterproof Cream Make-up and 2 patches of Max Factor Whipped Cream Fluid Make-up (non- waterproof) were applied on an arm and allowed to dry for approximately 2 hours. The waterproofing composition of the invention was then applied over the patch of Max Factor Whipped Cream Fluid Make-up and al1owed to dry. The arm was then placed under running water for approximately 5 minutes. The arm was patted dry to the touch.
RESULTS: The untreated non-waterproof make-up left a light colored mark on the arm and considerable residue on the paper towel. The waterproof make-up patch retained its color and size and left only a trace of residue on the paper towel. The Whipped Cream Fluid Make-up patch covered by the waterproofing composition of the invention did not show any change in color or size of the patch and left only a trace of material on a paper towel.
CONCLUSION: The waterproofing composition of the invention makes a non-waterproof make-up composition waterproof.
While the invention has been described in connection with the preferred embodiment, it is not intended to limit the scope of the invention to the particular form set forth, but, on the contrary, it is intended to cover such alternatives, modifications, and equivalent as may be included within the spirit and scope of the invention as defined by the appended claims.

Claims

WHAT IS CLAIMED IS:
1. A waterproofing composition comprising: a) about 5 - 85% of a volatile mineral spirit, b) about 0.7 - 2.1% gellant, c) about 1 - 50% of a primary film former; and d) about 5 - 25% of a solvent oil.
2. The composition of Claim 1 wherein the volatile mineral spirit is C9-12 isoparaffin, cyclomethicone, isododecane or mixtures thereof.
3. The composition of claim 2 wherein the gellant is quaternium 18 hectorite (bentone), stearalkonium hectorite, C18-35 acids, C18-36 acid glycol esters, triglycerides, glyceryl tribehenate, glyceryl tribehenate/calcium behenate, aluminum stearate, trihydroxystearin, aluminum magnesium hydroxy stearate, aluminum distearate or mixtures thereof.
4. The composition of claim 3 wherein the primary film former is ethylene vinyl acetate (EVA), a polyethylene with film-forming properties, a synthetic wax or mixtures thereof.
5. The composition of claim 4 wherein the solvent oil is mineral oil, isostearyl alcohol, cetyl octanoate, tricetyl citrate, squalane, natural oil, synthetic oil, ester, or mixtures thereof.
6. The composition of claim 5 wherein the volatile mineral spirit is C9-12 isoparaffin.
7. The composition of claim 6 wherein the gellant is bentone.
8. The composition of claim 7 wherein the primary film former is polyethylene.
9. The composition of claim 8 wherein the solvent oil is isostearyl alcohol.
10. The composition of claim 9 additionally comprising one or more colorants or preservatives.
11. The composition of claim 10 additionally comprising methyl paraben, propyl paraben, trisodium EDTA, diazolidinyl urea, or mixtures thereof.
12. A method for waterproofing a non-waterproof cosmetic composition applied to eyelashes, skin, or hair comprising applying to the cosmetic treated eyelashes, skin, or hair, a cosmetic composition comprising: a) about 5 - 85% of a volatile mineral spirit, b) about 0.7 - 2.1% gellant, c) about 1 - 50% of a primary film former; and d) about 5 - 25% of a solvent oil.
13. A mascara composition comprising: a) about 5 - 85% of a volatile mineral spirit, b) about 0.7 - 2.1% gellant, c) about 1 - 50% of a primary film former; and d) about 5 - 25% of a solvent oil; which composition is stored in a mascara tube with a cover, the cover containing a brush which is immersed in the composition when the cover is closed.
PCT/US1992/002964 1991-04-26 1992-04-13 Cosmetic waterproofing composition WO1992019215A1 (en)

Applications Claiming Priority (2)

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US691,943 1976-06-01
US69194391A 1991-04-26 1991-04-26

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Cited By (22)

