WO2004024024A1 - Powered toothbrush - Google Patents

Powered toothbrush Download PDF

Info

Publication number
WO2004024024A1
WO2004024024A1 PCT/US2003/028335 US0328335W WO2004024024A1 WO 2004024024 A1 WO2004024024 A1 WO 2004024024A1 US 0328335 W US0328335 W US 0328335W WO 2004024024 A1 WO2004024024 A1 WO 2004024024A1
Authority
WO
WIPO (PCT)
Prior art keywords
toothbrush
head
drive shaft
movable
powered
Prior art date
Application number
PCT/US2003/028335
Other languages
French (fr)
Inventor
Douglas J. Hohlbein
Original Assignee
Colgate-Palmolive Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Colgate-Palmolive Company filed Critical Colgate-Palmolive Company
Priority to EP03749560A priority Critical patent/EP1558171A4/en
Priority to AU2003267085A priority patent/AU2003267085B2/en
Priority to MXPA05002587A priority patent/MXPA05002587A/en
Priority to CA002498230A priority patent/CA2498230C/en
Priority to BRPI0314248-5A priority patent/BR0314248B1/en
Priority to CN03821805A priority patent/CN100594851C/en
Publication of WO2004024024A1 publication Critical patent/WO2004024024A1/en
Priority to US11/079,325 priority patent/US7007332B2/en
Priority to US11/367,767 priority patent/US7219384B2/en

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61CDENTISTRY; APPARATUS OR METHODS FOR ORAL OR DENTAL HYGIENE
    • A61C17/00Devices for cleaning, polishing, rinsing or drying teeth, teeth cavities or prostheses; Saliva removers; Dental appliances for receiving spittle
    • A61C17/16Power-driven cleaning or polishing devices
    • A61C17/22Power-driven cleaning or polishing devices with brushes, cushions, cups, or the like
    • A61C17/32Power-driven cleaning or polishing devices with brushes, cushions, cups, or the like reciprocating or oscillating
    • A61C17/34Power-driven cleaning or polishing devices with brushes, cushions, cups, or the like reciprocating or oscillating driven by electric motor
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61CDENTISTRY; APPARATUS OR METHODS FOR ORAL OR DENTAL HYGIENE
    • A61C17/00Devices for cleaning, polishing, rinsing or drying teeth, teeth cavities or prostheses; Saliva removers; Dental appliances for receiving spittle
    • A61C17/16Power-driven cleaning or polishing devices
    • A61C17/22Power-driven cleaning or polishing devices with brushes, cushions, cups, or the like
    • A61C17/32Power-driven cleaning or polishing devices with brushes, cushions, cups, or the like reciprocating or oscillating
    • A61C17/34Power-driven cleaning or polishing devices with brushes, cushions, cups, or the like reciprocating or oscillating driven by electric motor
    • A61C17/349Power-driven cleaning or polishing devices with brushes, cushions, cups, or the like reciprocating or oscillating driven by electric motor with multiple brush bodies
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61CDENTISTRY; APPARATUS OR METHODS FOR ORAL OR DENTAL HYGIENE
    • A61C17/00Devices for cleaning, polishing, rinsing or drying teeth, teeth cavities or prostheses; Saliva removers; Dental appliances for receiving spittle
    • A61C17/16Power-driven cleaning or polishing devices
    • A61C17/22Power-driven cleaning or polishing devices with brushes, cushions, cups, or the like
    • A61C17/32Power-driven cleaning or polishing devices with brushes, cushions, cups, or the like reciprocating or oscillating
    • A61C17/34Power-driven cleaning or polishing devices with brushes, cushions, cups, or the like reciprocating or oscillating driven by electric motor
    • A61C17/3409Power-driven cleaning or polishing devices with brushes, cushions, cups, or the like reciprocating or oscillating driven by electric motor characterized by the movement of the brush body
    • A61C17/3427Rotation around the axis perpendicular to the axis of toothbrush handle and in the plane defined by the bristle holder

