WO2002045663A1 - Nail enamel composition containing a urea-modified thixotropic agent - Google Patents
Nail enamel composition containing a urea-modified thixotropic agent Download PDFInfo
- Publication number
- WO2002045663A1 WO2002045663A1 PCT/US2000/042513 US0042513W WO0245663A1 WO 2002045663 A1 WO2002045663 A1 WO 2002045663A1 US 0042513 W US0042513 W US 0042513W WO 0245663 A1 WO0245663 A1 WO 0245663A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- nail enamel
- composition according
- chosen
- enamel composition
- urea
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q3/00—Manicure or pedicure preparations
- A61Q3/02—Nail coatings
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
Definitions
- the present invention relates to a nail enamel composition with at least one of improved thixotropic properties and improved clarity in the bottle. More specifically, the invention relates to the use of a urea-modified compound as a thixotropic agent in a nail enamel composition.
- Nail enamel compositions typically contain, in an organic solvent or mixture of solvents, film-forming ingredients, plasticizing ingredients, and colorants.
- the composition also contains a thixotropic agent, which may act to thicken the composition in order to allow better spreading on the nail.
- the thixotropic agent may also act to suspend the colorant.
- the classic thixotropic agent used in the prior art is a bentonite clay.
- Aromatic organic solvents in particular may cause these clays to swell, thus providing a gel with good thixotropic properties, i.e., rendering the composition capable of passing from a gelled state to a liquid state simply by stirring and capable of going from liquid to gel after standing.
- a composition containing such a gel thus may exhibit relatively good dispersion stability without sedimentation or separation over a long period. Further, such compositions may not require the vigorous shaking that other compositions often require after extended periods of storage.
- the clay thixotropes may produce cloudy suspensions, rendering the composition opaque and often giving it a more or less yellowish color inside the bottle, unpleasant to the eye. Although this opacity is generally masked by the presence of colorants and/or pigments in the composition, the use of the clay thixotropes may diminish gloss in the final formulated nail enamel product. Thus the need remains for a thixotropic agent that will not affect the glossiness of the nail enamel and yet will have sufficient thixotropic properties such that the stability of the composition is not compromised.
- the present invention is drawn to a novel nail enamel composition containing, in a cosmetically acceptable solvent, at least one film-forming substance and at least one urea-modified thixotropic agent wherein the urea-modified thixotropic agent is a urea urethane having the following formula:
- R is chosen from C n H 2n+1 - and C m H 2rn+1 (C p H 2p O) r -; n is an integer having a value of from 4 to 22; m is an integer having a value of from 1 to 18; p is an integer having a value of from 2 to 4; and r is an integer having a value of from 1 to 10;
- R' is chosen from:
- R" is chosen from:
- the cosmetically acceptable solvent is a solvent system comprising diacetone alcohol and at least one additional solvent chosen from C r C s alkyl acetates and C r C 6 alkyl alcohols.
- the nail enamel composition of the invention may also contain a plasticizer and optionally a coloring agent.
- a urea-modified thixotropic agent in place of, or in conjunction with, the clay thixotropes of the prior art, may result in a clear suspension with improved gloss and have further discovered that the clarity of the suspension may be further enhanced when the urea-modified thixotropic agent is present in a solvent system comprising diacetone alcohol and at least one additional solvent chosen from C C 6 alkyl acetates and C C 6 alkyl alcohols.
- nail enamel compositions containing clay thixotropes only are difficult to process because their creation requires a great deal of high shear.
- the clay thixotropes are naturally occurring products, they can vary in quality and consistency.
- compositions utilizing the urea-modified thixotrope, and in one embodiment, the urea-modified thixotrope in a specific solvent system may be easy to produce consistently at optimum conditions because their creation may not require high shear processing.
- the presently claimed invention is drawn to a nail enamel composition which contains, in a cosmetically acceptable solvent, at least one film-forming substance and at least one urea-modified thixotropic agent.
