WO1996006153A2 - Surface-active formulations - Google Patents
Surface-active formulations Download PDFInfo
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- WO1996006153A2 WO1996006153A2 PCT/EP1995/003211 EP9503211W WO9606153A2 WO 1996006153 A2 WO1996006153 A2 WO 1996006153A2 EP 9503211 W EP9503211 W EP 9503211W WO 9606153 A2 WO9606153 A2 WO 9606153A2
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- WIPO (PCT)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0063—Photo- activating compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/347—Phenols
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/42—Amides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/43—Guanidines
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
- A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/005—Antimicrobial preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
Definitions
- novel surface-active surfactant formulations comprise
- the antimicrobial activity of the deblocked surfactant systems reaches upon gram-positive and gram-negative bacteria as well as yeasts, dermatophytes and the like.
- the compounds of component (a j ) preferably correspond to the general formula
- R j is hydrogen, hydroxy, C 1 -C 4 alkyl, chloro, nitro, phenyl oder benzyl,
- R 2 is hydrogen, hydroxy, C 1 -C 6 alkyl or halogen
- R 3 is hydrogen, C 1 -C 6 alkyl, hydroxy, chloro, nitro or a sulfo group in the form of the alkali metal salts or ammonium salts thereof, R 4 is hydrogen or methyl, R 5 is hydrogen or nitro.
- Halogen is bromo or, preferably, chloro.
- Such compounds are typically chlorophenols (o-, m-, p-chlorophenols), 2,4-dichlorophenol, p-nitrophenol, picric acid, xylenol, p-chloro-m-xylenol, cresols (o-, m-, p-cresols), p-chloro-m-cresol, pyrocatechin, resorcinol, orcinol, 4-n-hexylresorcinol, pyrogallol, phloroglucine, carvacrol, thymol, p-chlorothymol, o-phenylphenol, o-benzylphenol, p-chloro-o-benzylphenol and 4-phenolsulfonic acid.
- the compounds of component (a 2 ) preferably correspond to the general formula
- X is sulfur or the methylene group, Ri and R are hydroxy, and
- R 3 , ' 3 , R , R'4, R 5 and R' 5 arc each independently of one another hydrogen or halogen.
- Typical examples of compounds of formula (2) are hexachlorophene, tetrachlorophene, dichlorophene, 2,3-dihydroxy-5,5'-dichlorodiphenylsulfide, 2,2 ' -dihydroxy-3 ,3 ' ,5 ,5 ' -tetrachlorodiphenylsulf ⁇ de, 2,2 , -dihydroxy-3,3',5,5',6,6'-hexachlorodiphenylsulfide and 3,3'-dibromo-5,5'-dichloro-2,2'-dihydroxydiphenylamine.
- the compounds of component (a 3 ) preferably correspond to the general formula
- Rj, R 2 , R 3 , R 4 and R 5 arc each independently of one another hydrogen or chloro.
- Illustrative examples of compounds of formula (3) are benzyl alcohol, 2,4-, 3,5- or 2,6-dichlorobenzyl alcohol and trichlorobenzyl alcohol.
- Component (8 4 ) is chlorohexidine and salts thereof together with organic and inorganic acids, which type of compound may preferably be incorporated into syndet systems.
- Component (& 5 ) is typically Cg-C ⁇ cocamidopropylbetaine.
- Amphoteric surfactants corresponding to component (a $ ) are suitably C ⁇ alkylaminocarboxylic and Ci ⁇ alkanecarboxylic acids such as alkylaminoacetates or alkylaminopropionates.
- the compounds of component (a 7 ) preferably correspond to the general formula
- Hal is chloro or bromo, n and m are 1 or 2, and n + m are 3.
- the quaternary ammonium salts of component (a 8 ) preferably correspond to formula
- R , R 7 , R 8 and Ro arc each independently of one another Ci- galkyl, -Cx alkoxy or phenyl-lower alkyl, and
- Hal is chloro or bromo.
- n is an integer from 7 to 17, is very particularly preferred.
