WO2004108108A1

WO2004108108A1 - Cosmetic preparation containing an insoluble colorant that produces fluorescent effects

Info

Publication number: WO2004108108A1
Application number: PCT/EP2004/006055
Authority: WO
Inventors: Klaus-Dieter SCHRÖDER; Werner Brüchert; Willy Weiss
Original assignee: Schwan-Stabilo Cosmetics Gmbh & Co. Kg
Priority date: 2003-06-04
Filing date: 2004-06-04
Publication date: 2004-12-16

Abstract

The invention relates to a preparation, in particular a cosmetic preparation for use in the field of decorative cosmetics for colouring and beautifying the skin, lips, hair, eyelashes and eyebrows. Said preparation contains at least one colorant that is insoluble in the preparation and produces fluorescent effects under UV light.

Description

COSMETIC PREPARATION CONTAINING AN INSOLUBLE COLORANT, THE FLUORESCENT EFFECTS

SHOWS

The invention relates to a preparation, in particular cosmetic preparation for decorative cosmetics for coloring and beautifying the skin, lips, eyelids, hair, eyelashes and eyebrows.

Preparations, in particular cosmetic preparations, come in various forms. The form of loose or pressed powder or cast powder in the form of a stick or in the form of extruded leads, which can be produced from an extrudable mass and have been dried by dehydration, are well suited for the field of decorative cosmetics. Examples of products to be considered according to the invention include: make-up, in particular the so-called party effect make-up, theater make-up, contour pencils, for example lip liner and eyeliner, lip coloring agents such as lip powder, cheek blush, eye shadow, mascara, Hair masks, eyelash coloring agents, semi-permanent tattoos and the like. According to the invention, in addition, in particular those cosmetics are made available that are special under UV light - so-called black light Fluorescence effects result. Preparations for coloring and beautifying skin and hair can also be produced from anhydrous lipid compositions which contain at least one oil which is liquid at room temperature, at least one wax and at least one powdery phase, the powdery phase consisting of at least one pigment which is insoluble in the preparation mentioned.

Preparations for coloring and beautifying skin and hair can also be produced from smooth pastes based on suitable fats, waxes and oils or in the form of W / O or O / W emulsions. Coloring agents are generally used to color the above-mentioned preparations, which are neither soluble in polar nor in non-polar solvents and therefore remain at the place of application and also do not bleed out. A sufficient number of recipe examples can be found in the standard cosmetic works, e.g. by K. Rothemann, "The Great Recipe Book for Skin and Personal Care Products", 1st ed. 1949, GA Nowak, "The Cosmetic Preparations", 3rd ed., 1984 or H. Janistyn, "Handbook of Cosmetics and Fragrances", 3rd volume, 2nd ed., 1973 or from Balsam, Sagarin et al., "Cosmetics, Science and Technology", 2nd ed., 1974 and others. Pigmented preparations of the type mentioned are well known to the person skilled in the art in many variations.

Those skilled in the art generally use the colorants approved by the respective regional or national legislation to color these preparations, which have proven to be suitable in the tests.

When using mixtures of the above-mentioned colorants, the above-mentioned preparations are available in a myriad of colors - starting from white over the entire spectrum of the rainbow up to black. However, these decorative preparations are very disappointing when the wearer, for example during a disco visit or a party, goes into rooms that are predominantly or exclusively illuminated with long-wave UV light - so-called "black light". White clothing lights up here light blue, also the titanium dioxide used in cosmetics shimmers through somewhat. The color impression of decorative cosmetics in such rooms usually remains very inconspicuous. For the production of cosmetics, colorants from the group of lacquered fluoresceins, in particular halogenated fluoresceins - the di-, Tri or Tetrabromofluoresceine - this is how fluorescent colors in the area of red tones are often created. However, the use of varnishes from these soluble dyes involves significant risks: the healthy skin has a pH in the range of 5-6; 5.5 is mentioned as ideal here - sweat also has the same pH range. Tear fluid, on the other hand, has a slightly basic pH in the range of 7.4. Due to the moisture in the skin, it is now possible for the dyes to bleed out of colorants based on lacquered fluoresceins because of the possible different pH values in the product and on the skin, because they are released from the lacquer again. This is particularly fatal because fluoresceins are very substantive and last for a long time - up to several days - on the skin. The traces of this are also made even more visible in UV light. Colored lacquers based on fluoresceins and halogenated fluoresceins thus result in a very interesting effect make-up for use under "black light" - however, because of a possible risk of bleeding, these preparations can have very unsightly side effects which are also difficult to remove from the skin and hair These possible side effects - at the latest after the first bad experience with such a product - become an obstacle to sales. Similar observations were also obtained with the coating of soluble quinoline and anthraquinone dyes. Titanium dioxide alone or optical brighteners, such as disodium distyryldiphenyl disulfonate or the like , essentially only result in light blue fluorescent colors and therefore only little variation in the range from yellow to red fluorescent colors - an overall unsatisfactory condition.

For example, it is known from EP 0 948 314 to use a polymeric colorant for dyeing cosmetics, in which a dicarboxylic acid residue, a diol residue and a coloring monomer are polymerized. Since the coloring component is polymerized into the polymer as a monomer, the selection of dyes is limited.

Furthermore, it is known from US Pat. No. 4,279,662 to use polymeric dye molecules as colorants. The dye molecule should have such a high molecular weight that it cannot be absorbed by the intestine in order to minimize toxicological problems.

Another approach is followed in the invention described in EP-A 0 445 342. Here soluble dyes are absorbed into solid carriers, encapsulated therein, enveloped or trapped. However, this is only possible if the carrier is transparent. However, the colorants known in the prior art are not yet satisfactory, in particular the selection of dyes and carriers is limited.

The task thus arose to provide a preparation, in particular a cosmetic preparation, which is suitable for cosmetic applications, in particular in the field of decorative cosmetics, for coloring and beautifying skin and hair. In particular, preparations such as make-up, e.g. the so-called party effect make-up, theater make-up, contour pencils, e.g. Lip liner and eyeliner, lip dye, lip powder, cheek blush, eyeshadow, mascara, hair mascara, eyelash dye, semi-permanent tattoos and the like are colored by colorants that are insoluble in the preparation so that they provide unusual and interesting effects, e.g. under UV light, so-called black light, intense and interesting colors and fluorescence on the applied areas, e.g. Skin, lips, eyelids, hair, eyelashes and eyebrows show without being affected under in vivo conditions, e.g. can dissolve soluble dyes from the preparations through the moisture of the skin or through sweat or tear fluid and negative optical impressions, which are intensified under black light, are avoided. Another object is to provide preparations which, under normal light conditions, in particular in daylight, using the colorants, if appropriate in addition to the aforementioned colorants, impart more intense color impressions by the fact that colorants which can be excited by means of UV light to fluoresce through daylight are caused by UV light -Share be stimulated to emit fluorescent light. In addition, it was an object of the invention to provide colorants which are suitable not only for lipid-containing preparations but also for gel-like and emulsion-like preparations, but also for powdered preparations and those in anhydrous form.