- a thixotropic agent can give nail enamel compositions at least one of higher gloss, high clarity, improved aesthetics in the bottle, excellent thixotropic properties, and improved application properties. It has been discovered that at least one of these properties may be even more greatly enhanced where the cosmetically acceptable solvent is a solvent system comprising diacetone alcohol and at least one additional solvent chosen from C C 6 alkyl acetates and C,-C 6 alkyl alcohols.
- urea-modified thixotropic agents used in the present invention are urea urethanes having the following formula:
- R is chosen from C n H 2n+1 - and C m H 2rn+1 (C p H 2p O) r -; n is an integer having a value of from 4 to 22; m is an integer having a value of from 1 to 18; p is an integer having a value of from 2 to 4; and r is an integer having a value of from 1 to 10;
- R' is chosen from:
- R is chosen from:
- a urea-modified product can be purchased from BYK-Chemie in a dilute solution with N-methyl-pyrrolidone as solvent under the trade name of BYK ® -410 and is generally described in U.S. Patent No. 4,314,924, the disclosure of which is hereby incorporated by reference herein.
- the at least one urea-modified thixotropic agent may be present in an amount of from about 0.05 to about 1.00% relative to the weight of the composition.
- the at least one urea-modified thixotropic agent may be present in an amount of from about 0.25 to. about 0.75% relative to the weight of the composition.
- the nail enamel composition of the invention may contain at least one additional thixotropic agent, used in conjunction with the at least one urea- modified agent.
- the composition may comprise from about 0.10 to about 0.30% of the at least one urea-modified thixotropic agent relative to the weight of the composition and up to about 1.0% of the additional thixotropic agent.
- the additional thixotropic agent(s) may be chosen from conventional silica and bentonite clay agents.
- the additional thixotropic agent is stearalkonium hectorite, sold by RHEOX as BENTONE 27.
- Film forming substances useful in the present invention include, but are not limited to, conventional film-forming agents such as nitrocellulose, other cellulose derivatives, such as cellulose acetate, cellulose acetate butyrate, and ethyl cellulose; polyesters; resins, such as polyurethane resins, alkyd resins, and polyvinyl resins such as polyvinyl acetate, polyvinyl chloride, polyvinylbutyrate; (meth)acrylic and vinyl copolymers such as styrene/butadiene copolymers, acrylate/vinyl acetate copolymers, acrylonitrile/butadiene copolymers, and ethylene/vinyl acetate copolymers.
- conventional film-forming agents such as nitrocellulose, other cellulose derivatives, such as cellulose acetate, cellulose acetate butyrate, and ethyl cellulose
- polyesters such as polyurethane resins, alkyd resins, and polyvin
- the primary film-forming agent may be nitrocellulose, which is known to give hardness and resistance to abrasion.
- this second film-forming substance may, for example, be chosen from cellulose acetate butyrate, polyesters, polyurethanes, and acrylates.
- the film- forming substance may be present in an amount of from about 5% to about 20% by weight relative to the weight of the composition, for example, from about 10% to about 14%.
- Suitable modifiers for the primary film-forming agent include arylsulfonamide resins such as arylsulfonamide formaldehyde or epoxy resins.
- the presently claimed composition also may contain at least one plasticizer.
- Plasticizers useful in the presently claimed nail enamel composition include plasticizers commonly employed in nail varnish compositions. These plasticizers encompass, but are not limited to, dibutyl phthalate, dioctyl phthalate,: tricresyl phthalate, butyl phthlate, dibutoxy ethy!
- a plasticizer used in the present invention may be the mixture of acetyl tributyl citrate and N-ethyl tosyl amide.
- the plasticizer may, for example, be present in an amount of from about 3% to about 12% by weight relative to the weight of the composition.
- the cosmetically acceptable solvents useful in the present invention are cosmetically acceptable organic solvents including, but not limited to toluene, xylene, C C 6 alkyl acetates, such as ethyl acetate, propyl acetate, and butyl acetate; ketones such as acetone or methyl ethyl ketone; alkanes such as hexane or heptane; C C 6 alkyl alcohols such as ethanol, isopropanol, and butanol; glycol ethers; N-methyl pyrrolidone; diacetone alcohol, and alkyl lactates.