- C 3 -Ci 2 di- or polycarboxylic acids typically malonic, succinic, glutaric, adipic, pimelic, suberic, azelaic and sebacic acid, undecanecarboxylic and dodecanedicarboxylic acid, fumaric, maleic, tartaric and malic acid as well as citric and aconitic acid;
- aminocarboxylic acids typically ethylenediaminetetracetic acid, hydroxyethyl- ethylenediaminetetracetic acid and nitrilotriacetic acid;
- aromatic carboxylic acids typically benzyl, phenylacetic, phenoxyacetic and cinnamic acid, 2-, 3- and 4-hydroxybenzoic acid, anilinic acid as well as o-, m- and p-chlorophenylacetic acid and o-, m- and p-chlorophenoxyacetic acid;
- alkali metal salts and amine salts of inorganic acids typically the sodium or potassium salts and amine(R 1 R 2 R 3 ) salts of hydrochloric, sulfuric, phosphoric, C C 10 alkylphosphoric acid and boric acid, in which amine salts Rj, R 2 and R 3 have the meaning indicated above;
- Rj is hydrogen or -C- ⁇ alkyl
- R 2 and R 3 are each independently of the other hydrogen, C j -C ⁇ alkyl, C 2 -C 12 alkenyl, C 2 -Ci 2 hydroxyalkyl, or a polyglycol ether chain containing 1 to 30 -CH 2 -CH 2 -O- or -CHY r CHY 2 -O- groups, wherein Yj or Y 2 is a hydrogen radical and the other is methyl, e.g.N-methylacetamide;
- R j , R 2 , R 3 and R 4 are each independently of one another hydrogen, C r C 8 alkyl,
- C 4 -C 18 aliphatic and monocyclic alcohols typically C 2 -C 18 alkanols, C 2 -C 18 alkenols and terpene alcohols e.g. ethanol, propanol, isopropanol, hexanol, cis-3-hexen-l-ol, trans-2-hexen-l-ol, l-octen-3-ol, heptanol, octanol, trans-2-cis-6-nonadien-l-ol, decanol, linalol, geraniol, dihydroterpineol, myrcenol, nopol and terpineol;
- Rj, R and R 3 arc each independently of one another hydrogen, hydroxy, halogen or C j - alkoxy, typically benzyl alcohol, 2,4-dichlorobenzyl alcohol, phenoxyethanol, l-phenoxy-2-propanol (phenoxyisopropanol) and cinnamyl alcohol;
- R j and R 2 are each independently of the other hydrogen, C r C 12 alkyl, C 2 -C 12 alkenyl, C r C 8 alkanoyl, C 3 -C 18 alkenoyl, R 3 -(OCH-CH 2 - 7 5 7j-, wherein
- R 3 is hydrogen, Cj-C 12 alkyl or C ⁇ -C ⁇ alkenyl, and R 4 is hydrogen or -CH 3 , and
- X is C 2 -C 10 alkylene or -( H 2 CH O)f3fjCH 2 -CH2- or -(CH 2 -CH-O) ⁇ 3 ⁇ -CH 2 -CH- . CH 3 CH 3
- All organic acids mentioned under (b) may also be obtained in the form of their water-soluble salts, such as the alkali metal salts, preferably the sodium or potassium salts or the amine(NRjR 2 R 3 ) salts, wherein
- Ri, R 2 and R 3 are each independently of one another hydrogen
- C r C 8 alkyl C ⁇ - alkenyl, C C 8 hydroxyalkyl, C 5 -C 8 cycloalkyl or polyalkenylenoxy- -Cigalkyl, or
- Component (b) can consist of only one compound of subclass (b j ) or also of mixtures of one or more than one compound of subclass (b j ), also together with components of further subclasses.
- a special antimicrobial activity is achieved with a combination of one or more than one compound of subclass (bj) and one or more than one compound of subclass b ⁇ ). Particularly preferred in this connection is a combination of cumene sulfonate and citric acid monohydrate.
- Suitable components (c) are anionic, nonionic or zwitterionic and amphoteric synthetic, surface-active substances.