The above objects are achieved with a preparation, in particular a cosmetic preparation for the field of decorative cosmetics for coloring and beautifying the skin, lips, eyelids, hair, eyelashes and eyebrows, which is characterized in that it contains at least one colorant contains, which is insoluble in polar and non-polar solvents and gives fluorescence effects under UV light. According to the invention, a preparation is thus made available with which cosmetics can be colored without being limited to special dyes. In particular, according to the invention, it becomes possible to achieve special effects with dyes that could not previously be used in cosmetics.

This is made possible by using insoluble or insolubilized coloring agents as coloring agents for the above-mentioned preparations, which, by way of salt formation, by the formation of a neutral salt - or by way of a real covalent bond - from a matrix of a polymer material with at least one functional group in the side chain and a soluble dye having at least one functional group. According to the invention, reaction products of polymers with at least one functional group and a dye with at least one group which is reactive with the functional group of the polymer are thus used as colorants. This makes it possible to provide dyes that cannot otherwise be used for cosmetics, for cosmetic products with special effects.

To achieve the object, either coloring agents can be used, for example by reacting polyesters which are also insoluble in the preparation and which contain at least one primary, secondary or tertiary amino group in the side chain, with anionic dyes or polyesters which contain at least one acid residue the side chain included, are made with cationic dyes. It is also conceivable to react polyacrylates or polymethacrylates or polyurethanes which have at least one of the abovementioned amino groups or at least one acid group in the side chain with dyes with oppositely charged functional groups. It is essential for the use that the colorants to be selected are stable to hydrolysis under in vivo conditions, which can be done by a simple test - namely by storing the colorant in a 1% aqueous solution of an organic hydroxy acid, such as lactic acid or citric acid, buffered to pH 5.5 over 24 hours at 37 ° C - easy to determine. Commercially available are, for example, colorants which consist of a polyester matrix obtained by the reaction of ethylene glycol, cyclohexanedimethanol, terephthalic acid, isophthalic acid and norbornanediamine and dyes which are derived from fluoresceins, quinoline dyes, triphenylmethane dyes and anthraquinone dyes. A suitable polyester matrix is also known to the person skilled in the relevant art as “polyester-3”. Dyes such as Cl-No are mentioned here. 45,380 (tetrabromofluorescein), Cl-No. 45.370: 1 (mixture of dibromo, tribromo and tetrabromofluorescein), Cl-No. 47,000 (quinophthalone, not for use on mucous membranes), Cl-No. 47.005 (quinophthalone disulfonic acid), Cl-No. 42,090 (triphenylmethane dye), Cl-No. 60.730 (anthraquinone dye, not for use on mucous membranes), Cl-No. 61,570 (anthraquinone dye).

Examples of pigments are titanium dioxide, zinc oxide, iron oxides, chromium oxide, chromium oxide hydrate, ultramarine, manganese violet, ferric blue, micaceous mica, mica coated with titanium dioxide, colored mica coated with metal oxides, bismuth oxychloride, bismuth oxychloride coated with metal oxides, platelet-shaped metal powder from Aluminum, brass, bronze, copper, silver or gold, carmine and its various salts with metals, as well as varnishing of organic colorants with aluminum, barium, calcium, strontium or zirconium. This list is only exemplary and not exhaustive. The quantities used depend on the desired effects and are limited by the maximum quantities regulated in the respective national legislation. The proportions of colorant are usually in a range from 0.1 to 50% by weight, preferably in a range from 5 to 35% by weight and particularly preferably in a range from 10 to 25% by weight. These quantities for the colorants are provided with the proviso that the sum of all the ingredients of the aforementioned preparation, in particular cosmetic preparation, is added to 100% by weight.

The average particle size of the aforementioned colorants varies depending on the area of application and is generally in a size range from 0.1 to 10 μm, in particular 0.5 to 10 μm, in the case of the plate-shaped colorants, such as the mica, the bismuth oxychlorides and the metal powders, the average particle size can also be are in a range from 5 to 150 μm. In addition to the colorants, so-called “non-coloring pigments” and other fillers, such as silicon dioxide, talc, kaolin, metal salts of fatty acids, such as Al, Mg, Ca, Zn or Sr stearate, palmitate or myristate, Boron nitride, starch, organically modified starch, nylon powder, polytetrafluoroethylene powder or mixtures thereof.

In order to avoid negative effects of prolonged storage, even during use by the end user - rancidity when using oil binders or emulsion binders or microbial spoilage due to contamination of the surface - the preparations can also be customary and of the respective Approved antioxidants and preservatives can be added to cosmetics legislation.

In addition to the colorants according to the invention, the preparation according to the invention contains the ingredients customarily used for such preparations.

The colorants provided according to the invention can be used for a wide variety of preparations which can be prepared in a manner known per se. For example, powder-like preparations are produced by homogeneously mixing their finely pulverized constituents and, if necessary, grinding them again and filling them loosely into suitable sales containers or using an oil binder or an emulsion binder to bring them into a form suitable for compacting and the resulting mixture under pressure into small sheet metal parts, so-called godets. It is also known to add gypsum to the base, to soak it with water and then to extrude it into mines or to pour it into suitable sales containers and let it harden. Instead of gypsum, an aqueous solution of a cellulose derivative such as e.g. Carboxymethyl cellulose or ethyl cellulose can be used, the product obtained then being subjected to a drying process. Ultimately, it is also known to mix the powder with a volatile silicone oil, e.g. a cyclomethicone, and pour it into suitable moldings, then dry the filled moldings at elevated temperature and then recover the evaporating solvent from a cooled water bath as a cold trap. The above-mentioned methods are sufficiently known from the literature to the person skilled in the relevant art.

If it is a lipid-containing preparation, it contains oils which are approved for the manufacture of cosmetics and which are customary in cosmetics and are volatile and / or non-volatile at room temperature, of vegetable, mineral or synthetic origin - organosilicon compounds such as dimethicone are mentioned here , Phenyltrimethicones, diphenyldimethicones or volatile oils, such as, for example, volatile short-chain dimethicones such as hexamethyldisiloxane, cyclomethicones such as hexamethyltricyclosiloxane, octamethyltetracyclosiloxane, decamethylpentacyclosiloxane, dodedamethylhexa-cyclosaffarine mixture, such as 12-cyclosaffarine mixture, such as in-parosaffarine mixture / cyclosaffarine mixture, such as in-parosaffarine mixture, such as in-parosafarine mixture / cyclosaffarine mixture, such as in-parosafarine mixture / cyclosaffarine mixture, such as in-parosafarine mixture / cyclosaffarine mixture, such as also-in-parosafarine mixture, such as in-parosaffarine / cyclosiloxane-abosoline-abosoloxane-abosoloxane-abosoloxane-abosoloxane-like mixture mentioned oils and the like more. Mineral oil and paraffin oil, as well as vegetable oils such as sesame oil, castor oil, may also be mentioned. Sunflower oil, peanut oil, rapeseed oil, mango seed oil (Magnifera Indica), Meadowfoam Seed Oil (Limnantes Alba), Macadamia Nut Oil (Macadamia Ternifolia Nut Oil), octyldodecanol, isopropyl myristate, isopropyl palmitate, Butyl stearate, isopropyl isostearate, isostearyl isostearate, Caprylic / Capric Triglyceride, Propylene Glycol Dicaprylate / Dicaprate and others.

