WO2015047260A1 - Cationic and nonionic surfactant cleansing composition - Google Patents

Cationic and nonionic surfactant cleansing composition Download PDF

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Publication number
WO2015047260A1
WO2015047260A1 PCT/US2013/061801 US2013061801W WO2015047260A1 WO 2015047260 A1 WO2015047260 A1 WO 2015047260A1 US 2013061801 W US2013061801 W US 2013061801W WO 2015047260 A1 WO2015047260 A1 WO 2015047260A1
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WIPO (PCT)
Prior art keywords
composition
cleansing composition
weight
thickener
cleansing
Prior art date
Application number
PCT/US2013/061801
Other languages
French (fr)
Inventor
Eugene Hardy
Marian Holerca
Rabab Ahmed
Evangelia Arvanitidou
Original Assignee
Colgate-Palmolive Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Colgate-Palmolive Company filed Critical Colgate-Palmolive Company
Priority to PCT/US2013/061801 priority Critical patent/WO2015047260A1/en
Priority to CA2922539A priority patent/CA2922539C/en
Priority to CA3080782A priority patent/CA3080782A1/en
Publication of WO2015047260A1 publication Critical patent/WO2015047260A1/en
Priority to US14/690,320 priority patent/US9265714B2/en
Priority to US15/049,089 priority patent/US10179100B2/en
Priority to US16/032,503 priority patent/US10383808B2/en
Priority to US16/448,183 priority patent/US10772817B2/en
Priority to US16/993,330 priority patent/US11052031B2/en
Priority to US17/348,411 priority patent/US20210308029A1/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/835Mixtures of non-ionic with cationic compounds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41Amines
    • A61K8/416Quaternary ammonium compounds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73Polysaccharides
    • A61K8/731Cellulose; Quaternized cellulose derivatives
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86Polyethers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61PSPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P31/00Antiinfectives, i.e. antibiotics, antiseptics, chemotherapeutics
    • A61P31/02Local antiseptics
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/005Antimicrobial preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/10Washing or bathing preparations
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/22Carbohydrates or derivatives thereof
    • C11D3/221Mono, di- or trisaccharides or derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/52Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/62Quaternary ammonium compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/662Carbohydrates or derivatives
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/75Amino oxides

