WO2014011838A1 - Lubricating oil - Google Patents

Lubricating oil Download PDF

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Publication number
WO2014011838A1
WO2014011838A1 PCT/US2013/050021 US2013050021W WO2014011838A1 WO 2014011838 A1 WO2014011838 A1 WO 2014011838A1 US 2013050021 W US2013050021 W US 2013050021W WO 2014011838 A1 WO2014011838 A1 WO 2014011838A1
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WO
WIPO (PCT)
Prior art keywords
lubricating oil
composition
oil composition
vol
petroleum naphtha
Prior art date
Application number
PCT/US2013/050021
Other languages
French (fr)
Inventor
D. Matthew Lacerenza
Original Assignee
Lacerenza D Matthew
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US13/546,021 external-priority patent/US20120277135A1/en
Application filed by Lacerenza D Matthew filed Critical Lacerenza D Matthew
Publication of WO2014011838A1 publication Critical patent/WO2014011838A1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M141/00—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
    • C10M141/04—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic halogen-containing compound
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/06—Well-defined aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/08—Aldehydes; Ketones
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
    • C10M2207/2815—Esters of (cyclo)aliphatic monocarboxylic acids used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/02—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen and halogen only
    • C10M2211/024—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen and halogen only aromatic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/04—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen, halogen, and oxygen
    • C10M2211/042—Alcohols; Ethers; Aldehydes; Ketones
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/10—Amides of carbonic or haloformic acids
    • C10M2215/102—Ureas; Semicarbazides; Allophanates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/16—Antiseptic; (micro) biocidal or bactericidal

Definitions

  • the present invention relates to a lubricating oil product which may be used for a wide variety of purposes.
  • lubricating oil compositions are known in the art.
  • the product sold under the trade name WD-40 is a well known lubricating oil.
  • U.S. Patent No. 2,758,088 to Barlett et al relates to a penetrating oil composition which comprises a mineral oil base stock containing a minor amount of a material having the formula RCH(XR') 2 where R and R' are alkyl radicals having from 4 to 18 carbon atoms and where X is selected from the class of oxygen and sulfur .
  • U.S. Patent No. 3,623,983 to Pattenden et al relates to a penetrating oil composition having from 50 to 85 weight percent of a refined mineral base oil, from about 10 to 25 wt% of a paraffinic distillate solvent oil, from about 4 to 25 wt% of a mixture of metal hydrocarbon sulfonate and aliphatic carboxylic acids of oxidized hydrocarbon wax, and about 0.5 to 25 wt% of a phosphate ester selected from the group consisting of a monoester, a diester, and mixtures thereof, of phosphoric acid with an alkoxylated long chain aliphatic alcohol wherein the aliphatic radical contains at least 12 carbon atoms per molecule and the alkoxylating is carried out using from 1 to 6 moles of a C 2 to C 3 alkylene oxide per mole of alcohol.
  • Walker relates to a penetrant and coating composition
  • the composition includes from about 2 to about 5 wt% of ashless acidic rust inhibitor, from about 25 to about 50 weight percent neutral alkaline earth metal sulfonate corrosion inhibitor component, from about 25 to about 50 weight percent phosphorous base corrosion inhibitor component, and a process oil component.
  • U.S. Patent Publication No. 2004/0102562 to Butuc relates to a composition of matter comprising at least one hydrocarbon base fluid mixed with at least one diblock copolymer, said copolymer being present in sufficient concentration for the composition to exhibit shear stresses that are a non-linear function of the fluid strain rate.
  • Still another lubricating oil composition is one which has been sold under the tradename LIQUIFIX.
  • a lubricating oil having a composition comprising an antibacterial composition, a corrosion preventive, petroleum naphtha, optionally a solvent, and the balance being an oil.
  • lubricating oil composition comprising an antibacterial composition, a corrosion preventive, petroleum naphtha, optionally a solvent, and the balance being an oil; and applying said lubricating oil composition to a surface of said object .