- the invention uses a solvent system comprising diacetone alcohol and at least one additional solvent chosen from C r C 6 alkyl acetates and C C 6 alkyl alcohols.
- the solvent system comprises diacetone alcohol, at least one C C 6 alkyl acetate and at least one C.,-C 6 alkyl alcohol.
- the solvent or mixture of solvents may be present, in one embodiment, in an amount of from about 40% to about 80% by weight relative to the weight of the composition, and, in another embodiment, from about 65% to about 78%.
- the nail enamel composition of the invention may also contain at least one coloring agent.
- coloring agents can be used, and examples include inorganic pigments such as titanium dioxide, iron oxides, titanated mica, iron oxide coated mica, ultramarine, chromium oxide, chromium hydroxide, manganese violet, bismuth oxychloride, guanine, and aluminum; pearlescent materials; and organic coloring agents such as ferric ammonium ferrocyanide, and D&C Red Nos. 6, 7, 34, Blue No. 1 , Violet No. 2, and Yellow No. 5.
- the inorganic pigments may be surface-treated as is customary to prevent migration or striation. Silicones and polyethylenes are most often used as the coatings for inorganic pigments and thus may be used according to the present invention. Colorant materials may also include chips or powder of mica or diamonds in the nail composition. Also useful are specialty materials giving rise to two-tone color effects such as liquid crystal silicones or multi-lamellar metallic particulates, which generally can be mixed with pigments or dyes to obtain a broader spectrum of brilliant color and increased luminous reflectance. Such materials are described in, e.g., U.S. Patent No. 3,438,796; U.S. Patent No. 4,410,570; U.S. Patent No. 4,434,010; U.S. Patent No.
- the coloring agent may be present in the nail enamel composition in an amount up to about 5% by weight relative to the total weight of the composition. In another embodiment, the coloring agent is present in an amount of from 2% to 3% by weight.
- composition according to the invention may also include additives recognized by a person skilled in the art as being capable of incorporation into such a composition.
- the composition may include at least one cosmetically active compound, which may be selected from vitamins, minerals, moisturizers, flavoring compounds, fragrances, masking agents, hardening agents such as silica and formaldehyde/glyoxal, UV absorbers, and fibers such as nylon and aramide fibers.
- Any art-recognized UV absorber can be used, both organic and inorganic.
- inorganic UV absorbers include titanium dioxide and zinc oxide, both of which may be used in nanoparticulate form.
- organic UV absorbers include octocrylene, octylmethoxy cinnamate, and benzophenone. Additional additive ingredients may include keratin and its derivatives, melanin, collagen, cystine, chitosan and its derivatives, ceramides, biotin, oligoelements, protein hydrolysates, and phospholipids.
- composition according to the invention may be prepared by a person skilled in the art on the basis of his or her general knowledge and according to the state of the art.
- composition according to the invention may be in the form of a product to be applied to the nails, such as a top coat, a base coat, or a pigmented nail lacquer or varnish.
- compositions were formulated as set forth in the following table. The amounts listed are in grams.
- compositions 1-3 were visually compared with a "classic" nail enamel composition, i.e., one containing only the traditional clay-based thixotrope. The comparisons are described below.
- Composition 1 which was a formulation according to the invention but which contained no colorants, i.e., was a clear top coat enamel. This formulation exhibited significantly improved body and viscosity, while maintaining excellent clarity, when compared to the "classic" composition.
- Composition 2 was similar to composition 1 but did not contain sucrose acetate isobutyrate, one of the plasticizers, or acrylates copolymer, one of the film-formers. Composition 2 did contain, however, pigments and pearlescent colorants and, in addition to the urea-urethane (BYK-410) as a thixotrope, contained a clay-based thixotrope, stearalkonium hectorite. The result was a pigmented/pearlescent nail enamel with no perceptible (visual) differences over the "classic" compositions.