Vegetable, animal or synthetic waxes may also be mentioned, e.g. Beeswax, Japanese wax (Rhus Succedanea), camauba wax, candelilla wax, sugar cane wax, jojoba oil (Buxus Chinensis) or hydrogenated jojoba oil, silicone waxes. Paraffin waxes, montan waxes, microcrystalline waxes or waxes obtained from the Fischer-Tropsch synthesis or petroleum jelly or mixtures of the waxes mentioned can be used.

The preparation may also contain triglycerides, in particular triglycerides which are solid at room temperature, which have been obtained by hydrogenating vegetable oils, such as e.g. hydrogenated vegetable oils such as Hydrogenated Cottonseed Oil, Hydrogenated Vegetable Oil, Hydrogenated Rapeseed Oil, Hydrogenated Castor Oil, Hydrogenated Coco Glycerides or Mango Seed Oil (Magnifera Indica), Meadowfoam Seed Oil (Limnantes Alba), Shea Butter (Butyrospermum Parkii), Macadamia Nut Oil (Macadamia Temifolia Nut Oil) or their mixtures. In addition to the usual commercial manners, the names familiar to the experts concerned in accordance with the "International Nomenclature of Cosmetic Ingredients" (the so-called "INCI names") are used to identify the raw materials mentioned. The required amount of use results from the suggestions that can be found in the aforementioned specialist literature and are derived from the desired application. In order to avoid the negative effects of prolonged storage, even during use by the end user - rancidity or microbial spoilage - the antioxidants and preservatives that are customary and approved by the relevant cosmetics legislation can also be added to the preparations.

The preparations according to the invention can also be in the form of water-based suspensions with solids without any addition of lipids or in the form of suspensions which additionally contain finely dispersed lipid bodies or in the form of colored emulsions. Emulsions can be produced using oils, fats and waxes known and approved for the production of cosmetics, such as dimethicone, phenyltrimethicone, diphenyldimethicone, silicone wax or volatile cyclomethicone and the like. Animal or vegetable waxes may also be mentioned, such as, for example, beeswax, Japanese wax (Rhus succedanea), camamauba wax, candelilla wax, sugar cane wax, jojoba oil (Buxus Chinensis) or hydrogenated jojoba oil, hydrogenated vegetable oils such as Hydrogenated Cottonseed Oil, Hydrogenated Vegetable Oil, Hydrogenated Rapeseed Oil, Hydrogenated Castor Oil, Hydrogenated Coco Glycerides or Mango Seed Oil (Magnifera Indica), Meadowfoam Seed Oil (Limnantes Alba), Shea Butter (Butyrospermum Parkii), Macadamia Nut Oil (Macadamia Ternifolia Nut Oil) or mixtures thereof. Raw materials derived from petroleum such as volatile isoparaffins, mineral oil, petroleum jelly, paraffin waxes, montan waxes, microcrystalline waxes or waxes obtained from the Fischer-Tropsch synthesis can also be used.

If emulsions are produced instead of water-based suspensions, the preparation can contain water as well as humectants, e.g. Glycerin, diglycerin, triglycerin, propylene glycol, butylene glycols, hexylene glycols, lactic acid or its salts, pyrrolidone carboxylic acid or its salts or mixtures of the substances mentioned and caring additives of medicinal plant extracts, which are available in sufficient numbers commercially. To improve the shelf life and to prevent the migration of water-containing preparations, it is customary to add film-forming substances in the form of solutions or dispersions. The use of shellac or of dispersions of polymers or copolymers of polyurethane, polyacrylate, polymethacrylate, polyesters, polyamides and the like is known. For the preparation of W / O or O / W emulsions, the person skilled in the art generally uses commercially available anionic or nonionic emulsifiers or mixtures thereof or with bases, such as e.g. Triethanolamine, partially neutralized or neutralized fatty acids, e.g. Myristic acid, stearic acid, isostearic acid or so-called dimer and trimer acids, which were obtained by additive conversion from oleic acid. The required quantities can be determined by simple laboratory tests. In principle, emulsifier-free systems, such as so-called "Pickering emulsions" can be produced.

If appropriate, the preparations can also contain vegetable, animal or synthetic thickeners, such as gum tragacanth, xanthan gum, carrageenan, locust bean gum, agar agar, alginates, pectin, gelatin, starch derivatives and modified starches, cellulose derivatives such as carboxymethyl cellulose, methylhydroxyethyl cellulose, methyl hydroxypropyl cellulose, methyl hydroxypropyl cellulose Carboxymethylhydroxyethylcellulose and the like or synthetic thickeners such as acrylate polymers and acrylate copolymers, which are known to the person skilled in the art under the INCI name Carbomer, and also mixtures of the substances mentioned. Preparations for coloring and beautifying skin and hair can also be prepared from anhydrous lipid compositions which contain at least one oil which is liquid at room temperature, at least one wax and at least one powdery phase, the powdery phase comprising at least one pigment which is insoluble in the preparation mentioned, for Achievement of special fluorescence effects an insoluble fluorescent pigment. These preparations are usually prepared by bringing the wax and oil to a temperature above the melting point of the wax, adding the powdery phase and mixing the whole thing, and then using a colloid mill, corundum disc mill or a three-roll mill to process them sufficiently to destroy agglomerates and to homogenize them , The preparation is then extruded and cut into mines, which can be processed into pencils with a sharpenable coating using the methods known from pencil production. Alternatively, the leads can also be inserted into suitable rotating mechanisms. Other suitable methods for further processing consist in heating the preparation above its melting point and pouring it in liquid form directly into sleeves made of a sharpenable material such as wood or plastic. It is also known to pour the heated and liquid preparation into molds, to remove the castings after they have cooled, and then to process them in the manner described above into wood-covered pencils. The castings obtained in this way can also be inserted into suitable turning mechanisms. Ultimately, it is also known to pour the heated and liquid preparation into the holding part of a turning mechanism and then to complete this part with the remaining parts to form a turning mechanism. The casting can also take place directly in an appropriately designed turning mechanism.

Another embodiment of preparations for decorative cosmetics are water-free pastes based on suitable fats, waxes and oils or in the form of W / O or O / W emulsions. Furthermore, preparations in the form of a liquid, a gel or an emulagor-free “Pickering emulsion” are also known for cosmetic applications. Soluble dyes are often used for liquid formulations.