  • the lubricating oil composition of the present invention in one embodiment may consist of a dearomatized hydrocarbon distillate (petroleum) , a post lubricant petroleum
  • the dearomatized hydrocarbon distillate may be any suitable distillate known in the art, such as one sold under the tradename EXXSOL DUO manufactured by Exxon
  • EXXSOL DUO is a dearomatized hydrocarbon distillate (petroleum) which has been hydrotreated light and which has a flash point greater than 105°C (221°F) and an autoignition temperature of 243°C (469°F) .
  • EXXSOL DUO is a clear liquid which is colorless and which has a density at 15°C of 809 kg/m 3 ; a boiling point in the range of from 237 to 277°C; and a viscosity of 2.54cSt at 40°C.
  • the post lubricant petroleum hydrocarbon may be any suitable hydrocarbon known in the art, such as one sold under the tradename APO-55 by the D.A. Stuart Company.
  • APO-55 has a flashpoint of 270°F and a specific gravity of 0.900. It is a clear amber liquid product.
  • the inclusion of the post lubricant petroleum hydrocarbon is desirable because it enhances the corrosion control properties of the composition.
  • the white mineral oil may be any suitable mineral oil known in the art, such as one sold under the tradename
  • the aforementioned constituents of the lubricating oil composition may be mixed together using any suitable technique known in the art.
  • the dearomatized hydrocarbon distillate is present in an amount from 15 to 25%
  • the post lubricant petroleum hydrocarbon is present in an amount from 5 to 15%
  • the balance is the white mineral oil.
  • the dearomatized hydrocarbon is present in an amount from 19 to 21%
  • the post lubricant petroleum hydrocarbon is present in an amount from 9 to 11%
  • the balance is the white mineral oil.
  • lubricating oil compositions in accordance with those described above have a flash point greater than 220°F, and in a preferred embodiment about 275°F. Still further, the lubricating oil compositions in accordance with those described above have a relatively high dielectric breakdown voltage of 35 KV as measured by ASTM D 877.
  • the lubricating oil composition described herein is odorless, non- staining, and has no electrostatic charge which attracts dust. Further, it has a long lasting shelf life.
  • Boiling point (initial 450°F / 232°C
  • VOC Volatile Organic Compounds
  • the lubricating oil composition may comprise, or consist of, an antibacterial composition, a corrosion preventive, petroleum naphtha, optionally a solvent, and the balance being an oil.
  • the lubricating oil composition may have from 3.0 to 6.0 vol% of said antibacterial composition, from 6.0 to 12 vol% of said corrosion preventive, from 3.0 to 7.0 vol% of said petroleum naphtha, optionally from 6.0 to 15 vol% of said solvent, and the balance being said oil.
  • the oil may be present in an amount from 65 to 78 vol% .
  • the antibacterial composition may be selected from the group consisting of a polychloro phenoxy phenol such as a Triclosan antibacterial, a 3 , 4 , 4 ' -trichlorocarbonilide such as a Triclocarban antibacterial, a benzylkonium chloride which is a nitrogenous cationic surface acting agent belonging to a quaternary ammonium group, and a 4-chloro-3, 5 dimethylphenol composition such as chloroxylenol .
  • a polychloro phenoxy phenol such as a Triclosan antibacterial
  • a 3 , 4 , 4 ' -trichlorocarbonilide such as a Triclocarban antibacterial
  • a benzylkonium chloride which is a nitrogenous cationic surface acting agent belonging to a quaternary ammonium group
  • 4-chloro-3, 5 dimethylphenol composition such as chloroxylenol .
  • the hydrocarbon oil-based corrosion preventive may be selected from the group consisting of a hydrocarbon oil-based corrosion preventive such as Steelshield 6299 manufactured by D.A. Stuart Co. of Warrenville, IL or a hydrocarbon-based corrosion preventive such as Steelshield 6292 manufactured by said D.A. Stuart Co.
  • the Steelshield 6299 composition includes 60 to 100 wt% of petroleum distillates hydrotreated heavy naphthalene, 1.0 to 5.0 wt% odorless mineral spirits, and 1.0 to 5.0 wt% phenol 2, 6-Bis ( 1, 1-dimethylethyl ) - 4- methyl .
  • the Steelshield 6299 corrosion preventive has particular utility for marine applications.
  • the Steelshield 6292 corrosion preventive has utility for other steel
  • the petroleum naphtha may be selected from the group consisting of petroleum naphtha hydrotreated heavy and petroleum naphtha light alkylate.
