WO2006003981A1 - Oil-in-water emulsion and process for production of food with the same - Google Patents

Oil-in-water emulsion and process for production of food with the same Download PDF

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Publication number
WO2006003981A1
WO2006003981A1 PCT/JP2005/012051 JP2005012051W WO2006003981A1 WO 2006003981 A1 WO2006003981 A1 WO 2006003981A1 JP 2005012051 W JP2005012051 W JP 2005012051W WO 2006003981 A1 WO2006003981 A1 WO 2006003981A1
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WO
WIPO (PCT)
Prior art keywords
oil
water emulsion
water
fat
foamed
Prior art date
Application number
PCT/JP2005/012051
Other languages
French (fr)
Japanese (ja)
Inventor
Yasue Nagao
Eriko Harada
Ken Kawashima
Original Assignee
Fuji Oil Company, Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fuji Oil Company, Limited filed Critical Fuji Oil Company, Limited
Priority to JP2006528795A priority Critical patent/JPWO2006003981A1/en
Publication of WO2006003981A1 publication Critical patent/WO2006003981A1/en

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Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G3/00Sweetmeats; Confectionery; Marzipan; Coated or filled products
    • A23G3/34Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
    • A23G3/50Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by shape, structure or physical form, e.g. products with supported structure
    • A23G3/52Aerated, foamed, cellular or porous products
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D7/00Edible oil or fat compositions containing an aqueous phase, e.g. margarines
    • A23D7/005Edible oil or fat compositions containing an aqueous phase, e.g. margarines characterised by ingredients other than fatty acid triglycerides
    • A23D7/0053Compositions other than spreads
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D7/00Edible oil or fat compositions containing an aqueous phase, e.g. margarines
    • A23D7/02Edible oil or fat compositions containing an aqueous phase, e.g. margarines characterised by the production or working-up
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G1/00Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/30Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/50Cocoa products, e.g. chocolate; Substitutes therefor characterised by shape, structure or physical form, e.g. products with an inedible support
    • A23G1/52Aerated, foamed, cellular or porous products, e.g. gas expanded