Definitions

  • ⁇ OQOiJ Cationic surfactants can provide antibacterial properties to a cleansing composition.
  • cationic surfactants are mixed with nonionic surfactants, there is generally a need to use thickeners to increase the viscosity to a level that is expected by consumers for a cleansing composition, such as a liquid hand soap or body wash.
  • thickeners can increase the viscosity, they can make the cleansing composition opaque or translucent. It would be desirable to provide a cleansing composition containing cationic and nonionic surfactants that is transparent.
  • An aqueous cleansing composition comprising a cationic surfactant, a nonionic surfactant, and a thickener comprising an alkoxylated methyl glucose ether, wherein a weight ratio of cationic surfactant to nonionic surfactant is greater than 0.9:1.
  • cationic surfactant does not include a cationic antibacterial agent selected from t e group consisting of benzalkoninm chloride, benzethonium chloride, and mixtures thereof. While these materials may function as a cationic surfactant, they are not included in the calculation.
  • ⁇ D00 J Transparency is defined as the abilit to read 12 ⁇ point font through the composition contained in a 4 z clear, glass sample bottle of 4cm thickness. Transparency is measured after 24 hours at 4.5°C.
  • jOOI f Viscosity is measured using a Brookfteld RVT viscometer with spindle # 5 at 25 rpra at 2S°C.
  • the composition includes a cationic surfactant.
  • the cationic surfactant can be any cationic surfactant, but it excludes the cationic bacterial agent for weight ratio calculation, in certain embodiments, the cationic surfactant comprises a quaternary ammonium alky I salt.
  • the quaternary ammonium alkyl salt can be an alkyltrimethylammonium salts.
  • the salt can be a halide, such as chloride or bromide, or a methosulfate.
  • the alkyl can be a C8-C24 alkyl or a C14-C18 alkyl.
  • the cationic surfactant is cetyltriraethylamraoniura chloride.
  • the cationic surfactant is present in an amount of 0.1 to 20 weight % of the composition. In other embodiments, the amount is 0.1 to 10, 0J to 5, 0.5 to 10,
  • the composition includes a nonionic surfactant.
  • the nonionic surfactants can be any nonionic surfactant.
  • Nonionic surfactants include, but are not limited to. amine oxides, fatty acid amides, ethoxylated fatty alcohols, block copoly mers of polyethylene glycol and polypropylene glycol, glycerol alkyl esters, alkyl polyglucosides, polyoxyethylerte glycol octylphenol ethers, sorbitan alkyl esters, polyoxyethylene glycol sorbitan alkyl esters, and mixtures thereof
  • amine oxides include, but are not limited to, laurylamidopropyl dimethylamine oxide, myrisrylamidopropyl dimethySaraine oxide, and mixtures thereof.
  • fatty acid amides include, but are not limited to, cocomonoethanolamide ⁇ !auramide monoethanolarnide, cocodiethanolamide, and mixtures thereof.
  • the nomomc surfactant is a combination of an amine oxide and a fatty add amide.
  • the amine oxide is a mixture of laurylamidopropyl dimethylamine oxide and myristyiamido ropyl dimethylamine oxide.
  • the nonionic surfactant is a combination of lauryl'myristylamidopropyl dimethylamine oxide and cocomonoeihanolarnide.
  • the non.ion.ic surfactant is present in an amount of 0.1 to 20 weight % of the composition, in other embodiments, the amount is 0.1 to 10, 0.1 to 5, 0.5 to 10, 0.5 to 5, or 0.5 to 3 weight %.