  • the solvent may be an alkaline isoparaffinic hydrocarbon solvent such as Isopar C solvent manufactured by ExxonMobil.
  • the Isopar C solvent is a synthetic branched alkaline
  • the oil may be selected from the group consisting of methyl palmitate/oleate ester derived from coconut oil and a methyl ester derived from soybean oil.
  • lubricating an object may comprise the steps of: providing a lubricating oil composition comprising, or consisting of, an antibacterial composition, a corrosion preventive, petroleum naphtha, optionally a solvent, and the balance being an oil; and applying the lubricating oil composition to a surface of the object.
  • the providing step comprises mixing a lubricating oil composition comprising from 3.0 to 6.0 vol% of said antibacterial composition, from 6.0 to 12 vol% of said corrosion preventive, from 3. to 7.0 vol% of said petroleum naptha, optionally from 6.0 to 15 vol% of said solvent, and the balance said oil.
  • the process further comprises selecting said
  • antibacterial composition from the group consisting of a polychloro phenoxy phenol, a 3, 4, 4 ' -trichlorocarbonilide, benzylkonium chloride, and a 4-chloro-3, 5 dimethylphenol composition; selecting said petroleum naphtha from the group consisting of petroleum naphtha hydrotreated heavy and petroleum naphtha light alkylate; using an alkaline
  • isoparaffinic hydrocarbon solvent as said solvent; and selecting said oil from the group consisting of methyl palmitate/oleate ester derived from coconut oil and a methyl ester derived from soybean oil.
  • the process may further comprise providing said oil in an amount from 65 to 78 vol% .
  • the lubricating oil composition may also optionally include from 1.0 to 3.0 vol% acetone.
  • the acetone may be present when the solvent is present or when the solvent is not present .
  • the lubricating oil compositions described herein may be applied without having to use an aerosol. It may be applied using a pump spray, a squeeze bottle, etc. There is no need for pressure.
  • the lubricating oil compositions described herein may also be applied by an oil can and a brush.
  • the lubricating oil compositions described herein have many applications in such areas as auto & motor sports applications; boating applications; farming applications;
  • the composition can be used to provide a protective coat to snow chains;
  • a lubricating oil composition of the present invention has an oily film that provides lubrication.
  • WD-40® has an oily film that provides lubrication.
  • LIQUID WRENCH® has a dry powdery film with slight if any lubrication quality.
  • JIG-A-L00® has a film that is sticky and gummy.
  • the lubricating oil compositions of the present invention offer greater and longer lasting lubrication under extreme heat changes as well as room temperature. This helps in stability when being used during summer months, moving tool parts (hedge trimmers, etc.) . Before using and after using of tools, the lubricating oil compositions of the present invention would keep them
  • compositions of the present invention are not flammable, whereas the comparative test products which were tested are flammable .
  • lubricating oil composition of the present invention performed satisfactorily in these tests.
  • the lubricating oil composition of the present invention is safe to use, can be removed by washing with soap and water, and does not contain any cancer agents.

Abstract

A lubricating oil composition includes an antibacterial composition, a corrosion preventive, petroleum naphtha, optionally a solvent, and the balance being an oil. The lubricating oil composition may also include acetone. A process for lubricating an object includes the steps of: providing a lubricating oil composition comprising an antibacterial composition, a corrosion preventive, petroleum naphtha, optionally a solvent, optionally acetone, and the balance being an oil; and applying the lubricating oil composition to a surface of the object.

Description

LUBRICATING OIL
BACKGROUND
(1) Field of the Invention
The present invention relates to a lubricating oil product which may be used for a wide variety of purposes.
(2) Prior Art
Many different lubricating oil compositions are known in the art. For example, the product sold under the trade name WD-40 is a well known lubricating oil.
U.S. Patent No. 2,758,088 to Barlett et al . relates to a penetrating oil composition which comprises a mineral oil base stock containing a minor amount of a material having the formula RCH(XR')2 where R and R' are alkyl radicals having from 4 to 18 carbon atoms and where X is selected from the class of oxygen and sulfur .