Definitions

  • Powered toothbrushes are one example of efforts to improve tooth cleaning by including one or more movable sets of cleaning elements .
  • Another approach to improving cleansing of teeth is use of a toothbrush head that is articulated or segmented to better follow the rounded curvature of teeth aligned in the human jaw.
  • U.S. Patent No. 6,314,606Bl issued November 13, 2001 to Douglas Hohlbein.
  • This patent disclosed a two part toothbrush head joined by a living hinge or other integrally molded elastomeric-type connector.
  • the part of the toothbrush head most remote from the handle is normally angled with respect to the head section nearest the handle.
  • the flexible angu- lation of the head accommodates to the curvature of the human jaw, as well as the relatively straight portions of the jaw.
  • the flexibility of at least a portion of the head provides a more gentle treatment of the gum line because the force applied by the user is moderated and more evenly distributed through the hinge (col- umn 1, lines 61-67) .
  • a powered toothbrush which drives a moving portion of the toothbrush head in a reciprocal mo- tion about a hinge joining the moving portion of the head to a fixed portion of the head.
  • the reciprocation movement provides a power assisted tip pulsing action.
  • the living hinge construction used in the aforementioned patent may be re- placed with a less rigid hinge such as a pivoting pin and socket joint.
  • the hinge construction may be of any type that does not affect the powered reciprocating of the moving portion of the toothbrush head.
  • the movable section of the toothbrush head can be powered by using the type of drive mechanism shown in U.S. Patent No. 5,625,916.
  • the movable portion of the toothbrush head has a flange extending therefrom to- ward the handle.
  • This flange preferably has a horizontal slot that accepts an offset in a drive shaft extending from the motive source in the toothbrush handle for example, a motor.
  • This offset in the drive shaft is similar to that shown in U.S. Patent No. 6,347,425B1 discussed above .
  • the slot in the flange interacts with the offset in the drive shaft to form a "slip clutch” so that if an excessive load is applied to the movable portion of the toothbrush head, the motor powering ' the toothbrush will not stall.
  • This "slip clutch” effect also has the advantage of being a safety mechanism when in use. More par- ticularly, the slip clutch limits operation of the movable portion of the head if the user applies excessive force to the handle .
  • the use of the flange extending from the powered portion of the toothbrush head also permits a low profile of the toothbrush head. That low, compact profile facilitates insertion and use of the toothbrush in the human mouth.
  • Figure 1 is a perspective view of a power toothbrush with a power driven movable portion of a toothbrush head.
  • Figure 2 is an enlarged cross-sectional view showing the movable portion of the toothbrush head with attached flange powered by an offset drive mechanism, in one position.
  • Figure 3 is an enlarged cross-sectional view showing the movable portion of the toothbrush in another position.
  • Figure 4 is an elevational view showing the slot in a tab on the flange attached to the movable portion of the toothbrush head in alternate positions.
  • Figure 5 is an elevational view showing an alternate design of the slot on the tab attached to the movable portion of the toothbrush head.
  • the powered toothbrush 10 of this invention includes a motor 12 powered by batteries or rechargeable energy source 14.
  • the toothbrush 10 can be operated by depress- ing or otherwise operating power switch 16 on the body of toothbrush 10.
  • a powered motor 12 rotates in a conventional manner.
  • a drive shaft 18 is connected to the motor 12 through a shaft coupling or other means of directly transferring the motor's rotation to drive shaft 18.
  • Toothbrush 10 contains a two part articulated head 20 comprising a movable portion 22 and stationary portion 24 formed as part of the overall powered toothbrush.
  • Movable portion 22 preferably has a soft elastomeric coating 23 which reduces the impact thereof on the users teeth and mouth during use.