- Suitable anionic surface-active substances are:
- - sulfates typically fatty alcohol sulfates, which contain 8 to 18 carbon atoms in the alkyl chain, e.g. sulfated lauryl alcohol;
- - C 8 -C 22 fatty alcohol ether sulfates typically the acid esters or the salts thereof of a polyadduct of 2 to 30 mol of ethylene oxide with 1 mol of a -C ⁇ fatty alcohol;
- alkane sulfonates containing 8 to 20 carbon atoms in the alkyl chain, e.g. dodecyl sulfonate; alkylamide sulfonates; alkylaryl sulfonates; ⁇ -olefin sulfonates; sulfosuccinic acid derivatives, typically alkyl sulfosuccinates, alkyl ether sulfosuccinates or alkyl sulfosuccinamide derivatives;
- X is hydrogen, C r C 4 alkyl or -COO M + ,
- Y is hydrogen or C ⁇ -C alkyl
- Z is -(CH 2 ) m 1 - m l is 1 to 5
- n is an integer from 6 to 18, and
- M is an alkali metal ion or an amine ion; alkyl ether carboxylates and alkylaryl ether carboxylates of formula
- X is a radical
- R is hydrogen or C ⁇ -C 4 alkyl
- M is an alkali metal cation or amine cation.
- the anionic surfactants used may furthermore be fatty acid methyl taurides, alkylisothionates, fatty acid polypeptide condensates and fatty alcohol phosphoric acid esters.
- the alkyl radicals in these compounds preferably contain 8 to 24 carbon atoms.
- the fatty alcohols which may be present in the above-mentioned surfactants are those containing 8 to 22, preferably 8 to 18 carbon atoms, typically octyl, decyl, lauryl, tridecyl, miristyl, cetyl, stearyl, oleyl, arachidyl or behenyl alcohol.
- the anionic surfactants are usually obtained in the form of their water-soluble salts, such as the alkali metal, ammonium or amine salts.
- Typical examples of such salts are lithium, sodium, potassium, ammonium, triethylamine, ethanolamine, diethanolamine or triethanolamine salts. It is preferred to use the sodium or potassium salts or the ammonium-(NR 1 R 2 R 3 ) salts, wherein R t , R 2 and R 3 are each independently of one another hydrogen, C ⁇ -C 4 alkyl or C Qhydroxyalkyl.
- the anionic surfactants preferably used in the formulation of this invention are Cg-C ⁇ fatty acid alcohol ether sulfates, more particularly the alkali metal salts of lauryl ether sulfate.
- Very particularly preferred anionic surfactants in the novel formulation are monoethanolamine lauryl sulfate or the alkali metal salts of fatty alcohol sulfates, preferably the sodium lauryl sulfate and the reaction product of 2 to 4 mol of ethylene oxide and sodium lauryl ether sulfate.
- Suitable zwitterionic and amphoteric surfactants are C -C ⁇ 8 betaines, C 8 -C 18 sulfobetaines, C 8 -C 4 alkylamido-C 1 -C 4 alkylenebetaines, imidazoline carboxylates, alkylamphocarboxy carboxylic acids, alkylamphocarboxylic acids (e.g. lauroamphoglycinate) and N-alkyl- ⁇ - aminopropionates or N-alkyl- ⁇ -iminodipropionates. It is preferred to use the C 1 o-C 2 oalkylamido-C ⁇ -C 4 alkylenebetaines and, more particularly, cocoamidopropylbetaine.
- Nonionic surfactants are typically derivatives of the adducts of propylene oxide/ethylene oxide having a molecular weight of 1000 to 15000, fatty alcohol ethoxylatcs (1-50 EO), alkylphenol polyglycol ethers (1-50 EO), ethoxylated carbohydrates, fatty acid glycol partial esters, typically diethylene glycol monstearate, fatty acid alkanolamides and fatty acid dialkanolamides, fatty acid alkanolamide ethoxylates and fatty acid amine oxides.
- the fatty acid alkanolamides and fatty acid dialkanolamides and, preferably, cocodiethanolamide are to be particularly highlighted.
- Suitable components (d) are the salts of saturated and unsaturated C 12 -C 22 fatty acids, typically lauric, myristic, palmitic, stearic, arachic, behenic, dodecenoic, tetradecenoic, octadecenoic, oleic, eicosanic and erucic acid, as well as the technical mixtures of such acids, typically coconut fatty acid which is preferably used in the novel formulation.