U.S. Patent No. 3,623,983 to Pattenden et al . relates to a penetrating oil composition having from 50 to 85 weight percent of a refined mineral base oil, from about 10 to 25 wt% of a paraffinic distillate solvent oil, from about 4 to 25 wt% of a mixture of metal hydrocarbon sulfonate and aliphatic carboxylic acids of oxidized hydrocarbon wax, and about 0.5 to 25 wt% of a phosphate ester selected from the group consisting of a monoester, a diester, and mixtures thereof, of phosphoric acid with an alkoxylated long chain aliphatic alcohol wherein the aliphatic radical contains at least 12 carbon atoms per molecule and the alkoxylating is carried out using from 1 to 6 moles of a C2 to C3 alkylene oxide per mole of alcohol.
Published U.S. patent application no 2005/0272614 to
Walker relates to a penetrant and coating composition
concentrate for metals having improved corrosion inhibiting properties. The composition includes from about 2 to about 5 wt% of ashless acidic rust inhibitor, from about 25 to about 50 weight percent neutral alkaline earth metal sulfonate corrosion inhibitor component, from about 25 to about 50 weight percent phosphorous base corrosion inhibitor component, and a process oil component.
U.S. Patent Publication No. 2004/0102562 to Butuc relates to a composition of matter comprising at least one hydrocarbon base fluid mixed with at least one diblock copolymer, said copolymer being present in sufficient concentration for the composition to exhibit shear stresses that are a non-linear function of the fluid strain rate.
Still other lubricating oil compositions are shown in U.S. Patent No. 6,610,634 to Tiffany III, U.S. Patent No.
5,958,850 to Matsuzaki et al . ; U.S. Patent No. 5,888,948 to Meny; U.S. Patent No. 5,534,173 to Faber; and U.S. Patent No. 5,362,411 to Bergstra.
Still another lubricating oil composition is one which has been sold under the tradename LIQUIFIX.
SUMMARY OF THE INVENTION
In accordance with the instant disclosure, there is disclosed a lubricating oil having a composition comprising an antibacterial composition, a corrosion preventive, petroleum naphtha, optionally a solvent, and the balance being an oil.
Still further, in accordance with the instant disclosure, there is provided a process for lubricating an object, said process broadly comprising the steps of: providing a
lubricating oil composition comprising an antibacterial composition, a corrosion preventive, petroleum naphtha, optionally a solvent, and the balance being an oil; and applying said lubricating oil composition to a surface of said object .
Other details of the lubricating oil of the present invention, as well as other objects and advantages attendant thereto are set forth in the following detailed description. DETAILED DESCRIPTION OF THE PREFFERED EMBODIMENT ( S ) The lubricating oil composition of the present invention in one embodiment may consist of a dearomatized hydrocarbon distillate (petroleum) , a post lubricant petroleum
hydrocarbon, and white mineral oil.
The dearomatized hydrocarbon distillate (petroleum) may be any suitable distillate known in the art, such as one sold under the tradename EXXSOL DUO manufactured by Exxon
Mobil/Hubbard-Hall Inc. EXXSOL DUO is a dearomatized hydrocarbon distillate (petroleum) which has been hydrotreated light and which has a flash point greater than 105°C (221°F) and an autoignition temperature of 243°C (469°F) . EXXSOL DUO is a clear liquid which is colorless and which has a density at 15°C of 809 kg/m3; a boiling point in the range of from 237 to 277°C; and a viscosity of 2.54cSt at 40°C.
The post lubricant petroleum hydrocarbon may be any suitable hydrocarbon known in the art, such as one sold under the tradename APO-55 by the D.A. Stuart Company. APO-55 has a flashpoint of 270°F and a specific gravity of 0.900. It is a clear amber liquid product. The inclusion of the post lubricant petroleum hydrocarbon is desirable because it enhances the corrosion control properties of the composition.
The white mineral oil may be any suitable mineral oil known in the art, such as one sold under the tradename
DRAKEOIL 350 by Calumet/Penreco .
The aforementioned constituents of the lubricating oil composition may be mixed together using any suitable technique known in the art.