Preparations according to the invention, which are in the form of soft pastes, preferably have a dynamic viscosity in the range from 50 to 3000 mPa.s, the dynamic viscosity using a Bohlin CVOR 200 rotary viscometer at shear rates of 10 ^"4 / s to 10 ³ / s below Using a plate cone or plate / plate measuring device. The measurements take place with increasing and falling shear again. The preparations according to the invention in the form of pastes generally have a viscosity profile in the form of a hysteresis curve, which indicates thixotropic properties of the preparations.

The preparation according to the invention will now be explained in detail with reference to the following examples, which, however, do not conclusively describe it. All quantities are given in percent by weight (% by weight), based on the total weight of the preparation. The internationally known "INCI names" or common names known to the person skilled in the art are used as raw material names. The form of the preparations is in each case indicated.

Example 1 - Effect Make-Up (Loose Powder)

Kaolin 22,500

Calcium carbonate 12,000

Talc 20,000 etherified starch (ANM rice) 14,000

Titanium dioxide 7,000 brown iron oxide 3,500

Sr Laurat 7,700

Mg myristsate 5,000

Polyester-3, Red-28 3,500

Polyester-3, Yellow 10,000

Alumina 3,500

Methyl paraben 0.150

Propylparaben 0.050

Perfume oil 0.100

In a ploughshare mixer with homogenizer, the "white" powder components are mixed with cooling and then the preservatives and the perfume oil are added. Then the iron oxide and the fluorescent colors are added and the mixture is mixed intensively. The mixture is then ground using a ring gear mill or using a vibrating sieve the loose powder is preferably applied to the skin with a tassel receives a light, reddish-brown, very grippy powder with good adhesion to the skin that shows orange to magenta fluorescence in long-wave UV light. By varying the amounts of red iron oxide and titanium dioxide, a lighter or darker shade of the powder can be achieved.

Example 2 - Effect lip powder (loose powder)

Kaolin 33,000

Talc 18,000 etherified starch (ANM rice) 16,300

Titanium dioxide 2,500

D&C Red 7 (C.l.-No. 15,850: 1) 3,300 red iron oxide (C.l.-No. 77,491) 3,500 yellow iron oxide (C.I.- -No. 77,492) 1,500

Sr Laurat 7,700

Mg myristsate 5,000

Polyester-3, Red-28 4,500

Polyester-3, Yellow 10 I 0.500

Methyl paraben 0.150

Propylparaben 0.050

Perfume oil 0.100

Alpha bisabolol 0.100

Na cyclamate 0.050

Alumina 3,500 colloidal silica 0.250

The powder mixture is produced analogously to Example 1. A matt, strong red lip powder with a good grip and good adhesion is obtained, which can be applied to the lips alone or over a lipstick. It shows a clear magenta fluorescence in long-wave UV light. Example 3 - Effect Makeup (Cast)

Mixture from Example 1 94,000

Binder 6,000

Binder:

Carboxymethyl cellulose 2,500

Gum arabic 2,000

Carragheen 2,500

Ethanol (cosmetic denatured) 6,000

Dowicil 200 1,000

Water 86,000

Gum arabic is poured over the ethanol in a suitable container. The water is heated to 80 ° C and poured onto the gum arabic, after which it is allowed to swell. Dowicil 200, the carboxymethyl cellulose and the carrageenan are then added with stirring. Allow to swell, stir the mixture free of kiumpen and then add the binder to the powder mixture and process everything into a thick paste. Possibly. a little water can be added. The mixture is poured into suitable, rustproof sheet metal parts, shaken if necessary and dried to constant weight at 50-60 ° C.

Example 4 - Eyeshadow (Pressed)

Powder mixture:

Kaolin 18,000

Talc 7,000 etherified starch (ANM rice) 14,500

Mica (TiO ₂ coated) 35.600

Sr Laurat 5,500

Mg myristate 3,500

Ultramarine 5,000

Chromium oxide hydrate green 4,500

Polyester-3, Yellow 10,000 Polyester-3, Blue 1 2,000

Disodium distyryldiphenyl disulfonate 0.200

Methyl paraben 0.150

Propylparaben 0.050

Oil Binder:

Isopropyl myristate 20,000

Isoproyllanolate 25,000 acetylated lanolin 15,000

Paraffin oil, viscous 39,400

Methyl paraben 0.150

Propylparaben 0.050

Tocopheryl acetate 0.400

Powder mix 82,000

Oil binder 18,000

The oil binder is made by heating the oil phase slightly and dissolving the preservatives in it. It can be used immediately and is also storable.

In a ploughshare mixer with a homogenizer, the powder components are placed down to the mica and mixed intensively with cooling. About 60% by weight of the oil binder is then sprayed in or added in portions. Then the mica is added and then the remaining oil binder in portions. The batch is sieved using a vibrating sieve and then compacted into small metal parts (Godets) using a suitable press. A pearlescent, blue-green compact powder with good adhesion is obtained, which shows a bright, yellowish fluorescence under long-wave UV light.

Example 5 - Eye Shadow (Extruded Mine)

Talc 18,500

Mica (TiO ₂ coated) 35,000

Pumice powder 18,000 Mg myristate 4,500

Sr Laurat 5,500

Bentonite 1,000

Guar Gum 2,000

PVP highly viscous 1,000

Titanium dioxide 3,000

Ultramarine 3,500

Polyester-3, Blue 1 7,500

Disodium distyryldiphenyl disulfonate 0.200

Methyl paraben 0.150

Dowicil 200 0.150

Guar gum and PVP are dissolved in about 10-15 parts of water while heating. In a mixing plant, e.g. a suitable kneader, the powder components are mixed well - first without adding the mica - then the mica is added. Then the aqueous solution of the binders is added and the mixture is kneaded until a homogeneous, very pasty mass has formed. This is shaped by means of an extruder into leads of, for example, 8 mm or 10 mm in diameter, which are cut to length and preferably dried at a somewhat elevated temperature. The leads can be made of a sharpenable material - e.g. Plastic wrappings or in a known manner from pencil production in wood - are introduced. The leads can also be encased in a hose made of a thermoplastic, shrinkable material in a known manner before further processing. But they can also be used in a turning mechanism. The example above results in a lead that gives a light blue, pearlescent line that glows light blue in long-wave UV light. By simply varying the pigment mixture using the abovementioned luminescent pigments, it is of course also possible to produce other lead colors with different fluorescence in long-wave UV light.

Example 6 - Lipliner (extruded lead)

Talc 21,000

Kaolin 12,000

Pumice powder 18,000

Mg myristate 5,800 Mica 15,000

Sr Laurat 3,800

Mg stearate 4,000

Bentonite 1,000

Carboxymethyl cellulose 2,500

Guar Gum 2,000 yellow iron oxide (C.l.-No. 77,492) 3,000

D&C Red No. 9 (C.l.-No. 15,585: 1) 5,500

Polyester-3, Red 22 6,000

Dowicil 200 0.150

Na cyclamate 0.050

Methyl paraben 0.150

Propylparaben 0.050

The production is carried out analogously to Example 5. The finished mass is extruded into mines with a thickness of approximately 4 mm, which are then further processed in the manner described. A lead with a strong red streak is obtained, which shows a strong yellowish-magenta fluorescence in the long-wave UV light.