Definitions

  • the present invention relates to an oil-in-water emulsion, and more particularly to an oil-in-water emulsion characterized by not containing an emulsifier.
  • Foaming tarites such as whipped cream used for topping ice cream and cakes, or oil-in-water emulsions such as coffee cream use multiple emulsifiers and inorganic compounds as stabilizers It is common to do.
  • vegetable cream one of the whipped creams, is made up of water, vegetable oils and fats, non-fat milk solids, various emulsifiers, and inorganic compounds that are stabilizers, pre-emulsified, homogenized, sterilized and cooled. Manufactured by aging.
  • phosphoric acid hexametaphosphoric acid, dibasic phosphoric acid, etc.
  • alkanoic acid metal salt of citrate is generally used in an amount of about 0.1 to 1% by weight.
  • emulsifiers so-called natural emulsifiers such as soybean lecithin and egg yolk lecithin and so-called synthetic emulsifiers such as sucrose fatty acid ester, glycerin fatty acid ester, sorbitan fatty acid ester, polyglycerin fatty acid ester and monoglyceride (hereinafter referred to as these emulsifiers).
  • Synthetic emulsifiers are used in combination, and the total amount used is approximately 1 to 5% by weight. Thus, the use of inorganic compounds and synthetic emulsifiers is considered indispensable for obtaining good cream properties (overrun, workability, texture, etc.).
  • Non-Patent Document 1 Non-Patent Document 2
  • Non-Patent Document 1 Toru Hidaka, “Emulsifier for Food” (Yuki Shobo) (pp. 127-147)
  • Non-Patent Document 2 Toru Hidaka, “Common sense of food additives” (Yuki Shobo) (No. 41- (Pp. 43, 121-128)
  • Patent Document 1 Japanese Patent Laid-Open No. 10-215783 (Pages 1 to 4)
  • An object of the present invention is to provide an oil-in-water emulsion that does not contain an emulsifier and has basic physical properties as a cream such as flavored balun. is there.
  • the present inventors have used an emulsion having a high non-fat solid content compared to a normal oil-in-water emulsion, so that no emulsifier is added.
  • the present invention has been completed by finding that it is an oil-in-water emulsion having basic physical properties as a cream.
  • Oil content is 10-50% by weight, moisture is 10-50% %, Non-fat solid content is 10 to 70% by weight, the oil-in-water emulsion according to (1), (3) non-fat milk solid content or non-fat cacao to the total non-fat solid content (1)
  • the oil-in-water emulsion according to (1) having a solid content of 5 to 50% by weight.
  • the fat in the oil contains hard butter or SUS (S: saturated fatty acid, U: trans isomer) (1)
  • SUS saturated fatty acid, U: trans isomer
  • a method for producing a foamed oil-in-water emulsion characterized by foaming (6)
  • the oil-in-water emulsion according to (1) and an aqueous composition are mixed and foamed.
  • the oil-in-water emulsion according to (1) and the aqueous composition are mixed and foamed without increasing the emulsifier.
  • This is a method for producing a foamed oil-in-water emulsion.
  • the invention's effect is a foamed oil-in-water emulsion.
  • the present invention it is possible to produce a good oil-in-water emulsion without blending an emulsifier, and the present invention can prevent an unfavorable flavor from being added by using an additive.
  • the emulsifier of the present invention is blended with a conventional oil-in-water emulsion using an emulsifier, and the oil-in-water emulsion is partially added and used, the addition destination is powerful. Without increasing the emulsifier, it is possible to impart milky and richness and shape retention.
  • the oil-in-water emulsion referred to in the present invention has an oil content of 10 to 50% by weight, a water content of 10 to 50% by weight, a non-fat solid content of 10 to 70% by weight, and has a foaming property. It is an oil-in-water type emulsion characterized by having no milky formula added.
  • the oil content of the oil-in-water emulsion is less than 10%, the foamability of the oil-in-water emulsion decreases, and if it exceeds 50%, the oil-in-water emulsion becomes unstable and stable production is achieved. Cause trouble.
  • it is 15% or more and 40% or less.
  • the oil and fat of the oil-in-water emulsion of the present invention is not particularly limited, but in order to further impart a foaming function, the oil and fat in the oil component is hard butter, particularly SUS (S: saturated fat It is preferable to include tridallyceralide represented by the following formula: acid, U: not including trans form! / (Unsaturated fatty acid).
  • SUS saturated fat
  • a suitable content of the above SUS is preferable because it improves the meltability and the functions imparted to heat-resistant shape retention and demulsification as the amount increases.
  • the oil content is desirably 45% or more, more preferably 70% or more.
  • Examples of the fats and oils rich in triglycerides represented by SUS include cacao butter, shea fat, mango kernel oil, monkey fat, lippe fat, palm oil, and fractionated oils thereof. One type or two or more types can be used. It is also possible to produce and use oils rich in triglycerides represented by SUS by selectively transesterifying the 1st and 3rd positions of glycerides and, if necessary, fractionating the middle melting point fraction. it can.
  • the water content of the oil-in-water emulsion of the present invention is less than 10%, the oil-in-water emulsion thickens and hinders stable production. If it exceeds 50%, the emulsification of the oil-in-water emulsion becomes unstable. It will hinder stable production. In addition, workability after whipping, heat-resistant shape retention, and water separation resistance are reduced. It can be optimally used in the range of 10 to 50%.
  • the origin of water contained in the oil-in-water emulsion may be water derived from dairy products containing milk solids that are not particularly specified, or a solvent when milk solids are dissolved or dispersed in water. Or the water
  • water-containing foods such as fruit juice, jam, various fruits, strawberries, cheeses, nuts, natural honey, coffee and tea can be used in combination of one or more.
  • the oil-in-water emulsion has a non-fat solid content of 10% or less, it exhibits an effect of imparting a milky taste and a rich taste to the foamable cream, and when it is 70% by weight or more, The viscosity of the oil-type emulsion will increase, hindering stable production.
  • the non-fat solid content of the oil-in-water emulsion can be used in the range of 20 to 60%.
  • non-fat solids examples include non-fat milk solids, non-fat cocoa solids, and saccharides.
  • the non-fat milk solid content gives a milky taste and richness to the foaming cream, and the non-fat cocoa solid content gives a chocolate flavor and a rich taste.
  • the content of the non-fat milk solids and the non-fat cocoa solids should occupy 5 to 50% by weight in the total non-fat solids.
  • the non-fat milk solids include fresh cream, milk, concentrated milk, skim milk, sweetened condensed milk, sugar-free condensed milk, whole milk powder, skim milk powder, butter milk, butter milk powder, whey, whey powder, casein, casein
  • Non-fat solids derived from milk contained in sodium, lactalbumin, etc. can be exemplified, and can be used alone or in combination of two or more.
  • the non-fat cocoa solid content is a part excluding cocoa butter from the solid content derived from cocoa beans, and as the non-fat cocoa content source, cocoa mass, cocoa powder, various chocolates using these as raw materials, and others
  • the processed product can be exemplified.
  • the saccharide is not particularly limited, and examples thereof include glucose, fructose, sucrose, maltose, enzymatic saccharified starch syrup, lactose, reduced starch saccharified product, isomerized liquid sugar, sucrose-conjugated starch syrup, oligosaccharide, and reduced sugar.
  • Sugar Polydextrose Sorbitol, Reduced Lactose, Trehalose, Xylose, Xylitol, Maltitol, Erythritol, Mannitol, Frata Oligosaccharide, Soy Oligosaccharide, Galato Oligosaccharide, Whey Oligosaccharide, Raffinose, Lactulose, Palatinose Oligosaccharide, Stethosaccharide Examples include sugars such as beer, aspartame, sugar alcohol and the like. These saccharides can be used alone or in combination of two or more.
  • the first method for preparing the oil-in-water emulsion of the present invention is the use of a powder of chocolate or chocolate-like food or the like according to a method according to the method for producing chocolate. There is a method in which those melted doughs are obtained and then emulsified by adding a water-based composition containing the above-mentioned non-fat solids and fats and oils.
  • conching can be performed after refining with a roll that is not particularly limited unless it significantly deviates from the normal chocolate production method.
  • the non-fat solids and the respective oils and fats are mixed with the aqueous composition and then heated to 30 to 70 ° C, or one or both of them is 30 to 70.
  • the emulsification may be carried out by homogenization (5 to 150 kgZcm2).
  • the emulsified oil-in-water emulsion is produced by cooling. It may be sterilized or sterilized before and after the emulsification process or homogenization process! /, But in the conventional cream production line that performs UHT treatment, the viscosity range that can be produced may be a factor that increases, so pasteurization can be performed. Recommended.
  • the highly fat-free solid emulsion obtained as described above can be suitably used for adding an aqueous composition, especially for modifying a foamable oil composition (foaming cream).
  • aqueous composition of the place is not limited to foaming oils and fats such as various commercial products of raw talyam and vegetable tarim, but has foaming power such as milk, concentrated milk, and cheeses.
  • Ozw-type emulsions such as soy milk, or even non-emulsified jams, various fruits, strawberries, natural honey, water-containing foods such as coffee and tea, and water
  • Two or more kinds can be used in combination, and there is no particular limitation, and the production method can employ a well-known and commonly used technique or a known technique.
  • the fats and oils in the oils are hard to impart good meltability, heat-resistant shape retention and water separation resistance. It is more preferable that the oil or fat in the oil contains triglyceride represented by SUS in order to impart notably a foaming function to be notter.
  • the content of the oil-in-water emulsion of the present invention in the foamed cream is suitably 5% by weight or more, more preferably 10 to 50% by weight. If the content is small, the foamable cream is modified. The effect is poor.
  • the timing of adding the oil-in-water emulsion to the foaming cream may be before, during, or after whipping, but it should be held before or during whipping rather than after whipping.
  • oil-in-water emulsion can be foamed alone.
  • Whole fat milk powder 16.0 parts, sugar 39.0 parts, vegetable oil and fat is a type that contains a lot of SUS A temper type hard butter (product name “Melano NEWSS-7” manufactured by Fuji Oil Co., Ltd., SUS content of about 81%) 45.0 parts was blended, and a chocolate-like food was produced according to a standard method of chocolate production.
  • SUS A temper type hard butter product name “Melano NEWSS-7” manufactured by Fuji Oil Co., Ltd., SUS content of about 81%) 45.0 parts was blended, and a chocolate-like food was produced according to a standard method of chocolate production.
  • the mixture was stirred while stirring at 3000 rpm with a homomixer (“ ⁇ . ⁇ . Homodisper” Special Machine Industries Co., Ltd.), held at 65 ° C for 30 minutes, cooled and oiled 38.4 wt. %, Non-fat solid content 37.6 wt% (non-fat milk solid was 8.3%), and water content 24.0 wt% was obtained.
  • a homomixer ⁇ . ⁇ . Homodisper” Special Machine Industries Co., Ltd.
  • oil-in-water emulsion thus obtained and water are mixed in a ratio of 70 parts: 30 parts, and foamed using a vertical mixer (“Hobart Mixer N-50” manufactured by Hobart Japan KK).
  • the workability (quality) of the product hereinafter referred to as oil-in-water emulsified foam was evaluated.
  • This mixture was prepared in the same manner as in Example 1 except that the oil content was 53.2% by weight, non-fat solid content was 22.8% by weight (non-fat milk solid was 5.3%), and the water content was 24.0% by weight.
  • An oil-type emulsion was obtained.
  • the oil-in-water emulsion thus obtained and the workability of the product foamed by the same blending method as in Example 1 according to the blending in Table 1 were evaluated.
  • Example 2 This mixture was mixed in the same manner as in Example 1 in accordance with the composition shown in Table 1, and the oil content was 53.2% by weight.
  • the oil-in-water emulsion thus obtained and the workability of the product foamed by the same blending method as in Example 1 according to the blending of Table 1 were evaluated.
  • Example 2 The oil-in-water emulsion obtained in Example 1 and a commercially available foaming cream (product name “Light Topping SV”, manufactured by Fuji Oil Co., Ltd.) are mixed in a ratio of 20 parts: 80 parts, and a vertical mixer Was used to foam.
  • a commercially available foaming cream product name “Light Topping SV”, manufactured by Fuji Oil Co., Ltd.
  • Oil-in-water emulsion 70 70 70 20 Water 30 30 30 30 30
  • Emulsification is stable, whipping work can be performed well, and the mouthfeel is light and the mouth melts well.
  • Emulsification is slightly unstable, work of whipping etc. is possible, and the product value is at a certain level although it has a texture and a feeling of stickiness.
  • Example 1 became a very light and fresh, foamy food with good meltability in the mouth, and a new oil-in-water emulsification differing in texture and meltability from the conventional foaming cream. It was a foam.
  • the oil-in-water emulsion of Comparative Example 2 in which an emulsifier is added to Comparative Example 1 is different from that of Comparative Example 1 in that the emulsification is stable, and an emulsifier is added and mixed with water.
  • the foamed foam was able to foam well, and the texture was a cream that existed as a conventional oil-in-water emulsion.
  • Comparative Example 1 that deviated from the range of fats and oils, moisture, and total non-fat solids, which was claimed in the present application, could not be emulsified without using an emulsifier.
  • foaming creams have a function-oriented type as used in Example 2, that is, milk taste.Some taste is slightly inferior, but workability is good. It is generally well known that, it is generally well known, but yes, by adding a part of the oil-in-water emulsion obtained in Example 1 to the Tsutatsu selling foaming cream, the milky taste, It is possible to impart richness and improve shape retention by a simple method.
  • Example 2 The oil-in-water emulsion obtained in Example 1 and strawberry puree (hawk food) were mixed at a ratio of 60 parts: 40 parts, and foamed using a vertical mixer.
  • temper type node butter manufactured by Fuji Oil Co., Ltd., SUS content of about 81%) 40.0 parts are mixed.
  • the above mixture was stirred at 3000 rpm with a homomixer while warming, held at 65 ° C for 30 minutes, and then cooled to 43.9% oil content, 36.1% non-fat solid content (non-fat milk solid 11 1%) and an oil-in-water emulsion having a water content of 20.0% by weight was obtained.
  • the oil-in-water emulsion thus obtained and water were mixed in a ratio of 70 parts: 30 parts, and the workability of the oil-in-water emulsion foam was evaluated using a vertical mixer. .
  • Example 4 According to the formulation in Table 2, among the blends of Example 4, SUS as a vegetable fat is relatively high, but the melting point is slightly lower than that used in Example 4 An oil-in-water emulsion was obtained by the same formulation and manufacturing method except that the product name “Sulfurate P110N” (Fuji Oil Co., Ltd., SUS content of about 55%) was used. The workability and quality of the oil-in-water emulsified foamed product were evaluated for the oil-in-water emulsion by the same blending method as in Example 4.
  • the palm oil middle melting point part It is oil-in-water with the same blending method except that it is partially cured and part of the sus part of u is replaced with a trans form or saturated fatty acid (product name "Melva 31" manufactured by Fuji Oil Co., Ltd.)
  • the emulsion was obtained, and the oil-in-water emulsion thus obtained was evaluated for workability and quality of the oil-in-water emulsion by the same formulation and production method as in Example 4.
  • an oil-in-water emulsion was obtained by the same formulation method except that soybean white squeezed oil having a low melting point as vegetable oil was used in the formulation of Example 4 and containing almost no SUS.
  • the oil-in-water emulsion thus obtained was evaluated for the quality of the workability of the oil-in-water emulsified foam by the same blending method as in Example 4.
  • Example 4 using vegetable oil containing a lot of SUS, a relatively high amount of SUS.
  • Example 5 which uses vegetable oil that is slightly lower in melting point than that used in Example 4, it becomes a very light, fresh, and foamy food that melts well in the mouth, resulting in a conventional foaming cream. It was a new foam that had a different texture and melted mouth than when foamed.
  • Example 6 where the SUS content was reduced as compared with Example 5 due to curing, the oil-in-water emulsified foam was quickly removed from water compared to Example 4, but it was sufficiently commercial and very valuable. Light and fresh, good melting in the mouth! Foam was obtained.
  • Comparative Example 3 the emulsification was unstable and it was easy to separate during cooling. Even when whipped for a long time, it did not foam and did not foam.
  • the above mixture is stirred with a homomixer at 3000 rpm while warming, held at 65 ° C for 30 minutes, and then cooled to 5.0% by weight of oil and 75.0% by weight of non-fat solids (30% non-fat milk solids) 0%), and an oil-in-water emulsion having a water content of 20.0% by weight was obtained.
  • the oil-in-water emulsion thus obtained was foamed using a vertical mixer alone to evaluate workability 'quality.
  • the above mixture is stirred with a homomixer at 3000 rpm while warming, held at 65 ° C for 30 minutes, and then cooled and oily 24.6% by weight, nonfat solids 20.4% by weight (fatless milk solids 6 1%), and an oil-in-water emulsion having a water content of 55.0% by weight was obtained.
  • the oil-in-water emulsion thus obtained was foamed using a vertical mixer alone to evaluate workability 'quality.
  • Example 7 Example 8 Comparative example 4 Comparative example 5 Chocolate-like food
  • Example 8 is a very light and fresh, foamy food with good meltability in the mouth, and is a new foamed product with a different texture and meltability than when foaming a conventional foaming cream. there were.
  • Example 7 the oil-in-water emulsified foam alone was somewhat hard, but could be implemented.
  • Comparative Example 5 was not separated when cooled with an oil-in-water emulsion, and even if whipped for a long time, it did not become shape-retaining.
  • the oil-in-water emulsion of Comparative Example 4 could be produced without any problem, but even if whipped for a long time, it did not have a shape retaining property and was not whipped.

Abstract

The invention aims at developing an oil-in-water emulsion which does not contain any emulsifying agent and has fundamental properties essential to cream, e.g., flavor and overrun. An oil-in-water emulsion having fundamental properties essential to cream in spite of its being free from emulsifying agents can be obtained by using an emulsion having a fat-free matter content higher than those of conventional oil-in-water emulsions.