In one exemplary embodiment of the lubricating oil composition of the present invention, the dearomatized hydrocarbon distillate is present in an amount from 15 to 25%, the post lubricant petroleum hydrocarbon is present in an amount from 5 to 15%, and the balance is the white mineral oil. In another exemplary embodiment, the dearomatized hydrocarbon is present in an amount from 19 to 21%, the post lubricant petroleum hydrocarbon is present in an amount from 9 to 11%, and the balance is the white mineral oil.
It has been found that lubricating oil compositions in accordance with those described above have a flash point greater than 220°F, and in a preferred embodiment about 275°F. Still further, the lubricating oil compositions in accordance with those described above have a relatively high dielectric breakdown voltage of 35 KV as measured by ASTM D 877. The lubricating oil composition described herein is odorless, non- staining, and has no electrostatic charge which attracts dust. Further, it has a long lasting shelf life.
Still further the lubricating oil compositions described hereinabove has the following physical data:
Specific gravity @ 25°C 0.8605
Refractive Index 1.4598
Boiling point (initial 450°F / 232°C
Volatile, % by volume 24.23
Evaporation Rate (n-butyl
acetate = 1) 1.1
Vapor Pressure (mm Hg @ 20°C) 1.0
Vapor Density less than 1.0
Solids, % by weight 90.63
Viscosity, cSt 150
VOC (Volatile Organic Compounds) g/L 77
Solubility in water Negligible
In another embodiment, the lubricating oil composition may comprise, or consist of, an antibacterial composition, a corrosion preventive, petroleum naphtha, optionally a solvent, and the balance being an oil. The lubricating oil composition may have from 3.0 to 6.0 vol% of said antibacterial composition, from 6.0 to 12 vol% of said corrosion preventive, from 3.0 to 7.0 vol% of said petroleum naphtha, optionally from 6.0 to 15 vol% of said solvent, and the balance being said oil. In an exemplary embodiment, the oil may be present in an amount from 65 to 78 vol% .
The antibacterial composition may be selected from the group consisting of a polychloro phenoxy phenol such as a Triclosan antibacterial, a 3 , 4 , 4 ' -trichlorocarbonilide such as a Triclocarban antibacterial, a benzylkonium chloride which is a nitrogenous cationic surface acting agent belonging to a quaternary ammonium group, and a 4-chloro-3, 5 dimethylphenol composition such as chloroxylenol .
The hydrocarbon oil-based corrosion preventive may be selected from the group consisting of a hydrocarbon oil-based corrosion preventive such as Steelshield 6299 manufactured by D.A. Stuart Co. of Warrenville, IL or a hydrocarbon-based corrosion preventive such as Steelshield 6292 manufactured by said D.A. Stuart Co. The Steelshield 6299 composition includes 60 to 100 wt% of petroleum distillates hydrotreated heavy naphthalene, 1.0 to 5.0 wt% odorless mineral spirits, and 1.0 to 5.0 wt% phenol 2, 6-Bis ( 1, 1-dimethylethyl ) - 4- methyl . The Steelshield 6299 corrosion preventive has particular utility for marine applications. The Steelshield 6292 corrosion preventive has utility for other steel
applications .
The petroleum naphtha may be selected from the group consisting of petroleum naphtha hydrotreated heavy and petroleum naphtha light alkylate.
The solvent may be an alkaline isoparaffinic hydrocarbon solvent such as Isopar C solvent manufactured by ExxonMobil. The Isopar C solvent is a synthetic branched alkaline
( isoparaffinic ) hydrocarbon solvent. The oil may be selected from the group consisting of methyl palmitate/oleate ester derived from coconut oil and a methyl ester derived from soybean oil.
In accordance with the foregoing, a process for
lubricating an object may comprise the steps of: providing a lubricating oil composition comprising, or consisting of, an antibacterial composition, a corrosion preventive, petroleum naphtha, optionally a solvent, and the balance being an oil; and applying the lubricating oil composition to a surface of the object. The providing step comprises mixing a lubricating oil composition comprising from 3.0 to 6.0 vol% of said antibacterial composition, from 6.0 to 12 vol% of said corrosion preventive, from 3. to 7.0 vol% of said petroleum naptha, optionally from 6.0 to 15 vol% of said solvent, and the balance said oil.