- saturated and unsaturated C 12 -C 22 fatty acids typically lauric, myristic, palmitic, stearic, arachic, behenic, dodecenoic, tetradecenoic, octadecenoic, oleic, eicosanic and erucic acid, as well as the technical mixtures of such acids, typically coconut fatty acid which is preferably used in the novel formulation.
- acids may be obtained in the form of salts, suitable cations being alkali metal cations such as sodium and potassium cations, metal atoms such as zinc atoms and aluminium atoms or nitrogen-containing organic compounds of sufficient alkalinity, typically amines or ethoxylated amines.
- suitable cations being alkali metal cations such as sodium and potassium cations, metal atoms such as zinc atoms and aluminium atoms or nitrogen-containing organic compounds of sufficient alkalinity, typically amines or ethoxylated amines.
- suitable cations being alkali metal cations such as sodium and potassium cations, metal atoms such as zinc atoms and aluminium atoms or nitrogen-containing organic compounds of sufficient alkalinity, typically amines or ethoxylated amines.
- These salt can also be prepared in situ.
- Component (d) can also be a mixture of the indicated salts.
- Suitable components (e) are dihydric alcohols, preferably those containing 2 to 6 carbon atoms in the alkylene radical, typically ethylene glycol, 1,2- or 1,3-propanediol, 1,3-, 1,4- or 2,3-butanediol, 1,5-pentanediol and 1,6-hexanediol. 1,2-propanediol (propylene glycol) is preferred.
- Component (f) is preferably ethanol, n-propanol and isopropanol or a mixture of these alcohols.
- Preferred novel formulations are those comprising
- Rj is hydrogen, hydroxy, Cj-Qalkyl, chloro, nitro, phenyl or benzyl,
- R 2 is hydrogen, hydroxy, C j -C ⁇ alkyl or chloro
- R 3 is hydrogen, Cj-Cgalkyl, hydroxy, chloro, nitro or a sulfo group in the form of the alkali metal salts or ammonium salts thereof,
- R 4 is hydrogen or methyl
- R 5 is hydrogen or nitro
- the pH of the novel formulation is 3 to 10, preferably 4.5 to 6.
- novel formulations obtained as soap or syndet solutions may additionally comprise customary additives, typically sequestrants, dyes, perfume oils, thickeners or solidifiers (consistency regulators), emollients, UV absorbers, skin-protection agents, antioxidants, additives which improve the mechanical properties, such as dicarboxylic acids and/or Al, Zn, Ca, Mg salts of C 14 -C 22 f tty acids and, if desired, preservatives.
- customary additives typically sequestrants, dyes, perfume oils, thickeners or solidifiers (consistency regulators), emollients, UV absorbers, skin-protection agents, antioxidants, additives which improve the mechanical properties, such as dicarboxylic acids and/or Al, Zn, Ca, Mg salts of C 14 -C 22 f tty acids and, if desired, preservatives.
- novel soap bars can be fabricated in per se known manner, typically by mixing the novel components (a) and (b) and, optionally, (c), (d), (e) and (f), as well as any additives in a jerk mixer at 18-25°C. After the composition obtained has been processed, it is extruded at 40 to 60°, preferably from 45 to 50°C, and then cut and stamped in moulds.
- Soap formulations of the invention can be prepared by mixing components (a) and (b) and, optionally, (c), (d), (e) and (f), in any order, with the requisite amount of water and stirring the mixture to homogeneity.
- the mixture is bulked to 100% with additional water. This procedure is a purely physical procedure. Accordingly, there is no chemical reaction of the individual components.
- the novel soap formulations can be applied thereto in dilute or undilute form, suitably in an amount of at least 2 ml, preferably in the undilute form, for hand disinfection.
- the invention is illustrated by the following Examples. Parts and percentages are by weight.
- citric acid monohydrate 8.0 parts citric acid monohydrate, and water to make up 100 parts are stirred to homogeneity and about 90% of the requisite water is then added.
- the pH is adjusted to 5.5 with monoethanolamine.
- Deionised water is then added to the solution to make up a total of 100 parts.
- the pH is checked again and, if necessary, monoethanolamine is added to adjust the pH to 4.0.