Description

水中油型乳化物およびこれを用レ、た食品の製造方法  Oil-in-water emulsion and method for producing food using the same
技術分野  Technical field
[0001] 本発明は、水中油型乳化物に関し、詳しくは乳化剤を配合していないことを特徴と する水中油型乳化物に関する。  [0001] The present invention relates to an oil-in-water emulsion, and more particularly to an oil-in-water emulsion characterized by not containing an emulsifier.
背景技術  Background art
[0002] アイスクリームやケーキ等のトッピングに使用されるホイップクリーム等の起泡性タリ ーム、あるいはコーヒー用クリーム等の水中油型乳化物は、複数の乳化剤や安定剤 である無機化合物を使用するのが一般的である。例えば、ホイップクリームのひとつ である植物性クリームは、水、植物性油脂、無脂乳固形分、各種の乳化剤、および安 定剤である無機化合物など力 なり、予備乳化、均質化、殺菌、冷却、エージングに より製造される。  [0002] Foaming tarites such as whipped cream used for topping ice cream and cakes, or oil-in-water emulsions such as coffee cream use multiple emulsifiers and inorganic compounds as stabilizers It is common to do. For example, vegetable cream, one of the whipped creams, is made up of water, vegetable oils and fats, non-fat milk solids, various emulsifiers, and inorganic compounds that are stabilizers, pre-emulsified, homogenized, sterilized and cooled. Manufactured by aging.
[0003] 無機化合物は、リン酸 (へキサメタリン酸、第二リン酸等)あるいはクェン酸のアル力 リ金属塩などが 0. 1〜1重量%程度使用されるのが一般的である。また、乳化剤とし ては、大豆レシチン、卵黄レシチンなどのいわゆる天然乳化剤とショ糖脂肪酸エステ ル、グリセリン脂肪酸エステル、ソルビタン脂肪酸エステル、ポリグリセリン脂肪酸エス テル、モノグリセリドなどのいわゆる合成乳化剤(以下これらの乳化剤を合成乳化剤と 記す)が組み合わされて使用されており、その総使用量は概略 1〜5重量%程度であ る。このように無機化合物や合成乳化剤の使用は、良好なクリーム物性 (オーバーラ ン、作業性、キメなど)を得るためには不可欠と考えられている。(例えば、非特許文 献 1 ·非特許文献 2参照)  [0003] As the inorganic compound, phosphoric acid (hexametaphosphoric acid, dibasic phosphoric acid, etc.) or alkanoic acid metal salt of citrate is generally used in an amount of about 0.1 to 1% by weight. As emulsifiers, so-called natural emulsifiers such as soybean lecithin and egg yolk lecithin and so-called synthetic emulsifiers such as sucrose fatty acid ester, glycerin fatty acid ester, sorbitan fatty acid ester, polyglycerin fatty acid ester and monoglyceride (hereinafter referred to as these emulsifiers). Synthetic emulsifiers) are used in combination, and the total amount used is approximately 1 to 5% by weight. Thus, the use of inorganic compounds and synthetic emulsifiers is considered indispensable for obtaining good cream properties (overrun, workability, texture, etc.). (For example, see Non-Patent Document 1 · Non-Patent Document 2)
[0004] 一方で、このような乳化剤、特に合成乳化剤はクリームの風味上好ましくないもので ある。また、近年の消費者の『健康』意識の増力 tl、天然志向の高まりから、このような 合成乳化剤や無機化合物などの添加剤の未使用または低減させた食品の開発が望 まれている。しかし水中油型乳化物に関してリン酸塩およびクェン酸塩の総含量を大 幅に低減した水中油型乳化物に関して例示されて ヽるが、レシチン等は配合されて いる。(例えば、特許文献 1参照) 非特許文献 1 :日高徹著、『食品用乳化剤』 (幸書房)(第 127〜147頁) 非特許文献 2 :日高徹著『食品添加物の常識』 (幸書房)(第 41〜43頁、 121〜128 頁) [0004] On the other hand, such emulsifiers, particularly synthetic emulsifiers, are undesirable in terms of cream flavor. In addition, the recent increase in consumer awareness of “health” and the increase in natural orientation have led to the demand for the development of foods with no or reduced additives such as synthetic emulsifiers and inorganic compounds. However, with respect to the oil-in-water emulsion, an example is an oil-in-water emulsion in which the total content of phosphate and citrate is greatly reduced, but lecithin and the like are blended. (For example, see Patent Document 1) Non-Patent Document 1: Toru Hidaka, “Emulsifier for Food” (Yuki Shobo) (pp. 127-147) Non-Patent Document 2: Toru Hidaka, “Common sense of food additives” (Yuki Shobo) (No. 41- (Pp. 43, 121-128)
特許文献 1:特開平 10— 215783号公報 (第 1— 4頁)  Patent Document 1: Japanese Patent Laid-Open No. 10-215783 (Pages 1 to 4)
発明の開示  Disclosure of the invention
発明が解決しょうとする課題  Problems to be solved by the invention
[0005] 本発明の目的は、水中油型乳化物であって、乳化剤を配合せず、且つ風味ゃォー バーランなどのクリームとしての基本物性を備えた水中油型乳化物を提供する事で ある。 [0005] An object of the present invention is to provide an oil-in-water emulsion that does not contain an emulsifier and has basic physical properties as a cream such as flavored balun. is there.
課題を解決するための手段  Means for solving the problem
[0006] 本発明者らは、上記課題を解決すべく鋭意研究した結果、通常の水中油型乳化物 に比べて高無脂固形分量の乳化物を用いることによって、乳化剤を配合しなくてもク リームとしての基本物性を備えた水中油型乳化物とあることを見いだし、本発明を完 成したものである。 [0006] As a result of diligent research to solve the above-mentioned problems, the present inventors have used an emulsion having a high non-fat solid content compared to a normal oil-in-water emulsion, so that no emulsifier is added. The present invention has been completed by finding that it is an oil-in-water emulsion having basic physical properties as a cream.
即ち本発明は、  That is, the present invention
(1)起泡性を有するクリームで、実質的に乳化剤を配合してないことを特徴とする水 中油型乳化物であり、(2)油分が 10〜50重量%、水分が 10〜50重量%、無脂固形 分が 10〜70重量%であることを特徴とする(1)記載の水中油型乳化物であり、 (3) 全無脂固形分に対する無脂乳固形分または無脂カカオ固形分の割合が 5〜50重量 %である(1)記載の水中油型乳化物であり、(4)油分中の油脂がハードバターまた は SUS (S:飽和脂肪酸、 U:トランス体を含まな!/ヽ不飽和脂肪酸)で表されるトリダリ セラリドを含むことを特徴とする(1)記載の水中油型乳化物であり、 (5) (1)記載の水 中油型乳化物を単独で起泡させることを特徴とする起泡済水中油型乳化物の製造 法であり、 (6) (1)記載の水中油型乳化物と水性組成物とを混合し、起泡させることを 特徴とする起泡済水中油型乳化物の製造法であり、 (7) (1)記載の水中油型乳化物 と水性組成物とを混合し、乳化剤を増すことなしに起泡させることを特徴とする起泡 済水中油型乳化物の製造法である。 発明の効果 (1) It is a foaming cream and is an oil-in-water emulsion characterized by substantially not containing an emulsifier. (2) Oil content is 10-50% by weight, moisture is 10-50% %, Non-fat solid content is 10 to 70% by weight, the oil-in-water emulsion according to (1), (3) non-fat milk solid content or non-fat cacao to the total non-fat solid content (1) The oil-in-water emulsion according to (1) having a solid content of 5 to 50% by weight. (4) The fat in the oil contains hard butter or SUS (S: saturated fatty acid, U: trans isomer) (1) The oil-in-water emulsion according to (1), wherein the oil-in-water emulsion according to (1) is used alone. A method for producing a foamed oil-in-water emulsion characterized by foaming. (6) The oil-in-water emulsion according to (1) and an aqueous composition are mixed and foamed. (7) The oil-in-water emulsion according to (1) and the aqueous composition are mixed and foamed without increasing the emulsifier. This is a method for producing a foamed oil-in-water emulsion. The invention's effect
[0007] 本発明によって、乳化剤を配合しなくても良好な水中油型乳化物を製造することが 可能となり、本発明は添加剤の使用により好ましくない風味が付加されることを防止 することができるという利点がある。また、従来の乳化剤使用の水中油型乳化物に、 本発明品である乳化剤を配合して 、な 、水中油型乳化物を一部添加して用いる使 用法に際しても、添加先に元力 ある乳化剤を増やすことなく乳味'コク味の付与や 保形性と ヽつた特性を付与することが可能である。  [0007] According to the present invention, it is possible to produce a good oil-in-water emulsion without blending an emulsifier, and the present invention can prevent an unfavorable flavor from being added by using an additive. There is an advantage that you can. In addition, when the emulsifier of the present invention is blended with a conventional oil-in-water emulsion using an emulsifier, and the oil-in-water emulsion is partially added and used, the addition destination is powerful. Without increasing the emulsifier, it is possible to impart milky and richness and shape retention.
発明を実施するための最良の形態  BEST MODE FOR CARRYING OUT THE INVENTION
[0008] 本発明において言うところの水中油型乳化物は、油分が 10〜50重量%、水分が 1 0〜50重量%、無脂固形分が 10〜70重量%であり、起泡性を有するクリームで、乳 ィ匕剤を配合してないことを特徴とする水中油型乳化物である [0008] The oil-in-water emulsion referred to in the present invention has an oil content of 10 to 50% by weight, a water content of 10 to 50% by weight, a non-fat solid content of 10 to 70% by weight, and has a foaming property. It is an oil-in-water type emulsion characterized by having no milky formula added.
ただし、水中油型乳化物の油分が 10%未満であると水中油型乳化物の起泡性が低 下し、 50%を超えると水中油型乳化物の乳化が不安定となり、安定的生産に支障を きたす。好ましくは 15%以上、 40%以下が望ましい。  However, if the oil content of the oil-in-water emulsion is less than 10%, the foamability of the oil-in-water emulsion decreases, and if it exceeds 50%, the oil-in-water emulsion becomes unstable and stable production is achieved. Cause trouble. Preferably it is 15% or more and 40% or less.
[0009] 本発明の水中油型乳化物の油脂については特に制限はないが、さらに起泡する 機能を強く付与するためには、油分中の油脂がハードバター、特に SUS (S :飽和脂 肪酸、 U:トランス体を含まな!/ヽ不飽和脂肪酸)で表されるトリダリセラリドを含んで ヽる のが好ましい。上記 SUS (最適には SOS ; Oはォレイン酸)の好適な含有量は、その 量がふえるにつれ、口融けの良さと耐熱保形性、解乳化性へ付与される機能も向上 するため、好ましくは油分中 45%以上、さらに好ましくは 70%以上含有していること が望ましい。 [0009] The oil and fat of the oil-in-water emulsion of the present invention is not particularly limited, but in order to further impart a foaming function, the oil and fat in the oil component is hard butter, particularly SUS (S: saturated fat It is preferable to include tridallyceralide represented by the following formula: acid, U: not including trans form! / (Unsaturated fatty acid). A suitable content of the above SUS (optimally SOS; O is oleic acid) is preferable because it improves the meltability and the functions imparted to heat-resistant shape retention and demulsification as the amount increases. The oil content is desirably 45% or more, more preferably 70% or more.