The process further comprises selecting said
antibacterial composition from the group consisting of a polychloro phenoxy phenol, a 3, 4, 4 ' -trichlorocarbonilide, benzylkonium chloride, and a 4-chloro-3, 5 dimethylphenol composition; selecting said petroleum naphtha from the group consisting of petroleum naphtha hydrotreated heavy and petroleum naphtha light alkylate; using an alkaline
isoparaffinic hydrocarbon solvent as said solvent; and selecting said oil from the group consisting of methyl palmitate/oleate ester derived from coconut oil and a methyl ester derived from soybean oil. The process may further comprise providing said oil in an amount from 65 to 78 vol% .
The lubricating oil composition may also optionally include from 1.0 to 3.0 vol% acetone. The acetone may be present when the solvent is present or when the solvent is not present .
The lubricating oil compositions described herein may be applied without having to use an aerosol. It may be applied using a pump spray, a squeeze bottle, etc. There is no need for pressure. The lubricating oil compositions described herein may also be applied by an oil can and a brush.
The lubricating oil compositions described herein have many applications in such areas as auto & motor sports applications; boating applications; farming applications;
garage/workshop applications; hobby and crafts applications; and home & garden applications. For example, the composition can be used to provide a protective coat to snow chains;
prevent rust on and lubricate snowblower chutes; winterize the undercarriage of cars to help prevent salt damage; prevent snowmobile runners from corrosion and rust damage; keep door handles from freezing; provides a protective coating on metal objects to prevent rust from forming; lubricates and
penetrates stuck objects; displaces moisture from car wiring; eases removal of stuck spark plugs from an engine; restores vintage door locks; cleans and protects brake mechanisms;
protects electrical connections in engines; prevents oxidation on battery connections; lubricates trunk latches; lubricates cover top zippers, removes barnacles from boat hulls; loosens lug nuts; loosens frozen parts; lubricates boat masts;
lubricates tractor throttle cables; helps dissolve rust;
shines steel; protects hammers from rust and corrosion; cleans and lubricates tools, saws, and blades; lubricates garage door tracks; keeps model trains rust-free; cleans metal figurines; lubricates molds; coats snow shovels; cleans gardening tools and implements; cleans old coins; and cleans and lubricates moving parts .
A test was conducted to provide comparative reactions under the same conditions. Three stages of heat and air contact to provide percent solids, evaporation and dry film texture (of the solid residue) . The products tested were a lubricating oil described herein (Product A) , WD-40®
lubricant, LIQUID WRENCH® lubricant, and JIG-A-LOO® lubricant. The following was found: Percent Solids on Evaporation, Active Lubricity
Temp./Hrs Product A WD-40 LIQUID WRENCH JIG-A-LOO 70°F / 2 99.7 88.0 0 7.1
85°F / 2 99.4 77.3 6.1
100°F/ 2 98.9 53.8 5.2
The above results show that increased temperature provides less active lubrication for three of the tested products. Though Product A (the lubricating oil of the present invention) and WD-40® have long lasting lubricity, Product A has far greater lubrication for longer periods under varying temperatures.
Residual Lubricity (solids) By Drying Air
Time Product A WD-40® LIQUID WRENCH® JIG-A-LOO®
168 Hrs. 95.7 34.5 3.9 0.59
The above results show that the product of the present invention has more retention qualities regarding lubricity than the other products . Film Texture: A lubricating oil composition of the present invention has an oily film that provides lubrication. WD-40® has an oily film that provides lubrication. LIQUID WRENCH® has a dry powdery film with slight if any lubrication quality. JIG-A-L00® has a film that is sticky and gummy.
As can be seen from the foregoing, the lubricating oil compositions of the present invention offer greater and longer lasting lubrication under extreme heat changes as well as room temperature. This helps in stability when being used during summer months, moving tool parts (hedge trimmers, etc.) . Before using and after using of tools, the lubricating oil compositions of the present invention would keep them
lubricated until the next use. The lubricating oil
compositions of the present invention are not flammable, whereas the comparative test products which were tested are flammable .
An ASTM D-4172 Four Ball Wear Test was performed using a lubricating oil composition of the present invention. The result was 0.76mm. An ASTM D-3825 surface tension test was performed using a lubricating oil composition of the present invention. The result was 30.33 dynes/cm. An ASTM D-3233-B falex pin and V Block test was performed using the lubricating oil composition of the present invention. The result of this test was as follows :
Load Starting Torque Final Torque
300 lbs @ 5 min. 6 lbs/in. 8 lbs/in.