  • These portions of head 20 are preferably joined by a hinge 25 that allows movable portion 22 to freely move relative to portion 24. It is envisioned that the portion of toothbrush 10 containing the head 20 could be adapted for replacement by inserting a new head into the powered portion of the toothbrush at or about the location indicated by reference numeral 28.
  • the stationary 24 and movable 22 portions of the toothbrush head 20 contain cleaning elements 30.
  • Cleaning elements 30 are arranged in both portions of head 20 in a known manner. Any suitable form of cleaning elements may be used as the cleaning elements 30 in the broad practice of this invention.
  • the term "cleaning elements" is intended to be used in a generic sense which could include conventional fiber bristles or massage ele- ments or other forms of cleaning elements such as elastomeric fingers or walls arranged in a circular cross- sectional shape or any type of desired shape including straight portions or sinusoidal portions. Where bristles are used, the bristles could be mounted to tuft blocks or sections by extending through suitable openings in the tuft blocks so that the base of the bristles is mounted within or below the tuft block.
  • the specific illustra- tion of the cleaning elements is merely for exemplary purposes.
  • the invention can be practiced with various combinations (such as stapled or in-mold technology bristles, etc.) and/or with the same bristle or cleaning element materials (such as nylon bristles, spiral bristles, rubber bristles, etc.)
  • the cleaning elements can be generally perpendicular to head 20, some or all of the cleaning elements may be angled at various angles with respect to the surface of head 20. It is thereby possible to select the combination of cleaning element configurations, materials and orientations to achieve specific intended results to deliver additional oral health benefits, like enhanced cleaning, tooth polishing, tooth whitening and/or massaging of the gums.
  • Movable portion 22 has a flange 26 attached thereto extending from the area of movable portion 22 adjacent the last row of cleaning elements and extending lengthwise toward the drive shaft 18.
  • This flange 26 may be molded as part of movable portion 22 or affixed thereto.
  • the flange 26 terminates at a tab 32 which is preferably aligned approximately perpendicular to the axis of drive shaft 18.
  • Tab 32 at the end of flange 26 contains a slot 34 for receipt of an offset end 36 or elbow of drive shaft 18 (See Figs. 2 and 4).
  • the offset end 36 of the shaft 18 engages the side edges of slot 34.
  • movable portion 22 of head 20 rapidly moves about hinge 25 resulting in a vigorous passage of cleaning elements 30 over the user's teeth and gums. This rapid movement helps to clean the user's teeth and stimulate the user's gums.
  • Figs . 4 and 5 illustrate alternative configurations 34 and 34A for slot 34.
  • Slot 34 of Fig 4 is closed at both ends to contain the offset end 36 of shaft 18 whereas slot 34A shown in Fig 5 allows movement of offset end 36 across the entire width of tab 32 attached to flange 26.
  • Flange 26 is preferably formed of a moderately flexible material that permits its movement independent of movable portion 22 of the toothbrush head 20.
  • the flexibility of flange 26 will allow the motor to continue turning even though the movable portion 22 of head 20 is not moving or only slightly moving.
  • tab 32 Under normal operation tab 32 will be displaced in a plane perpendicular to the axis of the toothbrush, and the drive shaft 18, as the offset end 36 of that shaft rotates with the shaft.
  • the amount of movement of tab 32, and consequent movement of movable portion 22 can be regulated by the distance between the axis of drive shaft 18 and the offset end 36 of that shaft.
  • Fig. 4 illustrates this movement as the drive shaft 18 moves to oppo- site extremes of rotation.
  • the full lines in Fig. 4 represent the placement of tab 32 when movable portion 22 of head 20 is in the position shown in Fig. 2.
  • the phantom lines correspond to its position when movable portion 22 is in the Fig. 3 position.
  • a cover 38 is placed over these parts.
  • the cover 38 is preferably flexible or molded to allow free movement of flange 26 under power of drive shaft 18.