Example 7 - Eyeliner (extruded lead)

Talc 21,000

Kaolin 12,000

Pumice powder 18,500

Mg myristate 5,800

Mica 15,000

Sr Laurat 3,800

Calcium sulfate hemihydrate 3,500

Bentonite 1,200

1,2-propylene glycol 1,500

Carboxymethyl cellulose 2,500

Ultramarine 4,000 black iron oxide 1,200

Polyester-3, Blue 1 9,500

Disodium distyryldiphenyl disulfonate 0.150

Dowicil 200 0.150 Methyl paraben 0.150

Propylparaben 0.050

The preparation is carried out analogously to Examples 5 and 6 above. The mass is extruded into leads with a diameter of approximately 4 mm. It should be noted here, however, that work must be continued very quickly after addition, since the preparation hardens quickly and irreversibly due to the use of calcium sulfate hemihydrate. The preparation is expediently prepared in small portions so that it can be extruded within a few minutes. The mines are dried at a somewhat elevated temperature and processed further in the manner previously described. A lead is obtained with a strong dark blue streak which fluoresces blue under long-wave UV light. With this preparation, too, further shades of color can easily be produced by simply varying the pigment mixture.

Example 8 - Effect Mascara (Cake Mascara)

Stearic acid 30,000

Isostearic acid 6,000

Camauba wax 11, 700

Beeswax 13,000

Vaseline, white 8,000

Triethanolamine 13,800

Methyl paraben 0.150

Propylparaben 0.050

Tocopheryl acetate 0.200

Perfume oil 0.100

Talc 5,000

Polyester-3, Red 28 12,000

Example 9 - Effect Mascara, Anhydrous

Beeswax 15,000

Camauba wax 3,500

Cetylstearyl alcohol 3,000

Hydrogenated Castor Oil 3,000

Nylon powder 5,000

Polyester-3, Red 28 20,000

Methyl paraben 0.150

Propylparaben 0.050

Tocopherol Acetate 0.200

C11-12 isoparaffin 50,100

The waxes are melted in a vacuum stirred kettle at about 70 ° C., then the nylon powder and the pigment are added and incorporated homogeneously with stirring. Then the preservatives and the antioxidant are added. The kettle is now vented a little and about half the amount of isoparaffin is sucked in. If the mixture shows a homogeneous structure, the rest of the isoparaffin is sucked in and the mixture is homogenized. One omits Cool with moderate stirring using the anchor stirrer to about 35 ° C, deaerate by applying a vacuum (water jet pump), cool down to room temperature and discharge the mass into the storage container. An intensely margarine-colored mascara mass is obtained which shows an intense red-violet fluorescence under long-wave UV light. It has a viscosity of around 18-20 Pas. The mass is ideally suited to be applied to the eyelash tips using a "conventional" mascara.

Example 10 - Effect Mascara (Emulsion)

Beeswax 8,000

Camauba wax 3,000

Cetylstearyl alcohol 2,500

Microcrystalline wax (mp 74 ° C) 2,500

Isostearic acid 6,500

Stearic acid 3,200

Talc 6,000

Ultramarine 12,000

Iron oxide black 3,000

Polyester-3, Red 28 5,000

Methyl paraben 0.150

Propylparaben 0.050

Germaben-Il 0.100

Propylene glycol 2,500

Tocopherol Acetate 0.100

Triethanolamine 4,400

Perfume oil 0.150

Water, demin. 40.850

In a vacuum stirred kettle, the water is heated to about 70 ° C and the triethanolamine is added. The fat phase is melted separately. The boiler is evacuated a little, the fat phase is sucked in and homogenized briefly, then allowed to cool to 55-60 ° C. Preservatives and antioxidants are used in the Dissolved propylene glycol. Now sprinkle in the pigments and talc and stir in the powder phase.

Example 11 - Effect Hair Mascara (Emulsion)

In the recipe shown in Example 10, the pigments used can be replaced by other luminescent pigments in variations:

Example 11.1

Instead of the pigments specified in Example 10, the following are used:

Polyester-3, Orange 5 20,000

An orange-colored effect hair mascara is obtained which shows a very clear yellow-orange fluorescence under long-wave UV light.

Example 11.2

Instead of the pigments specified in Example 10, the following are used:

Polyester-3, Yellow 11 12,000

Polyester-3, Blue 1 8,000

A green hair-effect mask is obtained which shows a clear yellow-green fluorescence under long-wave UV light. Example 11.3

Instead of the pigments specified in Example 10, the following are used:

Polyester-3, Blue 1 10,000

Ultramarine 4,000

Titanium dioxide 5,000

Disodium distyryldiphenyl disulfonate 1,000

A medium-blue hair effect mascara is obtained which shows a very clear light-blue fluorescence under long-wave UV light.

Example 12 - Cream Eye Shadow

Acetylated lanolin 6,000

Meadowfoam Seed Oil 3,000

Macadamia Nut Oil 2,000

Paraffin oil, low viscosity 23,000

Cyclomethicone D-5 9.250

Microcrystalline wax, mp 74 ° C. 13,500

Tocopheryl acetate 0, 100

Methyl paraben 0.150

Propylparaben 0.050

Mica coated with 28,000 titanium dioxide

Chromium oxide hydrate green 2,000

Ultramarine 2,700

Polyester-3, Blue 1 5,000

Polyester-3, Yellow 10 4,500

Polyester-3, Red 22 0.750

The fat components - except Cyclomethicone D-5 - are melted in a suitable vacuum stirred kettle, then the pigments - apart from the coated mica - are added and the liquid mass is homogenized. After that, the preservatives and the antioxidant are added and it gets short stirred. Then the coated mica and cyclomethicone D-5 are added, the mixture is briefly homogenized again and the mixture is slowly stirred cold. A light, blue-green pearlescent paste is obtained which shows an orange-colored fluorescence under long-wave UV light. The viscosity is 18 Pas.

Example 13 - Theater Makeup

Beeswax, white 17.700

Microcrystalline wax, mp 74 ° C 7,500

Paraffin oil, low viscosity 47,000

Mango Seed Oil 3,600

Hydrogenated Cottonseed Oil 3,000

Red iron oxide 6,000

Polyester-3, Red 28 15,000

Methyl paraben 0.150

Propylparaben 0.050

The preparation is carried out analogously to Example 12. A red paste with a viscosity of 25 Pas is obtained which shows a red-violet fluorescence under long-wave UV light.