- composition 3 was an inventive pigmented/pearlescent nail enamel utilizing only the modified urea-urethane as the thixotrope.
- This product displayed improved bottle aesthetics (gloss) and a smoother finish on the nail versus a "classic” nail enamel which utilized the clay type thixotropes.
- inventive compositions had higher gloss; better stability, i.e., even with pigments that are normally difficult to suspend; and improved application properties, e.g., almost no brush marks were perceptible on the nail after the composition dried, when compared to the "classic" compositions.
- improved application properties e.g., almost no brush marks were perceptible on the nail after the composition dried, when compared to the "classic" compositions.
- compositions were formulated as set forth in the following table. The amounts listed are in grams.
- compositions 5, 6, and 7 are almost identical to inventive composition 4, but each contains a different colorant or additive.
- composition 5 is a translucent nail enamel containing polyethylene teraphthalate, commonly known as "glitter” and having a particle size ranging from 100 microns to 0.32 cm.
- This composition displayed improved particle suspension and bottle aesthetics when compared to the "classic" composition.
- This example illustrates the ability of the present inventive compositions to suspend large particles even without the presence of the traditional clay or silica thixotropes, i.e., using only the modified urea- urethane thixotrope and a solvent system comprising at least one C r C 6 alkyl acetate, at least one C,-C 6 alkyl alcohol, and diacetone alcohol.
- Composition 6 contains two red pigments.
- Composition 7 contains pearlescent pigments.
- suspension, gloss, and stability were all improved for compositions 6 and 7.
- inventive compositions had higher gloss; better stability, i.e., even with pigments that are normally difficult to suspend; and improved application properties, e.g., almost no brush marks were perceptible on the nail after the composition dried, when compared to the "classic" compositions.
Abstract
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA002397587A CA2397587C (en) | 2000-12-04 | 2000-12-04 | Nail enamel composition containing a urea-modified thixotropic agent |
JP2002547449A JP2004514728A (en) | 2000-12-04 | 2000-12-04 | Nail polish composition containing urea-modified thixotropic agent |
CN00818815.7A CN1433296A (en) | 2000-12-04 | 2000-12-04 | Nail enamel composition containing urea-modified thixotropic agent |
PCT/US2000/042513 WO2002045663A1 (en) | 2000-12-04 | 2000-12-04 | Nail enamel composition containing a urea-modified thixotropic agent |
EP00992383A EP1341501A1 (en) | 2000-12-04 | 2000-12-04 | Nail enamel composition containing a urea-modified thixotropic agent |
AU2001243090A AU2001243090A1 (en) | 2000-12-04 | 2000-12-04 | Nail enamel composition containing a urea-modified thixotropic agent |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/US2000/042513 WO2002045663A1 (en) | 2000-12-04 | 2000-12-04 | Nail enamel composition containing a urea-modified thixotropic agent |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2002045663A1 true WO2002045663A1 (en) | 2002-06-13 |
Family
ID=21742215
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2000/042513 WO2002045663A1 (en) | 2000-12-04 | 2000-12-04 | Nail enamel composition containing a urea-modified thixotropic agent |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP1341501A1 (en) |
JP (1) | JP2004514728A (en) |
CN (1) | CN1433296A (en) |
AU (1) | AU2001243090A1 (en) |
CA (1) | CA2397587C (en) |
WO (1) | WO2002045663A1 (en) |
Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2868947A1 (en) * | 2004-04-20 | 2005-10-21 | Durlin France Sa | Cosmetic or dermatological thixotropic composition without acetone, useful for removing nail polish, comprises: rheologic agents of type urea-methane associated with emollient and cellulosic thickening agents; and an organic phase |