  • the composition has a cationic.nonionic weight ratio greater than 0.9; 1.
  • the ratio is at least 1: 1 ,
  • the composition does not contain an anionic surfactant.
  • the composition also includes a thickener comprising an alkoxylated methyl glucose ether.
  • the aikoxylation can be ethoxylated and/or propoxylated. In certain embodiments, it is ethoxylated.
  • the degree of aikoxylation can be any degree that provides thickening, in certain embodiments, the degree of aikoxylation is 100 to 200. In certain embodiments, the aikoxylation is 120 to 150.
  • the alkoxylated methyl glucose ether can be esierified with fatty acid, in certain embodiments, the alkoxylated methyl glucose ether at least one of an alkoxylated.
  • the alkoxylated methyl glueos.de is at least one of PEG-120 methyl glucose dioleate, PEG-120 methyl glucose trioleate, PEG-120 methyl glucose distearate.
  • the alkoxylated methyl glucose ether is PEG-120 methyl, glucose dioleate.
  • the thickener can be present in any amount to provide any desired viscosity level.
  • the thickener is present in an amount of 0.1 to 2 weight % of the composition.
  • the amount is 0.1 to 1 , 0,2 to I . 0.3 to 1, 0.4 to 1, 0.1 to 0.9, 0.1 to 0.8, 0.1 to 0.7, 0.3 to 0.8, or 0.4 to 0.8 weight %.
  • the amount is 0.4 to 0.7 weight .
  • the viscosity is at least 1000 mPas. In other embodiments, the viscosity is at least 2000, at least 3000, or at least 4000 mPas. In certain embodiments, the viscosity is 1 00 to 20000, 3000 to 6000, or 3500 to 5000 rnPas.
  • the composition does not include a polyacryiate thickener.
  • the composition, ca include a cationic antibacterial agent selected from the group consisting of benzalkonium chloride, benzethomum chloride, and mixtures thereof.
  • the composition includes ben aikonhim chloride.
  • These cationic antibacterial agents can be included in their regulatory amount, which can be 0.13 weight %.
  • composition is aqueous, in certain embodiments, water can be included in an amount of 70 to 95 weight % of the composition, In other embodiments, the amount of water is 90 to 95 weight %.
  • the composition can flutlier include salt, such as sodium chloride to assist in increasing viscosity at upper ranges of viscosity, in certain embodiments, the salt is present at 0.1 to 1.2 weight % of the composition, in certain embodiments, the amount is about 0.6 weight%.
  • salt such as sodium chloride to assist in increasing viscosity at upper ranges of viscosity
  • the salt is present at 0.1 to 1.2 weight % of the composition, in certain embodiments, the amount is about 0.6 weight%.
  • he cleansing compositions can be used to cleanse skin by washing skin with the cleansing composition and optionally rinsing with water.
  • the examples and comparativ examples are made by mixing of the materials.
  • the compositions are shown in Tables 1 and 2 below.
  • the examples list the cationicnonionic surfactant ratio. Hie viscosity and the transparency after storage at 4.5°C are measured.
  • the combination of the PEG-120 methyl glucose dioleate and the cationicrnonionic surfactant ratio provides a composition that is clear after cold storage and has a desired viscosity over 4000 naPas.
  • PEG-120 methyl glucose dioleate is present in all compositions, a desired viscosity is obtained, bat when the cationicrnonionic surfactant ratio is less tha 0.9 in the comparative examples, the composition is hazy after cold storage.