The aforementioned emulsion-based products can be easily removed by washing the hair with a shampoo. The mascara preparations can be easily removed from the eyelashes again using a make-up remover. The theatrical make-up can be removed well using a make-up remover based on low-viscosity paraffin oil, petroleum jelly and a proportion of a non-ionic emulsifier, eg cetylstearyl ethoxylate, and washed off without residue by washing with a mild fine soap or washing lotion. Example 14 - Effect Lipliner

Aqua 60.550

Propylene Glycol 8,500

Triethanolamine 1, 400

Isostearic Acid 0.550

Oleyl alcohol 0.750

Magnesium Aluminum Silicate 0.480

Xanthan gum 0.270

Acrylates / C10-30 Alkyl Acrylate Crosspolymer 0.450 Polyester-3, Red 28 26.500

Cellulose 0.250

Methyl paraben 0.150

Propylparaben 0.050

Tocopherol Acetate 0.100

The water, heated to 75 ° C., is placed in a vacuum stirred kettle, in which the xanthan gum and the acrylate polymer are dissolved. Then the magnesium aluminum silicate is added and the mixture is thoroughly mixed using a toothed lock washer (the boiler must be closed). Propylene glycol is placed in a separate vessel and heated to about 55 ° C. Methyl paraben, propyl paraben and tocopherol acetate are dissolved therein. Thereafter, oleyl alcohol, isostearic acid and oleyl alcohol are dissolved in it. This mixture is then added while stirring the amount of water in the kettle, after which the batch is thoroughly mixed again with the toothed lock washer. At about 35 ° C, the colorant is added to the mixture and worked in well using a toothed lock washer. This mixture is then deaerated by applying a vacuum, cooled and filled into storage containers. An intensely magenta lipliner with a dynamic viscosity of 500 to 700 mPas is obtained, which shows an intense red-violet fluorescence under long-wave UV light. Example 15 - Effect tattoo

Aqua 59.150

Sodium Lauroyl Sarcosinate 2.750

Acrylates / octylacrylamides copolymer 2,950

Diglycerin 2,000

Candelilla Gera 0.750

Cera Alba 0.550

Stearic Acid 0.800

Cetearyl Alcohol 0.550

Phenyl trimethicone 0.550

Microcrystalline wax 0.450

Carrageenan 0.220

Hectorite 0.130

Cellulose 0.150

Carbon Black (micronized) 2,200

Ferric Blue (micronized) 1,000

Polyester-3, Orange 5 10,000

Polyester-3, Red 22 15,000

Phenoxyethanol 0.400

Methyl paraben 0.150

Propylparaben 0.050

Tocopherol Acetate 0.100

Fragrance 0.100

The water, heated to 75 ° C., is placed in a vacuum stirred kettle, and the acrylate copolymer is added and incorporated using a toothed lock washer. Then carrageenan, cellulose and hectorite are added and incorporated using a toothed lock washer (with the boiler closed). The fat components are melted in a separate vessel at about 75 ° C and mixed with the sodium lauroyl sarcosinate. The mixture is then added to the water phase and processed into an emulsion using a toothed lock washer (with the boiler closed). Be in a separate jar Diglycerin and phenoxyethanol submitted and dissolved methylparaben, propylparaben and tocopherol acetates with gentle warming. The mixture in the kettle is cooled to about 45 ° C, then the preservation mixture is added. The pigments are then sprinkled in and worked in using a toothed lock washer (with the boiler closed) with intensive stirring. The fragrance is then added, the mixture is cooled to room temperature and discharged into a storage container. A dark, almost black preparation with a dynamic viscosity of about 1,000 to 1,200 mPas is obtained, which shows a yellow-red fluorescence in long-wave UV light. It is particularly suitable for painting water-resistant but washable patterns on the skin.

Example 16 - Effect Lip Blush

Aqua 55,200

PPG-17 / IPDI / DMPA copolymer 22,500

Shellac 5.350

Triethanolamine 1, 450

Butylene Glycol 1, 200

Acrylates / C-10-30 alkyl acrylate copolymer 1, 500

Polyester-3, Orange 5 5,500

Polyester-3, Red 22 3,500

Polyester-3, Red 28 3,000

Tocopherol Acetate 0.100

Phenoxyethanol 0.300

Methyl paraben 0.150

Propylparaben 0.050

Saccharin 0.050

Fragrance 0.150

About half the amount of water, heated to 75 ° C., is placed in a vacuum stirred kettle and the emulsifier is added. The other half of the water is placed in a separate vessel with a toothed ring stirrer, the triethanolamine is placed in it and the shellac is dissolved in it. The pH is adjusted to 7.4. The two water phases are combined and brought to 75 ° C. Now the acrylate copolymer is added, then the colorants are added and the Mixture homogenized by means of a toothed disc under a slight vacuum for about 10 min. The phenoxyethanol is placed in a separate vessel and the parabens, tocopherol acetate, saccharin and the fragrance mixture are dissolved therein. The mixture in the kettle is cooled to about 40 ° C, then the last mixture is added, and the whole is briefly mixed again using a toothed disk. It is then vented by applying a vacuum and the mixture is filled into suitable storage containers at room temperature. A red lip color is obtained which shows a strong yellowish-magenta fluorescence in the long-wave UV light. The mixture has a dynamic viscosity of 300-400 mPas.

According to the example above, other luminous colors such as e.g. Polyester-3, Blue 1 or Polyester-3, Yellow 10, or Polyester-3, Yellow 11 or mixtures thereof, if necessary also using suitable optical brighteners, e.g. Produce disodium distyryldiphenyl disulfonate effective body paintings that show little tendency to migrate on the skin and that show very attractive fluorescence under long-wave UV light. These mixtures are also suitable for application to the hair. The application can be carried out by means of suitable brushes or suitable foam applicators, which are customary in the trade.

Example 17 - Effect Lipstick, Matte, Extruded

Tristearin 34,000

Carnauba 3,350

Beeswax 5,000

Caprylic / Capric Triglyceride 7,500

Behenyl Alcohol 8,000

Nylon powder 4,500

Polyester-3, Red 28 20,000

Polyester-3, Yellow 10 8,500

Iran Oxides, Yellow C.l.-No. 77,492 3,500

Isopropyl myristate 3,000

Stearalkonium Hectorite 2,000

Methyl paraben 0.150

Propylparaben 0.050

Tocopherol Acetate 0.200

Fragrance 0.250 The waxes and oils are heated to 80 ° C in a suitable vacuum kettle, then the stearalkonium hectorite is added and the mixture is thoroughly mixed with a ring gear. The pigments and nylon powder are then added and the mixture is homogenized intensively. The preservatives, the antioxidant and the fragrance mixture are now added, the mixture is briefly homogenized again and the batch is deaerated.

The mixture is placed on a three-roll mill and passed twice. The mixture is then pressed and extruded into a strand with a diameter of approximately 8-10 mm and cut to length. The mines obtained are glued into wooden boards in a known manner and processed into sharpenable pencils. An intensely red lipstick with bright red fluorescence in long-wave UV light is obtained.