500 lbs @ 1 min. 15 lbs/in. 16 lbs/in.
750 lbs @ 1 min. 20 lbs/in. 19 lbs/in.
*1000 lbs @ 1 min 35 lbs/in. * comment
*Final torque spiked to 70 lbs/in. and load progressively dropped within 20 seconds. As can be seen from the foregoing results, the
lubricating oil composition of the present invention performed satisfactorily in these tests.
The lubricating oil composition of the present invention is safe to use, can be removed by washing with soap and water, and does not contain any cancer agents.
It is apparent that there has been provided a lubricating oil composition which has many uses . While the lubricating oil composition has been described in the context of specific embodiments thereof, other alternatives, modifications and variations may become apparent to those skilled in the art having read the foregoing description. Accordingly, it is intended to embrace those unforeseen alternatives,
modifications, and variations as fall within the broad scope of the appended claims .

Claims

WHAT IS CLAIMED IS:
1. A lubricating oil composition comprising an antibacterial composition, a corrosion preventive, petroleum naphtha, optionally a solvent, and the balance being an oil.
2. The lubricating oil composition according to claim 1, wherein said antibacterial composition is present in an amount from 3.0 - 6.0 vol% .
3. The lubricating oil composition according to claim 1, wherein said antibacterial composition is selected from the group consisting of a polychloro phenoxy phenol, a 3,4,4'- trichlorocarbonilide, benzylkonium chloride, and a 4-chloro-3, 5 dimethylphenol composition.
4. The lubricating oil composition according to claim 1, wherein said antibacterial composition is a polychloro phenoxy phenol .
5. The lubricating oil composition according to claim 1, wherein said antibacterial composition is a 3,4,4'- trichlorocarbonilide .
6. The lubricating oil composition according to claim 1, wherein said antibacterial composition is benzylkonium chloride .
7. The lubricating oil composition according to claim 1, wherein said antibacterial composition is a 4-chloro-3, 5 dimethylphenol composition.
8. The lubricating oil composition according to claim 1, wherein said hydrocarbon oil-based corrosion preventive is present in an amount from 6.0 to 12 vol%.
9. The lubricating oil composition according to claim 1, wherein said petroleum naphtha is present in an amount from 3.0 to 7.0 vol%.
10. The lubricating oil composition according to claim 1, wherein said petroleum naphtha is selected from the group consisting of petroleum naphtha hydrotreated heavy and petroleum naphtha light alkylate.
11. The lubricating oil composition according to claim 1, wherein said petroleum naptha is petroleum naptha hydrotreated heavy .
12. The lubricating oil composition according to claim 1, wherein said petroleum naphtha is petroleum naphtha light alkylate .
13. The lubricating oil composition of claim 1, wherein said solvent is present in an amount from 6.0 to 15 vol% .
14. The lubricating oil composition of claim 1, wherein said solvent is an alkaline isoparaffinic hydrocarbon solvent.
15. The lubricating oil composition of claim 1, wherein said oil is present in an amount from 65 to 78 vol%.
16. The lubricating oil composition of claim 1, wherein said oil is selected from the group consisting of methyl
palmitate/oleate ester derived from coconut oil and a methyl ester derived from soybean oil.
17. The lubricating oil composition of claim 1, wherein said oil is methyl palmitate/oleate ester derived from coconut oil.
18. The lubricating oil composition of claim 1, wherein said
011 is methyl ester derived from soybean oil.
19. The lubricating oil composition of claim 1, optionally containing from 1.0 to 3.0 vol% acetone.
20. A lubricating oil composition consisting of an
antibacterial composition, a corrosion preventive, petroleum naphtha, optionally a solvent, optionally acetone, and the balance being an oil.
21. A process for lubricating an object, said process comprising the steps of:
providing a lubricating oil composition comprising an antibacterial composition, a corrosion preventive, petroleum naphtha, optionally a solvent, and the balance being an oil; and
applying said lubricating oil composition to a surface of said object.