- citric acid monohydrate 8.0 parts citric acid monohydrate, and water to make up 100 parts are stirred to homogeneity and about 90% of the requisite water is then added.
- the pH is adjusted to 5.5 with monoethanolamine.
- Deionised water is then added to the solution to make up a total of 100 parts.
- the pH is checked again and, if necessary, monoethanolamine is added to adjust the pH to 4.0.
- citric acid monohydrate 8.0 parts citric acid monohydrate, and water to make up 100 parts are stirred to homogeneity and about 90% of the requisite water is then added.
- the pH is adjusted to 5.5 with monoethanolamine.
- Deionised water is then added to the solution to make up a total of 100 parts.
- the pH is checked again and, if necessary, monoethanolamine is added to adjust the pH to 4.0.
- citric acid monohydrate 8.0 parts citric acid monohydrate, and water to make up 100 parts are stirred to homogeneity and about 90% of the requisite water is then added.
- the pH is adjusted to 5.5 with monoethanolamine.
- Deionised water is then added to the solution to make up a total of 100 parts.
- the pH is checked again and, if necessary, monoethanolamine is added to adjust the pH to 4.0.
- n is an integer from 7 to 17, 4.0 parts cocamidopropylbetaine,
- Example 12 Test of the microbicidal activity of the novel formulations The microbicidal activity (in decimal logarithms) of the novel formulations according to Examples 1 to 11 is determined with a suspension test. This test is used to assess the bactericidal activity of water-soluble antiseptics, disinfectants and of liquid soaps.
- the test consists in seeding the test product in selected dilutions with the test bacillus. After a certain contact time, aliquots is taken and the number of surviving bacilli is determined. The difference between the number of the bacilli added and the number of the surviving bacilli is expressed as bacilli reduction in decimal logarithms. The concentration is 90%, the contact time is 30 seconds.
Abstract
Description
Claims
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
MX9701416A MX9701416A (en) | 1994-08-25 | 1995-08-14 | Surface-active formulations. |
CA002196771A CA2196771A1 (en) | 1994-08-25 | 1995-08-14 | Surface-active formulations |
EP95929863A EP0777717A2 (en) | 1994-08-25 | 1995-08-14 | Surface-active formulations |
BR9508775A BR9508775A (en) | 1994-08-25 | 1995-08-14 | Surfactant formulations |
SK244-97A SK24497A3 (en) | 1994-08-25 | 1995-08-14 | Surface-active formulations |
AU33452/95A AU3345295A (en) | 1994-08-25 | 1995-08-14 | Surface-active formulations |
JP8507758A JPH10504592A (en) | 1994-08-25 | 1995-08-14 | Surfactant composition |
FI970742A FI970742A0 (en) | 1994-08-25 | 1997-02-21 | Surface active compositions |
BG101308A BG101308A (en) | 1994-08-25 | 1997-03-11 | Surfactant compositions |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH261194 | 1994-08-25 | ||
CH2611/94-8 | 1994-08-25 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO1996006153A2 true WO1996006153A2 (en) | 1996-02-29 |
WO1996006153A3 WO1996006153A3 (en) | 1996-05-02 |
Family
ID=4237670
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP1995/003211 WO1996006153A2 (en) | 1994-08-25 | 1995-08-14 | Surface-active formulations |
Country Status (12)
Country | Link |
---|---|
EP (1) | EP0777717A2 (en) |
JP (1) | JPH10504592A (en) |
AU (1) | AU3345295A (en) |
BG (1) | BG101308A (en) |
BR (1) | BR9508775A (en) |
CA (1) | CA2196771A1 (en) |
CZ (1) | CZ55697A3 (en) |
FI (1) | FI970742A0 (en) |
HU (1) | HUT76688A (en) |
MX (1) | MX9701416A (en) |
SK (1) | SK24497A3 (en) |
WO (1) | WO1996006153A2 (en) |
Cited By (32)
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EP0903401A1 (en) * | 1997-09-17 | 1999-03-24 | Ciba SC Holding AG | Antimicrobial additive for washing agents |