Abstract

A powered toothbrush (10) is disclosed wherein a portion of the toothbrush head (20) is movable about a hinge (25). The movable portion (22) of the head reciprocates about that hinge through the interaction of a flexible extension (26) of that portion containing a slot (34). Movable within the slot is an offset end (36) of a rotating drive shaft (18) connected to the power source (14) in the toothbrush. Translation of rotation movement of the drive shaft to reciprocating movement of the hinged head (22) is achievable in a manner that the power source is not stalled or burned out if movement of the toothbrush head is prevented or limited.

Description

Title POWERED TOOTHBRUSH
Background of the Invention
As toothbrush design has evolved in an effort to improve cleaning of teeth and gums, the complexity of toothbrushes and their functions have increased. Powered toothbrushes are one example of efforts to improve tooth cleaning by including one or more movable sets of cleaning elements . Another approach to improving cleansing of teeth is use of a toothbrush head that is articulated or segmented to better follow the rounded curvature of teeth aligned in the human jaw. However, little has been done to synergistically combine these approaches in a manner that achieves effective cleaning of all teeth while carefully avoiding harm to the gum line. That is an object of this invention.
One approach to a segmented or articulated toothbrush head is shown in U.S. Patent No. 6,314,606Bl issued November 13, 2001 to Douglas Hohlbein. This patent disclosed a two part toothbrush head joined by a living hinge or other integrally molded elastomeric-type connector. Under one embodiment of this patent, the part of the toothbrush head most remote from the handle is normally angled with respect to the head section nearest the handle. According to the patent, the flexible angu- lation of the head accommodates to the curvature of the human jaw, as well as the relatively straight portions of the jaw. In addition, the flexibility of at least a portion of the head provides a more gentle treatment of the gum line because the force applied by the user is moderated and more evenly distributed through the hinge (col- umn 1, lines 61-67) .
Summary of the Invention
A powered toothbrush is disclosed which drives a moving portion of the toothbrush head in a reciprocal mo- tion about a hinge joining the moving portion of the head to a fixed portion of the head. The reciprocation movement provides a power assisted tip pulsing action.
To facilitate this movement, the living hinge construction used in the aforementioned patent may be re- placed with a less rigid hinge such as a pivoting pin and socket joint. However, the hinge construction may be of any type that does not affect the powered reciprocating of the moving portion of the toothbrush head.
The movable section of the toothbrush head can be powered by using the type of drive mechanism shown in U.S. Patent No. 5,625,916.
Another powered toothbrush is described in U.S. Patent No. 6,347,425B1 issued February 19, 2002 and assigned to the assignee of this invention. It discloses an elec- trically powered toothbrush having rotatable drive shaft with an end off-set from the central longitudinal axis of the drive shaft which provides a reciprocating, rocking motion to a set of cleaning elements.
In a preferred embodiment, the movable portion of the toothbrush head has a flange extending therefrom to- ward the handle. This flange preferably has a horizontal slot that accepts an offset in a drive shaft extending from the motive source in the toothbrush handle for example, a motor. This offset in the drive shaft is similar to that shown in U.S. Patent No. 6,347,425B1 discussed above .
The slot in the flange interacts with the offset in the drive shaft to form a "slip clutch" so that if an excessive load is applied to the movable portion of the toothbrush head, the motor powering 'the toothbrush will not stall. This "slip clutch" effect also has the advantage of being a safety mechanism when in use. More par- ticularly, the slip clutch limits operation of the movable portion of the head if the user applies excessive force to the handle . The use of the flange extending from the powered portion of the toothbrush head also permits a low profile of the toothbrush head. That low, compact profile facilitates insertion and use of the toothbrush in the human mouth. Brief Description of The Drawings;
This invention is capable of use in a broad array of consumer packaging and products . The drawings illustrate one use of the invention and are not to be construed as the only embodiment of the invention.
Figure 1 is a perspective view of a power toothbrush with a power driven movable portion of a toothbrush head.
Figure 2 is an enlarged cross-sectional view showing the movable portion of the toothbrush head with attached flange powered by an offset drive mechanism, in one position.
Figure 3 is an enlarged cross-sectional view showing the movable portion of the toothbrush in another position. Figure 4 is an elevational view showing the slot in a tab on the flange attached to the movable portion of the toothbrush head in alternate positions.
Figure 5 is an elevational view showing an alternate design of the slot on the tab attached to the movable portion of the toothbrush head.
Detailed Description of the Preferred Embodiment
The powered toothbrush 10 of this invention includes a motor 12 powered by batteries or rechargeable energy source 14. The toothbrush 10 can be operated by depress- ing or otherwise operating power switch 16 on the body of toothbrush 10.