上記 SUSで表されるトリグリセリドを多く含む油脂としては、カカオバター、シァ脂、マ ンゴー核油、サル脂、ィリッペ脂、パーム油及びこれらの分別油等が挙げられ、これら の中力も選ばれた 1種又は 2種以上を使用することができる。また、グリセリドの 1、 3 位を選択的なエステル交換を行い必要な場合には中融点画分を分取することによつ て SUSで表されるトリグリセリドを多く含む油脂を製造し用いることもできる。  Examples of the fats and oils rich in triglycerides represented by SUS include cacao butter, shea fat, mango kernel oil, monkey fat, lippe fat, palm oil, and fractionated oils thereof. One type or two or more types can be used. It is also possible to produce and use oils rich in triglycerides represented by SUS by selectively transesterifying the 1st and 3rd positions of glycerides and, if necessary, fractionating the middle melting point fraction. it can.
[0010] 本発明の水中油型乳化物の水分が 10%未満であると水中油型乳化物が増粘して 、安定的生産に支障をきたす。 50%を超えると、水中油型乳化物の乳化が不安定に なり安定的生産に支障をきたす。また、ホイップした後の作業性、耐熱保形性、離水 耐性が弱くなる。 10〜50%の範囲において最適に用いることができる。 [0010] If the water content of the oil-in-water emulsion of the present invention is less than 10%, the oil-in-water emulsion thickens and hinders stable production. If it exceeds 50%, the emulsification of the oil-in-water emulsion becomes unstable. It will hinder stable production. In addition, workability after whipping, heat-resistant shape retention, and water separation resistance are reduced. It can be optimally used in the range of 10 to 50%.
水中油型乳化物に含有される水分の由来は特に規定はなぐ乳固形分を含む乳製 品由来の水分であってもよいし、乳固形分を水に溶解もしくは分散させた場合には 溶媒もしくは分散媒の水分でも良い。このほか果汁、ジャム、各種フルーツ類、餡類、 チーズ類、ナッツ類、天然蜂蜜、コーヒー、紅茶などの含水食品を一種または二種以 上を併用して使用する事もできる。  The origin of water contained in the oil-in-water emulsion may be water derived from dairy products containing milk solids that are not particularly specified, or a solvent when milk solids are dissolved or dispersed in water. Or the water | moisture content of a dispersion medium may be sufficient. In addition, water-containing foods such as fruit juice, jam, various fruits, strawberries, cheeses, nuts, natural honey, coffee and tea can be used in combination of one or more.
[0011] また、水中油型乳化物の無脂固形分が 10%以下であると、起泡性クリームへの乳 味、コク味付与効果を発揮しがたぐ 70重量%以上であると水中油型乳化物の粘度 が上がり、安定的生産に支障をきたす。最適には水中油型乳化物の無脂固形分が 2 0〜60%の範囲で用いることができる。 [0011] When the oil-in-water emulsion has a non-fat solid content of 10% or less, it exhibits an effect of imparting a milky taste and a rich taste to the foamable cream, and when it is 70% by weight or more, The viscosity of the oil-type emulsion will increase, hindering stable production. Optimally, the non-fat solid content of the oil-in-water emulsion can be used in the range of 20 to 60%.
上記無脂固形分としては、無脂乳固形分、無脂カカオ固形分、糖類が挙げられる。 無脂乳固形分は起泡性クリームへの乳味感、コク味を付与し、無脂カカオ固形分は チョコレート風味やコク味を付与する。  Examples of the non-fat solids include non-fat milk solids, non-fat cocoa solids, and saccharides. The non-fat milk solid content gives a milky taste and richness to the foaming cream, and the non-fat cocoa solid content gives a chocolate flavor and a rich taste.
上記無脂乳固形分や無脂カカオ固形分の含有量は、全無脂固形分中、 5〜50重量 %を占めるのがよい。  The content of the non-fat milk solids and the non-fat cocoa solids should occupy 5 to 50% by weight in the total non-fat solids.
上記無脂乳固形分としては、生クリーム、牛乳、濃縮乳、脱脂乳、加糖練乳、無糖練 乳、全脂粉乳、脱脂粉乳、バターミルク、バターミルクパウダー、ホエー、ホエーバウ ダー、カゼイン、カゼインナトリウム、ラクトアルブミン等に含まれる乳由来の無脂固形 分が例示でき、単独又は 2種以上を組み合わせて用いることもできる。  The non-fat milk solids include fresh cream, milk, concentrated milk, skim milk, sweetened condensed milk, sugar-free condensed milk, whole milk powder, skim milk powder, butter milk, butter milk powder, whey, whey powder, casein, casein Non-fat solids derived from milk contained in sodium, lactalbumin, etc. can be exemplified, and can be used alone or in combination of two or more.
上記無脂カカオ固形分とは、カカオ豆由来の固形分のうちココアバターを除いた部 分であり、無脂カカオ分源としては、カカオマス、ココアパウダー及びこれらを原料と する各種チョコレート、並びにその他の加工品が例示できる。  The non-fat cocoa solid content is a part excluding cocoa butter from the solid content derived from cocoa beans, and as the non-fat cocoa content source, cocoa mass, cocoa powder, various chocolates using these as raw materials, and others The processed product can be exemplified.
[0012] 上記糖類としては特に限定されな 、が、例えばブドウ糖、果糖、ショ糖、麦芽糖、酵 素糖化水飴、乳糖、還元澱粉糖化物、異性化液糖、ショ糖結合水飴、オリゴ糖、還元 糖ポリデキストロース、ソルビトール、還元乳糖、トレハロース、キシロース、キシリトー ル、マルチトール、エリスリトール、マン-トール、フラタトオリゴ糖、大豆オリゴ糖、ガラ タトオリゴ糖、乳果オリゴ糖、ラフイノース、ラクチュロース、パラチノースオリゴ糖、ステ ビア、アスパルテーム、糖アルコール等の糖類が挙げられる。これらの糖類は、単独 で用いることもでき、又は 2種以上を組み合わせて用いることもできる。 [0012] The saccharide is not particularly limited, and examples thereof include glucose, fructose, sucrose, maltose, enzymatic saccharified starch syrup, lactose, reduced starch saccharified product, isomerized liquid sugar, sucrose-conjugated starch syrup, oligosaccharide, and reduced sugar. Sugar Polydextrose, Sorbitol, Reduced Lactose, Trehalose, Xylose, Xylitol, Maltitol, Erythritol, Mannitol, Frata Oligosaccharide, Soy Oligosaccharide, Galato Oligosaccharide, Whey Oligosaccharide, Raffinose, Lactulose, Palatinose Oligosaccharide, Stethosaccharide Examples include sugars such as beer, aspartame, sugar alcohol and the like. These saccharides can be used alone or in combination of two or more.
[0013] 以上に示された、水中油型乳化物の油分、水分、無脂固形分の配合量の関係は、 公知の起泡性クリームに比べて低水分 ·高無脂固形分であり、練乳に比べて高油分 であるが、その調製法の主なものを次に例示する。 [0013] The relationship between the oil content, water content, and non-fat solid content of the oil-in-water emulsion shown above is a low water content and a high non-fat solid content as compared to known foaming creams, Although it has a higher oil content than condensed milk, the main preparation methods are illustrated below.
すなわち本発明の水中油型乳化物の調製法の第一は、上記無脂固形分と上記油脂 の一部または全部力 ー且チョコレートの製造法に準じた製法によりチョコレート乃至 チョコレート様食品の粉末またはそれらの溶融した生地を得、次いで上記無脂固形 分や油脂を含んでもょ ヽ水性組成物を加えて乳化する方法が挙げられる。チョコレ ート様食品の製造に際しては通常のチョコレートの製造法を大きく逸脱しない限り特 に制限はなぐロールにより微細化の後、コンチングを行うことができる。  That is, the first method for preparing the oil-in-water emulsion of the present invention is the use of a powder of chocolate or chocolate-like food or the like according to a method according to the method for producing chocolate. There is a method in which those melted doughs are obtained and then emulsified by adding a water-based composition containing the above-mentioned non-fat solids and fats and oils. In the production of chocolate-like food, conching can be performed after refining with a roll that is not particularly limited unless it significantly deviates from the normal chocolate production method.
[0014] あるいは別の調製方法として、上記無脂固形分と上記油脂それぞれを、水性組成 物とを混合した後、 30〜70°Cに加温する、あるいはどちらか一方または両方を 30〜 70°Cに加温しておいて力も混合し、手で攪拌するような緩やかな攪拌方式、あるい は強力な剪断力を加えることのできる高速攪拌方式、例えばホモミキサー等のいず れの方式でも製造することができる。乳化は場合によっては均質ィ匕(5〜150kgZc m2)処理を行ってもよい。  [0014] Alternatively, as another preparation method, the non-fat solids and the respective oils and fats are mixed with the aqueous composition and then heated to 30 to 70 ° C, or one or both of them is 30 to 70. A gentle agitation method in which the force is mixed by heating to ° C and mixed by hand, or a high-speed agitation method that can apply a strong shearing force, such as a homomixer. But it can be manufactured. In some cases, the emulsification may be carried out by homogenization (5 to 150 kgZcm2).
[0015] 上記乳化処理した水中油型乳化物は冷却して製造される。乳化工程あるいは均質 化処理の前後で殺菌または滅菌してもよ!/、が、従来の UHT処理を行うクリーム製造 ラインでは製造可能な粘度幅が狭ぐ粘度が上がる要因となりうるので、低温殺菌が 推奨される。  [0015] The emulsified oil-in-water emulsion is produced by cooling. It may be sterilized or sterilized before and after the emulsification process or homogenization process! /, But in the conventional cream production line that performs UHT treatment, the viscosity range that can be produced may be a factor that increases, so pasteurization can be performed. Recommended.
また、解乳化しやすくボテ現象の起こりやす!、SUS型トリグリセリドを配合しても上記 の工程に準じて製造するときは、調製が可能である。  In addition, it is easy to demulsify and easily causes a bloating phenomenon. Even if SUS type triglyceride is blended, it can be prepared when it is produced according to the above process.
[0016] 次に、本発明の水中油型乳化物添加する対象である水性組成物について説明す る。 Next, the aqueous composition to which the oil-in-water emulsion of the present invention is added will be described.