EP0904343A1 (en) † | 1995-10-25 | 1999-03-31 | Reckitt & Colman Inc. | Germicidal acidic hard surface cleaning compositions |
WO1999028428A1 (en) * | 1997-11-28 | 1999-06-10 | Reckitt Benckiser Inc. | Concentrated liquid cleaner for hard surfaces |
JPH11189784A (en) * | 1997-12-26 | 1999-07-13 | Kose Corp | Detergent composition |
US5955408A (en) * | 1996-07-10 | 1999-09-21 | Steris Inc. | Triclosan skin wash with enhanced efficacy |
WO1999046987A1 (en) * | 1998-03-19 | 1999-09-23 | Bifodan A/S | Disinfecting composition |
US5968539A (en) * | 1997-06-04 | 1999-10-19 | Procter & Gamble Company | Mild, rinse-off antimicrobial liquid cleansing compositions which provide residual benefit versus gram negative bacteria |
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US5977035A (en) * | 1996-08-30 | 1999-11-02 | Tomey Technology Corporation | Liquid agent for contact lens containing carboxylated amine as a preservative or sterilizing component |
US6075002A (en) * | 1997-11-28 | 2000-06-13 | Reckitt & Colman Inc. | Biphenyl based solvents in blooming type germicidal hard surface cleaners |
US6100231A (en) * | 1997-11-28 | 2000-08-08 | Reckitt & Colman Inc. | Biphenyl based solvents in blooming type hard surface cleaners |
US6183757B1 (en) | 1997-06-04 | 2001-02-06 | Procter & Gamble Company | Mild, rinse-off antimicrobial cleansing compositions which provide improved immediate germ reduction during washing |
US6183763B1 (en) | 1997-06-04 | 2001-02-06 | Procter & Gamble Company | Antimicrobial wipes which provide improved immediate germ reduction |
US6184195B1 (en) | 1997-11-28 | 2001-02-06 | Reckitt Benckiser Inc. | Blooming type germicidal hard surface cleaners comprising biphenyl-based solvents |
DE19937295A1 (en) * | 1999-08-06 | 2001-02-15 | Cognis Deutschland Gmbh | Syndet soaps |
US6190674B1 (en) | 1997-06-04 | 2001-02-20 | Procter & Gamble Company | Liquid antimicrobial cleansing compositions |
US6190675B1 (en) | 1997-06-04 | 2001-02-20 | Procter & Gamble Company | Mild, rinse-off antimicrobial liquid cleansing compositions which provide improved residual benefit versus gram positive bacteria |
US6197315B1 (en) | 1997-06-04 | 2001-03-06 | Procter & Gamble Company | Antimicrobial wipes which provide improved residual benefit versus gram negative bacteria |
US6210695B1 (en) | 1997-06-04 | 2001-04-03 | The Procter & Gamble Company | Leave-on antimicrobial compositions |
US6214363B1 (en) | 1997-11-12 | 2001-04-10 | The Procter & Gamble Company | Liquid antimicrobial cleansing compositions which provide residual benefit versus gram negative bacteria |
US6284259B1 (en) | 1997-11-12 | 2001-09-04 | The Procter & Gamble Company | Antimicrobial wipes which provide improved residual benefit versus Gram positive bacteria |
US6287577B1 (en) | 1997-11-12 | 2001-09-11 | The Procter & Gamble Company | Leave-on antimicrobial compositions which provide improved residual benefit versus gram positive bacteria |
US6287583B1 (en) | 1997-11-12 | 2001-09-11 | The Procter & Gamble Company | Low-pH, acid-containing personal care compositions which exhibit reduced sting |
WO2001074983A1 (en) * | 2000-04-04 | 2001-10-11 | Becton, Dickinson And Company | Foamable antimicrobial formulation |
US6451748B1 (en) | 1999-06-23 | 2002-09-17 | The Dial Corporation | Compositions containing a high percent saturation concentration of antibacterial agent |
WO2003044144A1 (en) * | 2001-11-16 | 2003-05-30 | Becton, Dickinson And Company | Foamable antimicrobial formulation |
US6861397B2 (en) | 1999-06-23 | 2005-03-01 | The Dial Corporation | Compositions having enhanced deposition of a topically active compound on a surface |