A powered motor 12 rotates in a conventional manner. A drive shaft 18 is connected to the motor 12 through a shaft coupling or other means of directly transferring the motor's rotation to drive shaft 18.
Toothbrush 10 contains a two part articulated head 20 comprising a movable portion 22 and stationary portion 24 formed as part of the overall powered toothbrush. Movable portion 22 preferably has a soft elastomeric coating 23 which reduces the impact thereof on the users teeth and mouth during use. These portions of head 20 are preferably joined by a hinge 25 that allows movable portion 22 to freely move relative to portion 24. It is envisioned that the portion of toothbrush 10 containing the head 20 could be adapted for replacement by inserting a new head into the powered portion of the toothbrush at or about the location indicated by reference numeral 28.
The stationary 24 and movable 22 portions of the toothbrush head 20 contain cleaning elements 30. Cleaning elements 30 are arranged in both portions of head 20 in a known manner. Any suitable form of cleaning elements may be used as the cleaning elements 30 in the broad practice of this invention. The term "cleaning elements" is intended to be used in a generic sense which could include conventional fiber bristles or massage ele- ments or other forms of cleaning elements such as elastomeric fingers or walls arranged in a circular cross- sectional shape or any type of desired shape including straight portions or sinusoidal portions. Where bristles are used, the bristles could be mounted to tuft blocks or sections by extending through suitable openings in the tuft blocks so that the base of the bristles is mounted within or below the tuft block.
It is to be understood that the specific illustra- tion of the cleaning elements is merely for exemplary purposes. The invention can be practiced with various combinations (such as stapled or in-mold technology bristles, etc.) and/or with the same bristle or cleaning element materials (such as nylon bristles, spiral bristles, rubber bristles, etc.) Similarly, while the Figures illustrate the cleaning elements to be generally perpendicular to head 20, some or all of the cleaning elements may be angled at various angles with respect to the surface of head 20. It is thereby possible to select the combination of cleaning element configurations, materials and orientations to achieve specific intended results to deliver additional oral health benefits, like enhanced cleaning, tooth polishing, tooth whitening and/or massaging of the gums. The changes in orientation of movable portion 22 during operation are best understood by comparing Figs . 2 and 3. Movable portion 22 has a flange 26 attached thereto extending from the area of movable portion 22 adjacent the last row of cleaning elements and extending lengthwise toward the drive shaft 18. This flange 26 may be molded as part of movable portion 22 or affixed thereto. The flange 26 terminates at a tab 32 which is preferably aligned approximately perpendicular to the axis of drive shaft 18.
Tab 32 at the end of flange 26 contains a slot 34 for receipt of an offset end 36 or elbow of drive shaft 18 (See Figs. 2 and 4). As drive shaft 18 rotates unidi- rectionally under motor power the offset end 36 of the shaft 18 engages the side edges of slot 34. This causes the flange 26 to rotate counterclockwise around hinge 25 from a position immediately adjacent the back side 27 of the stationary portion 24 of had 20 (Fig. 2) to a position 15-30 degrees (angle D) from that position 6 (Fig 3) . As the drive shaft rotates, typically at several hundred revolutions per minute, movable portion 22 of head 20 rapidly moves about hinge 25 resulting in a vigorous passage of cleaning elements 30 over the user's teeth and gums. This rapid movement helps to clean the user's teeth and stimulate the user's gums.
Figs . 4 and 5 illustrate alternative configurations 34 and 34A for slot 34. Slot 34 of Fig 4 is closed at both ends to contain the offset end 36 of shaft 18 whereas slot 34A shown in Fig 5 allows movement of offset end 36 across the entire width of tab 32 attached to flange 26.
Flange 26 is preferably formed of a moderately flexible material that permits its movement independent of movable portion 22 of the toothbrush head 20. Thus, if the user applies considerable force on the end of movable portion 22, that tends to keep it in the position shown in Fig. 4 while drive shaft 18 is turning, the flexibility of flange 26 will allow the motor to continue turning even though the movable portion 22 of head 20 is not moving or only slightly moving. This flexibility in flange 26, coupled with the slot 34 or 34A in tab 32, prevents stalling of motor 12 in those situations where unusual pressure is exerted on the movable portion 22 of head 20.
Under normal operation tab 32 will be displaced in a plane perpendicular to the axis of the toothbrush, and the drive shaft 18, as the offset end 36 of that shaft rotates with the shaft. The amount of movement of tab 32, and consequent movement of movable portion 22 can be regulated by the distance between the axis of drive shaft 18 and the offset end 36 of that shaft. Fig. 4 illustrates this movement as the drive shaft 18 moves to oppo- site extremes of rotation. The full lines in Fig. 4 represent the placement of tab 32 when movable portion 22 of head 20 is in the position shown in Fig. 2. The phantom lines correspond to its position when movable portion 22 is in the Fig. 3 position.
To improve the cleansing of toothbrush 10 and pre- serve the operating parts 18, 26 and 32 from corrosion and or contamination, a cover 38 is placed over these parts. The cover 38 is preferably flexible or molded to allow free movement of flange 26 under power of drive shaft 18.