Abstract

An aqueous cleansing composition comprising a cationic surfactant, a nonionic surfactant, and a thickener comprising an alkoxylated methyl glucose ether, wherein a weight ratio of cationic surfactant to nonionic surfactant is greater than 0.9:1. The combination of the cationionic:nonionic surfactant ratio with the alkoxylated methyl glucose ether thickener provides the composition with cold weather stability. Cold weather stability is observed when the composition remains transparent after cold storage.

Description

CATIONIC AND ON IONIC SURFACTANT CLEANSING COMPOSmON
BACKGROUND
{OQOiJ Cationic surfactants can provide antibacterial properties to a cleansing composition. When cationic surfactants are mixed with nonionic surfactants, there is generally a need to use thickeners to increase the viscosity to a level that is expected by consumers for a cleansing composition, such as a liquid hand soap or body wash. While polyacrylate thickeners can increase the viscosity, they can make the cleansing composition opaque or translucent. It would be desirable to provide a cleansing composition containing cationic and nonionic surfactants that is transparent.
BRIEF SUMMARY
[000 1 An aqueous cleansing composition, comprising a cationic surfactant, a nonionic surfactant, and a thickener comprising an alkoxylated methyl glucose ether, wherein a weight ratio of cationic surfactant to nonionic surfactant is greater than 0.9:1.
|0003J The combination, of the catiotvionic:nonionic surfactant ratio with the alkoxylated methyl glucose ether thickener provides the composition with cold weather stability. Cold weather stability is observed when the composition remains transparent after cold storage.
{"0004] Further areas of applicability of the present invention will become apparent from the detailed description provided hereinafter, it should be understood that the detailed description and specific examples, while indicating the preferred embodiment of the invention, are intended for purposes of illustration only and are not in tended to limit the scope of the invention.
DETAILED DESCRIPTION
{00051 T e following description of the preferred embodiments) is merely exemplary' in nature and is in no way intended to limit the invention, its application, or uses.
[0006] As used throughout, ranges are used as shorthand for describing each and every value that, is within the range. Any valise withi the range can be selected as the terminus of the range. In addition, all references cited herein are hereby incorporated by referenced in their entireties. In the event of a conflict in a definition in the present disclosure and that of a cited reference, the present disclosure controls. |ftO 7| Unless otherwise specified, all percentages and amounts expressed herein and elsewhere in the specification should be understood to refer to percentages by weight. The amounts given are based on the active weight of the material.
|OO08| For the purpose of calculating a cationic surfactant to nonionic surfactant ratio, cationic surfactant does not include a cationic antibacterial agent selected from t e group consisting of benzalkoninm chloride, benzethonium chloride, and mixtures thereof. While these materials may function as a cationic surfactant, they are not included in the calculation.
{D00 J Transparency is defined as the abilit to read 12~point font through the composition contained in a 4 z clear, glass sample bottle of 4cm thickness. Transparency is measured after 24 hours at 4.5°C.
jOOI f Viscosity is measured using a Brookfteld RVT viscometer with spindle # 5 at 25 rpra at 2S°C.
OOllJ The composition includes a cationic surfactant. The cationic surfactant can be any cationic surfactant, but it excludes the cationic bacterial agent for weight ratio calculation, in certain embodiments, the cationic surfactant comprises a quaternary ammonium alky I salt. The quaternary ammonium alkyl salt can be an alkyltrimethylammonium salts. The salt can be a halide, such as chloride or bromide, or a methosulfate. The alkyl can be a C8-C24 alkyl or a C14-C18 alkyl. In certain embodiments, the cationic surfactant is cetyltriraethylamraoniura chloride.
{0012} In certain embodiments, the cationic surfactant is present in an amount of 0.1 to 20 weight % of the composition. In other embodiments, the amount is 0.1 to 10, 0J to 5, 0.5 to 10,
0,5 to 5, 1 to 5, or 2 to 4 weight %,