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US11633334B2 (en) | 2017-05-01 | 2023-04-25 | Gojo Industries, Inc. | Alcohol containing non-antimicrobial cleansing composition |
US11633451B2 (en) | 2016-03-31 | 2023-04-25 | Gojo Industries, Inc. | Antimicrobial peptide stimulating cleansing composition |
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BR0011860A (en) * | 1999-06-23 | 2002-04-30 | Dial Corp | Antibacterial compositions and process for reducing a population of bacteria on a surface |
JP2008106022A (en) * | 2006-10-27 | 2008-05-08 | Miura Co Ltd | Bactericide for skin |
EP2727991A1 (en) * | 2012-10-30 | 2014-05-07 | The Procter & Gamble Company | Cleaning and disinfecting liquid hand dishwashing detergent compositions |
JP5752220B2 (en) * | 2013-12-16 | 2015-07-22 | 花王株式会社 | Bactericidal detergent composition for hard surfaces |
JP7219583B2 (en) * | 2018-10-19 | 2023-02-08 | 大日本除蟲菊株式会社 | Fungicide composition |
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US6365563B1 (en) | 1997-09-17 | 2002-04-02 | Ciba Specialty Chemicals Corporation | Agglomerated antimicrobial detergent additive comprising swellable layered silicate and surfactant |
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TR199801841A3 (en) * | 1997-09-17 | 1999-10-21 | Ciba Specialty Chemicals Holding Inc. | Antimicrobial detergent additive. |
US6214363B1 (en) | 1997-11-12 | 2001-04-10 | The Procter & Gamble Company | Liquid antimicrobial cleansing compositions which provide residual benefit versus gram negative bacteria |
US6284259B1 (en) | 1997-11-12 | 2001-09-04 | The Procter & Gamble Company | Antimicrobial wipes which provide improved residual benefit versus Gram positive bacteria |
US6287583B1 (en) | 1997-11-12 | 2001-09-11 | The Procter & Gamble Company | Low-pH, acid-containing personal care compositions which exhibit reduced sting |
US6287577B1 (en) | 1997-11-12 | 2001-09-11 | The Procter & Gamble Company | Leave-on antimicrobial compositions which provide improved residual benefit versus gram positive bacteria |
US6075002A (en) * | 1997-11-28 | 2000-06-13 | Reckitt & Colman Inc. | Biphenyl based solvents in blooming type germicidal hard surface cleaners |
US6184195B1 (en) | 1997-11-28 | 2001-02-06 | Reckitt Benckiser Inc. | Blooming type germicidal hard surface cleaners comprising biphenyl-based solvents |
US6100231A (en) * | 1997-11-28 | 2000-08-08 | Reckitt & Colman Inc. | Biphenyl based solvents in blooming type hard surface cleaners |
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JPH11189784A (en) * | 1997-12-26 | 1999-07-13 | Kose Corp | Detergent composition |
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WO1999046987A1 (en) * | 1998-03-19 | 1999-09-23 | Bifodan A/S | Disinfecting composition |
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US6414023B1 (en) | 1998-03-19 | 2002-07-02 | Bifodan A/S | Disinfecting composition |
US6451748B1 (en) | 1999-06-23 | 2002-09-17 | The Dial Corporation | Compositions containing a high percent saturation concentration of antibacterial agent |
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US11633334B2 (en) | 2017-05-01 | 2023-04-25 | Gojo Industries, Inc. | Alcohol containing non-antimicrobial cleansing composition |
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Also Published As
Publication number | Publication date |
---|---|
FI970742A (en) | 1997-02-21 |
BG101308A (en) | 1997-09-30 |
MX9701416A (en) | 1997-05-31 |
EP0777717A2 (en) | 1997-06-11 |
BR9508775A (en) | 1997-12-23 |
JPH10504592A (en) | 1998-05-06 |
SK24497A3 (en) | 1997-07-09 |
WO1996006153A3 (en) | 1996-05-02 |
AU3345295A (en) | 1996-03-14 |
CZ55697A3 (en) | 1997-06-11 |
HUT76688A (en) | 1997-10-28 |
CA2196771A1 (en) | 1996-02-29 |
FI970742A0 (en) | 1997-02-21 |
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