Claims

What Is Claimed Is
1. A powered toothbrush comprising a power source and a movable toothbrush head, a rotatable drive shaft operatively connected to the power source, the drive shaft having an offset end engaged in a slot adjacent one end of a flexible flange connected to the movable toothbrush head, whereby the movable toothbrush head reciprocates as the offset end of the drive shaft travels in the slot.
2. The powered toothbrush of claim 1 wherein the movable toothbrush head is hinged to a stationary portion of the toothbrush body.
3. The powered toothbrush of claim 2 wherein the movable portion of the toothbrush head is flexibly con- nected to a stationary portion of the toothbrush head.
4. The powered toothbrush of claim 1 wherein the movable portion of the toothbrush head includes a soft elastomeric coating.
5. The powered toothbrush of claim 1 wherein a cover overlays the drive shaft and flexible flange.
6. The powered toothbrush of claim 5 wherein the cover is made of a flexible material.
7. The powered toothbrush of claim 5 wherein the cover is molded in a shape which permits free movement of the drive shaft and flexible flange therein.
8. The powered toothbrush of claim 2 wherein the movable portion and stationary portion of the toothbrush head contain cleaning elements .
PCT/US2003/028335 2002-09-12 2003-09-09 Powered toothbrush WO2004024024A1 (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
EP03749560A EP1558171A4 (en) 2002-09-12 2003-09-09 Powered toothbrush
AU2003267085A AU2003267085B2 (en) 2002-09-12 2003-09-09 Powered toothbrush
MXPA05002587A MXPA05002587A (en) 2002-09-12 2003-09-09 Powered toothbrush.
CA002498230A CA2498230C (en) 2002-09-12 2003-09-09 Powered toothbrush
BRPI0314248-5A BR0314248B1 (en) 2002-09-12 2003-09-09 powered toothbrush.
CN03821805A CN100594851C (en) 2002-09-12 2003-09-09 Powered toothbrush
US11/079,325 US7007332B2 (en) 2002-09-12 2005-03-14 Powered toothbrush
US11/367,767 US7219384B2 (en) 2002-09-12 2006-03-02 Powered toothbrush

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US41007802P 2002-09-12 2002-09-12
US60/410,078 2002-09-12

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US11/079,325 Continuation US7007332B2 (en) 2002-09-12 2005-03-14 Powered toothbrush

Publications (1)

Publication Number Publication Date
WO2004024024A1 true WO2004024024A1 (en) 2004-03-25

Family

ID=31994055

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2003/028335 WO2004024024A1 (en) 2002-09-12 2003-09-09 Powered toothbrush

Country Status (10)

Country Link
US (2) US7007332B2 (en)
EP (1) EP1558171A4 (en)
KR (1) KR100994309B1 (en)
CN (1) CN100594851C (en)
AU (2) AU2003267085B2 (en)
BR (1) BR0314248B1 (en)
CA (1) CA2498230C (en)
MX (1) MXPA05002587A (en)
RU (2) RU2321374C2 (en)
WO (1) WO2004024024A1 (en)

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KR20050042805A (en) 2005-05-10
CA2498230A1 (en) 2004-03-25
EP1558171A4 (en) 2008-01-02
AU2009202357B2 (en) 2011-06-02
KR100994309B1 (en) 2010-11-12
RU2321374C2 (en) 2008-04-10
BR0314248B1 (en) 2013-04-24
AU2009202357A1 (en) 2009-07-02
CN1728975A (en) 2006-02-01
CA2498230C (en) 2008-12-02
RU2007137465A (en) 2009-04-20
US7219384B2 (en) 2007-05-22
US20060200922A1 (en) 2006-09-14
RU2005110676A (en) 2005-09-20
AU2003267085A1 (en) 2004-04-30
US20050155168A1 (en) 2005-07-21
MXPA05002587A (en) 2005-05-05
RU2440798C2 (en) 2012-01-27
CN100594851C (en) 2010-03-24
US7007332B2 (en) 2006-03-07
EP1558171A1 (en) 2005-08-03
AU2003267085B2 (en) 2009-03-12
BR0314248A (en) 2005-07-05

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