Example 18 - Effect eyeliner, extruded

Stearic Acid 18,000

Castor Oil 9,500

Hydrogenated Castor Oil 5,500

Hydrogenated Vegetable Oil 8,000

Caprylic / Capric Triglyceride 6,000

Cetyl palmitate 4,500

Rhus succedanea 6,000

Behenyl alcohol 2,500

Microcrystalline Wax (mp 74 ° C) 2,500

Tale 4,500

Polyester-3, Blue 1 25,000

Black Iran Oxide 2,350

Disodium Distyryldiphenyl Disulfonate 0.350

Ultramarine 5,000

Methyl paraben 0.150

Propylparaben 0.050

Tocopherol Acetate 0.100

Processing is carried out analogously to Example 17, but the preparation is extruded into mines with a diameter of approximately 4 mm, which are then made into wood-cased in a known manner Pins processed further. You get a mine with blue color, the one under long wave

UV light gives a light blue fluorescent smear.

Example 19 - Effect Lipliner, Cast

Isopropyl myristate 19,000

Castor Oil 7,500

Hydrogenated Castor Oil 5,500

Hydrogenated Vegetable Oil 8,000

Carnauba 3,500

Microcrystalline Wax (mp 74 ° C) 9,000

Acetylated lanolin. 2,500

Isopropyl lanolate 3,700

Nylon powder 3,500

Polyester-3, Red 28 22,000

Polyester-3, Yellow 10 12,000

Red Iron Oxide 3,500

Methyl paraben 0.150

Propylparaben 0.050

Tocopherol Acetate 0.100

The lipid components are heated and melted to 80 ° C. in a suitable vacuum kettle with a stirrer and gear ring mixer, then the powder components are added and the mixture is homogenized. Finally the preservatives and the antioxidant are added. The preparation can now be poured directly into sleeves made of a sharpenable material and processed into effect lip liners with a lead with a diameter of approximately 4 mm. Alternatively, as already described above, the preparation can also be poured directly into the holding part of a suitable rotating mechanism. A pen with an intensely red lead is obtained, the smear of which shows a bright red fluorescence in the long-wave UV light. Example 20 - Effect eyeshadow pencil, cast

3,000 polybutene

Mineral Oil 2,500

Microcrystalline Wax, mp 74 ° C 4,500

Camauba 3,000

Beeswax 3,500

Hydrogentated Cottonssed Oil 4,000

Titanated Mica 25,000

Chromium Hydroxide Green 4,500

Polyester-3, Blue 1 10,000

Polyester-3, Yellow 10 4,500 Disodium Distyryldiphenyl Disulfonate 0.200

Tocopherol Acetate 0, 100

Methyl paraben 0.150

Propylparaben 0.050

Cyclomethicone 25,000

C-11 / C-12 isoparaffins 10,000

The lipid components, with the exception of the volatile oils, are heated and melted to 80 ° C. in a suitable stirred tank with a stirrer and gear mixer, then the powder components are added and the mixture is homogenized, after which the preservatives and the antioxidant are added. The mixture is then deaerated by applying a vacuum, then the volatile oils are added and the mixture is thoroughly mixed again. The preparation is then poured into sleeves made of a sharpenable material with an inner diameter of approximately 8-10 mm using a suitable system processed into eyeshadow pencils. Alternatively, the preparation can of course also be poured into flat pans that have to be inserted in airtight cassettes. A blue-green effect eyeshadow is obtained which shows a bright, blue-green fluorescence under long-wave UV light. Example 21 - Effect Body Painting, Cast (Body Painting Pen)

Castor Oil 5,000

Hydrogenated Castor Oil 6,000

Beeswax 4,200

Carnauba 4,000

Microcrystalline Wax, mp 85 ° C 8,500

Acetylated lanolin 4,500

Isopropyl lanolate 3,000

Rhus succedanea 2,500

Hydrogenated Rapeseed Oil 7,500

Titanated Mica 21, 500

Yellow iron oxide 4,200

Red Iron Oxide 2,800

Polyester-3, Red 22 13,500

Polyester-3, Yellow 10 12,500

Tocopherol Acetate 0.100

Methyl paraben 0.150

Propylparaben 0.050

The preparation is carried out in a known manner by melting the lipid components at about 80 ° C. in a suitable vacuum stirred tank with a stirrer and gear rim mixer and then adding and homogenizing the powder components with the exception of the coated mica. The preservatives, the antioxidant and the coated mica are then added, the batch mixed thoroughly with the stirrer alone and vented by applying a vacuum. However, the preparation is not poured into sleeves made of a sharpenable material, which is also possible in principle, but in rotating mechanisms with a rotating spindle, as are known in principle from deodorant sticks. A bright orange lead is obtained, which fluoresces intensely red-orange in the long-wave UV light.

Example 22 - Effect Hair Coloring Pencil, Cast

Tristearin 18,000

Hydroxystearic Acid 5,800

Carnauba 3,350 Beeswax 3,500

Caprylic / Capric Triglyceride 7,500

Hydrogenated Castor Oil 6,000

Castor Oil 5,500

Dipropylene Glycol 1, 500

Behenyl Alcohol 6,000

Microcrystalline Wax mp 84 ° C 3,500

Ceteareth-20 2,500

Nylon powder 4,500

Titanium Dioxide 8,500

Ultramarine 3,500

Polyester-3, Blue 1 19,500

Disodium Distyryldiphenyl Disulfonate 0.200

Methyl paraben 0.150

Propylparaben 0.050

Tocopherol Acetate 0.200

Menthyl lactate 0.250

The preparation is carried out in the manner described above, essentially analogously to Example 21. However, the preparation is not poured into sleeves made of a sharpenable material, which is also possible in principle, but in rotating mechanisms with a rotating spindle, as are known in principle from deodorant sticks , A medium blue lead is obtained, which fluoresces intensely light blue in the long-wave UV light.

By varying the colorants in the recipes shown above and only as examples, it is of course also possible to achieve other lead colors by simply trying.

Claims

Expectations

1. Preparation, in particular cosmetic preparation for the field of decorative cosmetics for coloring and beautifying the skin, lips, eyelids, hair, eyelashes and eyebrows, characterized in that it contains at least one colorant which is present in polar and non-polar solvents is insoluble and produces fluorescence effects under UV light.

2. Preparation according to claim 1, characterized in that this preparation is make-up, in particular party effect make-up, theater make-up, contour pencils such as e.g. Lipliner and eyeliner, lip coloring agents such as lip powder and lipstick, cheek blush, eye shadow, mascara or hair mascara, eyelash coloring agent, semi-permanent tattoos and the like.

3. Preparation according to claim 1 or 2, characterized in that the

Colorants from a matrix of a polymer material with at least one functional group in the side chain and at least one soluble dye with at least one functional group were obtained by salt formation by the formation of a neutral salt.

4. Preparation according to claim 1 or 2, characterized in that the colorant was obtained from a matrix of a polymer material with at least one functional group in the side chain and at least one soluble dye with at least one functional group by means of a real covalent bond.