22. The process of claim 21, wherein said providing step comprises mixing a lubricating oil composition comprising from 3.0 to 6.0 vol% of said antibacterial composition, from 6.0 to
12 vol% of said corrosion preventive, from 3. to 7.0 vol% of said petroleum naptha, optionally from 6.0 to 15 vol% of said solvent, and the balance said oil
23. The process of claim 22, further comprising selecting said antibacterial composition from the group consisting of a polychloro phenoxy phenol, a 3, 4, 4 ' -trichlorocarbonilide, benzylkonium chloride, and a 4-chloro-3, 5 dimethylphenol composition .
24. The process of claim 22, further comprising selecting said petroleum naphtha from the group consisting of petroleum naphtha hydrotreated heavy and petroleum naphtha light alkylate .
25. The process of claim 22, further comprising using an alkaline isoparaffinic hydrocarbon solvent as said solvent.
26. The process of claim 22, further comprising selecting said oil from the group consisting of methyl palmitate/oleate ester derived from coconut oil and a methyl ester derived from soybean oil .
27. The process of claim 22, further comprising providing said oil in an amount from 65 to 78 vol%.
28. The process of claim 21, wherein said providing step further comprising adding from 1.0 to 3.0 vol% acetone to said lubricating oil composition.
PCT/US2013/050021 2012-07-11 2013-07-11 Lubricating oil WO2014011838A1 (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106118824A (en) * 2016-06-29 2016-11-16 无锡伊佩克科技有限公司 A kind of preparation method of solvent cutback soft film anti-rust oil

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4073411A (en) * 1976-06-03 1978-02-14 Blue Cross Laboratories, Inc. Freeze-thaw stable emulsion cookware lubricant
US5174916A (en) * 1987-03-02 1992-12-29 Gordon Osgood Lubricant additive composition containing nonionic fluorochemical polymer and method of using same
US20030125224A1 (en) * 1999-06-23 2003-07-03 Seitz Earl P. Compositions having enhanced deposition of a topically active compound on a surface
US20030143135A1 (en) * 2002-01-31 2003-07-31 O'rear Dennis J. Upgrading fischer-tropsch and petroleum-derived naphthas and distillates
US20040202614A1 (en) * 2003-03-07 2004-10-14 Roger Davis Utensil spray composition and portable aerosol device and method therefor
US20080031831A1 (en) * 2005-10-21 2008-02-07 Technology & Marketing Consulting Oral anti-calculus compositions and methods of use thereof
US20080171680A1 (en) * 2007-01-12 2008-07-17 Kwang Soon Kim Composition of water-soluble metalworking fluid using distillation residue generated in production of biodiesel
WO2012006404A2 (en) * 2010-07-07 2012-01-12 Greensolve, Llc Solvent systems and methods of producing high flash point solvent systems including terpenes

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4073411A (en) * 1976-06-03 1978-02-14 Blue Cross Laboratories, Inc. Freeze-thaw stable emulsion cookware lubricant
US5174916A (en) * 1987-03-02 1992-12-29 Gordon Osgood Lubricant additive composition containing nonionic fluorochemical polymer and method of using same
US20030125224A1 (en) * 1999-06-23 2003-07-03 Seitz Earl P. Compositions having enhanced deposition of a topically active compound on a surface
US20030143135A1 (en) * 2002-01-31 2003-07-31 O'rear Dennis J. Upgrading fischer-tropsch and petroleum-derived naphthas and distillates
US20040202614A1 (en) * 2003-03-07 2004-10-14 Roger Davis Utensil spray composition and portable aerosol device and method therefor
US20080031831A1 (en) * 2005-10-21 2008-02-07 Technology & Marketing Consulting Oral anti-calculus compositions and methods of use thereof
US20080171680A1 (en) * 2007-01-12 2008-07-17 Kwang Soon Kim Composition of water-soluble metalworking fluid using distillation residue generated in production of biodiesel
WO2012006404A2 (en) * 2010-07-07 2012-01-12 Greensolve, Llc Solvent systems and methods of producing high flash point solvent systems including terpenes

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106118824A (en) * 2016-06-29 2016-11-16 无锡伊佩克科技有限公司 A kind of preparation method of solvent cutback soft film anti-rust oil

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