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Publication number Priority date Publication date Assignee Title
WO1996036310A1 (en) * 1995-05-15 1996-11-21 Rosemarie Nichols Smear-resistant cosmetic
WO1997017941A1 (en) * 1995-11-14 1997-05-22 The Procter & Gamble Company Antiperspirant cream compositions comprising select triglyceride gellants
WO1997017942A1 (en) * 1995-11-14 1997-05-22 The Procter & Gamble Company Antiperspirant cream compositions having improved rheology
FR2745494A1 (en) * 1996-03-04 1997-09-05 Oreal COMPOSITION COMPRISING AQUEOUS DISPERSION OF PARTICLES OF FILM-GENERATED POLYMER, AND USE OF A POLYMERIC SYSTEM COMPRISING SAID DISPERSION, IN PARTICULAR IN COSMETICS
EP0800820A2 (en) * 1988-12-06 1997-10-15 L'oreal Cosmetic composition comprising a pasty fatty material and volatile compounds
FR2747565A1 (en) * 1996-04-19 1997-10-24 Oreal Compositions comprising a fatty paste compound
US5718890A (en) * 1995-11-14 1998-02-17 The Proctor & Gamble Company Antiperspirant cream compositions comprising select triglyceride gellants
WO1998018431A2 (en) * 1996-10-31 1998-05-07 The Procter & Gamble Company Cosmetic compositions comprising an insoluble polymer, a film-forming polymer and an organophilic clay
US5882637A (en) * 1995-11-14 1999-03-16 The Procter & Gamble Company Antiperspirant cream compositions comprising fatty alcohol gellants
WO1999022710A1 (en) * 1997-10-31 1999-05-14 Color Access, Inc. Transfer-resistant color cosmetic composition
WO1999022711A1 (en) * 1997-10-31 1999-05-14 Color Access, Inc. Mascara waterproofing composition
US6143284A (en) * 1998-04-02 2000-11-07 The Procter & Gamble Company Packaged antiperspirant cream composition
US6190681B1 (en) 1998-04-15 2001-02-20 Yoram Fishman Long lasting liquid color compositions
US6261576B1 (en) * 1998-04-15 2001-07-17 Yoram Fishman Long-lasting liquid color formulations
US6982077B2 (en) 2001-10-24 2006-01-03 Lady Burd Exclusive Cosmetics Liquid lipstick
EP1704850A2 (en) * 2005-03-25 2006-09-27 L'oreal COMPOSITION FOR COATING KERATIN FIBRES, COMPRISING a continuous aqueous phase and at least one volatile oil
JP2008133358A (en) * 2006-11-28 2008-06-12 Yokozeki Yushi Kogyo Kk Oily gelling agent, gel composition obtained by using the same, and application thereof
JP2014129282A (en) * 2012-12-28 2014-07-10 Kao Corp Oily cosmetic for eyelash
EP2896429A1 (en) 2014-01-20 2015-07-22 COR S.a.r.l. Skin Protector
US9415243B2 (en) 2014-02-18 2016-08-16 Micdermco, L.L.C. Particle-free microdermabrasion formulations
FR3080035A1 (en) * 2018-04-16 2019-10-18 L'oreal COSMETIC COMPOSITION FOR KERATIN FIBERS
KR20220138942A (en) * 2021-04-07 2022-10-14 주식회사 브이티피엘 Natural waterproof mascara cosmetic composition and method for manufacturing natural waterproof mascara cosmetic through the same

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Cited By (47)

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Publication number Priority date Publication date Assignee Title
EP0800820A2 (en) * 1988-12-06 1997-10-15 L'oreal Cosmetic composition comprising a pasty fatty material and volatile compounds
EP0800820A3 (en) * 1988-12-06 1998-03-18 L'oreal Cosmetic composition comprising a pasty fatty material and volatile compounds
FR2747566A1 (en) * 1988-12-06 1997-10-24 Oreal COSMETIC COMPOSITION COMPRISING PASTY FAT BODIES AND VOLATILE COMPOUNDS
US6027739A (en) * 1995-05-15 2000-02-22 Lip Ink International Smear-resistant cosmetic
US5747017A (en) * 1995-05-15 1998-05-05 Lip-Ink International Lip cosmetic
US6509009B2 (en) 1995-05-15 2003-01-21 Rosemarie Nichols Smear-resistant cosmetic
US6010709A (en) * 1995-05-15 2000-01-04 Nichols; Rosemarie Smear-resistant cosmetic
US6395263B1 (en) 1995-05-15 2002-05-28 Rosemarie Nichols Smear-resistant cosmetic
WO1996036310A1 (en) * 1995-05-15 1996-11-21 Rosemarie Nichols Smear-resistant cosmetic
US6203809B1 (en) 1995-05-15 2001-03-20 Rosemarie Nichols Smear-resistant cosmetic
US6001374A (en) * 1995-05-15 1999-12-14 Lip-Ink International Smear-resistant cosmetic
WO1997017941A1 (en) * 1995-11-14 1997-05-22 The Procter & Gamble Company Antiperspirant cream compositions comprising select triglyceride gellants
US5718890A (en) * 1995-11-14 1998-02-17 The Proctor & Gamble Company Antiperspirant cream compositions comprising select triglyceride gellants
US5882637A (en) * 1995-11-14 1999-03-16 The Procter & Gamble Company Antiperspirant cream compositions comprising fatty alcohol gellants
US5871717A (en) * 1995-11-14 1999-02-16 Procter & Gamble Company Antiperspirant cream compositions having improved rheology
WO1997017942A1 (en) * 1995-11-14 1997-05-22 The Procter & Gamble Company Antiperspirant cream compositions having improved rheology
CN1094340C (en) * 1995-11-14 2002-11-20 普罗克特和甘保尔公司 Antiperspirant cream compositions having improved rheology
FR2745494A1 (en) * 1996-03-04 1997-09-05 Oreal COMPOSITION COMPRISING AQUEOUS DISPERSION OF PARTICLES OF FILM-GENERATED POLYMER, AND USE OF A POLYMERIC SYSTEM COMPRISING SAID DISPERSION, IN PARTICULAR IN COSMETICS
WO1997032566A1 (en) * 1996-03-04 1997-09-12 L'oreal Cosmetic composition including an aqueous dispersion of polymeric particles, and use thereof
US6010686A (en) * 1996-03-04 2000-01-04 L'oreal Cosmetic composition including a polymeric system, preparation of and use of this composition
EP0793957A1 (en) * 1996-03-04 1997-09-10 L'oreal Cosmetic composition comprising an aqueous dispersion of polymeric particles and use thereof
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