上記のようにして得られた高無脂固形分乳化物は、水性組成物添加用、とりわけ起 泡性油脂組成物 (起泡性クリーム)改質用として好適に使用でき、起泡済油脂組成物 を製造することができる。 [0017] 本発明で 、うところの水性組成物は生タリームゃ植物性タリームの各種巿販製品と いった起泡性油脂組成物にかぎらず、牛乳や濃縮乳、チーズ類といった起泡力をも たない乳製品、さらには豆乳などのような oZw型乳化物、さらには乳化物ですらな いジャム、各種フルーツ類、餡類、天然蜂蜜、コーヒー、紅茶などの含水食品そして 水を一種または二種以上を併用して使用する事もでき、特に限定はされず、その製 造法は周知慣用の技術や、公知の技術を採用できる。 The highly fat-free solid emulsion obtained as described above can be suitably used for adding an aqueous composition, especially for modifying a foamable oil composition (foaming cream). Can be manufactured. [0017] In the present invention, the aqueous composition of the place is not limited to foaming oils and fats such as various commercial products of raw talyam and vegetable tarim, but has foaming power such as milk, concentrated milk, and cheeses. Ozw-type emulsions such as soy milk, or even non-emulsified jams, various fruits, strawberries, natural honey, water-containing foods such as coffee and tea, and water Two or more kinds can be used in combination, and there is no particular limitation, and the production method can employ a well-known and commonly used technique or a known technique.
本来起泡力をもたない乳製品や oZw型乳化物、さらには含水食品そして水などは 、水中油型乳化物を混合のみの状態ではコク味を付与することが出来、攪拌により起 泡させることち可會である。  Dairy products and oZw type emulsions that do not inherently have foaming power, as well as water-containing foods and water, can give a rich taste only by mixing oil-in-water type emulsions, and foam by stirring. Kotochi is pretty.
コク味や乳味に乏しい起泡性油脂組成物に加える場合はコク味や乳味が向上し、口 融けは良いが耐熱保形性、離水耐性が弱い、あるいはその逆の物性の起泡性油脂 組成物に加えると、その長所を損なうことなぐ短所の機能を補うことができる。  When added to a foaming oil or fat composition with poor body taste or milky taste, the body taste and milky taste are improved, and the meltability is good, but the heat-resistant shape retention and water separation resistance are weak, or vice versa. When added to the oil / fat composition, the function of the disadvantages without losing the advantages can be compensated.
[0018] ただし、上記、水中油型乳化物中の油脂についての部分でも記載したが、口融け の良さと耐熱保形性、離水耐性をより強く付与するためには、油分中の油脂がハード ノターであることが、さらに、起泡する機能をより強く付与するためには、油分中の油 脂が SUSで表されるトリグリセリドを含んでいるのがより好ましい。  [0018] However, as described above for the fats and oils in the oil-in-water emulsion, the fats and oils in the oils are hard to impart good meltability, heat-resistant shape retention and water separation resistance. It is more preferable that the oil or fat in the oil contains triglyceride represented by SUS in order to impart notably a foaming function to be notter.
本発明の水中油型乳化物の、起泡済クリーム中の含有量は、 5重量%以上、さらに 好ましくは 10〜50重量%が適当であり、含有量が少ないと起泡性クリームを改質す る効果に乏しい。  The content of the oil-in-water emulsion of the present invention in the foamed cream is suitably 5% by weight or more, more preferably 10 to 50% by weight. If the content is small, the foamable cream is modified. The effect is poor.
起泡性クリームに水中油型乳化物を添加するタイミングはホイップの前、途中、のい ずれでもよ 、がホイップ後であるよりは、ホイップ前や途中にカ卩える方がょ 、。  The timing of adding the oil-in-water emulsion to the foaming cream may be before, during, or after whipping, but it should be held before or during whipping rather than after whipping.
また、水中油型乳化物は単独でも起泡が可能である。  In addition, the oil-in-water emulsion can be foamed alone.
実施例  Example
[0019] 以下に本発明の実施例を示し、本発明をさらに詳しく説明する力 本発明はこれら の実施例に限定されるものではない。なお、例中、%及び部は重量基準を意味する  Examples of the present invention will be described below, and the power for explaining the present invention in more detail. The present invention is not limited to these examples. In the examples,% and part mean weight basis.
[0020] <実施例 1 > <Example 1>
全脂粉乳 16. 0部、砂糖 39. 0部、植物性油脂としては SUSを多く含むタイプで あるテンパータイプハードバター (製品名「メラノ NEWSS - 7」不二製油株式会社製 、 SUS含量約 81%) 45. 0部を配合、チョコレート製造の定法に従いチョコレート様 食品を製造した。 Whole fat milk powder 16.0 parts, sugar 39.0 parts, vegetable oil and fat is a type that contains a lot of SUS A temper type hard butter (product name “Melano NEWSS-7” manufactured by Fuji Oil Co., Ltd., SUS content of about 81%) 45.0 parts was blended, and a chocolate-like food was produced according to a standard method of chocolate production.
次いで 30°Cに加温した水 24. 0部に、上記操作にて得られたチョコレート様食品を 粉砕したもの 70. 0部と上記テンパータイプハードバター 4. 0部、砂糖 2. 0部を 加え混合した。  Next, 20.0 parts of water heated to 30 ° C was pulverized from the chocolate-like food obtained in the above operation, and 70.0 parts, 4.0 parts of the above temper type hard butter and 2.0 parts of sugar. Added and mixed.
この混合物を、加温しながらホモミキサー(「Τ. Κ.ホモディスパー」特殊機化工業株 式会社製) 3000rpmにて攪拌を行い、 65°C30分保持後、冷却して油分 38. 4重量 %、無脂固形分 37. 6重量% (無脂乳固形は 8. 3%)、水分 24. 0重量%の水中油 型乳化物を得た。  The mixture was stirred while stirring at 3000 rpm with a homomixer (“Κ. Κ. Homodisper” Special Machine Industries Co., Ltd.), held at 65 ° C for 30 minutes, cooled and oiled 38.4 wt. %, Non-fat solid content 37.6 wt% (non-fat milk solid was 8.3%), and water content 24.0 wt% was obtained.
このようにして得た水中油型乳化物と、水を 70部: 30部の割合で混合し、縦型ミキサ 一(「ホバートミキサー N— 50」 ホバートジャパン株式会社製)を使用して起泡させた もの(以降、水中油型乳化起泡物と称する)の作業性'品質の評価を行った。  The oil-in-water emulsion thus obtained and water are mixed in a ratio of 70 parts: 30 parts, and foamed using a vertical mixer (“Hobart Mixer N-50” manufactured by Hobart Japan KK). The workability (quality) of the product (hereinafter referred to as oil-in-water emulsified foam) was evaluated.
[0021] <比較例 1 >  [Comparative Example 1]
実施例 1と同様の配合 ·製法にてチョコレート様食品を得、次 ヽで 30°Cに加温した水 24. 0部に、上記操作にて得られたチョコレート様食品を粉砕したもの 45. 0部と 上記テンパータイプノヽードバター 31. 0部をカ卩ぇ混合した。  A chocolate-like food obtained by the same composition and production method as in Example 1, and then the chocolate-like food obtained by the above operation was pulverized in 24.0 parts of water heated to 30 ° C in the next step 45. 0 parts and 31.0 parts of the above temper type node butter were mixed.
この混合物を実施例 1と同様の製法にて、油分 53. 2重量%、無脂固形分 22. 8重 量% (無脂乳固形は 5. 3%)、水分 24. 0重量%の水中油型乳化物を得た。また、こ のようにして得た水中油型乳化物と、表 1の配合に従い実施例 1と同様の配合'製法 にて起泡させたものの作業性'品質の評価を行った。  This mixture was prepared in the same manner as in Example 1 except that the oil content was 53.2% by weight, non-fat solid content was 22.8% by weight (non-fat milk solid was 5.3%), and the water content was 24.0% by weight. An oil-type emulsion was obtained. In addition, the oil-in-water emulsion thus obtained and the workability of the product foamed by the same blending method as in Example 1 according to the blending in Table 1 were evaluated.
[0022] <比較例 2>  [0022] <Comparative Example 2>
表 1の配合に従い、実施例 1の配合に大豆レシチン 0. 5部を配合した以外はすべ て同様の配合'製法にてチョコレート様食品を得、次いで表 1の配合に従い、比較例 1の配合にショ糖脂肪酸エステル(「リヨ一トーシュガーエステル S1670J 三菱化学 フーズ株式会社製 HLB16)を配合した以外はすべて同様の配合'製法にてカロえ 混合した。  According to the formulation in Table 1, all of the compounds of Example 1 were mixed with 0.5 part of soy lecithin, and a chocolate-like food was obtained by the same formulation method. Then, according to the formulation of Table 1, the formulation of Comparative Example 1 was obtained. All of the above were mixed with the same compounding method except that sucrose fatty acid ester ("Lyo-toe sugar ester S1670J HLB16 manufactured by Mitsubishi Chemical Foods Co., Ltd.)" was mixed.
この混合物を、表 1の配合に従い実施例 1と同様の製法にて、油分 53. 2重量%、無 脂固形分 22.8重量% (無脂乳固形は 5.3%)、水分 24.0重量%の水中油型乳化 物を得た。また、このようにして得た水中油型乳化物と、表 1の配合に従い実施例 1と 同様の配合'製法にて起泡させたものの作業性'品質の評価を行った。 This mixture was mixed in the same manner as in Example 1 in accordance with the composition shown in Table 1, and the oil content was 53.2% by weight. An oil-in-water emulsion having a fat solid content of 22.8 wt% (non-fat milk solid was 5.3%) and a water content of 24.0 wt% was obtained. In addition, the oil-in-water emulsion thus obtained and the workability of the product foamed by the same blending method as in Example 1 according to the blending of Table 1 were evaluated.
<実施例 2>  <Example 2>
実施例 1で得られた水中油型乳化物と、市販起泡性クリーム (製品名「ライトトッピング SV」、不二製油株式会社製)を 20部: 80部の割合で混合し、縦型ミキサーを使用し て起泡させた。 The oil-in-water emulsion obtained in Example 1 and a commercially available foaming cream (product name “Light Topping SV”, manufactured by Fuji Oil Co., Ltd.) are mixed in a ratio of 20 parts: 80 parts, and a vertical mixer Was used to foam.
評価は表 1に配合と共に示した。 The evaluation is shown in Table 1 together with the formulation.
[表 1] 実施例 1 比較例 1 比較例 2 実施例 2 [Table 1] Example 1 Comparative example 1 Comparative example 2 Example 2
<チョコレ一ト様食品の配合 > <Combination of chocolate-like food>
全脂粉乳 16.0 16.0 16.0 16.0 砂糖 39.0 39.0 39.0 39.0 メラノ N EWS S- 7 45.0 45.0 45.0 45.0 レシチン 0.5  Whole milk powder 16.0 16.0 16.0 16.0 Sugar 39.0 39.0 39.0 39.0 Melano N EWS S- 7 45.0 45.0 45.0 45.0 Lecithin 0.5
<水中油型乳化物の配合 >  <Formulation of oil-in-water emulsion>
チョコレート様食品 70.0 45.0 45.0 70.0 水 24.0 24.0 24.0 24.0 メラノ N EWS S- 7 4.0 31.0 31.0 4.0 砂糖 2.0 2.0 ショ糖脂肪酸エステル 0.5  Chocolate-like food 70.0 45.0 45.0 70.0 Water 24.0 24.0 24.0 24.0 Melano N EWS S- 7 4.0 31.0 31.0 4.0 Sugar 2.0 2.0 Sucrose fatty acid ester 0.5