[0013} The composition includes a nonionic surfactant. The nonionic surfactants can be any nonionic surfactant. Nonionic surfactants include, but are not limited to. amine oxides, fatty acid amides, ethoxylated fatty alcohols, block copoly mers of polyethylene glycol and polypropylene glycol, glycerol alkyl esters, alkyl polyglucosides, polyoxyethylerte glycol octylphenol ethers, sorbitan alkyl esters, polyoxyethylene glycol sorbitan alkyl esters, and mixtures thereof Examples of amine oxides include, but are not limited to, laurylamidopropyl dimethylamine oxide, myrisrylamidopropyl dimethySaraine oxide, and mixtures thereof. Examples of fatty acid amides include, but are not limited to, cocomonoethanolamide } !auramide monoethanolarnide, cocodiethanolamide, and mixtures thereof. {0014) In certain embodiments, the nomomc surfactant is a combination of an amine oxide and a fatty add amide. In certain embodiments, the amine oxide is a mixture of laurylamidopropyl dimethylamine oxide and myristyiamido ropyl dimethylamine oxide. In certain embodiments, the nonionic surfactant is a combination of lauryl'myristylamidopropyl dimethylamine oxide and cocomonoeihanolarnide.
[00151 in certain embodiments, the non.ion.ic surfactant is present in an amount of 0.1 to 20 weight % of the composition, in other embodiments, the amount is 0.1 to 10, 0.1 to 5, 0.5 to 10, 0.5 to 5, or 0.5 to 3 weight %.
[0016] The composition has a cationic.nonionic weight ratio greater than 0.9; 1. Optionally, the ratio is at least 1: 1 ,
|0O17| In certain embodiments, the composition does not contain an anionic surfactant.
[0018j The composition also includes a thickener comprising an alkoxylated methyl glucose ether. The aikoxylation can be ethoxylated and/or propoxylated. In certain embodiments, it is ethoxylated. The degree of aikoxylation can be any degree that provides thickening, in certain embodiments, the degree of aikoxylation is 100 to 200. In certain embodiments, the aikoxylation is 120 to 150. The alkoxylated methyl glucose ether can be esierified with fatty acid, in certain embodiments, the alkoxylated methyl glucose ether at least one of an alkoxylated. methyl glucose dioleate, an alkoxylated methyl glucose trioleate, alkoxylated methyl glucose distearate. In certain embodiments, the alkoxylated methyl glueos.de is at least one of PEG-120 methyl glucose dioleate, PEG-120 methyl glucose trioleate, PEG-120 methyl glucose distearate. In certain embodiments, the alkoxylated methyl glucose ether is PEG-120 methyl, glucose dioleate.
[0019] The thickener can be present in any amount to provide any desired viscosity level. In certain embodiments, the thickener is present in an amount of 0.1 to 2 weight % of the composition. In other embodiments, the amount is 0.1 to 1 , 0,2 to I . 0.3 to 1, 0.4 to 1, 0.1 to 0.9, 0.1 to 0.8, 0.1 to 0.7, 0.3 to 0.8, or 0.4 to 0.8 weight %. In one embodiment, the amount is 0.4 to 0.7 weight . In certain embodiments, the viscosity is at least 1000 mPas. In other embodiments, the viscosity is at least 2000, at least 3000, or at least 4000 mPas. In certain embodiments, the viscosity is 1 00 to 20000, 3000 to 6000, or 3500 to 5000 rnPas.
[O020| In certain embodiments, the composition does not include a polyacryiate thickener.
[0021] The composition, ca include a cationic antibacterial agent selected from the group consisting of benzalkonium chloride, benzethomum chloride, and mixtures thereof. In certain embodiments, the composition includes ben aikonhim chloride. These cationic antibacterial agents can be included in their regulatory amount, which can be 0.13 weight %.
|0022| The composition is aqueous, in certain embodiments, water can be included in an amount of 70 to 95 weight % of the composition, In other embodiments, the amount of water is 90 to 95 weight %.
[0023 j In certain embodiments, the composition can flutlier include salt, such as sodium chloride to assist in increasing viscosity at upper ranges of viscosity, in certain embodiments, the salt is present at 0.1 to 1.2 weight % of the composition, in certain embodiments, the amount is about 0.6 weight%.
[00241 T he cleansing compositions can be used to cleanse skin by washing skin with the cleansing composition and optionally rinsing with water.
EXAMPLES
[0025] The examples and comparativ examples are made by mixing of the materials. The compositions are shown in Tables 1 and 2 below. The examples list the cationicnonionic surfactant ratio. Hie viscosity and the transparency after storage at 4.5°C are measured.
Table 1
Figure imgf000005_0001
Cable 2
Figure imgf000006_0001
Viscosity ( Pas) 4600 4000 4340 4470
|0026| As cm be seen in the examples, the combination of the PEG-120 methyl glucose dioleate and the cationicrnonionic surfactant ratio provides a composition that is clear after cold storage and has a desired viscosity over 4000 naPas. When PEG-120 methyl glucose dioleate is present in all compositions, a desired viscosity is obtained, bat when the cationicrnonionic surfactant ratio is less tha 0.9 in the comparative examples, the composition is hazy after cold storage.