FR2907336A1 (en) * | 2006-10-19 | 2008-04-25 | Oreal | Nail varnish useful to form a glossy and long lasting film on the nails, comprises an organic solvent medium comprising an ester solvent and a gelling agent of a compound derived from reaction of polyisocyanate and primary amine |
FR2919790A1 (en) * | 2007-08-10 | 2009-02-13 | Oreal | Make-up product e.g. nail polish, packing and applying assembly for nails, has applicator taking product contained in container and applying product on nails, where applicator has incurved flexible strip defining concave applicator surface |
FR2919801A1 (en) * | 2007-08-10 | 2009-02-13 | Oreal | Composition, useful to obtain varnish film deposited on the nails, comprises medium, thixotropic thickener, and coloring agent comprising magnetic bodies, diffracting pigments, interferential pigments and/or light-reflecting particles |
EP2025320A1 (en) * | 2007-08-10 | 2009-02-18 | L'Oréal | Assembly for packaging and applying a high-viscosity nail varnish |
EP1820490A3 (en) * | 2006-02-13 | 2009-08-19 | L'Oréal | Custom-colored nail compositions |
EP1818043A3 (en) * | 2006-02-13 | 2009-08-19 | L'Oréal | Nail compositions in gelled form |
DE102009017277A1 (en) | 2009-04-11 | 2010-10-28 | Byk-Chemie Gmbh | Nail polish comprises a binder comprising e.g. nitrocellulose, an alcohol, preferably aliphatic alcohol, an ester, preferably aliphatic ester containing alcohol component and a polyamide-containing block polymer |
EP1595524B1 (en) * | 2004-03-23 | 2011-05-11 | L'Oréal | Nail composition comprising a sequenced polymer and a plastifying agent |
US20140234239A1 (en) * | 2013-02-20 | 2014-08-21 | O P I Products, Inc. | Suspending medium for glitter or pigments in urethane (meth)acrylates |
WO2014186355A1 (en) * | 2013-05-17 | 2014-11-20 | Chesson Laboratory Associates, Inc. | Methods of treating and/or preventing nail disorders and/or improving the appearance of a nail |
JP2018059096A (en) * | 2016-09-30 | 2018-04-12 | ライオン株式会社 | Liquid detergent composition |
US10133392B1 (en) * | 2013-07-19 | 2018-11-20 | Larry Levin | Smartphone nail polish |
US10842729B2 (en) | 2017-09-13 | 2020-11-24 | Living Proof, Inc. | Color protectant compositions |
US10987300B2 (en) | 2017-09-13 | 2021-04-27 | Living Proof, Inc. | Long lasting cosmetic compositions |
FR3120526A1 (en) * | 2021-03-09 | 2022-09-16 | L'oreal | COMPOSITION FOR NAIL TREATMENT |
US11622929B2 (en) | 2016-03-08 | 2023-04-11 | Living Proof, Inc. | Long lasting cosmetic compositions |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2972923B1 (en) * | 2011-03-25 | 2013-08-23 | Urgo Lab | FILMOGENIC COMPOSITION CONTAINING A SOLAR FILTER, ITS USE FOR THE TREATMENT OF SCARS |
JP2017105739A (en) * | 2015-12-11 | 2017-06-15 | 株式会社シードリーフ | Method for using cosmetic and cosmetic |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2000027347A1 (en) * | 1998-11-05 | 2000-05-18 | L'oreal | Nail coating compositions containing microspheres |
US6156325A (en) * | 1998-09-16 | 2000-12-05 | L'oreal | Nail enamel composition containing a urea-modified thixotropic agent |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6565835B1 (en) * | 2000-07-07 | 2003-05-20 | Kirker Enterprises, Inc. | Nail enamel compositions containing aluminum platelets |
-
2000
- 2000-12-04 CN CN00818815.7A patent/CN1433296A/en active Pending
- 2000-12-04 WO PCT/US2000/042513 patent/WO2002045663A1/en active Application Filing
- 2000-12-04 AU AU2001243090A patent/AU2001243090A1/en not_active Abandoned
- 2000-12-04 JP JP2002547449A patent/JP2004514728A/en active Pending
- 2000-12-04 CA CA002397587A patent/CA2397587C/en not_active Expired - Fee Related
- 2000-12-04 EP EP00992383A patent/EP1341501A1/en not_active Withdrawn