油分 38.4 53.2 53.1 38.4 無脂固形分 37.6 22.8 22.9 37.6 水分 24.0 24.0 24.0 24.0 水中油型乳化物の評価  Oil 38.4 53.2 53.1 38.4 Non-fat solid 37.6 22.8 22.9 37.6 Moisture 24.0 24.0 24.0 24.0 Evaluation of oil-in-water emulsions
〇 X 〇 〇 水中油型乳化起泡物  ○ X ○ ○ Oil-in-water emulsified foam
水中油型乳化物 70 70 70 20 水 30 30 30  Oil-in-water emulsion 70 70 70 20 Water 30 30 30
市販起泡性クリーム 80 水中油型乳化起泡物の言- P価  Commercial foaming cream 80 Oil-in-water emulsified foam-P value
〇 ― 〇 〇 ※ 評価基準 ○ ― ○ ○ ※ Evaluation criteria
〇:乳化が安定でホイップ等の作業が良好に出来、食感も軽くてみずみずしぐ口溶 けが良い。  ○: Emulsification is stable, whipping work can be performed well, and the mouthfeel is light and the mouth melts well.
△:乳化がやや不安定で、やや堅いもののホイップ等の作業が可能、食感もやゃボ テ感があるものの商品価値はあるレベル。  △: Emulsification is slightly unstable, work of whipping etc. is possible, and the product value is at a certain level although it has a texture and a feeling of stickiness.
X:乳化が不安定で作業不能、商品価値を損なう悪食感。  X: Emulsification is unstable and work is impossible.
一:作製不能。  1: Cannot be made.
[0024] その結果、実施例 1は非常に軽くてみずみずしい、口溶けの良い泡状の食品となり 、従来の起泡性クリームを起泡させた場合よりも食感、口溶けともに異なる新しい水中 油型乳化起泡物であった。  [0024] As a result, Example 1 became a very light and fresh, foamy food with good meltability in the mouth, and a new oil-in-water emulsification differing in texture and meltability from the conventional foaming cream. It was a foam.
しかし、比較例 1の水中油型乳化物は非常に硬く乳化も不安定であった (油中水型 への転相)。また、ホイップしょうとしても、そのままでは硬すぎるし、水性成分と混合し ようとしてもダマになりうまく起泡させることができな力つた。  However, the oil-in-water emulsion of Comparative Example 1 was very hard and unstable to emulsify (phase inversion into water-in-oil type). In addition, whip soy was too hard as it was, and even if it was mixed with an aqueous component, it was stupid and could not foam well.
[0025] また、比較例 1に乳化剤加えた比較例 2の水中油型乳化物は、比較例 1のものとは 違い、乳化は安定であつたし、乳化剤を添加して水と混合して水中油型乳化物を作 成したのち起泡させたものは、うまく起泡させる事が可能であり、食感も従来の水中油 型乳化物として存在するクリーム的なものであった。 [0025] Further, the oil-in-water emulsion of Comparative Example 2 in which an emulsifier is added to Comparative Example 1 is different from that of Comparative Example 1 in that the emulsification is stable, and an emulsifier is added and mixed with water. After the oil-in-water emulsion was made, the foamed foam was able to foam well, and the texture was a cream that existed as a conventional oil-in-water emulsion.
すなわち、本願の請求範囲である、油脂や水分 ·全無脂固形分の範囲を逸脱した比 較例 1は乳化剤を用いな 、と乳化できな 、ものであった。  That is, Comparative Example 1 that deviated from the range of fats and oils, moisture, and total non-fat solids, which was claimed in the present application, could not be emulsified without using an emulsifier.
なお市販起泡性クリームには実施例 2で用いたような機能重視タイプ、すなわち乳味 •コク味はやや劣るものの作業性が良いものがあり、乳味'コク味と作業性といった機 能は両立しにく!/、ことは一般に良く知られて 、るが、そう 、つた巿販起泡性クリームに 実施例 1で得られた水中油型乳化物を一部添加することで乳味、コク味を付与と保 形性の向上が平易な方法で可能である。  Note that commercially available foaming creams have a function-oriented type as used in Example 2, that is, milk taste.Some taste is slightly inferior, but workability is good. It is generally well known that, it is generally well known, but yes, by adding a part of the oil-in-water emulsion obtained in Example 1 to the Tsutatsu selling foaming cream, the milky taste, It is possible to impart richness and improve shape retention by a simple method.
し力も水中油型乳化物自体には乳化剤の添加されていないため、もとの巿販起泡性 クリームに添加されている乳化剤にあらたに乳化剤を上乗せすることもなぐトータル として乳化剤の総量を減らし尚且つ、乳味'コク味といったものの付与が可能である 事があきらかになった。 [0026] <実施例 3 > Since the oil-in-water emulsion itself does not contain any emulsifier, the total amount of emulsifier is reduced as a total without adding an emulsifier to the emulsifier added to the original foaming cream. In addition, it became clear that it was possible to add milky taste and richness. <Example 3>
実施例 1で得た水中油型乳化物と、イチゴピューレ(タカ食品)を 60部: 40部の割合 で混合し、縦型ミキサーを使用して起泡させた。  The oil-in-water emulsion obtained in Example 1 and strawberry puree (hawk food) were mixed at a ratio of 60 parts: 40 parts, and foamed using a vertical mixer.
その結果、苺の風味の強い、みずみずしい泡状の食品となった。なお、用いた苺ピュ ーレは単独では起泡力をほとんど持たな力つた。  As a result, it became a fresh, foamy food with a strong strawberry flavor. The cocoon puree used alone had almost no foaming power.
これにより、それ自身に起泡力を持たないイチゴピューレのようなものに添加すること で、特段乳化剤を加えなくとも起泡力が付与される事があきらかになった。  As a result, it became clear that the foaming power could be imparted without adding a special emulsifier by adding it to a strawberry puree that does not have foaming power.
[0027] <実施例 4 > <Example 4>
油脂、無脂固形分からチョコレート様食品を製造する過程を経ずに、水中油型乳化 物を得る例を示す。  An example of obtaining an oil-in-water emulsion without going through the process of producing a chocolate-like food from fats and fats and non-fat solids is shown.
30°Cに加温した水 20. 0部に全脂粉乳 15. 0部、砂糖 25. 0部を混合し、そこ に植物性油脂として SUSを多く含むタイプであるテンパータイプノヽードバター (製品 名「メラノ NEWSS— 7」不二製油株式会社製、 SUS含量約 81%) 40. 0部を混合 する。  Water heated to 30 ° C 20.0.0 parts of whole milk powder milk and 25.0 parts of sugar are mixed with temper type node butter (product name) which is rich in SUS as vegetable oil. “Melano NEWSS-7” manufactured by Fuji Oil Co., Ltd., SUS content of about 81%) 40.0 parts are mixed.
上記混合物を、加温しながらホモミキサーで 3000rpmにて攪拌を行い、 65°C30分 保持後、冷却して油分 43. 9重量%、無脂固形分 36. 1重量% (無脂乳固形 11. 1 %)、水分 20. 0重量%の水中油型乳化物を得た。このようにして得た水中油型乳化 物と、水を 70部: 30部の割合で混合し、縦型ミキサーを使用して水中油型乳化起泡 物の作業性'品質の評価を行った。  The above mixture was stirred at 3000 rpm with a homomixer while warming, held at 65 ° C for 30 minutes, and then cooled to 43.9% oil content, 36.1% non-fat solid content (non-fat milk solid 11 1%) and an oil-in-water emulsion having a water content of 20.0% by weight was obtained. The oil-in-water emulsion thus obtained and water were mixed in a ratio of 70 parts: 30 parts, and the workability of the oil-in-water emulsion foam was evaluated using a vertical mixer. .
[0028] <実施例 5 >  <Example 5>
表 2の配合に従い、実施例 4の配合のうち植物性油脂として SUSを比較的多く含む が融点が実施例 4で使用したものよりやや低 、タイプであるパーム油中融点部の分 別品 (製品名「ュ-レート P110N」不二製油株式会社製、 SUS含量約 55%)を用い る以外は全て同様の配合 ·製法にて水中油型乳化物を得、またこのようにして得た水 中油型乳化物を、実施例 4と同様の配合'製法で水中油型乳化起泡物の作業性 ·品 質の評価を行った。  According to the formulation in Table 2, among the blends of Example 4, SUS as a vegetable fat is relatively high, but the melting point is slightly lower than that used in Example 4 An oil-in-water emulsion was obtained by the same formulation and manufacturing method except that the product name “Sulfurate P110N” (Fuji Oil Co., Ltd., SUS content of about 55%) was used. The workability and quality of the oil-in-water emulsified foamed product were evaluated for the oil-in-water emulsion by the same blending method as in Example 4.
[0029] <実施例 6 >  <Example 6>
表 2の配合に従い、実施例 4の配合のうち植物性油脂として、パーム油中融点部を部 分硬化し susの uの部分の一部をトランス体や飽和脂肪酸に置換したもの (製品名「 メルバ 31」不二製油株式会社製)を用いる以外は全て同様の配合'製法にて水中油 型乳化物を得、またこのようにして得た水中油型乳化物を、実施例 4と同様の配合 · 製法で水中油型乳化起泡物の作業性 ·品質の評価を行った。 According to the formulation in Table 2, as the vegetable oil in the formulation of Example 4, the palm oil middle melting point part It is oil-in-water with the same blending method except that it is partially cured and part of the sus part of u is replaced with a trans form or saturated fatty acid (product name "Melva 31" manufactured by Fuji Oil Co., Ltd.) The emulsion was obtained, and the oil-in-water emulsion thus obtained was evaluated for workability and quality of the oil-in-water emulsion by the same formulation and production method as in Example 4.
評価は表 2に配合と共に示した。  The evaluation is shown in Table 2 together with the formulation.
[0030] <比較例 3>  [0030] <Comparative Example 3>
表 2の配合に従い、実施例 4の配合のうち植物性油脂として融点が低く SUSを殆ど 含まない大豆白絞油を用いる以外は全て同様の配合'製法にて水中油型乳化物を 得、またこのようにして得た水中油型乳化物を、実施例 4と同様の配合'製法で水中 油型乳化起泡物の作業性'品質の評価を行った。  According to the formulation in Table 2, an oil-in-water emulsion was obtained by the same formulation method except that soybean white squeezed oil having a low melting point as vegetable oil was used in the formulation of Example 4 and containing almost no SUS. The oil-in-water emulsion thus obtained was evaluated for the quality of the workability of the oil-in-water emulsified foam by the same blending method as in Example 4.
[0031] [表 2]  [0031] [Table 2]
※ 作業性'食感の評価は実施例と同じ。 * The evaluation of workability and texture is the same as in the examples.