Claims

C LAIM S WHAT IS CLAIMED IS:
1. AH aqueous cleansing composition composing a cationic surfactant, a nonionic surfactant, and a thickener comprising art alkoxyiated methyl glucose ether, wherein a weight ratio of cationic surfactant, to nonionic surfactant is greater than 0,9:1.
2. The cleansing composition of claim I further comprising a cationic antibacterial agent selected from the group consisting of benzalkonium chloride, beiizeihoniivrn chloride, and mixtures thereof.
3. The cleansing composition of claim 2, wherein the cationic antibacterial agent is benzaikoniom chloride,
4. The cleansing composition of any preceding claim, wherein the weight ratio of cationic surfactant to nonionic surfactant is at least 1:0.
5. The cleansing composition of any preceding claim, wherein, the thickener is an alkoxylaied methyl glucose ether esterified with fatty acid.
6. The cleansing composition of any preceding claim, wherein the thickener is at least one of an alkoxyiated meihyl glucose dioieate, an alkoxyiated methyl glucose trioleate, and alkoxyiated methyl glucose distearate.
7. The cleansing composition of any preceding clai m, wherein the thickener is ethoxylated,
8. The cleansing composition of any preceding claim, wherein the thickener has a degree of ethoxylation of 100 to 200.
9. The cleaning composition of any preceding claim, wherein the thickener is selected from the group consisting of PEG- 120 methyl glucose dioieate, PEG- 150 distearate, and mixtures thereof.
10. The c l e ansi ng composition o f any preceding claim, w herei the thi ckener is PEG - 120 methv! glucose dioieate.
1 1. The cleansing composition of any preceding claim, wherein the cationic surfactant comprises a quaternary ammonium aikyl salt.
12. The cleansing composition of any preceding claim, wherein the cationic surfactant comprises cetyi irimethyl amm nium chloride.
13. The cleansing composition of any preceding claim, wherein the nonionic surfactant comprises at least one surfactant chosen from an amine oxide and fatty acid amide.
14. The cleansing composition of any preceding claim, wherein the nonionic surfactant comprises laiHryl myrisiyl amdioprop l dimeifoylamlne oxide and cocomonoethanolarmde.
15. The cleansing composition of any preceding claim, wherein the thickener is present in an amount of 0.1 to 2 weight % of the composition, optionally 0.1 to 1 weight %.
16. The cleansing composition of any preceding claim, wherein the cationic surfactant is present in an amount of 0. i to 20 weight % of the composition, optionally 0.5 to 5 weight
17. The cleansing composition of any preceding claim, wherein the nonionic surfactant is present in an amount of 0.1. to 20 weight % of the composition, optionally 0.5 to 5 weight
I S, The cleansing composition of any preceding claim, wherein an amount of water is 70 to 95 weight % of the composition.
1.9. The cleaning compositio of any preceding claim farther comprising a salt, optionally in an amount of 0.1 to 1.2 weight % of the composition.
20, The cleansing composition of any preceding claim, wherein the composition does not contain a polyaerylate.
21 , The cleansing composition of any preceding claim, wherein the composition is transparent after 24 hours at 4.5°C. 2, A method of cleansing skin comprising washing skin with, the cleansing composition of any preceding claim, and optionally rinsing with water.
PCT/US2013/061801 2013-09-26 2013-09-26 Cationic and nonionic surfactant cleansing composition WO2015047260A1 (en)

Priority Applications (9)

Application Number Priority Date Filing Date Title
PCT/US2013/061801 WO2015047260A1 (en) 2013-09-26 2013-09-26 Cationic and nonionic surfactant cleansing composition
CA2922539A CA2922539C (en) 2013-09-26 2013-09-26 Clear cleansing compositions comprising an alkoxylated methyl glucose ether thickener, a cationic surfactant, and a non-ionic surfactant
CA3080782A CA3080782A1 (en) 2013-09-26 2013-09-26 Clear cleansing compositions comprising an peg-120 methyl glucose dioleate thickener, sodium chloride, a cationic surfactant, and a non-ionic surfactant
US14/690,320 US9265714B2 (en) 2013-09-26 2015-04-17 Cleansing composition comprising a cationic and nonionic surfactant mixture
US15/049,089 US10179100B2 (en) 2013-09-26 2016-02-21 Transparent aqueous cleansing composition comprising a nonionic and cationic surfactant mixture
US16/032,503 US10383808B2 (en) 2013-09-26 2018-07-11 Thickened cationic and nonionic surfactant cleansing composition
US16/448,183 US10772817B2 (en) 2013-09-26 2019-06-21 Cleansing composition comprising a nonionic/cationic surfactant mixture
US16/993,330 US11052031B2 (en) 2013-09-26 2020-08-14 Cleansing composition comprising a nonionic / cationic surfactant mixture
US17/348,411 US20210308029A1 (en) 2013-09-26 2021-06-15 Cleansing composition comprising a nonionic and cationic surfactant mixture

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20160115978A (en) * 2014-02-04 2016-10-06 바스프 에스이 Aqueous surfactant compositions
WO2017116462A1 (en) * 2015-12-31 2017-07-06 Colgate-Palmolive Company Personal care compositions
EP3878920A4 (en) * 2018-11-09 2022-07-27 Kao Corporation Rheology modifier

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