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6156325A (en) * | 1998-09-16 | 2000-12-05 | L'oreal | Nail enamel composition containing a urea-modified thixotropic agent |
WO2000027347A1 (en) * | 1998-11-05 | 2000-05-18 | L'oreal | Nail coating compositions containing microspheres |
Non-Patent Citations (1)
Title |
---|
See also references of EP1341501A1 * |
Cited By (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1595524B1 (en) * | 2004-03-23 | 2011-05-11 | L'Oréal | Nail composition comprising a sequenced polymer and a plastifying agent |
FR2868947A1 (en) * | 2004-04-20 | 2005-10-21 | Durlin France Sa | Cosmetic or dermatological thixotropic composition without acetone, useful for removing nail polish, comprises: rheologic agents of type urea-methane associated with emollient and cellulosic thickening agents; and an organic phase |
EP1591101A1 (en) * | 2004-04-20 | 2005-11-02 | Durlin France | Aceton free nail polish remover |
EP1820490A3 (en) * | 2006-02-13 | 2009-08-19 | L'Oréal | Custom-colored nail compositions |
EP1818043A3 (en) * | 2006-02-13 | 2009-08-19 | L'Oréal | Nail compositions in gelled form |
FR2907336A1 (en) * | 2006-10-19 | 2008-04-25 | Oreal | Nail varnish useful to form a glossy and long lasting film on the nails, comprises an organic solvent medium comprising an ester solvent and a gelling agent of a compound derived from reaction of polyisocyanate and primary amine |
FR2919790A1 (en) * | 2007-08-10 | 2009-02-13 | Oreal | Make-up product e.g. nail polish, packing and applying assembly for nails, has applicator taking product contained in container and applying product on nails, where applicator has incurved flexible strip defining concave applicator surface |
FR2919801A1 (en) * | 2007-08-10 | 2009-02-13 | Oreal | Composition, useful to obtain varnish film deposited on the nails, comprises medium, thixotropic thickener, and coloring agent comprising magnetic bodies, diffracting pigments, interferential pigments and/or light-reflecting particles |
EP2025320A1 (en) * | 2007-08-10 | 2009-02-18 | L'Oréal | Assembly for packaging and applying a high-viscosity nail varnish |
DE102009017277A1 (en) | 2009-04-11 | 2010-10-28 | Byk-Chemie Gmbh | Nail polish comprises a binder comprising e.g. nitrocellulose, an alcohol, preferably aliphatic alcohol, an ester, preferably aliphatic ester containing alcohol component and a polyamide-containing block polymer |
US20140234239A1 (en) * | 2013-02-20 | 2014-08-21 | O P I Products, Inc. | Suspending medium for glitter or pigments in urethane (meth)acrylates |
WO2014186355A1 (en) * | 2013-05-17 | 2014-11-20 | Chesson Laboratory Associates, Inc. | Methods of treating and/or preventing nail disorders and/or improving the appearance of a nail |
CN105339047A (en) * | 2013-05-17 | 2016-02-17 | 切逊实验室联合公司 | Methods of treating and/or preventing nail disorders and/or improving the appearance of nail |
US10987376B2 (en) | 2013-05-17 | 2021-04-27 | Chesson Laboratory Associates, Inc. | Methods of treating and/or preventing nail disorders and/or improving the appearance of a nail |
CN114831925A (en) * | 2013-05-17 | 2022-08-02 | 切逊实验室联合公司 | Method for treating and/or preventing nail disorders and/or improving nail appearance |
US10133392B1 (en) * | 2013-07-19 | 2018-11-20 | Larry Levin | Smartphone nail polish |
US11622929B2 (en) | 2016-03-08 | 2023-04-11 | Living Proof, Inc. | Long lasting cosmetic compositions |
JP2018059096A (en) * | 2016-09-30 | 2018-04-12 | ライオン株式会社 | Liquid detergent composition |
JP7004537B2 (en) | 2016-09-30 | 2022-01-21 | ライオン株式会社 | Particle dispersion detergent composition |
US10842729B2 (en) | 2017-09-13 | 2020-11-24 | Living Proof, Inc. | Color protectant compositions |
US10987300B2 (en) | 2017-09-13 | 2021-04-27 | Living Proof, Inc. | Long lasting cosmetic compositions |