[0032] その結果、 SUSを多く含む植物性油脂を使用した実施例 4、 SUSを比較的多く含 むが融点は実施例 4で使用したものよりやや低い植物性油脂を使用した実施例 5は では、非常に軽くてみずみずしい、口溶けの良い泡状の食品となり、従来の起泡性ク リームを起泡させた場合よりも食感、口溶けともに異なる新しい起泡物であった。また 硬化によって SUS含有量が実施例 5に比べ減少した実施例 6も、実施例 4に比べる と水中油型乳化起泡物の離水が早い点が見られるが十分に商品価値があり、非常 に軽くてみずみず 、、口溶けの良!、起泡物が得られた。 [0032] As a result, Example 4 using vegetable oil containing a lot of SUS, a relatively high amount of SUS. However, in Example 5, which uses vegetable oil that is slightly lower in melting point than that used in Example 4, it becomes a very light, fresh, and foamy food that melts well in the mouth, resulting in a conventional foaming cream. It was a new foam that had a different texture and melted mouth than when foamed. In addition, in Example 6 where the SUS content was reduced as compared with Example 5 due to curing, the oil-in-water emulsified foam was quickly removed from water compared to Example 4, but it was sufficiently commercial and very valuable. Light and fresh, good melting in the mouth! Foam was obtained.
[0033] し力 比較例 3は乳化が不安定で、冷却中に分離しやすかつた。また、長時間ホイ ップしても、保形性のあるものにはならず起泡しなかった。 [0033] In Comparative Example 3, the emulsification was unstable and it was easy to separate during cooling. Even when whipped for a long time, it did not foam and did not foam.
これにより油脂、無脂固形分からチョコレート様食品を製造する過程を経ずに、水中 油型乳化物を得る事が可能であり、また油脂としてはハードバターまたは SUSで表さ れるトリグリセラリドを含むのが望ましいという事があきらかになった。  This makes it possible to obtain an oil-in-water emulsion without going through the process of producing a chocolate-like food from fats and fats and fat-free solids, and the fats and oils contain triglycerides represented by hard butter or SUS. It became clear that it was desirable.
[0034] <実施例 7> <Example 7>
油分や水分、無脂固形分の異なる水中油型乳化物の本願発明における適正を見る  See appropriateness of oil-in-water emulsions with different oil content, water content and non-fat solid content in the present invention
30°Cに加温した水 24. 0部に全脂粉乳 11. 2部、砂糖 29. 3部を混合し、そこ に植物性油脂としてテンパータイプハードバター (製品名「メラノ NEWSS— 7」不二 製油株式会社製) 35. 5部を混合する。 24.0 parts of water heated to 30 ° C 11.2 parts of whole milk powder and 29.3 parts of sugar are mixed into this, and temper type hard butter (product name “Melano NEWSS-7” (Niisei Co., Ltd.) 3) Mix 5 parts.
[0035] 上記混合物を、加温しながらホモミキサー 3000rpmにて攪拌を行い、 65°C30分 保持後、冷却して油分 38. 4重量%、無脂固形分 37. 6重量% (無脂乳固形 8. 3% )、水分 24. 0重量%の水中油型乳化物を得た。このようにして得た水中油型乳化物 を、単独で縦型ミキサーを使用して起泡させ、作業性'品質の評価を行った。  [0035] The above mixture was stirred with a homomixer at 3000rpm while warming, held at 65 ° C for 30 minutes, and then cooled and oiled 38.4 wt%, nonfat solids 37.6 wt% (nonfat milk An oil-in-water emulsion having a solid content of 8.3% and a water content of 24.0% by weight was obtained. The oil-in-water emulsion thus obtained was foamed using a vertical mixer alone to evaluate workability 'quality.
[0036] <実施例 8 >  <Example 8>
表 3の配合に従い、 30°Cに加温した水 40. 0部に全脂粉乳 11. 0部、砂糖 19. 0部を混合し、そこに植物性油脂としてテンパータイプノヽードバター (製品名「メラノ N EWSS— 7」不二製油株式会社製) 30. 0部を混合する。  In accordance with the formulation in Table 3, 40.0 parts of water heated to 30 ° C was mixed with 11.0 parts of whole milk powder and 19.0 parts of sugar, and temper type node butter (product name `` Melano N EWSS—7 ”(Fuji Oil Co., Ltd.) 30. Mix 0 parts.
[0037] 上記混合物を、加温しながらホモミキサー 3000rpmにて攪拌を行い、 65°C30分 保持後、冷却して油分 32. 9重量%、無脂固形分 27. 1重量% (無脂乳固形 8. 1% )、水分 40. 0重量%の水中油型乳化物を得た。このようにして得た水中油型乳化物 を、単独で縦型ミキサーを使用して起泡させ、作業性'品質の評価を行った。 [0037] The above mixture was stirred with a homomixer at 3000rpm while warming, held at 65 ° C for 30 minutes, and then cooled to 32.9% oil content and 27.1% oil-free solid content (non-fat milk) An oil-in-water emulsion having a solid content of 8.1%) and a water content of 40.0% by weight was obtained. The oil-in-water emulsion thus obtained Was foamed using a vertical mixer alone, and the workability 'quality was evaluated.
[0038] <比較例 4 >  [0038] <Comparative Example 4>
表 3の配合に従い、 30°Cに加温した水 20. 0部に脱脂粉乳 30. 0部、砂糖 45. 0を混合し、そこに植物性油脂としてテンパータイプノヽードバター (製品名「メラノ NE WSS— 7」不二製油株式会社製) 5. 0部を混合する。  In accordance with the formulation in Table 3, 20.0 parts of water heated to 30 ° C was mixed with 30.0 parts of nonfat dry milk and 45.0 sugar, and temper type node butter (product name “Melano NE” as vegetable oil) was mixed there. WSS-7 ”(Fuji Oil Co., Ltd.) 5. Mix 0 parts.
上記混合物を、加温しながらホモミキサー 3000rpmにて攪拌を行い、 65°C30分保 持後、冷却して油分 5. 0重量%、無脂固形分 75. 0重量% (無脂乳固形 30. 0%)、 水分 20. 0重量%の水中油型乳化物を得た。このようにして得た水中油型乳化物を 、単独で縦型ミキサーを使用して起泡させ、作業性'品質の評価を行った。  The above mixture is stirred with a homomixer at 3000 rpm while warming, held at 65 ° C for 30 minutes, and then cooled to 5.0% by weight of oil and 75.0% by weight of non-fat solids (30% non-fat milk solids) 0%), and an oil-in-water emulsion having a water content of 20.0% by weight was obtained. The oil-in-water emulsion thus obtained was foamed using a vertical mixer alone to evaluate workability 'quality.
[0039] <比較例 5 > [0039] <Comparative Example 5>
表 3の配合に従い、 30°Cに加温した水 55. 0部に全脂粉乳 8. 3部、砂糖 14. 3 を混合し、そこに植物性油脂としてテンパータイプノヽードバター (製品名「メラノ NEW SS— 7」不二製油株式会社製) 22. 5部を混合する。  According to the formulation in Table 3, 55.0 parts of water heated to 30 ° C was mixed with 8.3 parts of whole milk powder and 14.3 sugar, and temper type node butter (product name “Melano” NEW SS-7 ”(Fuji Oil Co., Ltd.) 22. Mix 5 parts.
上記混合物を、加温しながらホモミキサー 3000rpmにて攪拌を行い、 65°C30分保 持後、冷却して油分 24. 6重量%、無脂固形分 20. 4重量% (無脂乳固形 6. 1%)、 水分 55. 0重量%の水中油型乳化物を得た。このようにして得た水中油型乳化物を 、単独で縦型ミキサーを使用して起泡させ、作業性'品質の評価を行った。  The above mixture is stirred with a homomixer at 3000 rpm while warming, held at 65 ° C for 30 minutes, and then cooled and oily 24.6% by weight, nonfat solids 20.4% by weight (fatless milk solids 6 1%), and an oil-in-water emulsion having a water content of 55.0% by weight was obtained. The oil-in-water emulsion thus obtained was foamed using a vertical mixer alone to evaluate workability 'quality.
評価は表 2に配合と共に示した。  The evaluation is shown in Table 2 together with the formulation.
[0040] [表 3] [0040] [Table 3]
実施例 7 実施例 8 比較例 4 比較例 5 チョコレ一ト様食品 Example 7 Example 8 Comparative example 4 Comparative example 5 Chocolate-like food
全脂粉乳 11.2 11.0 0.0 8.3 脱脂粉乳 0.0 0.0 30.0 0.0 砂糖 29.3 19.0 45.0 14.3 メラノ N EWS S- 7 35.5 30.0 5.0 22.5 水 24.0 40.0 20.0 55.0 油分 38.4 32.9 5.0 24.6 無脂固形分 37.6 27.1 75.0 20.4 水分 24.0 40.0 20.0 55.0 水中油型乳化物の評価  Whole milk powder 11.2 11.0 0.0 8.3 Nonfat dry milk 0.0 0.0 30.0 0.0 Sugar 29.3 19.0 45.0 14.3 Melano N EWS S- 7 35.5 30.0 5.0 22.5 Water 24.0 40.0 20.0 55.0 Oil 38.4 32.9 5.0 24.6 Nonfat solid 37.6 27.1 75.0 20.4 Moisture 24.0 40.0 20.0 55.0 Evaluation of oil-in-water emulsions
〇 〇 〇 X 水中油型乳化起泡物  ○ ○ ○ X Oil-in-water emulsified foam
水中油型乳化物 100.0 100.0 100.0 100.0 水 0 0 0 0 水中油型乳化起泡物の評価  Oil-in-water emulsion 100.0 100.0 100.0 100.0 Water 0 0 0 0 Evaluation of oil-in-water emulsion foam
△ 〇 X X  △ 〇 X X
[0041] その結果、実施例 8は非常に軽くてみずみずしい、口溶けの良い泡状の食品となり 、従来の起泡性クリームを起泡させた場合よりも食感、口溶けともに異なる新しい起泡 物であった。また、実施例 7は水中油型乳化起泡物単独ではやや固いものの、実施 可能であった。 [0041] As a result, Example 8 is a very light and fresh, foamy food with good meltability in the mouth, and is a new foamed product with a different texture and meltability than when foaming a conventional foaming cream. there were. In Example 7, the oil-in-water emulsified foam alone was somewhat hard, but could be implemented.
[0042] しかし、比較例 5は水中油型乳化物冷却時に分離しやすぐまた長時間ホイップし ても保形性のあるものにはならなかった。また比較例 4の水中油型乳化物は問題なく 作製出来たが、長時間ホイップしても、保形'性のあるものにはならず、ホイップしなか つた o  [0042] However, Comparative Example 5 was not separated when cooled with an oil-in-water emulsion, and even if whipped for a long time, it did not become shape-retaining. In addition, the oil-in-water emulsion of Comparative Example 4 could be produced without any problem, but even if whipped for a long time, it did not have a shape retaining property and was not whipped.
産業上の利用可能性  Industrial applicability
[0043] 以上説明したように本発明によって、乳化剤を配合しなくても良好な水中油型乳化 物を製造することが可能となり、本発明は添加剤の使用により好ましくない風味が付 カロされることを防止することができるという効果も有する。また、従来の乳化剤使用の 水中油型乳化物に、本発明品である乳化剤を配合していない水中油型乳化物を一 部添加して用いる使用法に際しても、添加先に元力 ある乳化剤を増やすことなく乳 味'コク味の付与や保形性といった特性を付与することが可能である。 [0043] As described above, according to the present invention, it is possible to produce a good oil-in-water emulsion without blending an emulsifier, and the present invention is undesirably flavored by the use of additives. This also has the effect of preventing this. In addition, when using a conventional oil-in-water emulsion that uses an emulsifier and adding a part of the oil-in-water emulsion that does not contain the emulsifier of the present invention, an emulsifier that has strength at the addition destination is used. Milk without increasing It is possible to impart characteristics such as imparting taste and richness and shape retention.