5. Preparation according to claim 1 or 2, characterized in that the matrix is selected from a polymer material among polyesters, polyacrylates, polymethacrylates or polyurethanes with at least one primary, secondary or tertiary amino group in the side chain or mixtures thereof and at least one anionic dye ,

6. Preparation according to claim 1 or 2, characterized in that the matrix is selected from a polymer material among polyesters, polyacrylates, polymethacrylates or polyurethanes with at least one acid residue in the Side chain or mixtures thereof and has been reacted with at least one cationic dye.

7. Preparation according to one of the preceding claims, characterized in that the colorant is the reaction product of an insoluble polymer material with at least one functional group in the side chain with a soluble dye with at least one functional group.

8. Preparation according to one of the preceding claims, characterized in that the colorant is the reaction product of an insoluble polyester which has at least one primary, secondary or tertiary amino group in the side chain, with an anionic dye or of an insoluble polyester which has at least one acid residue in the side chain has, with cationic dyes.

9. Preparation according to one of claims 3 to 5, characterized in that the matrix of a polymer material by the reaction of ethylene glycol, cyclohexanedimethanol, terephthalic acid, isophthalic acid and norbornane diamine was obtained and reacted with at least one anionic dye.

10. Preparation according to claim 12, characterized in that the anionic dye is C.l.-No. 42.090, C.l.-No. 45.370: 1, C.l.-No. 45.380, C.l.-No. 47,000, C.l.-No. 47.005, C.l.-No. 60.730, C.l.-No. 61,570 or mixtures thereof.

11. Preparation according to one of the preceding claims, characterized in that the colorant is stable to hydrolysis when stored for 24 hours and at 37 ° C in a 1% aqueous solution of an organic hydroxy acid, such as lactic acid or citric acid, and does not bleed out.

12. Preparation according to one of the preceding claims, characterized in that it additionally optionally contains at least one pigment such as titanium dioxide, zinc oxide, iron oxides, chromium oxide, chromium oxide hydrate, ultramarine, manganese violet, ferric blue (Berlin blue), mica, mica coated with titanium dioxide, colored mica coated with metal oxides, bismuth oxychloride, bismuth oxychloride coated with metal oxides, platelet-shaped metal powder of aluminum, brass, bronze, copper, silver or gold, carmine and its various salts with metals, lacquers of organic dyes Contains aluminum, barium, calcium strontium or zirconium or mixtures of the pigments mentioned.

13. Preparation according to one of the preceding claims, characterized in that the quantitative proportions of the colorants in a range from 0.1 to 50 wt .-%, preferably in a range from 5 to 35 wt .-%, very particularly preferably in a range from 10 to 25% by weight with the proviso that the sum of all ingredients of the preparation is 100% by weight.

14. Preparation according to one of the preceding claims, characterized in that it may also contain fillers such as silicon dioxide, talc, kaolin, metal salts of fatty acids such as Al, Mg, Ca, Zn or Sr stearate, palmitate or myristate , Boron nitride, starch, organically modified starch, nylon powder, polytetrafluoroethylene powder or mixtures thereof.

15. Preparation according to one of the preceding claims, characterized in that it is a loose powder.

16. Preparation according to one of the preceding claims, characterized in that it is a pressed (compacted) powder.

17. Preparation according to one of the preceding claims, characterized in that the pressed powder can be produced in the form of an extruded lead and then dried by dehydration.

18. Preparation according to one of the preceding claims, characterized in that it is a cast powder.

19. Preparation according to claim 18, characterized in that it is a cast powder in stick form.

20. Preparation according to claims 18 or 19, characterized in that the cast powder in stick form consists of a heat-softening mass which is hot pourable and solidifies again on cooling.

21. Preparation according to claim 17, 18 or 20, characterized in that it is preferably mines with a diameter between 4 and 10 mm.

22. Preparation according to one of the preceding claims, characterized in that it contains an oil binder as a binder.

23. Preparation according to claim 22, characterized in that it as

Binder contains an emulsion binder.

24. Preparation according to claim 23, characterized in that it

Contains calcium sulfate hemihydrate as a binder.

25. Preparation according to claim 23, characterized in that it contains guar gum, carrageenan, carboxymethyl cellulose, gum arabic or mixtures thereof as binders.

26. Preparation according to one of the preceding claims, characterized in that it is present as a water-based liquid or water-based gel.

27. Preparation according to one of the preceding claims, characterized in that it is in the form of an emulsion, in particular a W / O or O / W emulsion.

28. Preparation according to claim 27, characterized in that it is in the form of an emulator-free Pickering emulsion.

29. Preparation according to one of the preceding claims, characterized in that it optionally also contains at least one vegetable, animal or synthetic thickener

30. Preparation according to one of the preceding claims, characterized in that the thickening agent is gum tragacanth, xanthan gum, carrageenan, St. John's wort flour, agar-agar, alginate, pectin, gelatin, starch derivatives, carboxymethyl cellulose, methyhydroxyethyl cellulose, methyl hydroxypropyl cellulose, carboxymethyl hydroxyethyl cellulose, carboxymethyl or mixtures of the substances mentioned.

31. Preparation according to one of the preceding claims, characterized in that it optionally contains oils, fats and waxes approved for the production of cosmetics.

32. Preparation according to one of the preceding claims, characterized in that the oils and fats are selected from hydrogenated vegetable oils, hydrogenated cottonseed oil, hydrogenated vegetable oil, hydrogenated rapeseed oil, hydrogenated castor oil, hydrogenated coco glycerides, mango seed oil (Magnifera Indica) , Meadowfoam Seed Oil (Limnantes Alba), Shea Butter (Butyrospermum Parkii), Macadamia Nut Oil (Macadamia Temifolia Nut Oil), Dimethicone, Phenyltrimethicone, Diphenyldimethicone, volatile Cyclomethicone or from mixtures of these substances.

33. Preparation according to one of the preceding claims, characterized in that the waxes contained in the preparation are preferably selected from beeswax, Japanese wax, camauba wax, candelilla wax, sugar cane wax, jojoba oil, hydrogenated jojoba oil, silicone wax, paraffin wax, montan wax, microcrystalline wax, waxes from the Fischer-Tropsch synthesis or mixtures thereof.

34. Preparation according to one of the preceding claims, characterized in that it may also contain fillers such as silicon dioxide, talc, kaolin, metal salts of fatty acids such as Al, Mg, Ca, Zn or Sr stearate, palmitate or myristate , Boron nitride, starch, organically modified starch, nylon powder, polytetrafluoroethylene powder or mixtures thereof.

35. Preparation according to one of the preceding claims, characterized in that it may also contain humectants such as glycerol, diglycerol, triglycerol, propylene glycol, butylene glycols, hexylene glycols, lactic acid or its salts, pyrrolidone carboxylic acid or its salts or mixtures of the substances mentioned.