US11707426B2 (en) | 2017-09-13 | 2023-07-25 | Living Proof, Inc. | Color protectant compositions |
FR3120526A1 (en) * | 2021-03-09 | 2022-09-16 | L'oreal | COMPOSITION FOR NAIL TREATMENT |
Also Published As
Publication number | Publication date |
---|---|
JP2004514728A (en) | 2004-05-20 |
CN1433296A (en) | 2003-07-30 |
CA2397587C (en) | 2008-05-27 |
CA2397587A1 (en) | 2002-06-13 |
EP1341501A1 (en) | 2003-09-10 |
AU2001243090A1 (en) | 2002-06-18 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US6156325A (en) | Nail enamel composition containing a urea-modified thixotropic agent | |
CA2397587C (en) | Nail enamel composition containing a urea-modified thixotropic agent | |
US6451294B1 (en) | Method and makeup kit containing goniochromatic and monochromatic pigments | |
US5206011A (en) | Quick-drying nail enamel compositions | |
US20080081022A1 (en) | Poss Containing Cosmetic Compositions Having Improved Wear And/Or Pliability And Methods Of Making Improved Cosmetic Compositions | |
CA2607288C (en) | Long-wearing glossy cosmetic composition | |
US6555096B2 (en) | Nail enamel composition containing a urea-modified thixotropic agent in a solvent system | |
US5725866A (en) | Translucent composition that can be applied to the nail | |
US5882636A (en) | Phthalate free nail polish enamel composition | |
JPS61210020A (en) | Manicure | |
US20120164195A1 (en) | Cosmetic Films | |
US20010007676A1 (en) | Transparent clear suspension nail polish enamel | |
US20030175225A1 (en) | Nail enamel composition exhibiting a color change dependent upon an observer's viewing angle | |
US20070189995A1 (en) | Custom-colored nail compositions | |
EP1043967A1 (en) | Nail coating compositions containing microspheres | |
US6537530B2 (en) | Phthalate free nail polish enamel composition employing novel plasticizers | |
US20050238869A9 (en) | Nail make-up composition with a mirror effect | |
US8679465B2 (en) | Cosmetic composition for nails, free of phthalates, camphor and aromatic solvent | |
JP2007091751A (en) | Nail make-up composition with mirror effect | |
US20050220730A1 (en) | Nail polish compositions comprised of nanoscale particles free of reactive groups | |
US20080206173A1 (en) | Nail compositions in powdered form | |
JP6144602B2 (en) | Marble beauty nail | |
US20230165765A1 (en) | Optically-transforming nail coatings, methods, and systems | |
WO2022207457A1 (en) | Coloured aqueous dispersion of particles of at least one pigment comprising an ionic polymeric dispersant, a polyol, hyaluronic acid or a salt thereof, a filler and a polyoxyethylenated alkyl ether dimethylsilane compound | |
JPH01143817A (en) | Manicure |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AK | Designated states |
Kind code of ref document: A1 Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CR CU CZ DE DK DM DZ EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ PL PT RO RU SD SE SG SI SK SL TJ TM TR TT TZ UA UG US UZ VN YU ZA ZW |
|
AL | Designated countries for regional patents |
Kind code of ref document: A1 Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE TR BF BJ CF CG CI CM GA GN GW ML MR NE SN TD TG |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2397587 Country of ref document: CA |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2000992383 Country of ref document: EP |
|
ENP | Entry into the national phase |
Ref country code: JP Ref document number: 2002 547449 Kind code of ref document: A Format of ref document f/p: F |
|
WWE | Wipo information: entry into national phase |
Ref document number: 008188157 Country of ref document: CN |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
WWP | Wipo information: published in national office |
Ref document number: 2000992383 Country of ref document: EP |
|
REG | Reference to national code |
Ref country code: DE Ref legal event code: 8642 |