Claims

請求の範囲 The scope of the claims
[1] 起泡性を有するクリームで、実質的に乳化剤を配合してないことを特徴とする水中油 型乳化物。  [1] An oil-in-water emulsion characterized by being a foaming cream and containing substantially no emulsifier.
[2] 油分が 10〜50重量%、水分が 10〜50重量%、無脂固形分が 10〜70重量%であ ることを特徴とする請求項 1記載の水中油型乳化物。  [2] The oil-in-water emulsion according to claim 1, wherein the oil content is 10 to 50% by weight, the water content is 10 to 50% by weight, and the non-fat solid content is 10 to 70% by weight.
[3] 全無脂固形分に対する無脂乳固形分または無脂カカオ固形分の割合が 5〜50重量[3] The ratio of non-fat milk solids or non-fat cocoa solids to total non-fat solids is 5 to 50 wt.
%である請求項 1記載の水中油型乳化物。 The oil-in-water emulsion according to claim 1, which is%.
[4] 油分中の油脂がハードバターまたは SUS (S :飽和脂肪酸、 U:トランス体を含まない 不飽和脂肪酸)で表されるトリダリセラリドを含むことを特徴とする請求項 1記載の水中 油型乳化物。 [4] The oil-in-water emulsification according to claim 1, wherein the fat in the oil contains hard butter or tridallyceralide represented by SUS (S: saturated fatty acid, U: unsaturated fatty acid not containing trans form) object.
[5] 請求項 1記載の水中油型乳化物を単独で起泡させることを特徴とする起泡済水中油 型乳化物の製造法。  [5] A process for producing a foamed oil-in-water emulsion, wherein the oil-in-water emulsion according to claim 1 is foamed alone.
[6] 請求項 1記載の水中油型乳化物と水性組成物とを混合し、起泡させることを特徴とす る起泡済水中油型乳化物の製造法。  [6] A process for producing a foamed oil-in-water emulsion, wherein the oil-in-water emulsion according to claim 1 and an aqueous composition are mixed and foamed.
[7] 請求項 1記載の水中油型乳化物と水性組成物とを混合し、乳化剤を増すことなしに 起泡させることを特徴とする起泡済水中油型乳化物の製造法。 [7] A process for producing a foamed oil-in-water emulsion, wherein the oil-in-water emulsion according to claim 1 and an aqueous composition are mixed and foamed without increasing the emulsifier.
PCT/JP2005/012051 2004-06-30 2005-06-30 Oil-in-water emulsion and process for production of food with the same WO2006003981A1 (en)

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Publication number Priority date Publication date Assignee Title
WO2009034818A1 (en) * 2007-09-10 2009-03-19 Fuji Oil Company, Limited Foaming oil-in-water type emulsion
JP2009261332A (en) * 2008-04-25 2009-11-12 Fuji Oil Co Ltd Foaming oil-in-water emulsified product
US9468590B2 (en) 2009-12-10 2016-10-18 Neubourg Skin Care Gmbh & Co. Kg Emulsifier-free, polymer-stabilized foam formulations

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JPH10215783A (en) * 1996-12-05 1998-08-18 Fuji Oil Co Ltd Oil-in-water type emulsified matter
JP2002034451A (en) * 2000-07-26 2002-02-05 Kanegafuchi Chem Ind Co Ltd Foaming oil-in-water type composition
WO2004062384A1 (en) * 2003-01-16 2004-07-29 Fuji Oil Company, Limited O/w emulsion and process for producing food with the same

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JPH0928296A (en) * 1995-07-19 1997-02-04 Kao Corp Food product utilizing water-containing chocolate, its production and food additive utilizing chocolate
JP4390376B2 (en) * 1999-09-17 2009-12-24 株式会社Adeka Oil-in-water emulsified chocolate and composite food using the same

Patent Citations (3)

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Publication number Priority date Publication date Assignee Title
JPH10215783A (en) * 1996-12-05 1998-08-18 Fuji Oil Co Ltd Oil-in-water type emulsified matter
JP2002034451A (en) * 2000-07-26 2002-02-05 Kanegafuchi Chem Ind Co Ltd Foaming oil-in-water type composition
WO2004062384A1 (en) * 2003-01-16 2004-07-29 Fuji Oil Company, Limited O/w emulsion and process for producing food with the same

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009034818A1 (en) * 2007-09-10 2009-03-19 Fuji Oil Company, Limited Foaming oil-in-water type emulsion
JP2009261332A (en) * 2008-04-25 2009-11-12 Fuji Oil Co Ltd Foaming oil-in-water emulsified product
US9468590B2 (en) 2009-12-10 2016-10-18 Neubourg Skin Care Gmbh & Co. Kg Emulsifier-free, polymer-stabilized foam formulations

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